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By W. E. Cockfield

This paper is not intended as an original contribution to this subject, but rather as a review of the main theories which are held with regard to placer deposits, with, of course, particular reference to the placers of British Columbia. The present interest in gold mining has, however, brought the subject of placers to the fore, and possibly a brief outline of the geology of such deposits will serve as a basis for discussion on the subject. In Canada, the most valuable of our placers are deposits of gold, and consequently the discussion will centre largely on placer-gold deposits. The same principles apply, of course, to placer deposits of other metals. The Origin of Placer Deposits As a starting point, the idea which is prevailingly held is that placer or alluvial gold is detrital in origin, that is to say, the gold originally existed in veins, lodes, or disseminations in the country rock of the regions in which the placer deposits are now found, and that, through the various erosive forces of nature, it was liberated from those veins or lodes and concentrated in the form in which we now find it. 1 have not time to go thoroughly into the proof of this, but the lines of evidence are many. If we take the Cariboo district as a typical example, Johnston and Uglow(l) have shown, first of all, that the placer and vein gold are identical in character. Crystals occur both in the placers and in the lodes, but the crystals in the placers are nearly always slightly worn, indicating transportation.

Jan 1, 1932

By M. Hekmati1

SAG/AG mills have been most common choice in grinding circuits last decades. In the most cases, at the discharge of SAG/AG mills, a trommel screen is used that is equipped with baffles to provide appropriate residence time and improve separation efficiency. Using baffles, with the resultant maintenance requirements could lead to decrease in mill availability. In this research, an innovation in the structure of baffles of a trommel is presented. The results show that using new baffles led to 67% decrease in SAG mill downtime due to problems of baffles and 80% decrease in fine particles on recycle conveyor.

Jan 1, 2012

By J. R. Dinn

On the afternoon of Saturday, June 23rd last; there was an unusual occurrence at the surface plant of the Dominion Coal Company's Caledorria mine, Glace Bay, which operates on the Phalen seam, here lying at a depth of 170 feet from the surface. On that day, the writer, who was attending a business conference in the General Office about a mile distant from the Colliery, received a telephone call to the effect that there was a strong odour of gasoline or kerosene in the wash-house and lamp-house of the Colliery, and that the attendants in both the wash-house and the lamp-house had become ill and had had to be sent home. Instructions were given at once to cut off the electric current, and to close all doors to prevent access to the building. When the writer arrived at the plant and questioned the workmen, he was led to the belief that the gasoline tank in the lamp-house (used in connection with flame safety lamps) had leaked and that the gas, having volatilized, had displaced sufficient oxygen to cause the trouble. Emphasis was being placed on the kerosene, or, as some said, the gasoline, odour. In the lamp-house, there is a small shuttered window which opens on a corridor. Here the workmen receive their lamps from the lamp attendant. An examiner, with a flame safety-lamp, proceeded to test the atmosphere within the building by passing his lamp through the open window, since, if the trouble was due to volatilized gasoline, a gas cap would be shown on the flame of the safety-lamp. After holding the lamp for a few seconds inside of the window, he withdrew it and remarked, "There's no gas cap" . Almost immediately the lamp fell from his hand and he dropped unconscious to the floor of the corridor. The writer, who was standing beside him, felt no ill effects and removed him at once from the corridor. Steps were immediately taken to revive him ( artificial respiration) , and in about ten minutes he became conscious and was breathing naturally. In making the examination, his head was not inside the window, but in line with the frame of it. It was apparent that some gas more deadly than the hydrocarbons from gasoline was present.

Jan 1, 1934

By Patrick Fantin

Mining ? The Past Safety Not a priority; Health Not a priority; Energy Manual Labour; Horsepower? Literally. Financially Robust For the Owner?s; Mining ? The Future Safety Zero Harm Health Understanding and elimination of Industrial Disease Energy Efficient use of energy through technology. Full value of renewable energy. Financially Robust Continually build shareholder value through optimum CAPEX/OPEX.

May 1, 2013

By Benoît Plante

La mine Tio (QIT Fer et Titane Inc.) exploite à ciel ouvert un gisement d?ilménite massive depuis 1950, générant jusqu?à maintenant plus de 70 Mt de roches stériles potentiellement génératrices de drainage neutre contaminé (DNC), dont une partie est submergée dans le lac Petitpas, au nord de la mine. Si généralement l?ennoiement des rejets miniers a un effet bénéfique pour limiter la contamination des eaux, cela reste à prouver pour ce qui est des stériles générateurs de DNC. Des essais en réservoirs ont été réalisés afin d?évaluer la réactivité de trois différents types de stériles submergés, qui ont été choisis en fonction de leur teneur en ilménite. Afin d?évaluer l?impact de la matière organique sur la réactivité des stériles submergés, chaque type de stérile est étudié en immersion simple ainsi que combinée à des sédiments prélevés au lac Allard, à proximité de la mine, d?où l?eau utilisée dans les essais a aussi été prélevée. L?évolution des teneurs en Ca, Mg, Si et Ni durant les 8 premiers mois d?étude démontrent que les stériles immergés sont réactifs, mais l?impact de la matière organique demeure pour l?instant difficile à préciser. Tank tests on Tio mine waste rock The Tio mine (QIT Iron and Titanium Inc.) exploits a massive ilmenite ore as an open pit since 1950, producing over 70Mt of potentially contaminated neutral drainage (CND)-generating waste rocks. While the underwater disposal of mine wastes generally show a beneficial effect on water contamination, this method still needs to be approved for CND-generating waste rocks. Tank tests were realized in order to evaluate the reactivity in underwater conditions of 3 different waste rock types, chosen with regards to their ilmenite content. In order to evaluate the impact of organic matter on the reactivity of underwater waste rock, each waste rock type was studied in simple immersion and in combination with sediments sampled at Allard lake, located near the mine, where the water for the tests was also sampled. The evolution of Ca, Mg, Si and Ni during the 8 first months of testing show that the waste rocks are reactive underwater, but the impact of the organic matter is till hard to define.

Nov 1, 2008

By A. -M. Lafront

The corrosion resistance of die-cast and freely-solidified and electromagnetically-stirred thixocast AZ91D alloy has been studied using electrochemical noise technique in a 0.05M NaCI solution at pH 6.1 and 25°C. Specimens polished at different depths were immersed for a period of 75 min in order to assess the influence of the microstructure on corrosion kinetics and morphology. At depths between 10 and 50 µm (skin), all specimens showed general non-uniform corrosion with the lowest corrosion resistance. Between 100 and 200 µmn (interior skin), the observed corrosion was accompanied by superficial undefined pits due to metastable pitting. The corrosion form for 100-200 µm gave the best corrosion resistance. Stable pitting corrosion was observed beyond 400 µm deep on the bulk specimens. The skin of all thixocast specimens prepared billets showed a more corroded surface than that of die-cast. The interior skin as well as the bulk specimens showed better performance than that of the die-cast specimens.

Jan 1, 2007

In several European countries, including Russia, it has become economically attractive to utilize peat as a fuel for power generation, the production of metallurgical coke, the production of fuel briquettes for the domestic market and low-Btu gas. Although the economic base and availability of energy supplies in Europe is much different than it is in Canada, regional economics here may warrant the development of peat as an alternative source of energy. Canadian peatlands cover several thousands of square miles and have historically been considered as waste land. Now, with the increasing costs of other energy sources, it is apparent that fuel peat should be re-evaluated as a potential energy resource. A nation-wide inventory of peat deposits has been prepared and reserves evaluated for some of these areas where field surveys have been carried out. The paper describes alternative mining methods developed to meet some of the various conditions encountered on virgin peatland . These mining techniques are generally based on current peat technology exercised in other parts of the world and would be applicable in some of the peat regions of Canada. Cost estimates have been prepared for peat production in regions of Canada, and the socio-economic aspects of a large-scale fuel peat operation are discussed. Several potential utilization schemes have been described, with particular emphasis on electric power generation. The paper makes recommendations for steps to be taken in the development of a fuel peat industry in Canada.

Jan 1, 1978

By P. Chryssanthakis

"The aim of this study is to give a better understanding for the behaviour of the composite material RRS and the synergy effect of its components while an excavation face advances during tunneling. The lower part of the Q-system scale (i.e. Q-values of 0.4 or less for a tunnel span of 10 m) is commonly used for tunnel applications in softer rock formations. This is implied in the updated Q-chart, where the dimensioning of rock support by using Reinforced Ribs of Shotcrete (RRS) comprises the use of fiber reinforced shotcrete, S(fr), rock bolts and shotcreted beams reinforced with steel rebars. The newest part of the lower part of the Q-chart gives more information on required support compared to older Q-system versions. The RRS can be described as a three part composite material with the 3rd component being the reinforced concrete beam (with no fibers) and with steel rebars that are placed in groups and sprayed with pneumatically applied shotcrete in layers. The RRS usually have a total thickness varying between 0.20 and 0.50 m and a width between 0.25 and 0.60 m respectively. They are placed at different distances along the tunnel axis depending on the rock mass quality.In this study, an effort has been made to simulate RRS in a numerical code and to study its behaviour in a real case study. A double tube, triple lane tunnel in weathered tuff has been chosen as reference material for testing RRS under changing load. This was done by writing a FISH subroutine which is implemented in the discontinuous numerical code Universal Distinct Element Code (UDEC) that takes into account the characteristics of the reinforced beam (height, width, number of steel rebars, and spacing) in the calculation process. A rather extensive parametric study has been run by using the same key input rock mass parameters and in situ stresses (?H/?v = 0.5), and changing only the RRS key input parameters in order to simulate the changing loads during the face excavation process in tunneling. The critical part of this numerical modelling work that is under investigation in this study, is the period just after the excavation: i.e 4 hours; 16 hours after excavation; and finally after the complete curing (28 days) of the cement based components. The RRS are installed in three consecutive steps as follows: a) the application of S(fr) on the rock surface in order to even it up for the RRS application; b) radial bolting; and c) installation of the reinforcing steel rebars, that form the reinforced beam.The results show that: a) the S(fr) is almost overloaded in the first 4 hours after application in both tunnels; b) on the S(fr) and steel rebars, the stresses, axial and shear loads, as well as moments are decreasing after 16 hours and 28 days; and c) the bolts loads are increasing with time. The observed reduction in stresses and loads in both the S(fr) and reinforced beam is surprising. A possible explanation is that tunnel arches are self-supported to a lesser extent as time progresses due to redistribution of stresses in the nearby rock mass through the radial bolts. The loads in radial bolts are increasing by almost 25%. This can be seen from the overall results as we observe an increase in maximum principal stresses, displacements, shear displacements along joints and hydraulic apertures compared to tunnel baseline that has no support of any kind."

Jan 1, 2015

By Lan Vu

"The Ferderber mine consists of a series of Archean gold-bearing quartz lenses within a shear zone that crosscuts the central part of the quartz diorite Bourlamaque batholith. This zone has sharp contacts with the enclosing quartz diorite, and on average strikes N70E and dips 65SE. Along the contact with the shear zone, the quartz diorite is chloritized, sericitized and carbonatized. The chlorite schist within the zone is probably derived from mafic dykes.The geometry and distribution of structural features within the Ferderber shear zone suggest a long history of repeated movements. The majority of gold-bearing lenses were first emplaced during a probable early period of brittle shear which resulted from strike-slip movement. They were then folded and pulled into boudins by a later episode of reverse movement that accompanied ductile shear. New mineralized veins were emplaced in the shear zone and deformed at this time.Mineralized veins are dominated by quartz, carbonates, tourmaline and micas. Gold is more common within pyrite where chalcopyrite is abundant and is generally in contact with both pyrite and chalcopyrite at ""triple point"" grain junctions. This intimate association suggests that copper may have played an important role in gold deposition.Recent exploration has shown that the Bourlamaque batholith is cut by many parallel or en echelon shear zones. Study of ""Landsat"" and aerial photographs has indicated a number of linear structures striking ENE-WSW and ESE-WNW which form a conjugate system. The intersection of these two structural trends presents an interesting exploration target."

Jan 1, 1990

By J. Shahabpour

"Many porphyry copper deposits of the Kerman copper province in central Iran are associated with a consistent structurally con-trolled main drainage pattern, which is shown in this paper to be a useful regional prospecting tool in the search for new deposits. The main drainage trends also generally allow the distiction of high-grade (>0.2% Cu) from low-grade (<0.2% Cu) deposits. Topographic maps1:50 000 or geologic maps 1:100 000 have been found suitable for identification of promising drainages.IntroductionTrends of the main drainage systems transecting the high-grade porphyry copper deposits of the Kerman Region in Iran coincide with Quaternary age regional faults and fractures. Observation of such drainage trends can expedite regional evaluation prior to field examination. Thirty deposits located in the Kerman Region (Fig. 1) have been studied to identify common features that can be used for exploration purposes, especially for the first stage of regional exploration. A variety of field criteria are available for subsequent rapid field checking prior to trenching and more costly methods such as drilling, etc.Characteristic geomorphic features have been considered as aids in mineral exploration by many authors (e.g., Faniran, 1971; Piotrovski and Lubkashov, 1976; Verstappen, 1983). Clark et al. (1967) indicated the relationship between geomorphology and the supergene enrichment of copper in Atacama Desert, Chile, and correlated three periods of supergene enrichment with three periods of pediment disection. Seeland (1978) used fluvial drainage patterns for uranium and hydrocarbon exploration in the Wind River basin, Wyoming. Postolenko and Konopleva (1973) used the reconstruction of ancient valley systems for exploration of gold placers"

Jan 1, 1996

By D. Royston

In SAG mills fed with a variety of ore types, hard packing between the shell lifters can come and go depending on rock type and rock size distribution and the presence of a binder. Packing can appear in all sizes of SAG mills, and can be tenacious. High ball impact forces (depending on ball size) in larger mills may compact and encourage packing. Packing can have a negative impact on milling performance and a change in shell liner design may be required to remove it. However shell liner design changes need to be managed with care to ensure liner reliability. In smaller mills control of packing can extend shell plate wear-life and may help to maintain milling performance in fixed-speed mills through the liner wear-cycle.

Jan 1, 2012

Background ArcelorMittal?s (formerly QCM?s) Port Cartier iron ore pelletization operations 2 side-by-side induration furnaces each producing 578 t/h of cured pellets Firing No. 6 fuel oil and coke breeze (in bed) Very large heat losses to be addressed primarily by gas recirculation

May 1, 2011

By S. Litke

Elemental sulfur was stockpiled at the Mount Polley Mine for use as a source of sulfuric acid as part of research into leaching copper from oxide ores, but the project did not proceed beyond an initial pilot- scale evaluation. Since placement, the sulfur has oxidized and some sulfuric acid leached into the underlying rock. The reaction of the acid with these underlying materials has been studied as part of an evaluation of the effects of leachate from the pile. The rock underneath the sulfur pile is composed dominantly of primary and secondary alumino-silicates with less than 1% carbonate (calcite) and iron sulfide (pyrite). In its unaltered condition, the rock is classified as non-acid generating. Conceptually, it was expected the sulfuric acid would be neutralized by the rock to varying degrees resulting in a series of pH-controlled weathering fronts progressing from leached near the contact with the sulfur pile (pH <3), to active neutralization by silicates (pH 4–5), to active neutralization by carbonates (pH >7). The rocks underneath the pile were sampled to determine the extent to which the rocks had reacted and their long-term stability after removal of the acid source. INTRODUCTION When rock is blasted and excavated to facilitate mining ore, it is typically placed and stored on the surface in piles. The resulting drainage may have a neutral to basic pH (i.e., non-acidic drainage) or a low pH (i.e., acid rock drainage, ARD) depending on the mineralogy of the rock being stored in the piles. Acid- base accounting (ABA) can be used to characterise the two types of rock: potentially acidic drainage generating (PAG) and not potentially acidic drainage generating (NAG) (Price, 2009). According to Price (2009), NAG is defined as having an excess of neutralization potential (NP) in the rock in the form of calcium carbonate-like minerals when compared to acid potential (AP), i.e., a Neutralization Potential Ratio (NP/AP = NPR) greater than 2.0, whereas PAG is classified as having an excess of AP (i.e., an NPR less than 1.0). This is a conservative estimate and may be slightly modified depending on the mineralogy at specific mine sites. Rock with an NPR of 1–2 is also capable of generating acid (Price, 2009) and, depending on the mineralogy, may also be classified as PAG. Drainage from PAG material can generate acid immediately, or many years after it has been exposed to surface conditions. Disposal techniques depend on the category (i.e., NAG or PAG) and reactivity of the rock stored in the piles.

Jan 1, 2019

By J. A. Brusset

Introduction I am indebted for most of the information in this paper to Mr. P. S. Lea, Deputy Chief Inspector of Mines of Great Britain, and Mr. A. E. Crook, Engineering Inspector of Mines, Ministry of Fuel and Power. Other coal-mining men in Canada may be as surprised as I was to learn that there are twenty-five Diesel locomotives in service underground in British gassy coal mines. Many more are in use underground in non-gassy coal mines and in metal mines. Approval has been granted for an additional fifty flame-proof locomotives to be used in gassy mines, and these should be in operation by the end of 1946, or as soon as manufacturing facilities permit.

Jan 1, 1946

By Michael L. Free

The hydrometallurgy curriculum for undergraduate students at the University of Utah has evolved to contain a variety of tools to help students understand and apply hydrometallurgy in a context that has industrial relevance. In order for students to perform as engineers in an industrial hydrometallurgy setting, they need to understand thermodynamic and kinetic fundamentals and be able to apply these fundamentals to extraction, concentration, and recovery applications. Students must also understand related environmental, economic, and assessment issues in hydrometallurgy and be able to work with others. In order to meet these needs, the hydrometallurgy curriculum includes a variety of relevant subject information, on-line resources, laboratory experiences, and team work opportunities to help prepare students for careers involving hydrometallurgy. The development and use of these resources will be discussed in this paper.

Jan 1, 2014

By Claude Hubert, Alex C. Brown, Michel Richard, Rejean Sirois

"The Pierre Beauchemin gold deposit, situated 15 km NW of Rouyn-Noranda, produces an average of 1050 tonnes of ore a day. Reserves are 1.2 Mt grading 5.6 g/t Au. The deposit, located in a shear zone within the Flavrianpluton, in the Blake River Group, is hosted by four major rock types: meta-trondhjemite, meta-tonalite, hybrid rocks and meta-diorite (the prefu; ""meta-"" is omitted thereafter). The trondhjemite, tonalite, and metamorphic hybrid rocks are spatially distributed as a series of sub-horizontal tabular sills that form a genetically related group. Early fractures that permitted either the emplacement of pre-diorite felsic dikes or the formation of a visible alteration caused by early fluid circulation might have been developed in response to initial strain created during regional deformation. These fractures were precursors to the emplacement of diorite and the development of major shear planes. Sub-horizontal north-trending en échelon diorite lenses are observed at the mine. Together, these diorite lenses constitute larger scale diorite zones which are observed at the scale of the pluton. The diorite zones are interpreted as evidence of an episode of sub-vertical extension sustained by the layered trondhjemite, tonalite and hybrid system. The anisotropy created by the less competent sub-horizontal en échelon diorite was an important factor. In shear zone development and subsequent mineralization. The tonalite and diorite accommodated further defomation and developed the main N030°/40° ESE shears along with the spatially associated N060°/50°-60° SSE, and the N000°/10°-40° E shear zones. The N000° shears are interpreted as refracted or deflected equivalents of the N030° shears. The combined shears compose the Eldrich shear system which trends approximately N030°/40° ESE and has had a general reverse movement with a minor sinistral component.Gold mineralization occurs in all four major rock types as en échelon sigmoidal shaped lenses associated with the major N030° deformation system. The distribution of ore lenses can be divided into two categories: The first category occupies sub-horizontal diorite zones. The lenses trend N-S, dip 100 40° E, and are associated with shear zones, sub-horizontal fractures or tonalite-diorite contact planes. The second category of lenses is found in felsic granitic rocks; the lenses trend either N0300!40°ESE or N060°/50°-60° SSE. Local hydraulic breccia zones are observed near ore zones occupying felsic granitic rocks. These breccias may have resulted from high fluid pressures brought upon by confinement as a result of impermeable zones in an anisotropic tonalite-diorite system."

Jan 1, 1990

By S. S. Teal, W. W. Weber

"AS THE TITLE implies, this paper will deal with the unusual rather than the standard practices as employed . at the property of North Rankin Nickel Mines, Limited. Fortunately •the mining, with the exception of permafrost conditions, and the milling practices, are the normal approaches dictated by the size, type, and character of the orebody. The unusual aspects are linked directly or indirectly to the isolated location and are •principally ancillary requirements or services covering a broad range from climate to supplies and from finance to entertainment. It is our intent to cover the more salient points of interest together with a brief description of the general operation.To understand the primary motivation of the mine, it must be made clear that North Rankin was conceived as a foothold in the Canadian North, that region embracing 40 per cent of the Dominion which ex-tends north of the commercial tree-line and which includes nearly 50 per cent of the Precambrian Shield, our mainstay of Canadian mining. Secondly, this project was born in an atmosphere of premium sales in the nickel markets, assuring a rapid pay-back of the heavy •capital expenditures. And finally, it has •been coddled through the stark reality of a competitive metal market with the hope and trust that the experiences and achievements will lead over the bill to a bigger and better mine in this virgin territory. This is the briefest story of the mine's history, but it pays tribute to the many people who, in thirty years since .discovery, have championed this project."

Jan 1, 1959

By A. Manouchehrian, M. Cai

"Rockburst, which often occurs around underground openings in highly stressed hard rocks, is a sudden and violent unstable rock failure and is associated with energy release. Rockburst is very dangerous to workers and mining equipment, and it has been a major concern for deep underground construction and mining. Before excavation, rocks are loaded under a true-triaxial condition. Upon excavation, the rocks at the excavation boundaries are loaded in the maximum principal stress direction and unloaded in the minimum principal stress direction and this provides a necessary condition for unstable rock failure to occur. Understanding rock behavior under true-triaxial unloading condition is critical for developing measures to control unstable rock failure in underground construction.In this article, an explicit FEM tool is used to simulate rock behavior under true-triaxial unloading condition, with a focus on analyzing stable and unstable failure and the released energy during failure. Firstly, a uniaxial compression test was simulated. The results indicated that the adopted numerical tool was able to simulate stable and unstable failure by varying the Loading System Stiffness (LSS). In this research, Loading System Reaction Intensity (LSRI) was proposed as an indicator to identify stable and unstable failure. Secondly, unstable rock failure under true-triaxial unloading condition was simulated. A rock specimen was loaded in three directions; the lateral pressures (s3 and s2) were kept constant and the vertical stress (s1) was increased to a pre-defined stress. The specimen was suddenly unloaded in the minimum principal stress direction (s3) and loading in the s1 direction was continued until failure occurred. Different LSS values were considered and the results showed that the LSS influenced the failure mode; a soft loading system resulted in more violent failure and released more energy than that in a stiff loading system. The influence of specimen height to width ratio on rock failure was also investigated. It was found that failure in taller specimens was more violent than that in shorter specimens. Insights gained from the simulation are useful for better understanding of the influencing factors on the released kinetic energy during unstable rock failure and to find means to control rockburst damage in engineering practice."

Jan 1, 2015

By S. S. Yuan, Q. Z. Zhu, J. F. Shao

"This paper aims at enriching a homogenization-based anisotropic damage model for hard rocks under complex loading. A new damage criterion is proposed to capture material strain softening. Within the framework of irreversible thermodynamics, we are particularly concerned with two strongly coupled dissipative mechanisms: frictional sliding and damage by microcracking, which usually take place at cracks within cohesive geomaterials under compression. Focusing on the representative elementary volume containing multiple crack families, the free enthalpy of the matrix-cracks system is obtained. Importantly, a back-stress term is involved in the local stress applied to microcracks. This back stress plays the hardening/softening role in the friction criterion which is formulated at local scale. Strain hardening owns to the accumulation of frictional shearing and dilatancy while strain softening is caused by crack growth. The multiscale damage model is used to simulate laboratory tests on the Westerly granite under true triaxial compressions. INTRODUCTIONWhen subjected to compressive loads, hard rocks present nonlinear mechanical behaviors and induced material anisotropies. In that process, two main dissipative mechanisms have been largely identified: damage by crack growth and frictional sliding along closed crack faces, which are usually strongly coupled to each other on crack scale. Theoretical investigations have shown that the damagefriction coupling analyses allow explaining a large number of experimental phenomena involved in brittle or quasi-brittle materials. Concerning constitutive modeling, the standard Eshelby’s solution-based homogenization procedure for heterogeneous materials was recently applied successfully to describing the mechanical and poromechanical behaviors of cracked frictional solids."

Jan 1, 2015

By R. Lodha, C. Oprea, G. Oprea, H. Zargar, T. Troczynski

"The basic refractories used in non-ferrous industry contain chrome ore for improving the thermal shock resistance, thus reducing the penetration of molten metal and fayalite-type slags into the lining. The current study aims to replace chrome ore with Me4+ ions along with Fe3+ ions in order to form MgO-Al2O3- FeOx-Me4+O2 based complex spinel systems that could perform similar to the complex chromia-bearing spinel in the magnesia-chrome refractories. This system allows for lower temperatures of synthesis and sintering. In our study, compositions with 60% MgO were fired below 1500°C and resulted in complete formation of complex spinel, and open porosity less than 5%. The in-situ formation of the complex spinel from the fine mix of oxides in the MgO-Al2O3-FeOx-Me4+O2 system offers a suitable alternative of binding system to produce basic refractories at lower temperatures and of similar physical and mechanical properties with magnesia-chrome bricks fired above 1750ºC. INTRODUCTIONThe synthesis of magnesium aluminate spinel (MgAl2O4) (Maschio, Fabbri, & Fiori, 1988) or magnesium chromate spinel (MgCr2O4) from their respective oxides is diffusion controlled resulting in a sluggish reaction even at high temperatures. For instance, the diffusion of Mg2+ and Al3+ ions in the intermediate spinel layer during reaction is slower than the diffusion of Mg2+ in corundum and Al3+ in periclase. The interfacial layer of spinel formed during the reaction increases the diffusion path for the spinel forming cations. This accompanied by ~8% volume expansion retards further reaction resulting in incomplete spinel forming reaction during sintering and hence densification during the reaction cannot be achieved. In order to assess sintering studies with fine particulate oxides that would result in a lower diffusion path, a mechanical mixture of the hydroxides of aluminium and magnesium calcined at 1400ºC to 1600ºC for 1 hour does not result in complete spinel formation (Sarkar, Das, & Banerjee, 2003), which indicates that reaction sintering of stoichiometric magnesium aluminate spinel is retarded by initial reaction forming the interfacial spinel layer. The basic bricks used as linings in non-ferrous pyro-metallurgical convertors are manufactured using magnesia and chrome ore, the sintering of which produce spinel solid solution. This solid solution is a mix of both normal and inverse spinel structures that sinters at temperatures in excess of 1800ºC in air."

Jan 1, 2012