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By N. Katsikaros, A. Lewis-Gray, P. Richards

"To optimize gold recovery in complex leach-to-electrowinning processes, Gekko Systems developed the Gekko resin exchange column (G-REX) as an intermediate step, using a highly gold-selective resin to isolate contaminant metals. The AuRIX®100 resin produced by Purolite is licensed exclusively to Gekko, with the G-REX column designed specifically for this resin. Operational experience has been gained at the Castlemaine Goldfields Ballarat gold mine. In near-continuous operation since 2008, the Ballarat plant treats unclarified concentrate leach solution. The extension of this technology to higher throughputs and more complex chemistry is discussed.RÉSUMÉ Afin d’optimiser la récupération de l’or dans des procédés complexes impliquant la lixiviation suivie de l’extraction électrolytique, Gekko Systems a développé la colonne Gekko de résines échangeuses d’ions (G-REX) comme étape intermédiaire, à l’aide d’une résine hautement sélective pour la récupération de l’or qui permet d’isoler les métaux contaminants. Gekko détient la licence exclusive pour la résine AuRIX®100 produite par Purolite, et la colonne G-REX a été spécifiquement conçue pour cette résine. C’est à la mine d’or Ballarat de Castlemaine Goldfields que l’expérience opérationnelle a été acquise. L’usine de Ballarat, en exploitation quasi-continue depuis 2008, traite une solution concentrée non clarifiée de lixiviation. L’extension de cette technologie à des capacités supérieures et à une chimie plus complexe est examinée.AURIX®100 RESINAuRIX100 resin is a crosslinked polystyrene alkaline resin developed by Henkel (Virnig, Mackenzie, & Adamson, 1996). The resin beads are off-white in colour and spherical, with a nominal size of 100% +600 µm. This resin is highly selective for gold and silver over many metals, by way of extracting precious metal–cyanide complexes from leach solutions with a pH of less than 11.5. The higher end of the pH scale produces the best selectivity according to the order of preference: Au > Ag > Hg > Zn > Ni > Cu > Co > Fe. Purolite produces the resin and Gekko Systems maintains licensing of AuRIX100 resin for use in its G-REX column, as part of its unique suite of gravity gold–handling equipment.Significant cost savings over carbon-in-solution (CIS) systems are realized with AURIX100 resin: approximately 4–12% in capital savings and 27–40% in operating costs (Virnig, Mackenzie, Katsikaros, & Gray, 2004). Additionally, AuRIX100 resin is not susceptible to fouling; that is, the resin does not load with inorganic salts or organic compounds that would affect the loading and extraction of precious metals. To counter any potential for fouling by inorganic salts, a dilute acid wash is periodically conducted in service on the resin to unblock resin pores."

Jan 1, 2017

By V. E. Dawson

Brake testing of large mining trucks was initiated in British. Columbia in 1969 following an accident involving the failure of the service brakes of a l00-ton electric-drive truck. Some selected results of the 1976 brake test program are presented and discussed ?in this paper . The tests were conducted on end- dump trucks having load capacities ranging from 85 to 235 tons. All tests were made with the vehicles fully loaded operating on downhill grades varying from 8 to 10 %. Stopping distances were measured from initial speeds varying between 10 and 39 mph. The results are adequate, in most cases, to determine the "ultimate" capabilities of the service brakes of varying models and sizes of haulage trucks operating in British Columbia mines.

Jan 1, 1977

By K. S. Fraser, H. J. H. Pieterse

"A pressure oxidation plant to pretreat refractory sulphide ore at the Goldstrike plant in Nevada, was commissioned in early February 1990. The plant, with a nominal capacity of 1363 t/d, was commissioned over a one-week period and achieved design capacity and availability within ten weeks an unusually short period for a plant of this complexity.The pressure oxidation process is conducted under elevated temperature and pressure conditions, and in a corrosive environment. These conditions demand that the process and engineering design of the plant be carried out in a much more sophisticated and detailed manner than is normally required in a conventional gold plant.This paper provides an account of the process and engineering design of the Goldstrike pressure oxidation plant with special emphasis on the design of the vessels, slurry pumps, piping, valves, and control systems.BackgroundLocationThe Goldstrike property is located in Eureka County in northcentral Nevada on the Carlin geological trend. The mine is approximately 40 km northwest of the town of Carlin which is situated on Interstate Highway 80. The minesite is located 1700 m above sea level in the Tuscarora Mountains.Initial Goldstrike OperationsShallow, low-grade mineralization was discovered by diamond drilling in the Goldstrike area in the 1960s. A heap leach operation was established in the mid-I970s by the previous owners. The Post deposit was discovered in 1982. Gold production by mining and heap leaching reached I t/a (40 000 oz/a). American Barrick purchased the property in 1987 and started an aggressive program of deep drilling. This led to the discovery of the Betze and Deep Post deposits and established sufficient reserves to justify an initial 4100 t/d mill and a 5 500 000 t/a heap leach operation"

Jan 1, 1992

By N. Musee, N. Kornelius

This study presents a neural network approach to modelling the liberation of gold bearing ores. A complete mineralogical analysis of unmilled and milled ores, including gold deportment and gangue content are used as inputs to a self-organising neural net which generates order preserving topological maps. The arrangement and shapes of these clusters are coupled to unmilled free gold data to predict gold liberation in milled ores (absolute error: 4.2%). Moreover, the self-organising maps were diagnostic of the quality of data used, indicating that the relationship between particle size and gangue material content requires further investigation.

Jan 1, 2005

By Nn Li

Energy consumption in commercial buildings has been increasing rapidly in the past decade. The knowledge of future energy consumption can bring significant value to commercial building energy management. For example, prediction of energy consumption decomposition helps analyze the energy consumption patterns and efficiencies as well as waste, and identify the prime targets for energy conservation. Moreover, prediction of temporal energy consumption enables building managers to plan out the energy usage over time, shift energy usage to off-peak periods, and make more effective energy purchase plans. This paper proposes a novel model for predicting heating, ventilation and air conditioning (HVAC) energy consumption in commercial buildings. The model simulates energy behaviors of HVAC systems in commercial buildings, and interacts with a multiagent systems (MAS) based framework for energy consumption prediction. Prediction is done on a daily, weekly and monthly basis. Ground truth energy consumption data is collected from a test bed office building over 267 consecutive days, and is compared to predicted energy consumption for the same period. Results show that the prediction can match 92.6 to 98.2% of total HVAC energy consumption with coefficient of variation of the root mean square error (CV-RMSE) values of 7.8 to 22.2%. Ventilation energy consumption can be predicted at high accuracies (over 99%) and low variations (CV-RMSE values of 3.1 to 16.3%), while cooling energy consumption accounts for majority of inaccuracies and variations in total energy consumption prediction.

Aug 1, 2013

Up to thirty years ago, coal preparation in western Canada, except at four plants, had not included actual coal washing. The exceptions were at Nanaimo and Royston, B.C., where tub washers and wet tables were in use; at Hosmer, B.C., using. Robinson cones; and at Leitch Collieries, Passburg, Alta., using a feldspar jig. The two last named collieries had a short life and were not operating in 1920. The industry was divided, as at the present day, into two sections, steam (bituminous) coal and domestic (largely sub-bituminous) coal, the first generally supplying industrial needs and the second householcl and other heating requirements. The two sections overlap to some small degree today as prepared sizes, chiefly stoker, and briquettes, from steam coal are shipped for house-hold use, and domestic slacks are used in certain industrial plants. The .domestic operator, for reasons shown later, was not primarily concerned with actual coal washing as a phase of coal preparation, and bent his efforts to improvement of screening and loading plants, with hand-picking of coarse sizes. The bituminous operator, on the other hand, felt it necessary by 1920 to consider coal washing. When the mines were comparatively young, coal quality could be controlled to a considerable degree by selective mining, by leaving behind some of the seam or by-passing districts in a mine where the coal was of inferior quality to that in other districts. This obviously had its limitations, and so the next step was coal washing.

Jan 1, 1952

By L. Kong, V. G. Papangelakis, L. Li

"The Eh-pH diagram of lithium-titanium-water system at 25°C, 100 °C and 200 °C was constructed. It shows that there exist thermodynamic stability areas of Li2TiO3. This indicates a thermodynamic possibility for the formation of Li2TiO3 in aqueous solution. A hydrothermal process has been applied for the preparation of Li2TiO3 using TiCl4 and LiOH•H2O as raw materials. The prepared samples were examined with X-ray diffraction, scanning electron microscopy and thermo-gravimetric analysis and differential scanning calorimetry. The results show that temperature and washing condition have significant effects on the phase composition of the product. Phase-pure Li2TiO3 powders were obtained at 200°C with Li:Ti molar ratio of 2.0.INTRODUCTIONLithium-containing ceramics enriched in 6Li, such as Li2O, LiAlO2, Li4SiO4, Li2ZrO3 and Li2TiO3, are considered as tritium breeding materials (Saito et al., 1998; Roux et al., 1998; Johnson et al., 1998; Hoshino et al., 2002). In view of its admirable properties: low-activation, good thermal stability and thermal conductivity, excellent tritium release performance and reasonable lithium atom density (Kopasz et al., 1994; Roux et al., 1996; Saito et al., 1998; Wu et al., 2008), Li2TiO3 is recognized as one of the most promising candidates of tritium breeding materials. Meanwhile, Li2TiO3, as the precursor of H2TiO3-type lithium absorbent, receives more attention as the development of extracting lithium from salt lakes (Zhong, 2004; Zhang, 2010).Several synthetic techniques have been applied to prepare Li2TiO3 powders, such as solid-state methods (Lulewicz and Roux, 2002; Ramaraghavulu et al., 2011; Mandal et al., 2012), sol-gel processes (Deptula et al., 2002; Lee, 2008) and solution combustion routes (Cruz et al., 2006; Jung et al., 2006; Sinha et al., 2010). A solid-state method may produce a series of problems, including impurity contamination and difficulty in morphology control of the obtained powders, although the process involved is simple. The solgel process is prolonged and usually demands for multi-step reactions, while solution combustion route requires plenty of energy and easily causes product contamination by the fuel used. Owing to its environmentally benign and highly suitable characteristics in fabricating materials, hydrothermal technology has been widely used and became a powerful tool in the field of material synthesis (Yoshimura and Byrappa, 2008). For example, ZnO in the form of bulk single crystals, fine particles and thin films, which is an attractive photoelectric material, was successfully synthesized by hydrothermal process (Sekiguchi et al., 2000; Ohshima et al., 2004). A hydrothermal technique was also used to the preparation of carbon nanotube, which possesses outstanding mechanical, structural and electric properties (Bernholc et al., 1997), and is superior to the commonly used method (Gogotsi and Libera, 2000). There, it provides an option for preparing Li2TiO3. Laumann et al. (Laumann et al., 2010) synthesized cubic a-Li2TiO3 by hydrothermal reaction at 180 °C for 18 h, using TiO2 powder, comprising of anatase and rutile, and lithium hydroxide in de-ionized water. However, the prepared a-Li2TiO3 is extremely unstable with a maximum lithium loss of 75% when treated in bathing experiment."

Jan 1, 2012

By Euler De Souza, J. Daniel Stinnette, Julian Varaschin

"This paper outlines some of the factors that affect the airflow required for the ventilation of modern diesel-powered equipment and of electric equipment and examines how they can be applied in determining reasonable ventilation rates for Tier IV compliant diesel equipment and for electric equipment operating in mining environments. Airflow calculations for modern diesel-powered equipment and for electric equipment are more complex and must be based on a combination of factors that are unique to each mine. Methodologies for ventilation rate determinations for each case are proposed in this paper.INTRODUCTIONTraditionally, airflow requirements for production and support equipment operating in underground mines have been determined by multiplying the vehicle power by a ventilation rate that was either mandated by regulations or determined empirically from known quantities. However, in light of the drastic reductions to diesel equipment emissions mandated by the US EPA Tier IV and EURO Stage 4 regulations, there is still a great deal of uncertainty in the underground mining industry among those responsible for the ventilation of planned new mines or the expansion of current mines. The question remains, what ventilation rates should the ventilation system designer apply for modern diesel equipment?Also, given the ongoing development of grid/battery-electric equipment and active construction of fully electric mines, it has become critical to determine adequate airflow rates per brake kilowatt of electric engine power. One of the most important criteria for determining ventilation rates for electric equipment is the amount of heat they generate, as this is the most significant emission produced by electric equipment (which do not produce exhaust gases or particulates). Therefore, ventilation rates required to dissipate heat from electric equipment must be suitably determined for all electric vehicle fleets operating in underground mines."

Jan 1, 2019

By M. Leroux, J. A. Finch

"Sizing below 38 µm (400 mesh) is an increasing requirement in mill testing laboratories. The Cyclosizer is gaining wide acceptance in this role. A recent alternative is to use electro-formed sieves (micro-sieves), which are available with openings down to 5 µm. The advantage of micro-sieving is a cut size which is independent of mineral density, easier retention of the fi nest fraction and reduced purchase cost. A simple method of microsieving using an ultrasonic bath, which performs readily to 10 µm, is described.A systematic study of Cyclosizing and micro-sieving is reported for three samples; silica, copper oxide and a lead concentrate. Micro-sieving gave comparable results. Comparison with a standard sizing method, the Sedigraph 5000D, revealed misplaced material in each fraction by both methods. The range for micro-sieving was from 20% to 60% depending on the sieve and material; for the Cyclosizer it was a consistent 40-50% for all cones and all materials. The Cyclosizer can be sensitive to feed mass and particle size for dense materials. It is recommended that for minerals of specific gravity greater than 5, no more than 35 g of -38 µm be used.The disadvantage of micro-sieving is that it requires continuous operator attention and sieving time depends on sample mass. To fractionate 35 g-as used on the Cyclosizer and considered at reasonable mass for mill testing purposes-through 25-, 15- and 10-µm sieves requires about 80 minutes.IntroductionParticle size has a pronounced influence on mineral separation processes. Consequently, the measurement of particle size plays an important part in mill testing. By far the most common method is by screening. This, however, is usually limited to 38 µm (400 mesh) or occasionally 25 µm (500 mesh). Increasingly, mineral products are becoming finer than this limit and consequently finer sizing methods are required."

Jan 1, 1982

By Michael W. Russnak

Productivity and operating expenses are everything when it comes to judging how well your mine and company are doing. Stakeholders are always looking at these numbers and trying to understand if productivity is improving, if operating costs are trending downward and what you are basing your decisions on. o make improvements you first need to understand how you are performing. If you can?t get this basic information, you will never improve. You will not be able to make simple decisions related to maintenance, operations or production. Forget about planning, as you will only be guessing based on the numbers some stakeholder or your executive wants to see. The problem miners run into is not that the data doesn?t exist; it does, but typically it?s raw, it?s everywhere and its volume is huge. Today there is more on-board computing capability in shovels than we had on our desktops three years ago. Add other mobile equipment, plant systems and multiple OEM vendors to the equation and the challenge is daunting.

May 1, 2007

By Hua-Zhong Yu

Gold is one of the most widely used substrate materials for self-assembly. Self-assembled monolayers (SAMs) prepared from alkanethiols and their derivatives on gold are the most reliable and well-studied systems to date, which have attracted much attention because of interest in two-dimensional molecular assemblies, and of their potential applications in molecular devices, sensors, and functionalized interfaces. Gold electrodes are also very important in microelectronics and electroanalytical chemistry. This work reports the characterization of a new type of gold substrates for self-assembly. The gold substrates are constructed from recordable compact disks (R-CDs) with simple and straightforward wet-chemical treatment, and can be made at desired sizes and shapes that satisfy different experimental needs. In particular, an easy, inexpensive, and reproducible method to prepare self-assembled monolayers (SAMs) on CD-R gold substrates after removing the protective polymer films with concentrated nitric acid was described.

Oct 1, 2003

By D. E. M. Plaumann, B. S. Fee, R. D. Hansen, R. R. Klimpel

"The steps from experimental curiosity through to commercial product can be slow and tortuous in spite of the quality of the technological advances offered by the new development. Data generation and interpretation need to be done in lab tests as well as full-scale evaluations and, in each, the advantages of the new reagent must be clearly identifiable and measurable.The Dow Chemical Company has patented a novel new collector for the flotation of zinc. Fl (2-hexylthioethylamine hydrochloride) has several unique structural features that suggest atypical mechanisms for zinc collection. Laboratory data have demonstrated significant flexibility with respect to grade and recovery balance at dosages lower than those typically used for xanthates.In mill trials, the same phenomanon is evident - the choice between high grade and high recovery allows one to select the desired quality of zinc concentrate. One trial in particular was run over a three month timeframe and Fl gave improvements in recovery of 2.5% and a reduction in lead levels with less than 0.5% loss in grade. The dosages of other reagents in the flotation circuit were also reduced.Data demonstrating improved recovery and grade in lab trials will be discussed. Extensive data from the mill trial will illustrate how Fl works in both rougher and cleaner circuits."

Jan 1, 1990

By J. B. Brodie, C. Pelletier

"The vulnerability of Canadian and U.S. companies, their directors, officers and employees to onerous penalties associated with violations of environmental statutes and common law actions has provided the impetus for the increasing use of environmental audits. This trend is developing in direct proponion to the cost and difficulty of obtaining liability insurance. Companies operating in British Columbia should be cognizant of developing legislative and enforcement trends and their implications for individual and corporate responsibility. Canadian mining companies doing business in the U.S. should be particularly aware of the environmental exposure which may be assumed with property acquisition or by operations which produce or use any of an ever-increasing list of regulated substances.The environmental audit is now a key component of prudent business planning which will identify noncompliances and environmental liabilities, outline defensive strategies, and assist in a legal defence should charges be laid. This paper will discuss the purpose and mechanics of an environmental audit with emphasis on those features which will maximize protection against statutory and common law actions.IntroductionThe environmental audit is but one weapon in a comprehensive defensive strategy for corporate and individual survival in an increasingly litigious world. The principles of the environmental audit have been formulated as a logical response by management to an ever-growing list of environmental vulnerabilities, which often have the potential to result in plant shutdowns, prosecutions or fmancial liability of major proportions. Accordingly, the audit may play a critical role in maintaining profitability as well as assisting in the defence of a company and its employees against actions taken by regulatory agencies and citi7.cns under statute and common law. Should convictions result from these actions, the penalties are likely to be ameliorated by the demonstration of due diligence through management policy supporting the audit procedure.An awareness of environmental sensitivities, strict adherence to licensing requirements, and planning for environmental emergencies are now generally considered to be as important to profitable performance as operating costs, metal prices, and labour peace. Why is this so? The increased priority given to environmental matters is partly a result of changing attitudes amongst the mining profession, but perhaps more importantly, it is also a direct consequence of the proliferation of ever more stringent environmental legislation, the targeting of management for responsibility and the draconian penalties imposed for violations of such legislation. Contributing to this trend are recent court decisions involving disputes of an environmental nature in which the standard of care required for a successful defence now requires almost super-human diligence in environmental management. The principle of ""strict liability"" (in which negligence or permit violation does not have to be shown) is also being increasingly applied in the resolution of civil actions."

Jan 1, 1988

By M. K. Mishra, U. M. R. Karanam

Relative to slender pillars, larger size pillars exhibit improved strata control. Fly ash, though traditionally treated as a waste product, is emerging as an alternate engineering material. This paper deals with the development of a strong fly ash composite material with additives. The geotechnical properties of this fly ash composite were determined and used to trap model core pillars, which resemble squat pillars. The trapped samples were tested under uni-axial loading in the laboratory and the results showed higher load-bearing capacity of the model core pillars. The reinforced fly ash composites provide lateral confinement and exhibit improved post- failure behaviour of the model cores.

Jan 1, 2008

"The asbestos mining industry in the Eastern Townships of Quebec has early recognized the undesirable side-effects associated with mineral production, such as air pollution, noise and unsightly waste dumps. In order to efficiently achieve the industry's aim of eliminating or minimizing these objectionable features of mining, all of the asbestos producers in Quebec interchange information, knowledge and design dealing with the environmental control measures through the Environmental Committee of the Quebec Asbestos Mining Association.The paper describes what has been done and what is planned for the future in the various problem areas, such as control of dust emitted during the open-pit drilling operation, control of dryer stack emissions, control of the environment in ore, fibre and tailings handling operations, rehabilitation of the countryside covered by waste dumps, and many others."

Jan 1, 1971

?General Facts:Barrick?sFirst Mine in Peru Production started in November 1998 ?The Facilities:Open Pit, Primary and Secondary Crusher Valley Fill Heap Leach PadMerrill Crowe PlantRefinery Environmental Facts: High Rainfall - Average Annual Precipitation of 1,200 mm (47 inches) Rainfall Events: Common 20mm daily events High Altitude Site - Elevations range from 3900 to 4250m. Steep topography - Terrain ranges from 3:1 slopes up to cliffs. Water Issues: Sediment Control - Open Pit PAG Encapsulation - Waste Dump Stormwater control - Leach Pad Erosion Control Techniques ? Offsite impacts mitigation Social Issues: 11 communities surrounding the property Town of Huaraz

May 1, 2003

By A. A. Millar

THE output of coal from the Province of Alberta reached its peak; in the year 1928, when 7,334,179 tons were produced. Following this, a steady decline was recorded, and in 1930 a low mark of 4,564, 290 tons was made. Since that time, however, the tendency has been upward, and this year (1937) 5,551,682 tons were produced, compared with 5,696, 375 tons in 1936 and 5,462,973 tons in 1935. The value of the output in 1937 was $14,434,969, against $14, 720,004 in 1936. The coals of Alberta have been classed under three heads, viz., domestic, sub-bituminous, and bituminous The domestic (or lignite) and the sub-bituminous coals are used chiefly for domestic purposes, with the possible exception of the smaller sizes and the output of the two stripping pits at Stereo and Coal Valley The bituminous output is used mainly by the railways, for locomotive purposes, which, in 1937, accounted for 80.6 per? cenr of the total sales of bituminous coal. A fair proportion is sold for stationary engine and steam purposes and, in 1937, 25,000 tons were used in making briquettes at plants operated by the Canmore Coal Company, Limited, and Brazeau Collieries, Limited. The International Coal & Coke Company, Limited, used 99,500 tons in their plant at Coleman, for making coke. The bulk of the 66,000 tons of coke produced was sold for use at the smelter at Trail, B.C.

Jan 1, 1938

By Marc-André Villiard, C. St-Onge, V. Silla, J-C Milot

Rio Tinto Fer et Titane (RTFT) operates a metallurgical complex in Sorel-Tracey, Canada. In the Ore Preparation Plant (OPP), ilmenite ore is roasted through four parallel rotary kilns generating 95% of the plant wide sulphur dioxide (SO2) emissions. RTFT proactively set an annual emission cap for SO2 to be achieved by 2015. To achieve this targeted SO2 reductions, a technology evaluation and selection exercise was carried out, followed by detailed engineering and implementation. After a detailed evaluation of SO2 scrubbing technologies, the Circulating Dry Scrubber (CDS) system was selected as the most appropriate desulphurization system for this application. The system was implemented and commissioned from 2013 to 2015. General performance testing conducted in May 2015 demonstrated that the system achieved and surpassed the anticipated design values in terms of SO2 removal efficiency and hydrated lime utilisation. This paper summarizes the SO2 technology selection process, design features of the selected technology, project implementation and final performance testing of the SO2 abatement system.

Jan 1, 2015

By Robert B. Parsons

"The junior mining company's bank account is depleted, but there are high hopes for the company's property. Where to get the necessary development funds is a common problem facing many juniors.This month, Tax Notes discusses briefly the principal income tax implications of several alternative development plans that are typically available to the junior mining company and its shareholders.IntroductionAt some point in time, many junior exploration companies face a common dilemma-a promising prospect has been proven up and is read y for further development, but alas, the company is flat broke! In this situation, a number of alternatives is available to the company, including the possibility of ""going it alone"" by raising capital through a public offering, or by striking a deal with a ""major"" or some other substantial investor.This article focuses on the latter possibility, and discusses in broad term s the main income tax implications of various arrangements between a typical junior exploration company and a larger public company for the development of a particular property. It will be appreciated that a discussion of other important considerations, such as those pertaining to securities exchange regulation s and company law requirements, is beyond the scope of this article.Jointly Owned CorporationPerhaps the simplest way of dealing with the problem of financing the development of a property is to sell the property outright, pocket the proceeds, and run! Clearly, though, this alternative is unacceptable to most prospectors and developers, who are predictably reluctant to completely relinquish their equity interest in a promising property. An additional strike against such an outright sale is that the sale could trigger an income tax liability. Generally speaking, in the case of a simple sale of a mineral property, for income tax purposes the proceeds are applied to reduce the taxpayer' s unclaimed balance of Canadian development expense (""CDE""), with any unapplied excess being brought into income and taxed at ordinary corporate tax rates."

Jan 1, 1983

By S. J. Laskowski

In potash ore flotation, carried out in NaCI-KCI saturated brine (about 6-7 molar KC1 and NaCI solution), long-chain primary amines are used as flotation collectors. Long-chain primary amines are poorly soluble in water and their solubility further decreases at high electrolyte concentration. For ionic surfactants there is a characteristic temperature (Krafft Point, KP) below which their solubility is too low for micellization. In a previous study, the effect of pH on the KP of dodecylammonium chloride in water was determined [Q. Dai and J.S. Laskowski, Langmuir, 7, 1361-1365 (1991)]. This paper deals with the effect of electrolyte concentration on the KP of dodecylammonium chloride. The derived theoretical relationship between the KP and the critical micelle concentration (CMC) for dodecylamine can be used to calculate the KP for electrolyte concentrations of up to 0.5 mol/L (about 8% NaCI-KCI brine). A simple experimental procedure for the determination of the KP for higher electrolyte concentrations is also described. The results show that the Krafft point of dodecylamine increases from about 17-18°C (in distilled water) to about 80°C at 16% brine saturation.

Jan 1, 2006