Search Documents

By Jing Chai

The Cenozoic unconsolidated strata with the thickness of 100 to 240m in the east area of China are composed of clay, sandy clay and hardpan, etc. Numerous shafts of the coal mines in these areas have been damaged to various degrees since 1987, with the main reason for this being the subsidence of the super-thick unconsolidated strata. To prevent the continuing settlement deformation of unconsolidated strata caused by groundwater removal, long-term water injection through multiple boreholes controlled the settlement deformation of unconsolidated strata. A new type of fiber Bragg grating (FBG) sensing system was successfully used for real-time strain monitoring of the unconsolidated strata during water injection at a coal mine in China. A mathematical model for the compression settlement induced strain calculation is proposed which can assist understanding of the effect of water injection on the ground. With the increase in water injection, the unconsolidated strata compressed state was improved by the transition of the stress state from compressive to tensile stress. The wavelength change of fiber Bragg grating sensors corresponded with the trend of the water level in the same strata. Engineering practice indicates that these sensors can normally, safely and reliably survive conditions associated with hydrous unconsolidated strata. The FBG sensing can be used for continuous lifetime monitoring of the system, starting with real-time monitoring during low-pressure water injection process of multi-borehole. The results will give important guidance for water injection and mastering stratum subsidence.

Aug 1, 2013

By R. ZapataN.

"In the following report, Altonorte Smelter owned by Xstrata will explain its experience with its denominated furnace called ""Continuous Altonorte Reactor"" since started up in March 2002. The Reactor is the main and only smelting furnace since the operation of Reverb Furnace was stopped (15 days after the start up of the Reactor) and it can be operate with dry concentrate for injection by tuyere and wet concentrated via Garr Gun when the injection system fails. From the started up of the Reactor, three operational campaigns have been carried out where in each one they have been increased their smelting throughput and availability. The flexibility reached by the technology bath smelting has allowed a high level of smelting of concentrate and revert materials. The high availability of the Reactor and overcoming problems that were considered of high complexity like the extraction of white metal and slag, refractory campaign, etc. has allowed the Altonorte smelter to project to smelting 1,200,000 tonnes per year with its only Reactor in next year."

Jan 1, 2007

By Liu Liu

In the recent 10 years the rapid development of Chinese steel industry has attracted the attention of the world. The technological progress of converter steelmaking has played an important role in this process. First of all, slag splashing has been extensively adopted by Chinese steel companies in various sizes of converters from largest to smallest ones, and even including those using special hot metal containing V and Ti. Remarkable metallurgical results have been achieved. Up to now the average converter campaign life has reached nearly 10,000 heats, and the longest exceeds 30,000 heats in three melt shops. Based on this process, the long-life combined-blowing converter steelmaking technology has been developed. Slag splashing has been used to form a gas permeable "slag mushroom" on the top of bottom nozzles to protect the nozzles. In order to keep the effective bottom blowing, furnace bottom thickness control technique has been developed to prevent the furnace bottom growth. It makes the service life of bottom nozzle the same as the converter campaign life (average 10,000 heats and longest > 30,000 heats). The complete combined blowing was ensured through out the furnace campaign. Concentration product [C][0] is in the range of 0.0023 ~ 0.0030%, the T.Fe in the slag is lowered by 4 ~ 6%, and the [0] in steel is decreased by 100 ~ 250 ppm.

Jan 1, 2004

By X. Shi

Magnesium, the lightest structural metal, has not yet been considered as a serious contestant for automotive use due to its weaknesses in corrosion. Electroless nickel-boron alloys are well known for their corrosion resistance and hardness. An electroless nickel-boron layer was successfully deposited first on the chemical conversion pre-treated AZ31 alloy and also on the Ni-P coating which was deposited on the conversion coating. The electroless bath contained nickel sulphate and dimethylamine borane (DMAB) as main salts and the samples were activated by a 5 g/L AgNO3 solution before the electroless plating process. The presence of the conversion coating between the nickel coating and the AZ31 substrate acted as a barrier and prevented corrosion of the alloy. The morphology of the nickel-boron layer was studied using SEM. The crystal structure and the composition were examined by EDS and the hardness was measured. The corrosion behaviour of the nickel-boron layer deposited on the conversion coating and on the Ni-P coating was studied using potentiodynamic polarization in a 0.5M NaC1 solution. A saturated standard calomel electrode was used as a reference electrode. The results show that the nickel-boron coatings had a significantly better corrosion resistance than the AZ31.

Jan 1, 2006

By K. O. J. Sidwell

STRATMAT LIMITED, through its subsidiary, the Strategic Manganese Corporation, controls two adjoining iron-manganese properties five miles west of Woodstock, New Brunswick. One is a staked property of 77 claims traversed by one trunk highway, several secondary roads, and a branch line of the Canadian National railway. The other property, a 20-square-mile Concession immediately to the north-east, is also traversed by an excellent network of roads. Both proper-ties are situated in gently rolling farmland. The deposits were discovered in 1836 by Dr. C. T. Jackson. The first attempt to exploit them was made in 1848 when a blast furnace was erected with a capacity of 7 tons per day. The ore was mined by a series of deep trenches that followed the folds of the enclosing slates. In the late years of operation, bog iron ore from Burton and Maugerville, in Sunbury county, was used in conjunction with the Wood-stock ore. An additional 5-ton furnace was erected in 1863 and mining was carried on intermittently until 1884. No further extensive work was done until 1953. During the period of activity, approximately 70,-000 tons of ore are said to have been smelted ( 1). During these earl y operations the Iron Ore Hill and Moody Hill deposits were partially opened, with the ?bulk of the furnace feed being mined from the Iron Ore Hill workings. The low tenor and apparently limited extent of the deposits, the high. ?content of phosphorus, and the increasing scarcity of fuel, were the chief factors that brought the enterprise to an end.

Jan 1, 1957

By A. B. C. Stothart

"IntroductionIn the past four years Ontario Mines have made great progress in the development of reliable mine conveyance safety dogs. History shows that, prior to 1945, a rope failure on a descending conveyance was usually followed by unsatisfactory safety dog operation.It is proposed in this paper to discuss briefly;The history of this development. Progressive .development of one type (E. Long).Free fall testing of safety dogs. Anti-trailing rope device.HistoryOn February 2nd., 1945, a hoisting rope broke at the Paymaster mine. The safety dogs proved ineffective and permitted the cage to crash through to the bottom of the shaft, with disastrous results.Following this accident, the Ontario Government appointed a Technical Committee to investigate The Safety of Hoisting Equipment and Hoisting Practice in Ontario Mines. This Committee consisted of Dr. C. R. Young (Chairman) and Professors T. R. Loudon, E. A. Allcut, V. G. Smith, and Lloyd M. Pidgeon. The Ontario Mining Association (at the request of the Ontario Government) also appointed a Committee consisting of Messrs. R. E. Dye, R. D. Parker, and R. L. Healy."

Jan 1, 1950

By R. Darlington, S. Ji

"High pressure die casting is a promising process to make thin-wall components with high dimensional accuracy and excellent surface quality. However, the non-uniformity is one of the important features in castings. The inhomogeneity in tensile properties and microstructural characteristics were studied for the castings with different thicknesses made by high pressure die-cast Al-Mg-Si alloys. For the local mechanical properties in the die-castings, the casting skin provided the highest, whereas the casting centre provided the lowest yield strength, UTS and elongation. The yield strength, UTS and elongation were significantly decreased towards the casting centre. The microstructural inhomogeneity is characterised by the segregation of coarse fragmented dendrites, the reduction of solute concentrations of Mg and Si, and the increase of porosity level from the surface to the centre of castings. The growth velocities of eutectic a-Al phase estimated using the Jackson-Hunt model confirm that the growth variation is larger in the thin castings than that in thick castings.INTRODUCTION Inhomogeneity is an inherent characteristic in as-cast microstructures of a variety of alloys because of their non-uniform chemistry, microstructure, defects, topology and the resultant mechanical properties in the different ranges of localization (Campbell, 2003). Generally, three types of inhomogeneities characterise casting microstructures, which include (a) the casting defects of shrinkage and gas porosity, misruns, cold shuts, inclusions, hot tears and hot spots; (b) the non-uniform microstructure from the surface to the centre of castings; and (c) the non-uniform microstructure from the dendrites grown from primary solidification and the structure formed during the subsequent eutectic solidification in inter-dendritic regions. The chemical composition and the morphology between the primary dendrites and the inter-dendritic eutectics also differ in the as-cast microstructure. Obviously, the inhomogeneity is different in the castings obtained from different casting processes."

Jan 1, 2018

By F. Rashchi, N. Naseri Joda

Recycling of electronic wastes is an important subject both from an environmental point of view and also the recovery of valuable materials. In this research, PC board scraps were leached to recover Cu, Ag, Au and Pd. Due to the high cost of the shredding process and to avoid secondary pollution from odors and dusts, board scraps were cut into 5X5 cm2 pieces. To determine the most effective leachant, aqua regia, nitric acid, hydrochloric acid, ammonium persulfate and potassium persulfate were tested. The effect of the leaching parameters, the leachant concentration, temperature, leaching time and liquid to solid ratio were studied and optimized using response surface methodology.

Jan 1, 2011

By Jolanta Olkowska-Oetzel

Reactions of gold?phosphino complexes [(AuX)(PR3)] (X= Cl, Br, I; R = organic rest) with Se(SiMe3)2 lead to the formation of gold complexes with chalcogenide bridges. The reaction of the complex Ph3PAuCl and tBuSe(SiMe3) gives the cluster [Au5Se2(PPh3)4]Cl 1. The in situ preparation of the complex [(AuCl)2dpph] (dpph = Ph2P(CH2)6PPh2) by reaction of dpph with Me2SAuCl, and subsequent reaction with Se(SiMe3)2 leads to the formation of [(Au3Se)2(dpph)3]Cl2 2. Reactions of the gold(I) complex [(AuCl)2dpppe], (dpppe = Ph2P(CH2)5PPh2) with Se(SiMe3)2 and InCl3 in different molar ratios lead to the formation of [Au10Se4(dpppe)4]InCl5 3 and [Au4(SeInCl3)2(dpppe)2] 4. The reaction of [(AuCl)2dpph] with Te(SiMe3)2 and GaCl3 produces the isostructural cluster compound [Au4(TeGaCl3)2(dpph)2] 5. From the reaction of Se(SiMe3)2 with [(AuCl)2dppe] (dppe = Ph2P(CH2)2PPh2) and InCl3 [Au8Se4In(dppe)4](InCl4)3 6 can be isolated. The structures of 1 - 6 were determined by X?ray diffraction.

Oct 1, 2003

By Finley A. Campbell

"Nickel-copper sulphide deposits associated with basic rocks in the Quill Greek area and the White River area in the Yukon Territory have been studied and compared from the view-point of their general geology, structural geology, and the mineralogy of the ores. The relative amounts of the major constituents, magnesium, iron and calcium, and the minor constituents, nickel, cobalt and chromium have been determined spectrographically for two cross sections of the basic rocks at Quill Creek and one at White River. These data, along with petrologic and field evidence, were used to determine the sill and dyke-like character and nature of the basic intrusions. Loss on ignition is employed as a measure of the degree of serpentinization. The distribution determined shows that the serpentinization does not appear to have greatly influenced the inferred original distribution and lithophile associations of magnesium and nickel. The cobalt content may have been altered.The nickel content of the serpentinized peridotites ranges from an average of 0.36 per cent in one section to an average of 0.24 per cent in each of the other two sections studied. The cobalt averages 0.0038 per cent in the samples from the two Quill Creek sections and averages 0.0042 per cent at White River. These results have been compared with other available data.The sulphide ores are later than both the peridotite and gabbroic rocks and may be co-magmatic with them. There is no evidence in these areas to support an origin by lateral secretion; on the contrary, the alteration associated with the ores, the mineralogy and spatial relationship to basic and ultrabasic rocks, indicate the ores are derived from a basic magma."

Jan 1, 1960

By N. Behnood, W. Pascheto

"Laboratory wear tests are important tools that can be used for the evaluation of materials for wear applications and mitigation of wear problems in the mining industry. However, laboratory test parameters must be fully characterized and test results must be carefully interpreted if a material selection is to be made. Failure to do so may lead to erroneous conclusions. Suitable lab-oratory tests are valid only if they reflect the field conditions to which materials are subjected. Therefore, it is important to know, in detail, the field conditions, as well as the wear test techniques being considered. It is important to recognize the limitations of the various wear tests and the wear test data published in the literature. This work will review present wear testing technology, including the various wear tests avail-able, wear test equipment and test limitations. Several wear test procedures will be related to common equipment used in the mining industry.IntroductionThis paper will concentrate on non-lubricated wear mechanisms, because they are the most costly to the mining industry. Very frequently we are faced with the task of selecting materials for wear applications or improving existing systems that are giving poor performance. There are plenty of examples in the literature of practical wear cases and ranking of materials for wear applications. It is also very common to find materials manufacturers’ data -sheets listing wear tests results by comparing their materials performances against those of competitors. Much of the published wear data lack the description of the type of wear test, test parameters and the type of wear mechanism to which the data should be applied (if any).Before considering wear test data for a specific problem one should ask which type of wear mechanism is involved? What type of test and what test parameters were used to produce the results? Even if the type of wear tests and parameters are known, how accurate and useful are the published wear data? How are the results related to a particular type of wear? It is important to point out that even the standardized wear tests, such as those in ASTM standards, have limitations. Such limitations are recognized and clearly spelled out in the standards themselves. Basically, wear tests may lead to erroneous results if the test is not able to repro-duce the same wear mechanisms encountered in the field. Therefore, the use of published results may be helpful, as a starting point, but may be of little value for a final material selection.This work will discuss the main types of non-lubricated wear mechanisms encountered in the mining industry. In addition, it will discuss the many wear tests available and their correlation with the various types of wear mechanisms. The limitations of several standardized wear tests and the limitation of using published wear data will also be discussed."

Jan 1, 1997

By P. N. Calder, D. B. Apel, S. D. Butt

Mine-wide (MW) microseismic systems use widely spaced transducers to determine the source location and parameters of stronger microseismic events, while high frequency (HF) systems use fewer transducers to monitor local areas for the weaker events that can precede stronger events. Previous monitoring at the Creighton Mine indicated that an HF transducer located 120 m away from an active stope recorded two types of activity in response to production blasting: the first occurring at the same time as the production blasts and associated with the passage of the direct seismic waves from the blast through the local area, and the second occurring several hours later and associated with the arrival of a slower moving stress change through the rock mass (which was identified by the mine’s MW system). Interpretations of locally increased stress levels, based on analysis of the recorded HF events, correlated with the nearby occurrence of two strong seismic events. These results were applied to a similar monitoring trail at the Kidd Creek Mine where the transient stress changes induced by several development blasts were monitored. It was observed that increases in HF activity corresponded with the occurrence of MW events near the transducer location, and that fewer HF events were recorded the longer this occurred after the blast. Local geological features appeared to influence the number and occurrence of both HF and MW events.

Jan 1, 2000

By M. Tsesarsky, M. Hazan, E. Gal

"Rock masses comprised of stiff inclusions in softer matrix are common in various geological environments. The heterogeneity and multi-scale nature of these materials make the evaluation of their mechanical properties a challenging task, which cannot be accomplished using conventional laboratory tests and composite mixture rules. We employ the homogenization method to estimate the mechanical properties of geological materials with inclusions. The homogenization method solves the equations of elasticity on the material (microscopic) scale for a unit cell subjected to unit strains under periodic boundary condition. The micro-scale elasticity equations are solved using the Finite Elements Method, and are in turn used to obtain the structure scale (macroscopic) material matrix.In this research, Finite Element models for unit cells with spherical and ellipsoidal inclusions were developed. Using the unit cells, a parametric study of the geometrical and statistical microscopic properties of the material composites was performed. The following parameters were studied: volumetric ratio, Young’s modulus ratio, size-distribution of inclusion and inclination angle of inclusions. The main purpose of the parametric study was to study the deviation from isotropy as a function of the aforementioned parameters.It was found that for volumetric ratio of 5%-40%, the deviation from isotropy increases, as the volumetric ratio of inclusions increases. For spherical inclusions, most of the cases studied exhibit quasiisotropic behaviour; whereas ellipsoidal inclusions exhibit considerable deviation from isotropy. The inclination of the ellipsoidal inclusions enlarges the deviation from isotropy (9% at random orientation and 26% at 0°)."

Jan 1, 2015

By K. Sawamukai, S. Ogasawara, D. Umenai, T. Tsuruta

"Removal of cobalt, strontium or cesium ion from the aqueous solution containing each metal ion only using microorganism was examined. Arthrobacter nicotianae which had a high ability to remove cationic metal ion was used for the removal of each metal. The removal of cobalt, strontium or cesium using A. nicotianae cells was affected by the solution pH, concentration of metal ion, and cell amount. The effects of above mentioned factors on the removal of each metal and time course of strontium from the solution containing each metal only using A. nicotianae cells were reported in this paper. INTRODUCTIONRadioactive elements, such as cesium, iodine, strontium, plutonium, barium, cobalt, lanthanum, yttrium, and tellurium, were detected around Fukushima Daiichi nuclear power plant, which was damaged by the magnitude 9.0 earthquake and the tsunami followed.The removal of radioactive elements from contaminated sources is a worthwhile subject to investigatein terms of environmental control. Research efforts have been especially concentrated on studying microorganisms that remove uranium including bacteria (Andres et al, 1993, Hu et al, 1996, Marques et al, 1991, Strandberg et al, 1981), actinomycetes (Byerley et al, 1987, Friiss and Myers-Keith, 1986, Golab et al, 1991), fungi (Byerley et al, 1987, Galun et al, 1983a, Galun et al, 1983b,Tsezos and Volesky, 1981, White and Gadds, 1990) and yeasts (Strandberg et al, 1981, Schmate II et al, 1978).We have investigated removal and recovery of uranium from aqueous systems using microorganisms isolated from uranium mines. We identified some strains of bacteria with extremely high uranium removing abilities (Sakaguchi et al, 1996), and thus, the microbial biomass may be considered as an adsorbing agent for the removal and recovery of uranium and heavy metals present in aqueous systems around Fukushima Daiichi nuclear power plant.In the present study, we screened various species and strains of bacteria, actinomycetes, fungi, and yeasts for their ability to adsorb uranium (Tsuruta, 2002). Basic features affecting uranium adsorption?co-existing cations and anions, cell amounts, pH, and the adsorption time course?by Arthrobacter nicotianae cells, which adsorbed the largest amount of uranium, were also investigated. In addition, we examined the removal of an other actinoid element, thorium ion, which may be present with uranium in refining effluents.In this paper, the removal of cobalt, strontium, or cesium from the solution containing each metal ion using A. nicotianae cells is discussed."

Jan 1, 2012

By F. Habashi

"Extractive metallurgy was divided into the three sectors pyro-, hydro-, and electrometallurgy in 1959 when Professor Joseph Newton at the Idaho School of Mines in Moscow mentioned this in his book Extractive Metallurgy. Pioneer hydrometallurgists who built this discipline can be traced to the alchemists in the ninth century. It is now a mature subject of great importance in which pressure plays a vital role. Short biographies of some hydrometallurgists and the processes they invented are briefly outlined.INTRODUCTIONHydrometallurgy is the use of aqueous solutions to recover metals from ores. It is a relatively new discipline when compared with pyrometallurgy the use of fire to melt ores and recover metals which was practiced in ancient times. Hydrometallurgy can be traced to the time of alchemists whose concern was the transmutation of base metals into gold. Although alchemists did not succeed in their venture yet they described many reagents that are useful today. For example, they prepared sulfuric acid by distillation of iron vitriol, muriatic acid by distillation of sulfuric acid with salt, and nitric acid by reaction of sulfuric acid by reaction of sulfuric acid with salpeter. Jabir Ibn Hayyan the Muslim alchemist who lived in the ninth century (Figure 1) described aqua regia a mixture of nitric and hydrochloric acid that can dissolve gold although either acid has no action on gold. THE MIDDLE AGESIn the Middle Ages, it was reported that copper was recovered at Rio Tinto in Spain by allowing copper-containing pyrite to be exposed in piles to the action of air and rain. Copper sulfate solution obtained was treated with pieces of iron to precipitate metallic copper—a process that was called cementation. Georgius Agricola (1494–1555) (Figure 2) a medical doctor in Saxony who used to visit mines and smelters to examine miners and metal workers, described in his book De Re Metallica the parting of gold, i.e., separating of silver from gold by acids."

Jan 1, 2016

By Rhual L. Guerguerian

MINING has been practised by mankind for over sixty centuries (1). In 1876, the "ball mill" was patented, and during the century that followed rotary grinding developed to the state where individual machines are treating tens of thousands of tons of ore per day. This paper gives a brief description of design practices prior to the availability of advanced facilities, followed by modern analytical design development at Dominion over the past ten years.

Jan 1, 1978

By M. A. Tomlinson, A. Di Feo, T. C. Cheng

"Goldcorp is evaluating the potential for economic reprocessing of historic tailings at several sites, including the Aunor A facility located in Timmins. The overall project is investigating the ability to recover value, remove sulphide minerals and alternative tailings re-deposition strategies. Desulphurization of tailings will eliminate potential acid generation while improved tailings re-deposition could reduce long-term liabilities and closure costs. Through a task-share project between CanmetMINING and Goldcorp, tailings obtained from Aunor A site have been characterized using mineral association analysis and diagnostic separation techniques. The selected tailing samples contain about 2 g/t of gold. Mineralogical analysis has identified coarse agglomerates bound with gypsum and significant free gold, confirmed by high recoveries in cyanide leach tests. However, despite no evidence of surface passivation on the minerals, conventional flotation techniques were found to be ineffective in concentrating gold or sulphides due to the high fines content and highly agglomerated particles.INTRODUCTION Aunor Mine is one of the historic mines that belongs to Porcupine Gold Mines (PGM) in Timmins, Ontario. PGM has undertaken an extensive mine closure program to remediate the legacy and closed mines with the funding supported by operating mines since 2006. Over the course of 100 years of operation in the Porcupine camp, it is estimated (Stevens et al., 2013) that about 130 million tonnes of tailings have been generated. Aunor Mine produced 2.5 million troy ounces of gold between 1940 and 1984, while processing over 7.6 million tons of ore. The original gold grade of Aunor Mine ores was about 10 g/t. With 95% gold recovery at the time, an estimate of 0.5 g/t of gold remains in the Aunor Mine tailings. Aunor Mine has two tailings impoundment areas: designated as Aunor A and Aunor B. The two sites are similar in size, about 7 hectares each. The amount of tailings in the Aunor A site alone is about 3.2 million tonnes. In 2017, bulk tailings were sampled from five designated locations in Aunor A. They were characterized using mineral association analysis and diagnostic separation techniques. The bulk tailings samples contained about 10% total sulphur, 10% iron, 2% arsenic and 2 g/t of gold. The prime objective of this collaborative work between CanmetMINING and Goldcorp is to facilitate the timely development and deployment of innovative tailings reprocessing solutions, specifically in the areas of desulphurization, and recovery of metals. This work targeted specific tailings of interest to Goldcorp which goals are to improve its environmental footprint and to reduce long-term liability. Thus, it is imperative to look for innovative reprocessing options that can overcome not only technological challenges but also achieve economic benefits to offset the costs associated with reprocessing the tailings. Moreover, the greater goal is to demonstrate and deploy tailings reprocessing solutions to solve one of the industry’s most difficult challenges for a sustainable mining industry in Canada."

Jan 1, 2019

By A. J. Petrina

"At Craigmont Mines Limited, Merritt, B.C., tests were begun in March, 1965 to evaluate the use of shotcrete as a method of ground support m development headings; previously, ail drifts had. required support, which was accomplished mainly by timber and occasionally by the use of rockbolts. The tests demonstrated conclusively the effectiveness of shotcrete for supporting Craigmont's ground. Gradually, the use of timber for ground support was virtually eliminated in favour of shotcrete. This paper describes the equipment used, the operation of the equipment, pertinent cast data and opera ting details. Also discussed are other uses developed for the shot-creting equipment, the use of reinforcing bar rockbolts, and a method used at Craigmont for lining long vertical ore passes with steel plate and concrete as part of the raising cycle."

Jan 1, 1968

By Ashu Garg, Anirban Bhattacharya

"Friction stir spot welding of aluminum alloy AA6061-T6 sheets was performed with circular (plunge depths 0.4 and 0.6 mm), square and triangular tool pin (plunge depth 0.4 mm) with constant 0.2 mm shoulder penetration to characterize various zones of weld nugget. It was observed that the depth of the stir zone formed below the tool pin is comparatively similar for different tool pins but wider for circular tool pin. The size of another stir zone formed at the interface of tool pin and a tool shoulder is observed to be larger for triangular and square tool pin due to the higher swept rate. Predicted strain from finite element analysis, calculated strain rate using Zener-Hollomon relationship and experimentally measured grain size distribution indicates severe amount of plastic deformation in-and-around the nugget/spot region. Finer grains in various stir zones were observed than thermo-mechanically and heat affected zones. Grain size (at distribution peaks) in stir zones varied around 2.54 µm to 3.69 µm for different tool pin profiles as compared to base metal grain size of 20 µm. Microhardness results indicate that the welded region is quite softened than base metal and maximum hardness is mostly observed around the thermo-mechanically affected zone.INTRODUCTION Friction stir spot welding (FSSW) is widely used for joining the sheets of materials like aluminum, copper, magnesium, etc. The process begins by plunging a rotating tool (generally having a pin and a shoulder) into the sheets to be welded. Continuous stirring of the tool and downward plunging force generates localized heat due to friction at the tool-sheet interface and plastic deformation of the sheet metal. The material gets softened and the plasticized material adjacent to the tool pin starts flowing due to the action of tool rotation and tool plunge thereby causing intermixing and bonding between the overlapped sheets. The tool stirring also promotes grain refinement in the weld nugget associated with high strain, strain rate and thermal cycle. The formation of new microstructure also affects the mechanical properties and efficiency of FSSW joints. Studies also showed that the tool pin design and tool shoulder feature exerts a noteworthy influence on the material flow and intermixing during the FSSW process (Reilly et al., 2015; Hirasawa et al., 2010). Sarkar et al. (2016) studied the material flow and intermixing during FSSW using tracer material method and reported that the size and width of flow zone increases with tool penetration depth. The influence of tool rotational speed on microstructure and stir zone temperature was investigated during FSSW of dissimilar AA6061-AA5754 alloys (Gerlich et al., 2007). They reported that the average grain size in stir zone of AA6061 weld increases with increase in tool rotational speed. In another work, Gerlich et al. (2008) studied the local melting and tool slippage during FSSW of Al alloys. Tool slippage was investigated by calculating the strain rate using Zener-Hollomon relation. Garg and Bhattacharya (2017a) studied the effect of dwell time, tool pin profiles and tool rotational speed on shear strength, microstructure, temperature and strain distribution during FSSW of AA6061. In another work, Garg and Bhattacharya (2017b) analyzed the effect of different tool pins and pinless tools on the shear strength and microstructure during similar and dissimilar FSSW of AA6061-T6 and pure Cu. Chang et al. (2004) proposed mathematical relationship between the average grain size and Zener-Hollomon parameter during friction stir processing of Mg alloy. Solhjoo (2010) presented a mathematical approach to determine the critical strain as a function of peak strain required for initiation of dynamic recrystallization in austenitic stainless steel. Fratini and Buffa (2005) also proposed the numerical model to determine the grain size during continuous dynamic recrystallization phenomenon."

Jan 1, 2018

By G. Zárate, G. Tapia

Anglo American Chile has been doing copper concentrate leaching studies at the laboratory and small pilot plant scale since 1992. Among the processes evaluated are bacterial leaching and pressure leaching using Mantos Blancos, Salobo Project and Quellaveco Project concentrates. Late in the nineties, it was decided to focus the research on pressure leaching, either medium or total pressure oxidation. Preliminary scouting tests were run with Mantos Blancos concentrate samples during 2000, which were repeated during 2003 together with samples of Los Bronces and El Soldado concentrates, in order to define the most suitable concentrate for running a pilot plant campaign at AARL, which was carried out in two campaigns, a first one from November 2003 through January 2004 and a second one during April 2004. Mantos Blancos was the selected concentrate and the laboratory and pilot plant results are discussed in this paper together with some preliminary economic estimates.

Jan 1, 2004