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By Oliveira JF

Thiourea is an alternative reagent for cyanide in gold leaching. The recovery of gold from acidic thiourea solutions by adsorption on activated carbon is based on methods similar to those applied for the extracting of gold from cyanide solutions, but the mechanism involved in the process is not completely understood. In the present work, studies were carried out to evaluate the adsorption of gold onto activated carbon. Experimental data showed good agreement with both the Freundlich and Langmuir isotherms. The adsorption of gold from acidic thiourea solutions proved to be an endothermic process, while the adsorption from cyanide is known to be exothermic. The isosteric heat of adsorption of -11.3 kcal/mol in the early stages of the adsorption is an indication of a process involving chemisorption. The effect of temperature was studied between 15¦C and 55¦C. An activation energy of 3.5 kcal/mol was determined by the Arrhenius plot, which indicates that the controlling step in the kinetics of adsorption is the diffusion onto the porous structure of the activated carbon.

Jan 1, 1993

By A H. Hofstra, G P. Landis, P Emsbo, A G. Hunt

Models of the evolution of the hydrothermal systems that form porphyry Cu (Mo-Au) deposits are compromised because aqueous magma-derived fluids in the ore zones of most deposits have changed from their original magmatic compositions as a result of cooling, depressurising, mineral precipitation, brine-vapour unmixing and fluid-rock reactions. However, in deep quartz-rich, sulfide-poor veins from numerous porphyry type deposits, we have identified parental fluids trapped in inclusions at near magmatic temperatures and pressures above the brine-vapour unmixing solvus. We have analysed these inclusions for bulk salinity, density, solute chemistry, helium isotopic ratios and elemental composition. These parental inclusions contain 35 - 70 volume per cent bubble, are low to moderate salinity, contain up to ten mol per cent CO2, and commonly contain a chalcopyrite daughter crystal. Our results indicate that these Cu-rich fluids transport Cu from a plutonic complex below upward into a hydrothermal system, where decompression, cooling, unmixing and water-rock reaction drive ore-mineral precipitation. Na/Cl ratios greater than one indicate that in addition to chlorine, sulfur and/or carbonate must play a key role in Cu transportation. Helium isotope ratios indicate that between ~15 and 100 per cent of helium in these fluids is mantle-derived. We suggest that in addition to He, volatiles from mafic magmas in the mantle are also likely to supply CO2, Cu and S to the fluids that form porphyry copper deposits. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By C Mroczek, B Mitchell

Perilya Broken Hill, from its inception, has budgeted for more than 2.0 million tonnes per year from the Southern Operations. This tonnage was planned to come from in excess of 100 stopes per year in a remnant mining environment with numerous mined voids and consequent mining challenges. To mine an average of two stopes per week requires patience, flexibility and detailed knowledge to best manage the potential risks and hazards. The evolution of the Perilya Broken Hill Mine Planning Process has necessitated the establishment of a process to identify and manage these risks during the planning stage in a reliable but efficient manner. This process is to ensure that vital steps for each stope are not missed, and that each personÆs work can be tracked by other members of the team. This paper outlines the planning process from resource to stope closure.

Jan 1, 2005

By Muir D. M

Highly saline process water has a number of implications for the CIP process during the leaching, adsorption and recovery of gold. The reduced oxygen solubility in saline water can seriously reduce the rate of gold leaching, while dissolved oxygen meters do not necessarily reveal actual oxygen concentrations in saline water. High levels of magnesium in the ground water necessitate operation at lower pH (-9), with the potential for greater cyanide loss via HCN stripping. In addition increasing salinity renders viscosity modifiers largely ineffective.The adsorption capacity of aurocyanide onto activated carbon is improved with increasing salinity, but misleading results can be obtained in assessment of gold loading kinetics of plant carbon samples already loaded, or partially loaded, in saline water if subsequently tested in fresh water. Elevated chloride levels in the Zadra elution process can cause severe anode corrosion in the elecuowinning cell. The Anglo elution process is tolerant to only slight increases in water salinity, but elution times can be reduced by ethanol addition. Care is required in carbon regeneration, as salts can catalyse carbon decomposition as well as increase kiln corrosion.

Jan 1, 1994

By Borshoff J, Von Pechmann E

The uranium mineralization in the White's East area of The Embayment is hosted by Lower Proterozoic schists of the Masson Formation which have undergone polyphase de- formation and upper greenschist metamorphism. Significant mineralization is also present in apatite rocks. The ore zones occur near an unconformity with overlying Middle Proterozoic sandstone and breccia conglomerate. Kink breccias and fracture systems related to post Middle Proterozoic reverse faults are the con- trols for mineralizing fluid migration. Pitchblende is the main uranium mineral and it occurs as fine disseminated grains, fibrous webs, clusters composed of botryoidal aggregates and locally as veins. Two genera- tions of uranium mineralization are present. The first generation (pitchblende I) occurs as fine grained inclusions within chlorite II, and the second (pitchblende II) as hydraulic fracture networks and massive veins intimately associated with sericite-hematite-chlorite III. Two hydrothermal alteration phases have affected both Lower Proterozoic and Middle Proterozoic sequences. The most extensive alteration mineral is chlorite, of which a number of varieties has been identified. Mg-rich chlorites are generally associated with the first phase alteration assemblages and are commonly replaced by hematite, seri- cite and Mg-Fe chlorites in massive pitch- blende zones. Other alteration minerals in- clude tourmaline, apatite, talc, quartz, magnesite, graphite, pyrite and rutile.

Jan 1, 1984

By J Manuel, R Muddle

The demand for iron ore has increased significantly in recent years, with new iron ore sources being mined to meet this demand. As the composition of sinter blends changes with the availability and cost of iron ore, so too does interest in the impact of new ore types on granulation and ultimately productivity. This paper describes a study into granulating characteristics of seven iron ore types, including various hematite and goethite ores. The effect of ore type on feed moisture requirements, green bed permeability, green bed strength and granule size distribution was examined for single ore blends containing coke, flux and returns. The ore size distribution was varied in these blends and its effect on granulating characteristics examined. It was found that the optimum moisture requirement of the ore was more dependent on ore type than ore size distribution, but ore size distribution (and specifically intermediate particle loading) had a greater effect on green bed permeability. The saturation moisture value for an ore was found useful in predicting both optimum granulation moisture and green bed permeability.

Jan 1, 2005

By Muir D

A review of the various methods of degrad- ing cyanide either from gold processing liquors or electroplating baths is presented with some discussion on their relative merits or problems. Whilst alkaline chlorination is common practice in many U.S. and Canadian plants it poses particular problems for certain plants. Alter- native methods include electrolysis, hydrolysis and air oxidation with activated carbon as catalyst which are also integral steps in the carbon-in-pulp process. A basic study of the degradation of cyanide ion has been carried out therefore to determine the effect of temperature, oxygen and carbon. It is shown that carbon is an excellent catalyst for degradation by air and likely to lead to higher losses of cyanide in a C.I.L. circuit. Degradation by hydrolysis is important at high temperatures and high pH such as employed in the Pressure Zadra or Anglo elution processes. Carbon catalysed degradation of cyanide by oxygen in effluent streams may be an environmentally acceptable alternative to conventional chlorine degradation.

Jan 1, 1987

According to the temporal and spatial distribution of regional metallogenesis, the Pacific Rim can be divided into four global metallogenetic systems. The Asia-Australia W-Sn metallogenetic belt is the typical representative of intracontinen- tal metallogenetic systems. This belt resulted from Mesozoic and partly pre-Mesozoic tectonic magmatism, mainly re- lated to S-type granite of crustal source, that was generated by collisional orogeny combined with oceanic subduction in intracontinental and continental margin settings. Based on the concept of metallogenetic series, there is a group of min- eralised ore types showing a definite spatial and temporal distribution from endogenetic to exogenetic. These metalloge- netic series are widely distributed in the Asia-Australia W-Sn metallogenetic belt, and are well developed in Southeast China. Five metallogenetic series and two petro-minerogenesis evolution models have been established according to their tectonic settings, various types of granitoids and metallogenetic evolution.

Jan 1, 1995

By M A. Gontalves, A F. D C Varajpo

The Rio Capim kaolin district, located in the north-east of Parß State, Brazil, constitutes one of the worldÆs largest high-whiteness kaolin reserves for the paper coating industry. It contains, at the base of the main ore, a soft kaolin that gradually changes at the top into a ferruginous duricrust followed by a flint kaolin. The flint kaolin is completely discarded during the exploitation of the soft kaolin. With the view of a more complete beneficiation, aiming at a sustainable development of the minerals industry, the use of this residual flint kaolin has been considered for the manufacturing of zeolites. Zeolites were synthesised from the flint kaolin through a reaction between metakaolinite with soda at 80¦C, for durations of 24 to 144 hours. The transformation into metakaolinite was carried out at 800¦C and was not affected by the titanium oxides. For a synthesis time of only 24 hours, a zeolite 4A very close to its theoretical definition was obtained, whereas for synthesis times longer than 96 hours, a slight formation of hydro-sodalite was also observed. The synthesised zeolites were tested as cationic adsorbents on 0.5 molar solutions of Cu, Pb, Cd and Zn. The adsorption was measured for contact durations of one and three days. It was noted that the exchange kinetics were slow and that the retention was significantly greater after three days than after one day. The retention was greater than 50 per cent of the theoretical exchange capacity for Pb, Cd and Zn, which was different to Cu, where the retention exceeded its theoretical exchange capacity.

Jan 1, 2008

The Comstock Lode, a world-class precious metal vein district near Virginia City in western Nevada, U.S.A. (Fig. 1), produced 8.3 million ounces (0.28 X 106 kg) of gold and 193 million ounces (6.56 X 106 kg) of silver during the period 1859 to present (Bonham and Papke, 1969). More than 95% of production was from the Comstock fault, while the adjacent Silver City, Occidental and Flowery vein systems produced about $10 million (U.S.). Within the Comstock fault high-grade ore bodies, or bonanzas, were distributed over 2.3 miles (3.8 km) along strike and persisted to >3000 feet (>900 m) below the surface (Fig. 2). Bonanzas consisted of as much as 1.4 million tons (1.3 million tonnes) of ore grading up to 1.9 oz./ton (65 gm/ton) Au and 30 oz./ton (1020 gm/ton) Ag (Table 1). Some bonanzas occurred in the main Comstock fault plane while others, including the highest grade bonanzas, formed in hangingwall frac- tures. After 1880 most ore consisted of lower-grade vein material surrounding mined- out bonanzas and large volumes of mineralized vein and wall rock in the Comstock hanging- wall that were mined from open cuts. Deep mining was hindered by large quantities of hot water and bad ground which ultimately defined the limits of underground production. The widths and richness of Comstock bonanzas strongly influenced U.S. mining law, milling and underground mining methods, and securi- ties regulations that are in practice today. Within the district Mesozoic metasedimentary rocks, metavolcanic rocks, and granitic in- trusions are overlain by Miocene volcanic rocks (Thompson and White, 1964). Veins cut all lithologies. Miocene volcanic rocks and their K-Ar ages (Vikre, McKee and Silberman, 1987) include Santiago Canyon rhyolite (22

Jan 1, 1987

Detailed mapping in the Permian-Triassic clastic sediments of the Southern Alps delineates a number of strike-slip faults, both dextral and sinistral, associated with the major Alpine Fault to the west and displacing a tight array of fault blocks. Concurrent steeply plunging folds are deforming early major folds of probable Cretaceous age, and generating schist locally. To the east a major collapse zone has developed along the crest of a Cretaceous anticline, located over an ancient Permian submarine scarp, with a number of small normal faults. Further east, extensive Carboniferous to Triassic rocks of much the same appearance are exposed as horsts and grabens in a large possible extension zone through central and east Canterbury. This may have crept incrementally from Cretaceous from the offshore Bounty Trough to reach the eastern margins of the Southern Alps in the Pleistocene.

Jan 1, 1990

By Skinner J, Brackenbury K

The AuPlus" Systems have been applied in the gold mining industry to achieve improved gold recoveries, faster leach kinetics and reduced cyanide consumptions. Calcium or hydrogen peroxide, collectively known as peroxygens, can be used. The choice depending on plant design and the nature of the ore. Laboratory test work and plant trials are included in this paper to illustrate the benefits of peroxygen usage in extractive gold metal- lurgy.

Jan 1, 1991

By Gottlieb P, Sutherland DN

The paper describes a method of making quantitative mineralogical measurements on many of the major lead/zinc orebodies in Australia. The work was done using QEM*SEM. It was found that a relationship betwen phase-specific surface area and particle size, when plotted in a suitable way, gave a straight line with slope related to the grain size of the mineral in question. The method provides an excellent way of differen- tiating between minerals in existing orebodies and, consequently, an easy way to establish a comparison between a new prospect or orezone and current operations.

Jan 1, 1988

This paper reviews the use of MTU diesel engines in uses such as Off-Highway Vehicles, Rail traction, Generating Sets, Marine Propulsion and Defence Applications, and focuses on a central theme of maximum power in the minimum of space.

Jan 1, 1986

The paper will review the fundamental policy issues and options that have been considered in the determination of the proposed allocation and pricing (ie royalty) regime for minerals under the Crown Minerals Act 1991. It will consider such influences on the new disposal, allocation, pricing and management arrangements for the Crown's mineral estate as the existence of prior ownership claims, exclusivity in access, the requirement for cost recovery and the treatment of contingent liabilities.

Jan 1, 1993

By Maru Y

The use of mercury for amalgamation has been an integral part of the small-scale gold mining industry in developing countries owing to its low investment cost, simplicity of the technique and high gold recovery. However, its impact on health and environmental hazards have not been given the attention they deserve. In spite of the growing awareness and concerns over the mercury pollution problem by regul-atory authorities, precautionary measures such as bans on the use of mercury in some countries have been largely ineffective.This paper first reviews some of the mechanisms of mercury poll-ution, and mercury toxicity which varies according to its oxidation state. It then describes how mercury released to the atmosphere would go through the "Mercury Cycle". Compar-isons have also been made with previously measured mercury levels in small scale Papua New Guinean miners with their counterparts in other developing countries.

Jan 1, 1994

The latent conditions clause in various general conditions of contract have traditionally proved to be a source of significant disputes in tunnelling contracts, even when extensive geotechnical investigations have been carried out at the tunnel site and a report of these investigations provided with the tender documents, informing the contractor of the nature and extent of subsurface conditions likely to be met with during execution of the works. This paper discusses the contractual aspects of the new latent conditions clause in the recent Australian Standard AS 2124-1986, General Conditions of Contract, in relation to tunnelling contracts. A comparison of this new clause is made with other latent conditions clauses in general conditions of contract in use in Australia and other commonwealth countries. It is seen that the new latent conditions clause in the recent Australian Standard 2124-1986 has, by providing for a reasonable apportionment of risks, attempted to minimize contractual disputes relating to latent conditions in tunnelling contracts and to provide a satisfactory basis for quick and efficient settlement of such disputes should they arise during execution of these contracts.

Jan 1, 1987

By J E. Eberhardt

Ore sorting has long been used to raise the efficiency and thus lower the environmental impact of mineral processing operations. It was first instituted as hand sorting, according to a humanly perceived difference in the ore, but is now automated using large mechanical sorters in order to meet the high tonnage throughput required in most minerals processing applications. In the past, ore sorting was generally used as a niche processing route when other approaches failed, and in this context, consequential environmental benefits are often not the first consideration in adopting sorting. When applicable, ore sorting offers environmental benefits in reductions in fines waste, reagent usage and energy consumption in milling. Although there are significant opportunities for the use of ore sorting technology in many minerals processing operations, industry applications, to date, have been limited mainly to the processing of diamonds, magnesite, talc and uranium ores. This limitation has principally been due to a lack of suitable sensing technologies for a wide range of ore types. The authors report on a wide-ranging review of the automated sorting of mineral ores, and in particular, on methods for discrimination of ore characteristics prior to mechanical sorting.

Jan 1, 2002

An Ore Reserve Estimate aims to foreqast the impact of the complex mixture of factors which constitute a mining and milling operation. The factors are pulled together in the Mine Plan which then constrains the reserve estimate. At the Zinc Mine at Broken Hill the complexity of the ore lodes highlights some of the factors which affect the ore grade estimates and at Elura the different metallurgical characteristics of the ore types influences their economic viability.

Jan 1, 1990

Direct smelting of copper in a single vessel has long been the extractive metallurgist's dream. Such a process offers the important alvantage. of (i) maximum use of the energy available from oxidizing the sulphur and iron of the concentrate: (ii) restriction of SO2 emissions to a single constant-strength source; (iii) minimum materials handling and (iv) elim-ination of at least one process step. Extensive developmental work was carried out in the 1960's and 1970's to implement such single-step processes. Some of the processes reached the prototype stage and it appeared that copper smelting technology was on the thresthold of a new, efficient, minimum-pollution era. Since that time, however, the forward thrust has slowed and single-step copper smelting is still a process of the future.The paper describes the potential advan-tages of single-step smelting; its history and current status; and the reasons why it has not been adopted industrially. It concludes that the potential benefits of single-step smelting are powerful and that many of the difficulties encountered in the 1970's will be overcome in the 1980's.

Jan 1, 1985