Search Documents

By D Martín, G. Díaz, F. Cubeddu, A. B. Mejias

The Modified ZINCEXTM Process (MZP), developed by Técnicas Reunidas, is an industrially proven flexible process. It can handle a wide range of primary and secondary raw materials, producing SHG zinc. The core of the Modified ZINCEXTM Process is the zinc solvent extraction unit. This unit is an effective barrier for any leachable impurities present in the raw material. As a result of this an ultra-pure zinc solution is always obtained. The high versatility of the process makes the application of the technology in different scenarios possible. MZP can be effectively applied when developing a whole new plant (Skorpion) or adapting its scheme to an existing refinery (Akita), in both cases giving the same results. Flexibility in terms of capacity of the plant is a great advantage of the MZP, there is the possibility to adapt the global process to a wide range of production capacities. Zinc production capacities of over 150 000 t/a may be achieved with a single solvent extraction plant train. The robustness of the Modified ZINCEXTM Process has been recently proven on two new plants currently in operation: Portovesme (Italy) and Horsehead (USA) after start up during 2013. The status of both plants is described in this paper.

Jan 1, 2014

By Juergen Antrekowitsch, Stefan Steinlechner

"Waelz oxide from steel mill dust recycling is usually sold to the primary zinc industry, where it is first charged to the roasters to eliminate the remaining fluorides and chlorides. This limits the overall amount of secondary materials which can be used because of different operating problems in the roasters. Another option, in the case where the halides are low, would be direct leaching with low or medium concentrated sulphuric acid. Unfortunately, because of the carryover of some steel mill dust, iron is also present in the Waelz oxide, reaching contents up to 5 wt.%. Since the objective is to treat the solution more or less directly by electrowinning, with only a few simple preliminary purification steps, iron in the solution is a very important factor. Various trials have been done to investigate the dissolution behavior of the iron contained in the Waelz oxide. Although the zinc extraction should reach a maximum, all other elements, especially iron, should be low. This paper describes the results of our research in this area and offers possible options for Waelz oxide utilization. There is also a focus on how other elements, present in the material, influence the dissolution behaviour of zinc and iron, and whether a loss of zinc is unavoidable, if low iron dissolution is required.INTRODUCTION One of the most important secondary zinc resources is the zinc oxide originating from steel mill dust recycling. For the treatment of high zinc containing steel mill dusts, the Waelz kiln process is the so called “best available technology” and it dominates the industry, with roughly a 90% market share. The product Waelz oxide contains mostly zinc oxide, but it also contains lead compounds and halides due to evaporation with the zinc. In addition, it contains iron and some slag compounds due to mechanical carry-over. The presence of halides limits the use of the material as an alternative concentrate for primary zinc electrowinning. Such halides can be reduced to a certain extent by washing and/or solvent extraction (see following chapter). Although lead is not troublesome and theoretically represents a second recoverable valuable metal, iron is unwanted and causes additional problems during leaching. Even though Waelz oxide is generally a highly welcome input material in primary zinc metallurgy, due to its high zinc content, it still contains halides, and in the majority of cases, the oxide must first be treated in a roasting process. Different circumstances, like accretion formation because of the lead and halogen compounds as well as unwanted cooling effects in the roaster, limit the amount of Waelz oxide which can be substituted for the primary concentrate. Another, even more limiting factor, is the allowable concentrations of chlorides and fluorides in zinc electrowinning, the last step in the primary zinc processing route (Ruetten, 2011)."

Jan 1, 2016

By A. Liem, R. L. Johnson, C. Sturgess, E. Kuzub

New challenges in mineral processing arise as high-grade ores become less available and the mining industry is forced to exploit lower grade ores. One of the challenges in beneficiating lower grade ores is the liberation of mineral particles while maintaining control over material management. Lower grade ores need fine grinding to free valuable minerals, but finely divided particles can cause severe problems, such as dustiness and flowability, in subsequent stages of material management. There are at least two approaches that can be taken to resolve this dilemma, both of which relate to particle size enlargement. First, the application of a dust suppressant can be used to control that aspect of material management. The optimal choice of dust suppressant agent depends on effectiveness and cost, both of which can be strongly influenced by the selection of application method. Second, agglomeration combining small particles into larger units-can reduce dust and improve the flow characteristics of the material at the same time. There are several mechanisms that can be employed to agglomerate mineral materials. Although agglomeration adds a new processing step, it is often cost effective. This paper describes these two approaches and their respective challenges, as they relate to a mined ore. We report on modified or newly developed procedures for characterizing mineral ores with respect to material management. On the same material, we use agglomeration processing to capture fines within larger particles and show how dustiness and other aspects of material handling are affected. We conclude by discussing their specific application in accordance with the mineral properties and processing needs.

Jan 1, 2004

By Tamas Kekesi, Gergo Rimaszeki, Tibor Kulcsar

The efficient purification of soldering waste material can be achieved in a single operational step by the electrolytic refining in pure hydrochloric acid - tin-chloride media. The complex formation of the ionic species may offer a beneficial level of natural inhibition. Using the PCR (periodic current reversal) technology, is efficient in affecting the morphology of the cathodic deposit. In order to optimize the process, the investigation of the solution stability and the electrode reactions is essential. The natural tendency of the Sn(II) oxidation and precipitation can be overcome by properly controlling the concentration of the main components and the ratio of Sn(IV)/Sn(II) in the electrolyte solution. Polarization curves were obtained for different concentrations tin and hydrochloric acid. Conclusions referring to the electrode reaction were derived from the overvoltage - current plots. The morphology of the deposit can be correlated with the exchange current density, also determined from the polarization curves. The cathodic current efficiency and the morphology of deposited metal are affected by the distribution of tin species and the principal electrolysis parameters.

Jan 1, 2011

By N. Razavinia

Most mining and metallurgical industries produce relatively large quantities of low grade waste heat which they vent, for the most part, to the environment. To date, little is being done to recover some of this heat and transform it from low grade to a high grade energy form such as electricity. A few decades back this was also true of paper, plastics and metals. Recycling was not a prominent activity. Today, we all know that it is and that recycling is a must for sustainable development. To this end, we feel that we are now at that point in time when the recycling of waste heat to electricity must be given serious consideration. By recycling waste heat one can achieve at least one if not two of the following benefits: 1) reduction in the carbon footprint ? by improving the overall energy efficiency of a process, and 2) production of electricity at an economically viable cost. We have developed a process that captures, concentrates and converts (3 C?s) waste heat to electricity. The process comprises 3 distinct interacting units. The first unit captures and concentrates waste heat using heat pipe technology. The second unit converts some of the concentrated heat to mechanical work which can then be readily converted to electricity. This unit is based on the classical piston/cylinder engine arrangement that is widely used by consumers to power systems with compressed air, for example. The third unit of the process dissipates the heat that the engine cannot convert to high grade energy. It also uses heat pipe technology to achieve this. The combination of the 3 units forms a unique system for recycling waste heat. This paper describes the system and it presents some results that show how the system can be made to be economically viable.

Aug 1, 2013

By B. B. Adhikari, S. Alam, Ohto Kawakita, Abe Pangeni

Effective recovery of gold was investigated by using adsorption gels prepared from pure cellulose, cotton and paper by treating with concentrated sulfuric acid. Only gold was adsorbed with extraordinary high loading capacity from varying concentrations of hydrochloric acid separated from other precious metals and base metals. The formation of fine powders of metallic gold was visually observed, which is attributable to the selective reduction of gold (III) ion to metallic gold clue to its high oxidation-reduction potential. Recovery of gold from the leach liquor of hydrochloric acid of circuit boards from spent mobile phones was attempted using pure cellulose gel.

Jan 1, 2011

By Adam J. Szladow

"INTRODUCTIONThe low calorific value and the high moisture and ash contents of run-of-mine (r.o.rn.) lignite limits the utilization of Saskatchewan lignites to thermal power plants in Saskatchewan, Manitoba and western Ontario. On the other hand, the low sulphur content and the low mining cost make lignites potentially attractive for new coal markets, if suitable processes can be found for upgrading. Economic upgrading to a higher quality fuel would make lignites more acceptable for industrial and utility boilers.This paper presents a summary of the process engineering evaluation of coal upgrading technologies conducted in support of a study of selected lignite upgrading processes. The summary presents the relative advantages and offers specific comments on the application of coal upgrading technologies for lignites. ResourcesLignite comprises the largest fossil fuel energy deposits in Saskatchewan. The total resources of immediate and future interest exceed 27 billion tonnes. The measured and indicated lignite resources of immediate interest are large enough to last for over 200 years at the current production rate of about 10 million tonnes per year (Table 1).Saskatchewan lignitedeposits are present in three different geologic formations: (I) the Ravenscrag Formation of Paleocene Age in southern Saskatchewan; (2) the Swan River Formation of Lower Cretaceous Age in central north Saskatchewan; and (3) the Judith River Formation of Upper Cretaceous Age in central west Saskatchewan. The deposits in the Swan River and Judith River Formation are not currently of economic interest.The Ravenscrag deposits are confmed to four lignite basins, namely: the Estevan, the Willow Bunch, the Wood Mountain and the Cypress basin (Fig. 1). The estimated resources of immediate interest in the four basins are over 7 billion tonnes (Table I). These resources include lignite seams at least 1.5 m thick, at depths of less than 45 m.The average quality of lignite varies relatively little between the four basins considering the distance between deposits (Table 2). There is, however, a progressive increase in moisture and ash content, and a decrease in calorific value and carbon content as one moves westward from the Estevan to Wood Mountain and Cypress basins. The Estevan area deposits are of higher rank despite the fact that they are stratigraphically younger than the Willow Bunch deposits (Cameron and Marconi, 1979).In upgrading lignite to a higher quality fuel, it is important to know not only the average proximate and ultimate analysis (Table 2) but also other lignite characteristics influencing the product quality . For example, Figure 2 shows the effect of lignite HIC ratio on the product equilibrium moisture for hydrothermal treatment of lignite. It is apparent that lignites with a higher HIC ratio, or high liptinite content yield much better quality product for the same hydrotreatment conditions. Other examples of lignite characteristics which are important in upgrading include distribution of sulphur forms and mineral matter, maceral composition and degree of surface oxidation."

Jan 1, 1989

By F. H. Samuel, P. Burke, F. Mucciardi, J. Gruzleski, S. A. Musmar

A new thermal analysis technique has been developed and tested. It utilizes the enhancement in heat transfer characteristics associated with a recent advancement in heat pipe technology. Heat is extracted from a liquid sample of a melt taken in-situ within a vessel or furnace. The rate of heat extraction is such as to cause the sample to solidify. The technique was tested in both laboratory scale and industrial scale (Grenville Castings, Perth, Ontario). A 356 Al Alloy, subjected to various melt treatments was used to perform the tests. Classical thermal analysis was also performed simultaneously using a preheated graphite cup and at the same melt conditions. The comparison showed the potential of the new technique over classical thermal analysis. The major advantages of the new method are that it conducts the analysis inside the melt (i.e. a physical sample is not removed from the melt), it consumes less time and the cooling rate can be precisely controlled during the solidification process. Moreover, the resolution of the results is better than that of conventional techniques. Aluminium

Jan 1, 2006

By P. Radziszewski

Industrial practice in mineral processing shows that an important problem in understanding and monitoring in-mill parameters is due to the lack of fundamental knowledge and appropriate sensors. With the development and growing use of DEM charge motion simulators for mill optimisation and design, it is possible to describe the fundamentals of grinding mill behaviour, in improving the understanding of internal grinding mill dynamics and in developing solutions to industrial practice. The main challenge to bringing this DEM technology to the mill operator however was the need for substantial computing power and time. However, what about a simplified DEM charge motion model running in real-time? What about the use of sensor technologies to correct any possible drift in simulator prediction? Could such a technological system be used to predict mill performance and eventually be used for mill control and optimisation? Some of these questions are answered with the development of an "on-line" DEM charge motion simulator package (SAGTools?) along with that of a number of sensor technologies (liner wear, acoustic, instrumented ball) that can contribute to simulator precision. With the objective of bringing this modelling and sensor technology into the concentrator control room to assist operators, this paper aims to describe the main elements of this emerging and developing technology and discuss how it can lead to online mill performance prediction and eventual control.

Jan 1, 2007

By J. P. Jylhä, A. Jokilaakso

The Outotec Flash Smelting process is widely used in primary copper production. A layer of slag on top of matte (copper–iron sulphide melt) creates a barrier through which matte droplets descend. Droplets of different sizes settle through the layer at different rates, which increases possibility of copper losses as smaller matte droplets may be removed with the slag. In this work CFD-DEM (computational fluid dynamics – discrete element method) coupling was used to simulate matte droplets settling through the slag during slag tapping. Discrete droplets and slag flow were simulated with DEM and CFD, respectively. This new approach enables tracking and solving movement and interactions of individual droplets. User-defined models were created to take coalescence and reaction kinetics into account. Coalescence created larger droplets, while the reactions decreased droplet size and increased its density. Drag caused funnelling effect, which pulled droplets towards the centre line of the descending cluster. This research is the only study known by the present authors in modelling liquid-liquid systems with the CFD-DEM coupling. Simulating coalescence and chemical reactions for discrete droplets enables more realistic simulations. However, CFD- DEM simulations are computationally resource intensive already without additional models, so a full scale industrial settler modelling still waits for further increase in computer performance. INTRODUCTION Flash smelting is a method used in copper and nickel production. In the flash smelting process, oxidation of sulphides in a concentrate is used to release energy needed to smelt the feed. In the process, copper matte is formed. Matte has copper content in the range of 55 – 70% (Sridhar, Toguri, & Simeonov, 1997), the rest is mainly sulphur and iron but has still many other impurities (Taskinen, Seppälä, Laulumaa, & Poijärvi, 2001). Oxidized iron forms iron-silicate slag while SO2 is collected for acid production (Davenport & Partelpoeg, 2015). The Outotec flash smelting furnace (FSF) can be divided in four major component: concentrate burner, reaction shaft, settler and uptake. Concentrate, flux and oxygen enriched air are injected into the reactor through the concentrate burner. The mixture then reacts in the reaction shaft forming matte and slag, which are collected in the settler, while off-gases flow out of the reactor through uptake for heat and dust recovery, and SO2 collection for H2SO4 production. The matte and slag form separate layers due to immiscibility and density difference. Raw material feed is continuous, but the matte and the slag are tapped periodically. A flash smelting furnace is depicted in Figure 1.

Jan 1, 2019

By N. Sarmady, Mei Li, N. C. Parson, W. J. Poole

"The mechanical behaviour of AA6082 is a function of the extrusion conditions and in particular, the quench rate after extrusion. It is well known that precipitation of Mg-Si phases on grain boundaries during quenching can negatively affect the ductility of the alloy. In this study, AA6082 alloys containing 0.5 wt. % Mn and 0.15 wt. % Cr were direct chill (DC) cast, homogenized and then extruded to produce 3 mm x 42 mm strips. The microstructure in the as-extruded strips was unrecrystallized due to the Zener-Smith drag from the Mn/Cr dispersoids. It was shown that a solution treatment of 5 minutes at 560°C did not significantly affecting the as-extruded microstructure but if the as-extruded strip was cold rolled prior to heating, recrystallization occurred concurrently with the solution treatment. As such, 3 initial microstructures were produced, i.e. unrecrystallized and recrystallized with a grain size of 9 and 40 µm. After the solution treatment, controlled cooling experiments were conducted using the Gleeble 3500 thermomechanical simulator with cooling rates of 10, 25, 80°C/s as well as water quenched. The mechanical properties (e.g. yield stress, fracture stress and fracture strain) were determined from tensile tests for the different combinations of initial microstructure and cooling rate. The relationship between the quench rate and precipitation of Mg-Si phases on grain boundaries was examined by FEG-SEM. It was found that the yield stress decreased as the cooling rate decreased and that there was complex relationship between the fracture properties and the microstructure.INTRODUCTION As the automotive industry strives to reduce fuel consumption and CO2 emissions with the goal of reducing the environmental impact, there is a need for lighter vehicles. As a result, aluminum alloys are gaining popularity to replace steel parts as structural components. An exemplar of this is the Ford F-150 pickup truck which has an aluminum body and is ˜750 pounds lighter than the previous steel version of the vehicle. The structure includes a mix of aluminum sheet, extrusions and cast alloys. The current research is concerned with the performance of aluminum extrusions in applications such as side rails, crash tubes and other structural parts. These components experience a combination of bending, stretching and folding both during the forming of the part and in service, e.g. crash of a vehicle. There is a need to have detailed information on the influence of processing on final material performance, in particular the cooling rate after extrusion."

Jan 1, 2018

By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005

By J. D. Christian

WHEN mining development began in the Kirkland Lake camp, twenty-five years ago, there was very little information obtainable from surface showings as to the nature of the ore deposits. A length of almost a mile of the main 'break' lay under the south arm of the lake, and elsewhere most of the outcrops were covered with glacial drift. Shafts were sunk on ore-bodies of uncertain value, either on the outcrop of the veins or-because of the lake to the north-in the south or hanging-wall. In the second year of the camp's development, the Great War broke out and retarded progress for its duration. He would have been a real optimist who, in those early years, could have foreseen mining at depths of more than a mile.

Jan 1, 1939

By Li Chongyang, Liu Baolan, Jia Xiaolin, Li Suping

An Al/Al2O3 gradient coating applied on a heat-resistant stainless steel was prepared through a slurry process by using aluminum and ?-Al2O3 powders as the transition filler material, alpha alumina as the surface coating material, aluminum dihydrogen phosphate as the binder, and sodium molybdate as the corrosion inhibitor. The effects of heat treatment temperature, adhesive/filler ratio and ?-Al2O3 content on the bonding strength, microhardness and thermal shock resistance were investigated. The crystal phase and microstructure were characterized by XRD and SEM. The results indicated that the composition of the coating changed continuously from surface to coating-substrate interface. The coating could offer high bonding strength and good thermal shock resistance when heat treated at 700°C.

Jan 1, 2010

By C. Kuehmann, B. Tufts

QuesTek Innovations has applied its Materials by Design® methodology to computationally design a new ultra high-strength corrosion resistant steel. Ferriurn® S53 eliminates the need for toxic cadmium coatings currently used on conventional steels in landing gear systems. S53 has the strength of 300M steel, and corrosion resistance similar to 15-5PH stainless steel. S53's corrosion resistance improves stress corrosion cracking resistance and reduces susceptibility to hydrogen embrittlement, improving component reliability and providing an opportunity for extended overhaul and repair intervals. Ultimate tensile stress is 1965 to 2000MPa. S53 was designed to be mechanically equivalent to 300M, with the key addition of intrinsic corrosion resistance. Alloy design, microstructural characterization, and mechanical properties are discussed herein.

Jan 1, 2006

By C. Van Den Heuvel, C. B. Van Buuren

BIOX® has been successfully demonstrated over the past 2 decades for the recovery of gold from refractory sulphide concentrates. To date 12 successful BIOX® plants have been installed in 8 countries spanning 4 continents with the 13th installation currently nearing completion in the Philippines. In 2010 BIOMIN introduced the ASTER™ process for improved water balances in commercial BIOX® applications by supporting tightening environmental legislation on water usage and availability in both arid and tropical regions. Previously, a common challenge for BIOX® plants was the inability to recycle thiocyanate containing water due to the low tolerance of the organisms. ASTER™, a biological thiocyanate and cyanide destruction process, renders a non-toxic solution for re-use in BIOX®. Two commercial ASTER™ plants are in operation with the 3rd ASTER™ plant under construction in the Philippines. A 3rd BIOMIN technology, specifically developed for double refractory ores is available for implementation. The HiTeCC process has shown considerable success on ores where competition from disseminated carbon has rendered ineffective gold recoveries. Through HiTeCC, gold is desorbed from the carbonaceous matter by manipulating the ionic strength and temperature of conventionally treated CIL product. One Australian commercial plant utilises HiTeCC while a 2nd installation is set for commissioning 4th Quarter 2014. BIOMIN’s premier solutions for refractory gold processing are described herein.

Jan 1, 2014

By K. Adham, T. Buchholz

"Significant capacity increases to meet new production demands can often be fulfilled through debottlenecking of an existing production facility, rather than the more expensive option of building new plants and facing new environmental and infrastructure challenges. To achieve that goal, it is important to model and calculate the existing ultimate capacity of each processing plant area, and that of each key equipment sector within the plant areas. This paper describes a methodology of how process modeling tools can be used to simulate the processing steps, how to estimate their existing and ultimate capacities, and how to determine the sweet-spots (minimum cost points) for a plant expansion – leading to a road map of the subsequent debottlenecking project implementation.The debottlenecking technique is presented through a generic work-flow narrative which can be applied to different mineral processing studies, starting with establishment of heat-and-mass balances, drawing a bottleneck diagram, brainstorming capacity increase options, and preparing a cost-capacity curve. Hatch has successfully applied this technique to a number of plant capacity studies, with great benefits to our industrial clients.INTRODUCTIONWith the softening of the metals and minerals prices, and the escalated costs of building new processing plants, it is now economically more viable to improve and debottleneck the existing facilities, rather than build new ones. However, spending new money on old plants requires careful considerations, in order to identify the most economically advantageous incremental steps of improvement and the best potential returns on investment. Process modeling, hand in hand with plant measurements, can identify the best scenarios to balance the three aspects of plant capacity (nameplate, utilization and yield), both at the global and the individual system and subsystem levels."

Jan 1, 2016

By T. Yalcin

"This paper describes the development of a process flowsheet designed to provide high dewatering rates and to bring about savings in tailing disposal costs. The flowsheet comprises a hydrocyclone, a settling cone and a thickener arranged in closed circuit. The mill tailing, after pulp density adjustment, is fed to the hydrocyclone which yields two products. The underflow product is sent to the settling cone for further dewatering. The overflow product, together with the settling cone overflow, goes to the thickener which, with the aid of flocculants, gives a clear effluent and a relatively dilute underflow. The latter combines with the original mill tailing to form the hydrocyclone feed. Solids finally leave the system in the settling cone underflow which can reach pulp densities of up to 78%, making it suitable for direct disposal or for use as mine backfill.Some discussion is included for the selection and sizing of equipment required for this process. INTRODUCTIONDewatering is an essential process for the disposal of mill tailings which forms an added burden in milling practice, often with little or no return. It is, therefore, desirable to conduct this process as economically as possible. One way of reducing costs would be to increase the rate of dewatering so that savings can be made in the size of dewatering unit s which would lead to lower capital and operating expenditures.A common method of dewatering mill tailings is gravity sedimentation which is frequently carried out with the aid of flocculation. In most cases, flocculation greatly enhances the sedimentation process, but only until a pulp density of 50% to 55% is reached in the settled material.Centrifugal sedimentation in hydrocyclones can provide high pulp densities rapidly, but does not result in a clear effluent.This paper outlines a suitable combination of gravity and centrifugal sedimentations that results in an over-all high rate of dewatering. The system developed produces a material of high pulp density while at the same time giving clear effluent."

Jan 1, 1989

By A. I. Gorshkov, Y. A. Bogdanov, O. Y. Bogdanova

Abstract - Detailed crystal-chemical study of iron and manganese oxides and some other minerals from low-temperature hydrothermal deposits in a newly discovered inactive mound in the TAG hydrothermal field were used to determine the precipitation sequence of mineral phases during lowtemperature processes and their post-sedimentary transformations. Particles of primary sedimentary X-ray amorphous proto-ferrihydrite with high silica content were replaced in situ by nontronite, ferrihydrite, or goethite during alteration. Ferrihydrite is the only proto-hematite phase. The transformation of the iron minerals, related to change in the physicochemical environment, is an important characteristic of low-temperature hydrothermal processes. The occurrence of hydrogenetic Fe vernadite and Mn feroxyhyte in the uppermost part of low-temperature deposits and bottom sediments near the base of the mound is evidence for cessation of low-temperature hydrothermal processes. Among the investigated mineral phases, goethite, nontronite, and hematite are stable in reduced sediments only.

Jan 1, 1999

By I. Filzwieser, M. B. Hanel, A. Filzwieser

The paper describes the current density increase within the last 150 years. From the beginning in 1885 at 30 A/m² up to the highest used current densities nowadays at 420 A/m² towards future pathways were even 1000 A/m² can be achievable. A short tour through history will highlight the milestones of the process of electrolytic refining of copper. Besides the improvement of the existing technology, the biggest changes leading to higher possible current densities are linked to the introduction of the ISA stainless steel plates and the introduction of the parallel flow principle. Furthermore, the parameters influencing the limitations regarding current density and therefore the practical used current density as well as the influence from the chemical composition of the electrolyte is discussed. Finally, the possibility of further increasing the current densities by enhancing the relative movement between electrolyte and electrode will give an outlook about the future of the copper electrolysis process. INTRODUCTION The current density is the most important characteristic to describe the productivity of a copper refining electrolysis besides the characteristic number for the electrical efficiency. Over the last 150 years, current density has risen from a few amperes per square meter to over 400 A/m² without any significant change in the principle of electrolytic refining. This increase in current density is documented exemplary by the electrolysis of Montanwerke Brixlegg in Austria (Brixlegg, 1963, 2013). The very beginning of the technology of electrolytic refining of copper was first patented in England by James Elkington in 1865 and the first electrolytic copper refinery was built in Newark, New Jersey, in 1883 (Armstrong, 1999). The secondary smelter Montanwerke Brixlegg, Austria, has been operating an electrolysis plant since 1884. In 1988, the third "Mount Isa" electrolysis plant worldwide and the first in Europe was put into operation in Brixlegg. Since 2010, the so-called high-current electrolysis (parallel flow METTOP-BRX Technology) with a current density of approx. 400 A/m² has been operated in half of the electrolysis process.

Jan 1, 2019