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By D. M. Hausen

"Refractoriness in Carlin-type gold ores results mostly from fine locking of gold in pyrite, locking in various gangue phases, notably quartz, and a ""preg robbing"" condition attributed to organic carbon. All three conditions may occur in any given deposit, including Newmont &apos;s Carlin and Gold Quarry deposits in Nevada, where types of ref ractoriness occur locally in minor amounts.Measurements of specific gravity, water absorption and screen size distributions of gold in alteration rock types from Gold Quarry show transitional changes from siliceous cherts through decreasingly silicified and increasingly argillized siltstones.Low permeability of siliceous ores contributes to ""size dependent"" refractoriness in cyanidation test work. Colligative physical and chemical measurements demonstrate that silicified cherty ores are difficult to grind, poorly permeable, and less amenable to cyanidation. Refractoriness in pad or column leaching of coarsely crushed siliceous siltstones and cherts is shown to correlate with interrelated measurable mineralogic and physical parameters.IntroductionMetallurgical treatment of variably amenable and refractory types of gold ore may be guided by both analytical and mineralogic data on the interlocking of gold (microscopic an d sub- microscopic) in assorted gangue/sulphide phases. Most oxidized ores from the Carlin gold mine, north of Carlin, Nevada, are amenable to direct cyanidation. The permeability of most oxidized ores from Carlin coupled with the fine size of the gold < 1.5 um) yields rapid extractions and high recovery without fine grinding.Small portions of the Carlin ore body, and also the nearby Maggie Creek and Gold Quarry orebodies, are less amenable to cyanidation, and are classified as refractory. Refractory conditions may be attributed mostly to the association or interlocking of gold with pyrite and /or microcrystalline quartz or chert, and also by the adsorption of leached gold by deleterious forms of carbon, termed ""preg-robbing"" carbon. Each of these conditions are described and defined, with emphasis on a form of silica-locking, which has been referred to as "" size dependent"" refractoriness."

Jan 1, 1985

By R. E. Dye

IF gold mining is to assume, or it might be better said to resume, a place of &apos; importance in the national economy of this country following the present war, then one must accept the thesis that gold will maintain the place it has for many generations held in the minds of men as a substantial and lasting emblem of material wealth-a metal in exchange for which men have always been ready to give up the possession of their worldly goods. The thought bas been advanced by some that gold is not necessary as a basis for exchange, that it has no real value anyway and, therefore, the world would wake up some morning to find that no one wanted gold and that, over night, its possession bad in some way ceased to be desired. Holding an equally extreme view there are those who advance the idea that, following the war, gold will in some mysterious way enjoy a fantastic increase in value. Neither of these extreme views can be successfully supported. To presume that by legislation or by general agreement gold would be or could be, over night, dethroned to the position of common stone is wholly beyond the realm of any possibility. The thought that this could come to pass is advanced by, and is attractive to, only those peoples who do not have gold and do r:ot have the means of producing it. To believe that the fundamental value of gold will suddenly change is likewise fantastic. I refer to the fundamental value, not the dollar price, of gold, for it cannot be denied that, with the colossal war expenditures now being made and with the huge national debts which are being piled up, there is a possibility, indeed per-haps a likelihood, that the dollar price .of gold may be revised upward. For the purpose of this discussion, however, that possibility is irrelevant and need not be considered.

Jan 1, 1943

By R. E. Bou Serhal

Many miners are exposed to dangerously high levels of noise on a daily basis. Over the past 15 years, a continually increasing number of occupational hearing loss has been reported from the mining community in the United States, of which, more than 95% is attributed to prolonged noise exposure. Although the noise exposure levels may differ between coal miners and metal and non-metal miners, in the absence of noise control at the source, the solution is the same: use of personal hearing protection devices (HPD). While protecting the miners? hearing it is also essential to no longer hinder their ability to communicate. With access to an advanced HPD that is customized to the miners? ears we are able to combine these two requirements. Using an intra-aural instantly custom molded HPD miners are protected from high levels of noise. The HPD is equipped with wireless capabilities, and contains both a speaker and an In-Ear Microphone (IEM). Therefore, the miners? speech may be captured from inside the ear and transmitted to the remote listener. This IEM signal is relatively noise-free since it is isolated from the background noise. The IEM speech signal, however, is ?boomy? and is missing some high frequency content, making fricative consonants hard to understand. Nonetheless, the IEM speech signal is correlated with the natural speech signal and may be manipulated through statistical techniques to more closely resemble natural speech. By improving the intelligibility and quality of the IEM signal, numerous applications may be enabled. One use of the enhanced IEM signal will be for radio communication. Using wireless radio communication in a noisy mining environment is sometimes the only practical and affordable solution to allow communication between miners equipped with personal hearing protection devices. Traditionally, one of the weaknesses of such wireless radio communication lies in the lack of designating receivers: whether they are the intended receiver or not, all those carrying a radio receiver are subjected to the broadcasted signal. The current work will detail a new concept of a "radio-acoustical virtual environment" where the radio signal will only be received by miners within a given spatial range, such range depending on the user?s vocal effort as well as the ambient and perceived background noise levels.

Aug 1, 2013

By C. O. Swanson

"OUR INTEREST in estimates of world reserves of lead and zinc is focussed mainly on the information they give about the sufficiency of metal supplies for the future. However, we soon realize that the estimates can be interpreted in several different ways. Accordingly, it is necessary to have some under-standing of the elements represented by a compilation of world re-serves, and we will start by examining the accuracy of the estimates and what they attempt to measure.Variations in Estimates of the ReservesIf we study the estimates of world reserves that have been published in recent years, we note immenediately that they vary over a considerable range. For example, an article by Shea in 1947 gave world reserves as about 36 million tons of lead and 60 million tons of zinc. Shea did not in elude the United States but I have added to his totals the estimates made by the Bureau of Mines for that country in arriving at the foregoing figures. For approximately the same date, the American Zinc Institute and the Lead Industries Association reported world reserves as about 50 million tons of lead and 77 million tons of zinc. A comparison of the two sets of figures shows a mean variation of 30 per cent. For individual countries the difference between estimates can be even larger. A few years ago the estimate of Canada's reserves made by the United States Bureau of Mines was 7.4 million tons of lead and 14.0 million tons of zinc, while the Gordon Commission reported 1 O. 7 million tons of lead and 26.0 mil-lion tons of zinc. In this case the mean variation was 55 per cent."

Jan 1, 1960

By Masami Nakamoto

Controlled thermolysis of gold(I) thiolate complex, [C14H29(CH3)3N][Au(SC12H25)2], at 180 °C for 5 h under an N2 atmosphere produces novel gold nanoparticles passivated by alkyl groups derived from the precursor complex, the TEM photograph of which shows spherical particles with average diameter 26 nm. Since Brust et al. reported the two-phase reduction of AuCl4 - by NaBH4 to afford monodispersed gold nanoparticles passivated by alkanethiolate ligands (1), plenty of preparative investigations on gold nanoparticles (2,3) and its surface modification (3,4) have appeared, because of their potential applications in microelectronics (5). However, those preparative methods generally involve the reduction of AuCl4 - by reducing agent NaBH4 in the presence of suitable organic stabilizers such as alkanethiol (1-4), phosphane (5), quarternary ammonium salts (6), surfactants (7) or polymers (8). On the other hand, O?Brien et al. recently reported the preparation of organically capped gold nanoparticles at 190 °C, where tri-n-octylphosphine oxide and/or n-octadecylamine are used both as a reaction medium and as a passivating ligand (6), but this procedure also needs NaBH4 as reducing agent. Our strategy of novel preparative method of gold nanoparticles is the combination of reductive elimination of thiolate ligands and simultaneous attachment of organic moiety on the growing nuclei. Gold(I) thiolate complexes with ammonium cations were useful for our preparative method. We now report the controlled thermolysis of gold(I) thiolate complexes, [R(CH3)3N][Au(SC12H25)2] and [R(CH3)3N][Au(SC6H4-p-R?)2] (R= C14H29, C12H25; R?= C8H17, CH3), under an N2 atmosphere, where the powder of gold(I) thiolate complexes completely melts to afford the precursor liquid and then the liquid gradually decomposes. In spite of no use of reducing agent and solvent, reduction reaction is thermochemically induced to afford novel gold nanoparticles passivated by alkyl groups rather than by alkanethiolate ligands. Figure 1a shows a typical transmission electron microscopy (TEM) image of gold nanoparticles prepared by thermolysis of [C14H29(CH3)3N][Au(SC12H25)2] at 180 °C for 5 h, indicating a controlled growth of spherical gold nanoparticles. As shown in Fig. 1b, these spherical gold nanoparticles display the size distribution ranging from 5 to 50 nm. Although the particle size is larger than that of thiol-derivatized gold nanoparticles (less than 5 nm) prepared by NaBH4 reduction (1-3), the aggregation of gold nuclei is smoothly regulated and the growth of core gold is limited to be 26 nm in average diameter in spite of thermal procedure.

Oct 1, 2003

By P. Plante

Contaminated neutral drainage (CND) is characterized by the presence of metal concentrations above regulatory requirements at circumneutral pH in mine drainage. The generation of CND by tailings and waste rocks is a growing concern for the mining industry due to increasingly restrictive regulatory requirements. Difficulties in CND prediction arise from the low oxidation rates of sulfide minerals and from the metal retention potential within the wastes. In fact, sorption phenomena may induce an important delay in the development of CND. For now, it is not possible to adequately consider this delay using the prediction tools developed for acid-mine drainage, such as humidity cells, columns and lysimeters. This work aims to present the new approaches currently under study for CND prediction, particularly the use of a chelating agent in kinetic tests. The main challenge of CND prediction is to quantify the metal retention potential of mine wastes, especially when sorption phenomena are involved in metal retention. Three approaches are currently used to overcome this difficulty. Firstly, the sorption potential is estimated using batch sorption studies. The second approach consists of artificially saturating the sorption potential of the mine waste by contact with a contaminated leachate in sorption-enabling conditions until saturation of the retention potential. These approaches both require that the possible metals involved in CND are known (as well as their chemical speciation) prior to the tests, which require an exhaustive material characterization. Although the two methods enable a qualitative estimation of the retention potential of mine wastes, their results are difficult to scale up from the laboratory to the field since some important parameters are not taken into account. A third proposed approach consists of inhibiting metal sorption at the source using chelating agents. The hypothesis is that chelating the metals immediately upon their release from the oxidation of sulfide minerals will inhibit all geochemical interactions (sorption, complexation, secondary mineral precipitation, ion exchange, etc.) between the metal and its environment. The ideal chelating agent will inhibit geochemical interactions after metal release in the drainage waters without having any impact on the sulfide oxidation and acid neutralisation rates. These approaches were tested over a waste rock sample that is known to naturally generate CND after a few decades of weathering. Results show that kinetic testing (weathering cell, ± 70 g samples) using a chelating agent (EDTA) in the leaching water renders higher metal concentrations in the leachates than a control sample without EDTA, suggesting that sorption (and possibly other geochemical interactions) is inhibited. These results suggest that the combination of these approaches can be efficiently used for more precise CND prediction from mine wastes. Future work will be done using the chelating agent approach over larger scale tests such as columns (± 80 kg samples) and field cells (± 100 tons) in order to propose an integrated approach for CND prediction.

Aug 1, 2013

By C. O. Staples, J. G. Morrow

The application of cationic flotation to the upgrading of magnetic concentrates was investigated in the laboratory by both batch and continuous test procedures. It was found that the collection of coarse gangue particles with amine, heretofore considered a serious obstacle to this particular application of cationic flotation, is greatly enhanced by a drastic reduction in what might otherwise be considered normal impeller speed. Gangue flotation is in-dependent of variations in the rate of aeration. The collector and Crother additions and the impeller speed which favour the formation of a matte froth yield optimum results.

Jan 1, 1966

By E. E. N. Smith

"Uranium exploration by Eldorado prospectors north of Lake Athabasca began in late 1944 and resulted in initial discoveries in 1946 in the Beaverlodge region with mill production starting in early 1953. The operation was closed in mid-1982 having produced 21,457,947 kilograms U30 8 from the Eldorado FayVerna mine, Eldorado satellite operations and from other district producers on a custom basis.The Fay- Verna mine consists of pitchblende-brannerite orebodies spatially associated with both sides of a regional eastwest structure, the St. Louis Fault. The orebodies in the footwall (Fay) are elongate deposits of two types raking steeply to the southwest along the 50 degree south dip of the fault.One type consists of networks of fractures and veins filled with pitchblende, calcite and quartz in chlorite, epidote-altered mylonitized mica schists and amphibolites of the Middle Aphebian Tazin Group. The other type is comprised of fragments of mylonitized metasomatic quartz-feldspar granite of Late Middle Aphebian age cemented with a matrix of pitchblende, brannerite, calcite and some quartz. The vein networks lie en echelon in the footwall of the breccia ore bodies which, in part, are capped by the mud gouge of the St. Louis Fault; in other places, the breccia orebodies are overlain by basal conglomerates, grits and arkoses of the late Aphebian Martin Formation which itself immediately underlies the plane of the fault.Orebodies in the hanging wall (Verna) are a series of irregular, tabular deposits lying within a tightly overturned syncline of Tazin mica schists, amphibolites and siliceous mylonites. They consist of pitchblende, calcite-filled fractures grouped into zones and deposits displaying stratabound habits within individual rock types.Also described are several Eldorado satellite properties which were significant producers of uranium and which display complementary geology to that in the Fay- Verna mine.In general, uranium deposits in the Eldorado Beaverlodge region are closely related to minor structures associated with major faults. Uranium appears to be best concentrated where the rocks are well mylonitized and brecciated. Pitchblende fills networks of veins and fractures in metasediments and metavolcanics as well as matrix material cementing brecciated, mylonitized granite. All deposits in the Beaverlodge region lie in close proximity to the unconformity between the Martin Formation and the underlying Tazin Group."

Jan 1, 1986

By Emilie Williams

Introduction Mouska Mine, Doyon Division site Background and timeline Obstacles to standard paste delivery system Components of Mouska paste system Technical considerations Operational considerations Mouska Mine Underground gold mine 30 km east of Rouyn-Noranda, Quebec Part of Doyon Division, 100% owned by IAMGold Commercial production since 1991 Cumulative production over 850,000 oz Conventional mining until 2009 485 m shaft from surface 560 m internal shaft 500 tpd (ore and waste) Off-site milling Approximately 150 employees

Oct 1, 2010

By Himanshu Dehra

The pre-fabricated outdoor rooms are often utilised near the mines and construction sites for office purposes. The paper has presented modelling and simulation results of the integration of commercially available glass coated photovoltaic (PV) energy technology and solar ventilation technology into a pre-fabricated outdoor room. The pre-fabricated outdoor room has been setup at Concordia University, Montréal for full scale testing of the glass coated PV modules with solar air ventilation. The computer simulation model has been developed for PV modules installed on a double wall wooden frame in an outdoor room based on its preliminary field testing. The testing apparatus was a wooden frame assembly of double wall with solar air ventilation: two adjacent glass coated PV modules, air column and plywood board filled with polystyrene. The measurement data collected from various sensors were: solar intensity, ambient air temperature, room air temperature, electric power, surface temperatures of PV modules and plywood board, air velocities and air temperatures in the air column. The enhancement in the air velocity of the air column was achieved with an exhaust fan fixed in an outdoor room. The simulation model is used to perform the two dimensional energy analyses with applied one dimensional solution of steady state heat conduction equations. The simulation model is based on conjugate heat exchange paths with network boundary conditions of convection, radiation heat exchange and solar air ventilation heat transport. The model parameters are based on measured values of ambient air temperature, room air temperature, air velocity at outlet of air column in double wall, electric power and available solar intensity. The model has predicted fairly well energy performance of glass coated PV modules with solar air ventilation installed on a wooden frame. The model is also useful for predicting heating, ventilating and air-conditioning (HVAC) requirements for the pre-fabricated outdoor rooms.

May 1, 2007

By John D. Lupton

This paper will discuss the benefits and advantages of using 3D survey data in stope analysis. Obtaining detailed 3D survey data of underground mine progress and production is a challenge. It is almost impossible to ?see? around corners, underneath overhangs, or deep into dark, dusty, humid underground voids. Thus, valuable ore can remain permanently encased in backfill. Without the benefit of 3D survey data, underground mines have the difficult task of meeting grade quotas without the benefit of knowing exactly what has been mined. Lack of this data usually results in unfavorable month end Reconciliation factors, where grades must be adjusted to match grades assessed by the Mill.

Apr 1, 2005

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Shigeto Kuroiwa, Eri Takida, Tsuyoshi Hirajima, Masashi Yamane, Yuji Imaizumi, Mitsuru Sawada, Keiko Sasaki

Selective flotation of molybdenite and chalcopyrite using various oxidation treatments (i.e., ozone treatment, hydrogen peroxide, and Fenton-like reagent) was studied in this work. It was found that ozone treatment produced a depressing effect on both minerals, resulting in a lower separation of both minerals. On the other hand, oxidation treatment using hydrogen peroxide (H2O2) and Fenton-like reagent could deliver selective oxidation on chalcopyrite surface and depress its floatability. However, bench-scale copper- molybdenum (Cu-Mo) flotation tests show that oxidation treatment using H2O2 required a higher dosage of H2O2 and a longer treatment time in order to deliver comparable flotation results to that of conventional Cu- Mo flotation using NaHS treatment. On the contrary, Fenton-like reagent could deliver selective Cu-Mo flotation results comparable to that of NaHS treatment at a lower dosage of H2O2 and a shorter conditioning time. Contact angle measurements and X-ray photoelectron spectroscopy (XPS) analysis were employed to understand the depressing mechanism of these oxidation treatments. It was found that the chalcopyrite surface covered by various oxidation products that render the surface hydrophilic. Meanwhile, the surface of molybdenite was slightly oxidized, making the surface remained hydrophobic. INTRODUCTION Molybdenite (MoS2), the main source of molybdenum, is associated with copper sulfide minerals, mainly chalcopyrite (CuFeS2), as a trace mineral. Molybdenite is a valuable mineral and plays an important role in making the copper-molybdenum (Cu-Mo) processing plant economically viable (Laskowski, Castro, & Ramos, 2013). Therefore, it is important to recover molybdenite efficiently and effectively and separate it from copper minerals. Conventional separation of copper and molybdenum minerals is usually carried out in selective Cu- Mo flotation process using a copper depressant (i.e., sodium hydrosulfide (NaHS), Noke’s reagent, or cyanides) (Ansari & Pawlik, 2007; Bulatovic, 2007). However, this process still suffers due to imperfect molybdenum recovery. Moreover, the copper depressants use in this process are toxic and harmful to the environment. As alternative, various methods have been developed to replace these toxic and hazardous depressants, for example, by synthesizing new non-toxic or low-toxic depressants or by using various oxidation methods such as sodium hypochlorite in an alkaline medium, manganese dioxide, oxygen, and plasma pre-treatment (United States Patent Office Patent No. US 2559104 A, 1951; Patent No. US2238250 A, 1941; Barzyk, Malysa, & Pomianowski, 1981; Hirajima et al., 2014). However, the oxidation phenomenon and mechanisms are still not clear since detailed surface analyses have not done and the plasma pre-treatment method is facing technical issues for industrial scale application.

Jan 1, 2019

By J. A. Russell

"UNTIL the last few years, the collieries of the Dominion Coal Company, Limited, while highly mechanized as to the cutting and transportation of the coal, still relied on the hand-loading of coal from the seam onto face conveyors. In these circumstances it was possible to assure that no large proportion of extraneous materials would be loaded with the coal, and the product could be quite well cleaned for the market by screening and hand-picking.Within the past few years, however, the Company has introduced an intensive programme of mechanization which will result in the virtual elimination of hand-loading .of coal. It has been the experience of other producers that mechanical loading inevitably leads to a very large increase in the amount of impurities in the product. This is occasioned by the fact that, at least up to the present, all types of loading machines have relied on the coal being broken from the seam by under-cutting and shooting. In this operation, a certain amount of roof and pavement material inevitably becomes mixed with the coal and, since selective loading is impossible with a loading machine, all this foreign material is loaded out with the product."

Jan 1, 1952

By Y. Mitani, H. Ikemi, K. Kitamura, H. Honda

"Instead of carbon capture and geological storage (CCS) that does not rely on structural aquifers, injecting carbon dioxide into sedimentary rock deep underground has been considered. For advection velocity of the fluid is slow, the permeability of sedimentary rock deep underground is low. In order to perform the CCS on the low permeable sedimentary rock, it is necessary to clarify the behavior of long term storage properties of carbon dioxide (CO2).In this study, the permeability and storativity of CO2 injected into low permeable rock has been evaluated. The injection of supercritical CO2 has been conducted on the specimen of Ainoura sandstone (unit weight: 2.39 g/cm3, porosity: 11.9 %) saturated with water by using flow pump method. The experiment has been set up to reproduce the similar condition of deep underground reservoir under 20 MPa confining pressure, 10 MPa pore pressure, 35°C temperature and 3 µl/min CO2 injection rate. In order to prevent an increase in pore pressure, the boundary condition on the outlet side of specimen has been kept a constant pressure.As a result, it has been possible to observe step by step the change of the differential pressure between both ends of specimen. Furthermore, the relative permeability and specific storage of rock under supercritical CO2 injection has been examined by the theoretical analysis of flow pump permeability test incorporating Darcy’s law for two-phase flow. It is observed that CO2 has been transmitted gradually while CO2 stored in the rock. It is also clarified that residual water has existed in specimen after showing the constant differential pressure in the end of the experiment. Using the results of the experiment, 3D core-scale flow-simulation by using TOUGH2 has been conducted due to confirm the flow of fluid and CO2 distribution in the specimen. From the experimental results and analytical solution to them, permeability and storativity are identified, and simulation results support the validity of the experimental results."

Jan 1, 2015

By Jasmin Raymond

Ground source heat pumps are used to heat or cool building and heat water supply. Such heat pumps use the earth as a heat source or sink to efficiently provide or store thermal energy. For example, a ground source heat pump typically requires less then a third of the electric or fossil fuel energy of a conventional heater. Ground source heat pumps could therefore help reduce the energy consumption of active mines where low-grade geothermal resources are abundant. In most heat pumps, water or a water-antifreeze mixture having a temperature ranging from -6.5 to 43.5 °C is circulated through a heat exchanger at a rate of 0.000033 to 0.000067 m3/s (2 to 4 L/min) for each kilowatt of heating/cooling capacity. The groundwater that is continuously pumped to drain mines could be used to operate heat pumps. Water feeding a heat pump can alternatively circulate in a close loop network of pipes buried underground or installed in a surface water body. Retention water ponds, tailings and waste dumps commonly found at active mine sites could provide excellent environments to install the close loop system. Further research will help take advantage of the unexploited geothermal resources associated with actives mines.

May 1, 2007

By A. R. Pasieka, J. C. Wilson

"Compressed air still remains an essential source of power in underground hardrock mining. As a power medium it has a high convenience factor, although, in many cases, it is expensive to generate and maintain. Until new methods of breaking rock and/ or satisfactory alternatives to air-driven rock drills are developed, compressed air is indispensable. It is essential to utilize this source of power to a maximum by keeping all pneumatic tools supplied with air in adequate quantity and at optimum pressure.In search of the optimum operating air pressure, con-trolled drilling tests were undertaken at dynamic pressures ranging from 90 to 140 psi.Test results show the effect of increasing air pressure on: the performance of various jackleg drills at varying pressures, the life cost of drill steels and TC bits, and drilling efficiency at varying pressures. From the fore-going, a criterion is proposed for selecting efficient rock drills, and, also, optimum air pressure at each mine can be determined for its particular conditions."

Jan 1, 1966

By Neda Zangeneh

Production efficiency from low permeability gas shales require techniques to optimize hydraulic fracture completions. One completion strategy involves the simultaneous or near simultaneous hydraulic fracturing of multiple horizontal wells to maximize the fracture network area and stimulated reservoir volume. However, changes to the in-situ stress field caused by an earlier hydrofrac on subsequent hydraulic fractures are not accounted for in traditional hydrofrac design calculations. Presented here are the results from a set of transient, coupled hydro-mechanical simulations of a rock mass containing two wellbores using the discontinuum-based distinct-element method. The results demonstrate the influence of stress-shadows generated by a hydraulic fracture on the development of subsequent hydrofracs from an adjacent well. It is shown here that these interactions have the potential to change the size and effectiveness of the hydraulic fracture stimulation by changing the extent of the hydraulic fracture around the secondary well.

Jun 1, 2012

By S. Ivanova

The results presented in this paper show that the gold solution dilution is a key parameter to control the dispersion of gold on ?-Al2O3 the selected support. The variation of concentration leads to changes in pH which modify the nature of gold complexes from HAuCl4 formed in the solution. These complexes are presented. Some of them (AuCl3(OH)- and AuCl2(OH)2 -) react with the surface of alumina and give interesting interaction. AuCl2(OH)2 complex has been considered as an ideal complex because of the strong anchorage of a bidentate species on the alumina. This complex is formed mainly in a solution of gold with a concentration of 10-4 M giving a pH of 3.5-4.5. The nature of the anchorage and the amount of chlorine, has an influence upon the formation of Au-Cl bridges which modify the dispersion of the gold on alumina of the final catalyst as shown by TEM.

Oct 1, 2003

By J. E. Hawley

"IntroductionA STUDY of the trace elements in the ash •of coals from nine seams in the Sydney coalfield, Nova Scotia, was undertaken at the suggestion of Dr. W. A. Bell, Geological Survey of Canada, as a part of a larger study of these and other Nova Scotia coals being made by the Geological Survey and the Nova Scotia Department of Mines under the direction of Dr. P. A. Hacquebard.The main purpose of this investigation has been to •determine if a knowledge of the trace element distribution might be of assistance in the recognition of individual seams, the distinction of which is not always easy or positive in folded and faulted strata by ordinary stratigraphic and structural means.The study has been so conducted as to afford information on the variation of trace elements in individual petrographic intervals or divisions in each of the seams examined, intervals determined by Dr. Hacquebard on the basis of their banded ingredients, vitrain, clarain, durain, fusain, etc, as observed under the microscope in polished sections. The results, as well, indicate the trace element composition of the coals of the area as a whole, and quantitative data for fifteen elements are given, along with concentrations of thirteen other elements, stated in terms of intensity ratios. Data on distribution of germanium, though considered here along with other elements, are dealt with elsewhere*."

Jan 1, 1955

By André Chagnon, Yvon Héroux

"Résumé - Cette étude porte sur l&apos;altération de la matière organique et des argiles dans les boues carbonatés dévoniennes du faciès ""F"" de la Formation de Pine Point et ses équivalents stratigraphiques la Formation d&apos;Evie et l&apos;unité bitumineuse de la base de la Formation de Horn River. La matière organique se compose principalement de bitume solide et de quelques fragments de fossiles (organo­ clastes). La majorité des échantillons ne renferment que de l&apos;illite et des interstratifiées illite/smectite.Si on compare les températures d&apos;homogénéïsation (Th = l00°C) des inclusions fluides de la sphalérite et des dolomites associées à la minéralisation aux températures estimées à partir de la réflec­ tance de la collinite (84°C à ll7°C), l&apos;on ne peut pas conclure à la présence d&apos;une anomalie ther­ mique dans le district minier de Pine Point. De plus, la réflectance des organoclastes n&apos;est pas plus élevée dans le district minier de Pine Point que dans les localités plus éloignées des gîtes. L&apos;analyse des minéraux argileux conduit à la même conclusion : aucune anomalie thermique n&apos;est décelable dans les unités échantillonnées à l&apos;intérieur du district minier de Pine Point quelque soit l&apos;indicateur utilisé.La kaolinite et la matière organique altérée, affichant des valeurs anomales de sa réflectance, se trouve essentiellement en présence de soufre et de sulfures. Cela suggère une origine authigène de la kaolinite et une altération de la matière organique reliées au phénomènes de minéralisation.Abstract- The alteration of organic matter and clays is studied in the Devonian Pine Point Formation carbonate muds, ""F"" facies, and its lateral equivalents the Evie Formation and the biturninous unit at the base of the Horn River Formation. The organic matter is mainly composed of solid bitumen with few fossil fragments (organoclasts). Most samples contain only illite and mixed layer illite/smectite.If we compare the Th(l00°C) from fluid inclusions of sphalerite and dolomites associated with mineralization to the temperatures calculated from the reflectanœ (Ro) of the collinite (84°C to 117°C), we cannot detect a thermal anomaly in the Pine Point mining district. This result is based on the reflectance values of organoclasts from the mining district that are not higher than those reflectance values measured on organic matter (OM) away from the ore deposit. A similar conclusion is reached from the clay study: none of the parameters used allow us to identify a thermal anomaly in the samples from the mining district.The kaolinite and the altered OM showing anomalous Ro values mainly occur with sulfides and sulfur. This association suggests an authigenic origin for the kaolinite and an alteration of the OM due to the mineralization events."

Jan 1, 1994