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By Turgay Gurun

"Digital simulation can be used as an analytical tool to optimize the design of crushing plants without need for large-scale experimental programs.General mathematical description of a crushing operation permits the simulation of a crushing plant flowsheet under various operating conditions. The process model encompasses multistage open- and closed-circuit crushing of hard and soft rock. Crushing balances are analyzed in the light of crusher and screen performance and a comparison of different closed-circuit arrangements is made in terms of process and layout criteria.The simulation model allows comparison of process alternatives to be made in terms of equipment selection and capital and operating cost estimation. It thus provides the pertinent practical information to maximize plant efficiency, and to minimize expenditures in such items as equipment, structures, power consumption, and so on."

Jan 1, 2014

By E. D. Musin, S. S. Gudkov, A. V. Epiforov, S. V. Balikov

The standard technology for processing of gold-bearing sulfide raw material has many problems associated with the use of cyanide as a gold lixiviant. Therefore, many tests to find alternative gold recovery methods are being undertaken. This paper describes some technological solutions, which can become alternatives to cyanide technology in the future. Pressure oxidation (POX) of refractory gold-bearing sulfide concentrates from five different Russian gold deposits were investigated. Concentrate 1 was gold-copper concentrate. Concentrate 2 was gold-pyrite concentrate. Concentrates 3-5 were pyrite-arsenopyrite double refractory concentrates. The POX tests were at temperatures of 110, 200 and 220 °C and oxygen pressures of 1.5, 2.4 and 3.0 MPa were carried out. Gold lixiviants, such as chloride, thiosulfate, sulfite and thiocyanate were tested. The recovery of gold from sulfide gold-bearing concentrates by non-cyanide methods was 97- 99%, and from double refractory concentrates, 86-93%. The tested reagents are less toxic than cyanide, and their use will reduce of the cost of gold production. These methods make it possible to recover gold in acidic media, and eliminate the washing operation and POX slurry neutralisation. In addition, precious metals recovery from POX cakes using lead reduction smelting was investigated. It was shown that the “POX-pyrometallurgical” technology for double refractory concentrates processing could be used with recoveries of gold and silver of 97 and 96%, respectively. Keywords: Recovery of gold, refractory sulfide gold-bearing concentrates, double refractory concentrates, pressure oxidation, non-cyanide lixiviants of gold, chloride autoclave leaching, thiosulfate leaching, thiocyanate leaching, sulfite leaching, reduction smelting, POX-pyrometallurgical technology

Jan 1, 2020

By S. Swanepoel, A. V. Cherkaev, Q. G. Reynolds, M. Erwee

Ferrochrome (FeCr) is a vital ingredient in stainless steel production and is commonly produced by smelting chromite ores in submerged arc furnaces. Silicon (Si) is a componrnt of the FeCr alloy from the smelting process. Being both a contaminant and an indicator of the state of the process, its content needs to be kept within a narrow range. The complex chemistry of the smelting process and interactions between various factors make Si prediction by fundamental models infeasible. A data-driven approach offers an alternative by formulating the model based on historical data. This paper presents a systematic development of a data-driven model for predicting Si content. The model includes dimensionality reduction, regularized linear regression, and a boosting method to reduce the variability of the linear model residuals. It shows a good performance on testing data (R2 = 0.63). The most significant predictors, as determined by linear model analysis and permutation testing, are previous Si content, carbon and titanium in the alloy, calcium oxide in the slag, resistance between electrodes, and electrode slips. Further analysis using thermodynamic data and models, links these predictors to electrode control and slag chemistry. This analysis lays the foundation for implementing Si content control on a ferrochrome smelter.

Mar 14, 2024

By R. D. Alorro, B. Tadesse, E. Aghaei

Cinnabar (HgS) and native mercury (Hg) are the most common naturally occurring forms of mercury found in most gold ores subsequently released into the environment during processing. Mercury and its compounds are extremely toxic and recognised as serious health and environmental hazards. This research investigates the possibility of mercury (Hg) removal from waste solutions from gold processing using iron-aluminium (Fe-Al) bimetallic particles. The synthesis of Fe-Al bimetallic particles using zero-valent aluminium and ferric chloride as precursors were performed following the optimisation of influencing factors. The presence of both metals in the prepared bimetals was confirmed by XRD analysis. The experiments for mercury removal by bimetals were designed using the central composite design and Minitab software based on two variables including contact time and adsorbent dosage. The best result of Hg(II) removal (>90%) was achieved using 4 g/L bimetals and contact time of 75 min. However, the statistical analysis of results indicated that these parameters have only a minor contribution to the removal of Hg(II) by Fe-Al bimetals. Higher bimetal dosage and contact time resulted in a higher Fe dissolution from the Al surface which can be attributed to the presence of nitrate (# $) ions in the solution. However, adding 0.1 M NaCl to the Hg solution had a positive impact on Hg removal by improving the conductivity and electron transfer within the solution. The Fe-Al bimetallic particles are promising substances for further testing of Hg removal from gold processing waste solutions with different conditions and constituents. Keywords: Mercury removal, gold processing, Fe-Al bimetals, optimisation

Jan 1, 2020

By J. O. Claassen

"SynopsisMining value chains are dynamic systems and should be managed according to systemic flow-based principles. This includes a detailed focus on the impact of variable geological conditions on material flow, product quality, and production cost, visibility of the total mining system to operators and managers, as well as the synchronization of resources and activities in downstream processes. Thirty mining operations across the African continent were studied to establish to what extent systemic flowbased principles are applied in day-to-day operations. The study indicated that although most mining operations have identified the relevant geoprocessing variables, only a small number apply this information in a flow-based management approach. Most mining operators do not focus on developing a clear flow view of the mining value chain and on making it visible to operators and managers to enable them to optimally set and reset operations. Daily synchronization of geoprocessing variables is limited to a small number of variables, e.g. synchronizing ore hardness with drilling or milling requirements, in less than 30% of the operations evaluated. Operations where these principles have been adopted reported a noteworthy improvement in performance. The study indicates that notable potential exists in most of the operations evaluated to implement flowbased management principles, including geometallurgical principles. This can significantly improve value chain performance without exorbitant capital layouts and enhance ROCE. IntroductionObjective of the studyThe study seeks to establish to what extent systemic flow-based principles have been adopted in the southern African mining industry and the implications thereof. Specific attention is given to the importance of defining and managing geoprocessing dependencies (geological variables directly impacting mining and plant performance – the geometallurgical approach), establishing a flow view of the mining system, which typically includes a dashboard of the flow of ore/product quality and cost from the mining face to the customer, and limiting the impact of dependencies through synchronization of activities and resources, e.g. ensuring that a continuous miner does not wait for a roofbolter, or that reagent addition rates are matched with a specific ore/concentrate composition."

Jan 1, 2015

By X. Zhang, Z. T. Yuan, C. Zhang, H. M. Zheng, X. M. Wang, L. X. Li, N. Li

In metal mines, comminution is commonly used to liberate minerals for subsequent mineral concentration processes, such as flotation, magnetic separation and gravity separation. However, ores are aggregates of valuable minerals and their disseminated gangue minerals, and these minerals exhibit diverse comminution behaviours. In carbonate-bearing iron ores, hematite, siderite, and quartz are the predominant minerals, of which hematite is the objective recoverable mineral. In this regard, the present study aimed to identify the imperfections in siderite minerals by X-ray computed tomography (XCT), and thus quantitatively characterise their size and shape in terms of Feret diameter and aspect ratio, as well as other parameters. XCT images indicated the protogenetic ubiquity of pores <5 μm in diameter and cracks of 7-8 μm inside siderite particles. In the ground product of artificially mixed siderite and hematite, siderite particles were smaller than hematite particles. Siderite particles had a larger surface area and greater surface roughness than hematite particles of the same volume, which was attributable to the intrinsic holes and cracks in siderite particles. This study provides an insight into the relationship between the inherent imperfections of minerals and their comminution properties. Keywords: Siderite; X-ray computed tomography; particle imperfections; grinding behaviour; sliming

Jan 1, 2020

By R. Xie, J. Liu, Y. Zhu, Y. Li

The surface chemistry features of spodumene and feldspar were investigated by XPS, zeta potential measurements and first principle calculation. The results indicated that the zeta potential of feldspar was more negative than that of spodumene. The most possible active sites on spodumene and feldspar were Al sites and O sites. However, the number, type and activity of these sites were different. The flotation behaviour of five new collectors (cationic collector decyloxy-propyl-amine (DPA), anionic collector α-bromododecanoic acid (α-BDDA), N-Dodecyliminodiacetic acid (DIDA), and mixed collector DPA-BDDA and DPA-DIDA) were investigated through micro flotation experiments and analysed based on the surface chemistry features of spodumene and feldspar. The results revealed that cationic collector DPA processed a high collecting capacity for both minerals. The highest recovery of spodumene and feldspar was 91.60% and 95.30% respectively. The anionic collector α-BDDA and DIDA showed poor flotation behaviour. The recovery of spodumene and feldspar when using α-BDDA as collector was less than 5% and when using DIDA as collector was less than 1%. For the mixed collector DPA-BDDA, the recovery of spodumene and feldspar was 82.27% and 32.61% respectively at pH 4.5. For mixed collector DPA-DIDA, the recovery of spodumene and feldspar was 35.69% and 9.08% respectively at pH 5.8. The results indicated that the cationic collector had high collecting capacity, but low selectivity. The collecting capacity of anionic collector for spodumene and feldspar was poor at the same concentration compared with cationic collectors. Mixed collector DPA-BDDA showed good flotation behaviour and selectivity on spodumene. The ―COO- in mixed collector might improve the selectivity. However, too much ―COO- would increase the electrostatic repulsion, which might cause low selectively and poor recovery. Keywords: Spodumene, feldspar, surface chemistry features, mixed collector, flotation

Jan 1, 2020

By B. McFadzean, N. Patterson, M. Becker, S. Geldenhuys

The retreatment of secondary tailings for platinum group metals recovery presents a range of potential challenges, which vary depending on the nature of the original ore and the type of pretreatment it was subjected to. These challenges include the prevalence of ultrafine particles, which promote slimes coatings on valuable minerals, hinder bubble-particle attachment, increase pulp viscosity, and lead to higher gangue entrainment; surface oxidation of minerals, which alters their floatability; and the presence of deleterious gangue minerals and residual platinum group metal species that are inherently difficult to recover by flotation. This study compares the batch flotation performance across a range of tailings samples from the eastern and western limbs of the Bushveld Complex. A complementary mineralogical analysis was conducted to gain deeper insights into mineral behaviour. The paper evaluates these findings to identify the key factors contributing to poor platinum group metal performance.

Mar 6, 2026

By S. M. Spottiswoode

A simple method for the application of excess shear stress (ESS) analysis to the mining of planar reefs is examined. The potential for seismicity associated with mining is expressed as the calculated increase in ESS on a regular grid of points 50 m above the reef, and is compared with observed seismicity around a deep-level, relatively geologicaly-undisturbed gold mine. Thirty regions were studied, involving over 2000 seismic events with magnitudes greater than 1,5 on the Richter scale and associated with almost 2 million square metres of stoping. The total seismicity, measured either as the number of seismic events or as the total radiated energy, corelated more closely with changes in ESS than with ERR. The incidence of rockbursts also favoured the ESS model. Corelation coeficients of around 0,8 for seismicity and ESS indicated that the assumptions inherent in the method used are collectively reasonable. The total seismicity in each region was found not to be strongly controlled by the presence of dykes and faults, although numerous individual seismic events were located close to such features.

Jan 1, 1988

By H. Zhong, S. Wang, Q. Sun

The flotation performance of 2-(benzylthio)-acetohydroxamic acid (BTHA) to diaspore was first evaluated by micro-flotation tests. The adsorption mechanism was further investigated through adsorption experiments, molecular dynamics simulation, zeta potential and X-ray photoelectron spectroscopy (XPS). The results demonstrated that BTHA had a stronger ability to collect diaspore in comparison with another diaspore collector, benzohydroxamic acid (BHA), especially under the condition of weak alkalinity, the flotation recovery can reach 90%. The more negative interaction energy (ΔE) between BTHA and diaspore from molecular dynamics simulation results revealed that BTHA had an easier adsorption ablity onto diaspore than BHA, which matched with adsorption results. The zeta potential and XPS revealed that Al atoms might bond with -C(=O)NHOH by formation of Al-O bonds. Keywords: Diaspore, flotation; adsorption; 2-(benzylthio)-acetohydroxamic acid

Jan 1, 2020

The Annual General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, 26th August, 1970, at 4.15 p.m. Mr. J. K. E. Douglas (President) was in the Chair. There were also present sixty-three Fellows, thirty-five Members, one Graduate, eight Associates, five Students and nineteen Visitors, making a total of one hundred and thirty-two. The President declared the meeting open at 4.20 p.m. OBITUARIES The President: &apos;It is my sad duty to announce the deaths of the following members of the Institute. Dr J. A. Papenfus, Fellow, who joined the Institute in 1942 and passed away on the 28th of May, 1970. Mr D. G. Beadle, Fellow, who joined the Institute in 1946 and passed away on the 17th of June, 1970. Gentlemen, Derek Beadle was very well known in this Institute. His papers on dust will be remembered and, at the time of his untimely death, he was one of our assistant editors. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, I would ask you to rise and observe a few moments&apos; silence.&apos; MINUTES The President: &apos;May we confirm the minutes of the General Meeting held on 15th April, 1970, as published in the July, 1970, issue of the Journal&apos;. Agreed. WELCOME TO VISITORS The President: &apos;Ladies and Gentlemen, we are honoured this afternoon by the presence of many distinguished guests and I extend to you all a most cordial welcome. We are happy to have with us Dr A. A. von Maltitz, President of the Chamber of Mines of South Africa, who is also Honorary President of this Institute. We also have one of our Honorary Vice- Presidents, Mr T. L. Gibbs, the Government Mining Engineer; Mr D. E. Hamm, President, Institution of Certificated Mechanical and Electrical Engineers, S.A.; Mr S. C. M. Naude, Director, Witwatersrand Technical College; Mr I. R. G. Stephen, Senior Vice-President, The S.A. Institute of Electrical Engineers; Mr G. M. Tompkins, President, The S.A. Institution of Mechanical Engineers; Professor P. B. Ackermann, President of the Geological Society of S.A.; Mr A. S. Robinson, Vice-President of the S.A. Institute of Civil Engineers; Professor W. Mare, President of the Institute of Land Surveyors of the Transvaal; Mr B. D. Charlton, President of the S.A. Institute of Assayers and Analysts; Mr R. Hemp, The President, The Mine Ventilation Society of S.A.; Mr L. J. Prince, The President, The S.A. Association of Mine Managers; Mr J. Botha, The President, The S.A. Institute of Foundrymen; Mr G. Niterl, The President, The Institute of Welding; Mr M. R. Gericke, President, S.A. Council of Professional Engineers; Mr N. A. Honnet, Chairman, Orange Free State Branch; Mr P. R. C. Cooke, Chairman. The South African Chemical Institute (S. Tvl&apos; Section). Gentlemen, we are very honoured indeed, to have these distinguished gentlemen with us this afternoon, as our honoured guests. We are also pleased to have with us, one of our Honorary Fellows, Mr F. G. Hill, and several Past-Presidents. I also extend a very warm welcome to all our lady guests and to all our other visitors.&apos; MEMBERSHIP The President: &apos;I have pleasure in announcing that the names of the following candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership in the following grades: NEW APPLICATIONS Fellows: Herbert Dalton-Brown, Stephen William Morel. Members: Clive Lester Workman-Davies, Basil James Russell Botha. Students: Timothy Nigel Watson, John William Hairbottle. I wish to welcome the new members to the Institute and to congratulate those members who have been transferred to a higher grade.&apos; ANNUAL REPORTOFTHE COUNCILAND ACCOUNTS FOR THE YEAR ENDED 30th JUNE, 1970 The President: &apos;I now have pleasure in presenting to you, the Annual Report and Statement of Accounts for the year ended June, 1970. These have been handed to you this afternoon and, as is customary, I propose they be taken as read. Before moving their adoption, however, I would like to refer to some of the salient features, leaving as is usual, the task of dealing with the finances, to our Honorary Treasurer. It is encouraging that membership has continued to grow, and now stands at 1,613, an increase of 61 over last year&apos;s total. Your Council, however, is aware that there are still people in our mining and metallurgical industries, who could qualify for membership, but who have not yet joined the Institute. A drive to increase membership was accordingly organised, and members of Council were given the responsibility for campaigning in sections of industry, and for publicising the objectives and advantages of belonging to the Institute. Up to now there has not been much reaction to this campaign, but I hope we will see results in the coming year. At the same time, Council has recognised the need for change in the conduct of the Institute&apos;s affairs in order to meet the changing needs of our membership. Our members, both mining and metallurgical, are in the first place, geographically more widely dispersed than they used to be, and secondly, with the growth of the metallurgical industry, their technical interests are now more diversified. The Institute must cope with these changing needs if we are to continue to perform a useful function. The

The Annual General Meeting of the Institute was held in Kelvin House, Johannesburg, on Wednesday, 26th August, 1970, at 4.15 p.m. Mr. J. K. E. Douglas (President) was in the Chair. There were also present sixty-three Fellows, thirty-five Members, one Graduate, eight Associates, five Students and nineteen Visitors, making a total of one hundred and thirty-two. The President declared the meeting open at 4.20 p.m. OBITUARIES The President: &apos;It is my sad duty to announce the deaths of the following members of the Institute. Dr J. A. Papenfus, Fellow, who joined the Institute in 1942 and passed away on the 28th of May, 1970. Mr D. G. Beadle, Fellow, who joined the Institute in 1946 and passed away on the 17th of June, 1970. Gentlemen, Derek Beadle was very well known in this Institute. His papers on dust will be remembered and, at the time of his untimely death, he was one of our assistant editors. As a mark of respect to the memory of the deceased and in sympathy with the bereaved, I would ask you to rise and observe a few moments&apos; silence.&apos; MINUTES The President: &apos;May we confirm the minutes of the General Meeting held on 15th April, 1970, as published in the July, 1970, issue of the Journal&apos;. Agreed. WELCOME TO VISITORS The President: &apos;Ladies and Gentlemen, we are honoured this afternoon by the presence of many distinguished guests and I extend to you all a most cordial welcome. We are happy to have with us Dr A. A. von Maltitz, President of the Chamber of Mines of South Africa, who is also Honorary President of this Institute. We also have one of our Honorary Vice-Presidents, Mr T. L. Gibbs, the Government Mining Engineer; Mr D. E. Hamm, President, Institution of Certificated Mechanical and Electrical Engineers, S.A.; Mr S. C. M. Naude, Director, Witwatersrand Technical College; Mr I. R. G. Stephen, Senior Vice-President, The S.A. Institute of Electrical Engineers; Mr G. M. Tompkins, President, The S.A. Institution of Mechanical Engineers; Professor P. B. Ackermann, President of the Geological Society of S.A.; Mr A. S. Robinson, Vice-President of the S.A. Institute of Civil Engineers; Professor W. Mare, President of the Institute of Land Surveyors of the Transvaal; Mr B. D. Charlton, President of the S.A. Institute of Assayers and Analysts; Mr R. Hemp, The President, The Mine Ventilation Society of S.A.; Mr L. J. Prince, The President, The S.A. Association of Mine Managers; Mr J. Botha, The President, The S.A. Institute of Foundrymen; Mr G. Niterl, The President, The Institute of Welding; Mr M. R. Gericke, President, S.A. Council of Professional Engineers; Mr N. A. Honnet, Chairman, Orange Free State Branch; Mr P. R. C. Cooke, Chairman. The South African Chemical Institute (S. Tvl. Section). Gentlemen, we are very honoured indeed, to have these distinguished gentlemen with us this afternoon, as our honoured guests. We are also pleased to have with us, one of our Honorary Fellows, Mr F. G. Hill, and several Past-Presidents. I also extend a very warm welcome to all our lady guests and to all our other visitors.&apos; MEMBERSHIP The President: &apos;I have pleasure in announcing that the names of the following candidates, having been published in accordance with By-Law 5.2.2, Council has elected them to membership in the following grades: NEW APPLICATIONS Fellows: Herbert Dalton-Brown, Stephen William Morel. Members: Clive Lester Workman-Davies, Basil James Russell Botha. Students: Timothy Nigel Watson, John William Hair-bottle. I wish to welcome the new members to the Institute and to congratulate those members who have been transferred to a higher grade.&apos; ANNUAL REPORTOFTHE COUNCILAND ACCOUNTS FOR THE YEAR ENDED 30th JUNE, 1970 The President: &apos;I now have pleasure in presenting to you, the Annual Report and Statement of Accounts for the year ended June, 1970. These have been handed to you this afternoon and, as is customary, I propose they be taken as read. Before moving their adoption, however, I would like to refer to some of the salient features, leaving as is usual, the task of dealing with the finances, to our Honorary Treasurer. It is encouraging that membership has continued to grow, and now stands at 1,613, an increase of 61 over last year&apos;s total. Your Council, however, is aware that there are still people in our mining and metallurgical industries, who could qualify for membership, but who have not yet joined the Institute. A drive to increase membership was accordingly organised, and members of Council were given the responsibility for campaigning in sections of industry, and for publicising the objectives and advantages of belonging to the Institute. Up to now there has not been much reaction to this campaign, but I hope we will see results in the coming year. At the same time, Council has recognised the need for change in the conduct of the Institute&apos;s affairs in order to meet the changing needs of our membership. Our members, both mining and metallurgical, are in the first place, geographically more widely dispersed than they used to be, and secondly, with the growth of the metallurgical industry, their technical interests are now more diversified. The Institute must cope with these changing needs if we are to continue to perform a useful function. The

By RT White

For a number of years the steel tube and pipe industry has worked on resolving problems of product quality. These have largely been resolved and new products have been developed to take advantage of new developments. To fully coordinate market acceptance guidance on use of galvanized piping was also required. This was largely achieved locally in 2004 with the publication by the SABS of ARP 060 - Guidance on the use and application of hot dip galvanized steel piping for the transportation of potable water in South Africa. Use of this document is not easy however and a need to have a simple computer model to assist the specifier was identified. Working with a major tube and pipe manufacturer this is now being developed and this paper will provide the background to the model?s development and its intended use. There is still a need for a partner Code of Practice on the performance of galvanized piping in buried conditions and the need for this will be highlighted together with current available information.

Jan 1, 2006

By Y. Belloa, C. Dorfling

The presence of impurities such as Se and Te in copper sulfate leach solutions can have a detrimental effect on electrowinning efficiency. These elements can be removed from the solution by precipitation; sulfurous acid is commonly used as a precipitation reagent, while studies have also reported improved precipitation with the addition of metallic copper. This paper aimed to determine the effect of conditions used during the solution purification step on the characteristics of the precipitates that formed. Precipitation tests were performed in a batch reactor with copper sulfate leach solutions obtained from the base metal refinery of a platinum group metal producer. The effects of agitation rate (250 and 500 rpm), SO2 flow rate (4.4 and 5.8 mL/min.L), temperature (65 and 95°C) and metallic copper powder addition (0, 1 and 2 g/L) on the characteristics of the precipitates formed during the tests were determined using scanning electron microscopy. The major phases detected in the precipitates formed when using SO2 as the only precipitation reagent were elemental Se and Cu2Se. The introduction of copper powder led to the production of different sulfide phases for the experiments conducted at 65°C irrespective of the values of the other reaction parameters. At 95°C, Cu crystals, Cu2O and tiny inclusions of Cu2(Se,Te) were the prominent phases noticed in the precipitates produced from all the tests conducted with copper powder as precipitation enhancing reagent. Keywords: copper, precipitation, selenium, tellurium

Jan 1, 2020

By Q. G. Reynolds

The dual-electrode direct current (DC) arc furnace uses two graphite electrodes, one connected as cathode and one as anode. Such an arrangement avoids some of the design difficulties associated with the anode hearth traditionally used in single-electrode and twin-cathode DC furnaces, but can introduce other design and operational difficulties including deflection of the arcs toward the furnace walls. Counter-intuitively, both arc jets in a dual-electrode furnace travel from the electrode down to the bath surface, despite carrying electric current in opposite directions?this is suggested in the theory of the governing equations of arc formation, and confirmed by experiments using high-speed photography. The dual-electrode arc system at small pilot-plant scale is studied using a transient magnetohydrodynamic model capable of predicting arc deflection and interaction from first principles, and the results are compared to the behaviour of twin-cathode systems at similar power. Finally, a simple arrangement of the furnace busbars, M configuration, is shown to provide some passive protection against arc deflection.

Jan 1, 2011

By J. Petersen, T. Moyo, J. Dinga

The leaching of chalcopyrite in ferric sulfate media is notorious for its slow and inhibited kinetics. Different methods have been proposed to improve the kinetics, including the use of organic compounds as additives to the leaching media. In this study, the enhancing effect of methanol, ethanol, 1-propanol, and 2-propanol on the leaching of chalcopyrite in aerated acid ferric sulfate solutions using different reactor systems was investigated. The results revealed a clear improvement of copper dissolution by methanol and 1-propanol relative to tests with no additives under similar conditions. Operating a continuous-flow mini-column reactor yields surprisingly good results, potentially related to the maintaining of a consistent leaching micro-environment on the mineral surface. Scanning electron microscopy studies showed that the alcohols result in the removal of surface deposits formed during the anodic dissolution, potentially thus facilitating improved cathodic reduction of the ferric ion to drive the anodic dissolution.

Jan 1, 2023

By B. Besa, S. Nalukui

Globally, the demand for mineral products is ever increasing. Extraction of these mineral resources results in the continuous production of a huge volume of waste material, including tailing dumps. The mass of tailings usually exceeds the actual resource and often contains hazardous contaminants. This study investigated the effects of tailings disposal on soil, water, and air quality in the Nampundwe area. Water, soil, and dust samples were collected from different locations in the surrounding communities. The constituents analysed in the samples included copper, cobalt, iron, sulfate, and silica. According to the results obtained, some seepages occurred from the tailings impoundment to the shallow aquifer in the area. However, the general water quality meets the Zambia Environmental Management Agency (ZEMA) statutory limits. Recorded concentrations of sulfate (1500 mg/l), copper (1.5 mg/l), cobalt (1.0 mg/l), iron (2.0 mg/l), and silica were between 0.003 mg/l and 705 mg/l, which is far below ZEMA’s statutory limit. Silica concentration was also evident in the air. The highest concentration recorded was 260 ppcc (particle per cubic centimeter) recorded in July 2019 from the northern direction of the tailings dam. The concentration was below the statutory limit of 350 ppcc. The topsoil from the northern part of the tailings recorded a silica dust concentration of 39.9 ppcc. Iron was evident in the underground soil with a concentration of 8.01 ppcc, cobalt 0.005 ppcc, copper 0.051 ppcc, while sulfate was recorded as 0.41 ppcc.

Oct 9, 2024

By L. A. Cisternas, R. I. Jeldres, D. Calisaya

"Flotation of copper-molybdenum sulphide ores in seawater entails critical challenges such as selective recovery of molybdenite, effective pyrite depression, and reducing the lime addition required to reach highly alkaline conditions. It is essential that laboratory flotation tests aimed at solving these problems give reliable, reproducible results and indicate the correct approach for industrial operations. Rougher flotation of coppermolybdenum sulphide ores in seawater was investigated using two different cells: a modified Denver cell and a standard commercial cell. The effect of an organic reagent on the flotation performance was tested, and the fast/slow-floating model was used to describe the results. The modified Denver cell significantly improved the reproducibility of the flotation test results, due to technological enhancements such as the impeller being driven from below without a stator, which enables the whole froth surface to be scraped with a paddle at a constant depth and rate. Organic reagents are a promising alternative to inorganic reagents for depressing pyrite in seawater. However, further studies should be conducted to investigate their impact on molybdenite recovery, as well as to evaluate the possibility of depressing pyrite after molybdenite separation. The fast/slow-floating model was found to be appropriate for describing the flotation kinetics of the copper-molybdenum ores. The parameters are useful for comparing the performance at different conditions. IntroductionOwing to the increasing scarcity of fresh water, the use of seawater mining and mineral processing is becoming increasingly important (Cisternas and Moreno, 2014). Seawater can be desalinated by reverse osmosis, but this involves considerable costs, limiting it to the big mining companies (Akgul et al., 2008; Leidner et al., 2012; Ghaffour, Missimer, and Amy, 2013). Furthermore, desalination has environmental consequences (Lee, Arnot, and Mattia, 2011); for example, a desalination plant designed to process 2.5 m3/s requires an electrical energy supply of around 30 MJ/s. To supply this power demand, a thermoelectric plant burning bituminous/sub-bituminous coal mixtures at a thermal power generation efficiency of 35% might release around 1200– 1500 t of CO2 per day. Furthermore, the effluents from desalination plants are typically discharged into the sea, and their high temperature and ionic content inevitably modifies the marine environment, with unknown consequences. The direct use of seawater is, therefore, more attractive, but it also poses major challenges since seawater contains ions that adversely affect mineral recoveries. In particular, in the flotation of sulphide ores in seawater, the floatability of molybdenite is depressed (Castro, 2012; Laskowski, Castro, and Ramos, 2014)."

Jan 1, 2017

By M. de Beer

The conversion of carbon-containing feedstock into liquid fuels can proceed via the Fischer-Tropsch synthesis, which is catalysed using supported cobalt catalysts. These catalysts contain noble metals to facilitate the reduction of oxidic cobalt species in the catalyst precursor to metallic cobalt, which is the catalytically active species for the Fischer-Tropsch synthesis. This is thought to occur via hydrogen spillover, i.e. the diffusion of atomic hydrogen over the support from the noble metal to the oxidic cobalt moieties. Noble metals may also affectthe dispersion of cobalt in the active Fischer-Tropsch catalyst. The economic aspect of the addition of noble metals to the Fischer-Tropsch catalyst is discussed.

Jan 1, 2014

By P. Minkkinen, R. C. A. Minnitt

Particle size distribution analysis is important to many industries for assessing product quality, process efficiency, and compliance with contractual standards, while ensuring sample accuracy, and representativeness. Inaccurate particle size distribution results, arising from fines due to excessive handling can lead to penalties and buyer-seller disputes. A non-representative particle size distribution means samples will not accurately represent the chemical components either. Sampling blasthole cuttings poses challenges due to large material volumes, segregation, and uneven settling of particles in dense gold bearing ores. Commonly used sampling methods, such as spear or sectoral sampling, may lack representativeness. Particle size distribution analysis is crucial for evaluating sampling methods by comparing test sample representativeness against a reference standard derived from multiple particle size distribution analyses. Acceptable samples must fall within the 97.5% confidence intervals of the standard; deviations analyses lying outside these boundaries indicate a strong likelihood of segregation errors. A case study demonstrates this approach by using a 6.005 kg benchmark sample to assess two additional samples (1 kg and 5 kg), highlighting particle size distribution’s role in detecting sampling errors and refining protocols. An example of three test samples collected from reverse circulation drill cuttings compared to a standard reference sample is presented to illustrate a quality assurance/quality control procedure for reverse circulation drilling.

Oct 2, 2025