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By F. Habashi

"A short account will be presented on the extraction of rare earths from monazite sand, bastnasite ore, and phosphate rock of igneous origin. This includes mineral beneficiation, leaching methods, fractional crystallization [of historical interest], ion exchange, solvent extraction, precipitation from solution, and reduction to metals. INTRODUCTIONOriginally, the term rare earths was only used for the oxides, R2O3, which are similar to one other in their chemical and physical properties and are therefore difficult to separate. Within the rare earth group, the elements scandium, yttrium, and lanthanum differ in their atomic structure from the elements cerium to lutetium (the lanthanides, Ln). Scandium occupies a special position with respect to this classification and its other properties, and therefore does not belong to either of these groups. The rare earth elements always occur in nature in association with each other. The isolation of groups of rare earth elements or of individual elements requires costly separation and fractionation processes owing to the great similarity of the chemical and physical properties of their compounds, which explains why the history of their discovery has extended over such a long period.The word “rare”, when used to describe this group of elements, originates from the fact it was thought that these elements could only be isolated from very rare minerals. Considering their abundance in the Earth’s crust, the term rare is now inappropriate. These elements are lithophilic and are therefore concentrated in oxidic compounds such as carbonates, silicates, titano-tantalo-niobates, and phosphates.The abundance of the rare earth elements taken together is quite considerable. Cerium, the most common rare earth, is more abundant than cobalt. Yttrium is more abundant than lead, whereas Lu and Tm are as abundant as Sb, Hg, Bi, and Ag. For all practical purposes promethium does not occur in nature. It forms only in nuclear reactors."

Jan 1, 2012

By G. Scamans, J. Lazaro-Nebreda, Z. Fan, J. B. Patel

"Melt quality is crucial for both continuous and shape casting of light alloys and in order to improve it, removal of excessive inclusions, accumulated impurities and unwanted gases becomes necessary. To address this problem, a new multi-purpose high shear liquid metal treatment technology, based on intensive melt shearing by a rotor/stator unit, has been developed. The device ensures achieving uniform temperature and chemical composition and an efficient dispersion of gas and solid phases in the melt with minimal disturbance of melt surface, and can be used, among other things, for de-gassing and de-ironing of Al-alloy melts. Efficient degassing is achieved by dispersing each argon bubble into many small ones, which significantly increases the overall surface area of the bubbles and the time they remain in the melt capturing hydrogen before reaching the surface. This allows using much lower inert gas flow and mixing times than conventional rotary degassing. When applied to Al-alloy scrap, with accumulated iron, the high shear melt treatment speeds up the nucleation and growth of primary Fe-rich intermetallic particles, allowing a faster removal rate. Therefore it reduces processing times, increasing recycling productivity, and facilitates full metal circulation of secondary Al-alloys.INTRODUCTION Aluminium and magnesium alloys are widely considered in various industrial sectors for the purpose of weight saving (Polmear, 1995). In particular, they are used in the automotive sector, where components are mostly manufactured by high pressure die casting (HPDC) because of its simplicity and relatively low cost, but efficiency and mechanical properties are quite low compared with other processes. To date, the main focus to overcome this problem has been for improving the HPDC machinery (Dahle, 2001) but little attention has been paid to the opportunities of controlling the nature and quality of the molten metal supplied to the die. In this way, liquid metal treatment, which involves a variety of physical and/or chemical processing methods to improve melt quality prior casting, is crucial for both continuous and shape casting products."

Jan 1, 2018

By W. G. Jewitt

THE Box mine, situated in Saskatchewan on the north shore of lake Athabasca, is unique in two respects. It is the first and, so far, the only gold mine in Saskatchewan, and it is the only gold mine in Canada to employ a large-scale forced caving system as the main mining method. Discovered in 1934 by Tom Box, an Edmonton prospector, its subsequent history, while breaking no records for speed, has been one of steady and more or less normal development. Camp and plant are situated close to the shore of Beaverlodge bay, sorne 50 miles east of the Saskatchewan-Alberta boundary and 35 miles south of the north boundary of the Province. The railhead at Waterways, Alberta, is about 220 miles to the southwest. Prince Albert lies some 450 miles to the south. The surrounding country presents a rather rugged variation of the usual Precambrian topography, with hills rising five to six hundred feet above lake Athabasca. The numerous lakes and islands, together with the wide expanse of lake Athabasca, compose an attractive scene, at least in the not over-long 'open water' season. The winters are long but not extremely cold, judged by prairie standards. The small lakes break-up around May 20th and the 'freeze-up' stops navigation early in October. Though apparently remote, the Box mine is fortunate in having reason-ably cheap transportation from Edmonton. The 300-mile railway from Edmonton to Waterways is the most expensive section, the rate for 1st class freight being $1.70 per hundred pounds and for 5th class freight $0.77 per hundred. Freight from Waterways to the mine, approximately 140 miles down the Athabasca river and 90 miles along lake Athabasca, is delivered by barges and tugs for 50 cents per hundred pounds. All freight is delivered during the 'open water' shipping season, which lasts from about .Tune 7th to October 7th. In normal years, barges are loaded to 3 to 3 1/2feet draught up to September 1st. After that date, and earlier in dry years, shallow water at Waterways reduces the barge loads. Barges of 100 to 200 tons capacity handle all mining freight, including pieces up to 15 tons in weight, without undue difficulty.

Jan 1, 1940

By Al Goodier

"This paper discusses the experience of Noranda Mines Limited, Matagami Division, with the vertical crater retreat (VCR) method in the mining of narrow-vein stopes. Although limited to only one stope, the viability of this method at the Radiore No.2 Mine has proven that further use of VCR in narrow-vein mining will be made.IntroductionThe Radiore No.2 property is located east of the Bell River in the southeast quadrant of Isle-Dieu Township, approximately 4.5 km east of the town of Matagami. The new James Bay Highway is 2.5 km north of the property and access to the mine is by a 2.5-km logging road.The property was staked by Radiore Uranium Mines in March 1961 and the sulphide body was first indicated by an E.M. survey. Diamond drilling commenced in the fall of 1961 and was completed by the end of 1962. As per an agreement in 1970, the claims were sold and assigned to Orchan Mines Limited. Subsequently, the property was transferred to Bell Allard Mines Limited, a wholly owned subsidiary of Orchan Mines. Early in 1979, Noranda Mines Limited acquired the property and it is now part of Noranda's Matagami Division.Geology and MineralizationThe deposit is in a band of volcanic rocks north of the Bell River complex. The lens of massive sulphides dips almost vertically and strikes almost east-west. The north contact is essentially sharp against andesite material; the south contact is less well defined, as the massive sulphides tend to grade into more disseminated material.The orebody varies from 5 to 20 feet in width, by 350 feet long and 200 feet in height. The overburden is composed of sand, gravel and clay, varying from 0 to 26 feet in depth. The ore reserves were 153,340 tons grading 1.97% copper and 1.01% zinc including 10% of dilution at zero grade."

Jan 1, 1982

By J R. M Hutcheson

Advocate Mines Limited came into initial production on June 30, 1963, with an annual capacity in excess of 60,000 tons of high-quality chrysotile asbestos fihres, thus strengthening Canada's position in world production. The history of this development is traced from discovery through initial exploration, financing, orebody delineation and evaluation, pilot-plant production and product evaluation, construction of the plant, construction of deep?-sea shipping facilities, provision for a closed shipping season, and provision for the remoteness and for the lack of services, through to realization of full production capacity. The many unique aspects of the project are given special attention, particularly in the light of the first year of full-capacity operation. The marketing of the products in a highly competitive world market is reviewed, with special emphasis on product evaluation, quality control and the shipping of high-quality products to consumers throughout the world. C ANADA'S newest asbestos producer, Advocate Mines Limited, is located at the north end of the Burlington Peninsula, White Bay District, Newfound-

Jan 1, 1965

By W. Keith Buck

Introduction During World War II years, the magnetometer was used by various field parties of the Geological Survey of Canada, specifically in the search for chromite, a strategic war mineral. Throughout the summer of 1944, Professor J. W. Ambrose used the instrument experimentally on eight separate projects (1). Since then, several members of the Survey have come to consider its use to be of valuable assistance in the season's mapping. Dr. C. H. Stockwell, in particular, regards use of the magnetometer as a necessary part of detailed geological survey work. Throughout the field season of 1949, the magnetometer was used by Dr. Stockwell?s party as an aid to mapping in detail, to the scale one thousand feet to the inch, the south-west quarter of Dasserat township, Temiskaming county, Quebec. The principal geophysical project that was undertaken was the location of the Horne Creek fault and the Diabase fault in the area approximately midway between Arntfield and Kearns, on the Quebec side of the Interprovincial border. The location of these faults on either side of this central area was known. The Horne Creek fault is a subsidiary fault to the Cadillac 'break' which extends ?westward from Val d'Or through Cadillac to beyond Larder Lake. It lies to the north of that major fault zone and has a general southwesterly trend.

Jan 1, 1951

By Art Hamilton

Abstract -The Zn-Pb-Cu-Ag ore deposits of the Boundary and N-5 zones near Bathurst, New Brunswick, occur in a polydeformed volcano-sedimentary sequence that is part of the Ordovician Tetagouche Group. Massive and disseminated sulfides are hosted by an argillaceous to cherty sedimentary sequence that is stratigraphically underlain by a siliceous fragmental unit and is overlain by a feldspar-rich crystal tuff and related tuffaceous rocks. The deposits have a low iron sulfide con­ tent relative to that of most stratabound sulfide deposits of the Bathurst-Newcastle mining district. The ore is commonly associated with chlorite- and talc-rich sediments. The N-5 deposit is considered to be the fault-displaced extension of the Boundary deposit. The Boundary deposit is estimated to contain 891 000 t grading 3.310Jo Pb, 7.96% Zn, 0.32% Cu and 44 g/t Ag; the estimate for the N-5 zone is 330 000 t grading 3.24% Pb, 7.15% Zn, 0.33% Cu, and 37 g/t Ag. The ore is processed at 1000 tpd at the Heath Steele mill.

Jan 1, 1992

By S-E. Vandat

The goal of this work was to select an appropriate electrode for dummy load of diesel engine in fully salt-water in the DESA factory. The electrochemical corrosion rate of general structural steel, commercial pure aluminum and cathode copper calculated as weighting, volumetric and commercial in fully salt-water by city power. After several tests and then applying the fuzzy logic method, it was determined that general structural steel is the best selection for this purpose.

Jan 1, 2005

By R. Blazej

Machinery Systems Division (MSD) in the Institute of Mining Engineering at Wroclaw University of Technology specializes in belt conveying systems analyzing, calculating and design. Within the division operates the certified Laboratory of Belt Transportation (LTT) and Laboratory of Rollers. Since few years, a group of several people have begun work on developing a comprehensive system for the automatic evaluation of condition of conveyor belts working in the mines. Group uses both magnetic devices developed by specialized companies servicing belts and its own machine vision system developed for assessment of belts covers and edges during belt movement (up to 7 m / s) on the specially designed for this purpose the test conveyor. Recently they have got the research grant funded by the National Centre for Research and Development (NCBiR) for development of the system for automatic diagnosing of conveyor belts? condition and aiding of rational belt management. On the basis of previously created diagnostic tool called ABCDE (Automatic Belt Condition Diagnostic Equipment) the five modules: vision-A magnetic-B, preventive-C, forecasting?D, and determining safety factor-E will be developed. They will automatically interpret data about conveyor belts? condition to indicate the extent and timing of repairs, to prevent failures and to select the optimum moments for their replacements. The system will use results of ongoing research & development and planned research concerning modeling of belt wear using evolutionary genetic algorithms. The reached stage of research can not yet allow to start the implementation work by potential users. It is therefore necessary to pursuit research in real scale, the development of new modules (C-E) and intensive testing of the system in working condition with system calibration to optimize the economic effects.

Aug 1, 2013

By P. Dinham, G. C. Summerton, N. McCulloch, S. Dowling, D. C. Craig

"Development of a process for the treatment of a nickel copper matte rich in the minerals heazlewoodite, chalcocite and bornite has demonstrated significant base metal recoveries and metal separation efficiencies. The determination of chemical and mineralogical changes occurring in the individual leaching stages in laboratory experiments has enabled a better understanding of the complex leaching chemistry. The chemistry and mineralogy of the piloting and laboratory processes are discussed.INTRODUCTIONThe nickel-copper sulfide ores of the South African Bushveld Complex are among the most important Platinum Group Metal (PGM) bearing ores, and contain the world’s largest reserves of platinum. The treatment used in the recovery of PGMs from these ores includes three types of processes, namely ore concentration using physical techniques such as flotation and gravity separation, concentration by pyrometallurgical means, hydrometallurgical extraction of the base metals followed by the PGMs. Following milling of the ore, flotation involves the separation of high value minerals from gangue by taking advantage of the differences in their hydrophobicity. These differences are generally maximized through the use of a surfactant or wetting agent. Concentrates are then thermally treated and melted which brings about physical and chemical changes that enable the recovery of base metals and PGMs. The main aim of the smelting and converting process is to separate and eliminate the valuable metals from the bulk of the unwanted gangue and essentially all of the iron and to concentrate the metal VALUES (into a high grade converter matte. The matte can be further enriched by magnetic separation, producing a PGM-rich magnetic fraction and a base metal-rich non-magnetic fraction. The magnetic fraction is treated by hydrometallurgical processes to produce a PGM concentrate which is further refined to separate and purify the individual metals. The non-magnetic fraction is treated to produce marketable metal VALUES (such as nickel, copper, cobalt and to a lesser extent PGMs. The principal objective of any hydrometallurgical extractive process is to leach the desired elements selectively into an aqueous phase so as to separate them from the bulk of the material. (Crundwell, Moats, Ramachandran, Robinson and Davenport, 2011; Hundermark, Mncwango, de Villiers and Nelson, 2011)."

Jan 1, 2012

By H. F. Zurbrigg

"The Frood-Stobie Mine is by far the largest metal producer in the Sudbury area. Its efficient development was made possible by the consolidation of three mining properties that covered parts of the same ore body. They were known as the Frood Mine, the Frood Extension, and the Stobie Mine.The southwest or Frood portion of the orebody was discovered by Thomas Frood and A. J. Cockburn in 1884. Cockburn's interest was acquired by J. H. Metcalf and W. B. McAllister and patents were issued to Frood, Metcalf, and McAllister in 1884. The property was purchased by the Canadian Copper Company (lnco) in 1886.James Stobie discovered the northeast or Stobie part of the orebody in 1885. In 1886 Stobie and Rinaldo McConnell applied for the location and patent was issued in 1886. They sold the property to the Canadian Copper Company (lnco) the same year.The Frood Extension property included very little of the ore zone at surface but it covered ore down the dip from Frood. Frank Cochrane was granted title to the property in 1908 and sold it to the Mond Nickel Company in 1910. The title was transferred to the International Nickel Company in 1929 at the time of the Inco-Mond merger.Prior to 1930 the three properties produced a total of about 1 ,000,000 tons of ore from mining done during the periods 1887-1903, 1913-1915 and 1925-1929. Since 1929 the Frood-Stobie operation has produced more than 120,000,000 tons of ore, about half from open pits and half from square set and blast hole stoping. The current production rate is in excess of 6,000,000 tons per year.The principal products from the ore are nickel and copper. The by-products are iron ore, cobalt, platinum, palladium, rhodium, ruthenium, iridium, gold, silver, selenium, tellurium, and sulphuric acid."

Jan 1, 1949

By W. E. Lockley

This paper will attempt to answer a number of questions which are important to the safe and continued operation of an electric power system. 1. WHY should electrical protective devices be tested? 2. WHAT devices should be tested ? 3. WHEN should they be tested ? 4. HOW should they be tested? 5. WHO should test them ?

Jan 1, 1977

By Jaeheon Lee

"Biooxidation of gold ores or concentrates could be a very attractive alternative to pressure oxidation (POX) or roasting to liberate the gold grains from various sulfides. Crushed heap bioleaching was successful in US and many operations using tank bioleaching of gold concentrate are currently running around the world. Many parameters need to be considered during the project of sulfidic refractory gold ore process. Capital and operation costs are among the most important ones. Run-of-mine heap biooxidation could be very inexpensive and the smaller the crush size (particle size), the more expensive the capital and operating costs for biooxidation application are expected. The capital cost of biooxidation could be a fraction of the cost for building POX plant or roaster and the operating cost could be 1/3 of POX or roasting depending on the method utilized. A new biooxidation process, Sand Farming, is introduced as an alternative to POX and tank biooxidation process. A relatively coarser particle size (P80 = 650 µm) of the process benefits the low cost of grinding against the conventional grinding size (P80 = 75 µm) for other options. The cost of Sand Farming is less than 40% of that of pressure oxidation with comparable gold recovery from the downstream process. This paper will review the laboratory scale testwork for various biooxidation process of sulfidic refractory gold ores and concentrates and provide the economic evaluation showing the biooxidation could be the most economic method without much sacrificing the overall gold recovery. INTRODUCTIONThe decreased availability and lower grade of raw materials has motivated industries to consider recovering values utilizing low cost process options. The process may treat high grade concentrates or submill grade ores that cannot be processed economically by conventional milling-flotation or leaching. Sulfidic refractory gold ores/concentrates have been economically processed by roasting, pressure oxidation, and biooxidation in stirred tank reactor. The process selection is based on a series of studies including multi-year long ore characterization and metallurgical investigations."

Jan 1, 2016

By R. Khanna, I. Mansuri, S. Devasahayam

"Recycling polymer based end-of-life materials as carbon resources for a partial replacement of coke/coal can make important contributions towards enhancing the environmental sustainability of steelmaking processes. An in-depth high temperature (1550°C) investigation has been carried on waste CDs/DVDs focussed specifically on char generation, characterization and dissolution into molten iron. The simultaneous presence of carbon and oxygen in polymeric chains on polycarbonate substrates resulted in the generation of a significant pore structure and exposed surfaces. Carbon dissolution studies into molten iron were carried out on the raw polymer as well on chars; high levels of carbon pick-up were observed in both cases after 15 minutes of contact at high temperatures. INTRODUCTIONOver the past sixty years, plastics have played an important part of our daily lives and are being increasingly used in all aspects of the global economy. More than 260 million tons of plastics are produced annually worldwide. Their rapid growth and extensive utilization with a short life span (such as packaging) has created a massive waste problem. Although the waste plastic component in municipal solid waste (MSW) amounts to only about 10 %, plastics have a high volume-to-weight ratio and these are generally not biodegradable. In Australia, ~19.20 % of plastics were recycled in 2009-2010 (PACIA, 2010); with the total consumption being estimated at 1,501,258 tonnes, 288,194 tonnes of plastics were recycled. There are serious environmental concerns with the two key waste management options, i.e. land filling and incineration, and there exists an urgent need for developing alternative recycling approaches. In this paper, we focus our attention on recycling waste CDs/DVDs polycarbonate substrates as a carbon resource in steelmaking.CDs/DVDs used for music/data/image are made from aromatic polycarbonate resin (hereafter abbreviated PC). This resin is also widely used as an engineering plastic in applications such as automobiles, mobile phones, notebook type personal computers, cameras & video cameras, electric & electronic appliances, fire equipment, life & living goods, roofing sheets, etc. High consumption and growth (~10% annually) of PC utilization is attributed to its excellent properties such as outstanding impact resistance, transparency, heat resistance, and dimensional stability. The molecular formula and composition of PC resin is given below:"

Jan 1, 2012

By A. L. Irwin

THE disposal of tailing or waste material, which is generally a very large proportion of the ore treated, is a major problem in the location and operation of any concentrating enterprise and especially so where the life of the operation is expected to continue for many years. Many factors need to be taken into consideration in the selection of a tailing site, chief among which are economical handling of the material, subsequent re-treatment of the tailing, and precaution against stream pollution by waste water. The final location of many mill sites bas been governed largely by the selection of a sui table area for tailing storage. The Sullivan concentrator of the Consolidated Mining and Smelting Company is situated about three miles from the Sullivan mine at Kimberley, B.C., and one of the deciding factors in its location at this distance from the mine was the availability of a suitable area in which tailing could be deposited. In view of the indicated long life of the property, a far-sighted policy bad to be adopted in the matter of tailing storage, for not only would it be necessary to accumulate a huge tonnage of finely ground material, but also reclamation for iron recovery at some future date bad to be considered. Some idea of the extent of the problem may be grasped when it is noted that, by the end of 1938, over 18,000,000 tons of tailing bad been impounded in an area of some 200 acres.

Jan 1, 1939

By Daniel Lachapelle, Nuri Hmidi, Turgut Yalcin

"Simulation can serve as a convenient tool in studying the behaviour and performance of grinding circuits by facilitating the evaluation of various scenarios and identification of optimum operating conditions. This technique was applied to the St Andrew Goldfields Ltd.’s Stock Mine Mill which is a 1300 tpd gold milling facility, offering custom milling services as well as processing the Company’s own ores. Lack of adequate instrumentation in the mill poses a challenge in attaining optimum performance especially with changing ore types and characteristics. The grinding process is monitored essentially by manual measurement and adjustment of pulp densities at various streams. A simulation program was designed to assist in the effective implementation of this mode of grinding control. Product sizes from both the primary and secondary grinding circuits were correlated empirically to relevant process variables using a database formed from the results of past sampling campaigns. The simulator was created in Microsoft Excel whose data analysis and optimization tools coupled with its Visual Basic Programming capabilities were found to provide an excellent environment for the development of a cost-effective, efficient and user-friendly simulation program.INTRODUCTIONGrinding is often a very costly unit process in milling operations, mainly due to the excessive energy consumption associated with it. For example, for a Canadian copper-zinc flotation mill, grinding was listed as being the most costly item taking up 30.4% of the total milling expenses, followed by the flotation cost at 2 1 .O% (Kidd Creek Mines Ltd., 1982). A survey on 45 copper flotation mills around the world showed the average grinding cost to be 34.5% of the total milling cost (Weiss, 1985).Overgrinding aggravates the cost issue, while insufficient grinding either causes loss of valuable minerals to tails or results in low-grade concentrates. Therefore, it is essential that grinding circuits be carefully controlled and monitored. To this end, a great deal of effort has been devoted over the years to the modelling and simulation of grinding systems in order to assist in the efficient running of these processes."

Jan 1, 2001

By F. Guo

"The leaching kinetics of zinc sulphide concentrate was studied under total pressures ranging from 0.3 MPa to 0.5 MPa and leaching temperatures ranging from 358 K to 378 K. The apparent activation energy of leaching reaction under different total pressures was calculated. The results show that for the extraction of zinc at low-temperature pressure leaching is controlled by an interfacial chemical reaction. This was supported mineralogical analysis of the leaching residue. The kinetic equation for low-temperature pressure leaching of zinc sulphide concentrate was further established by quadratic regression on the basis of shrinking core model.INTRODUCTIONThe Roast-Leach-Electrowinning Process (RLE) is the primary route for zinc production and responsible for more than 85% of the total zinc production (Souza et al., 2007). During the roasting of zinc concentrates, fugitive SO2 causes pollution. The prevention of SO2 emissions from the RLE process can be one of the challenges to this technology (Deller, 2005). In the 1980s, the Zinc Pressure Leach (ZPL) process changed the concept of zinc hydrometallurgy, in which zinc sulphide concentrate is directly leached at approximately 423 K and approximately 0.7 MPa oxygen overpressure and the sulphidic sulphur is oxidized into elemental sulphur so that the pollution by SO2 is completely avoided. Since 1981, five zinc plants have adopted the ZPL process either for expansion by integration with existing roasting facilities, or for the production of zinc without any roasting at all (Collins et al. 1994; Barth et al. 1998). The innovation of the ZPL process has made the zinc industries more competitive although it needs an autoclave. The direct leaching technology of zinc is still in development."

Jan 1, 2012

By A. M. Ramadan

The composition of phosphate rocks, mainly used in manufacturing fertilizers, varies among deposits; therefore, phosphate rocks from different sources are expected to behave differently in acidulation processes. This paper examines the effect of preconcentration of phosphate ore from El-Sebaiya East, Egypt, using flotation on uranium leaching. A high-grade ore sample (27.3% P2O5, 168 mg/kg U) supplied by the Al-Nasr Mining Company, was subjected to reverse single-stage flotation to separate carbonate from the phosphate sample. Subsequently, P2O5 and U concentrations were 32.2% (92.1% recovery) and 225 mg/kg, respectively. After the leach process, the U concentration in the liquor was 319 mg/L.

Jan 1, 2014

By H. Sakurai, M. Kato, F. Tanaka

The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. The conditions in the CL- furnace change its settling efficiency, resulting in high variability of copper losses in slag. Modifications of the operation and maintenance procedures for the CL-furnace have significantly and sustainably reduced the copper losses in Gresik smelter to below 0.7%. A series of flow patterns evaluation in the CL-furnace demonstrated how the chemical reactions and settling conditions of the CL-furnace has been improved by the new operating procedures. Settling mechanisms for the matte droplets in the CL-furnace is also discussed using image analysis of solidified slag. INTRODUCTION The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. Since the top-blowing in the S- furnace agitates the molten bath strongly, matte droplets are dispersed over the slag phase when melts flow out of the S-furnace. Thus, the CL-furnace has an important role to settle and recover matte droplets efficiently. Since many papers have ascribed major part of copper losses to matte droplets suspended in slag (Tanaka 2007; Genevski et al., 2008; Starodub et al., 2016), flow patterns of slag in the CL-furnace can affect greatly on the profitability of smelters which have adopted the Mitsubishi process. PROCESS DESCRIPTION Figure 1 illustrates the Mitsubishi process schematically. The Mitsubishi process is the only system for continuous production of blister copper from copper concentrates and consists of 3 furnaces connected by enclosed launders those ensure the minimum emission of fugitives. In a smelting furnace (S-furnace) copper concentrates are fed with flux, oxygen-enriched air to form a mixture of slag and matte which cascades down to a slag-cleaning furnace (CL-furnace). The CL-furnace settle matte droplets in the mixture on the crucible from which matte is siphoned to a converting furnace (C-furnace), while discharging the cleaned slag (CL-slag). The C-furnace converts matte to blister copper by the top-blowing of oxygen- enriched air.

Jan 1, 2019

By J. D. Zhu

A numerical model for predicting microporosity formation in aluminum castings has been developed, which describes the redistribution of hydrogen between solid and liquid phases, the transport of hydrogen in liquid by diffusion and Darcy flow in the mushy zone, One of the key features of the model is that it uses a two-stage approach for porosity prediction, In the first stage, the volume fraction of porosity is calculated based on the reduced pressure, whereas, in the second stage, at fractions solid greater than the liquid encapsulation point, the fraction porosity is calculated based on the volume of liquid trapped within the continuous solid network, which is estimated using a correlation based on the Niyama parameter, The porosity model uses thermal data calculated using the commercial finite element package ABAQUSTM. The model has been applied to examine the evolution of porosity in a series of experimental samples cast using unmodified A356 in which the initial hydrogen content was varied from 0,048 to 0.137 [cc/100g], A comparison between the model predictions and the experimental measurements indicates good agreement in terms of the variation in porosity with distance from the chill and the variation resulting from initial hydrogen content.

Jan 1, 2005