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By P. V. Avotins, D. R. Nagaraj, S. S. Wang

Xanthates and dithiophosphates are the most commonly used collectors in the flotation of sulfide minerals. Other reagents such as thionocarbamates, mercaptobenzothiazoles (MBT), mercaptans and xanthogen formates occupy niche positions in industrial collector use. Over the last ten years there has been much activity by chemical companies to develop new collector compositions. The new collectors are aimed at meeting specific process needs such as recovering an increment of valuable metals, improved sulfide separations, increased flotation kinetics, and reducing reagents costs. A review of the patent literature shows that American Cyanamid (Cytec), Dow Chemical, Phillips Petroleum, Sentrachem Ltd., Henkel, Montan Chemicals and Elf Aquitaine, among others, have been active in sulfide collector research. Several companies have achieved considerable success in laboratory and plant tests of the new collectors; however, commercial acceptance for plant usage has been slow. Those most advanced have been plant tested extensively and some are in day-to-day use. The new collector types in this category are: Modified thionocarbamates, dithiophosphinates, organic sulfides, trithiocarbonates, monothiophosphates, and modified thioureas. Others such as substituted mercaptobenzothiazoles and monothiophosphinates have been tested in the laboratory. The chemistry of collectors developed in the last 10 years, their preparation, physical properties and their potential for commercial use are reviewed in this paper.

Jan 1, 1994

By J. J. Scott

Friction Rock Stabilizers, trade name Split Set*, is a new support system invented by the author and under development by Ingersoll-Rand and Lee-Norse Company. Split Sets are a substitute for standard bolts or fully grouted resin bolts and have certain advantages which are: 1. Improved safety for the miner 2. A rational design is possible based on rock mechanics principles 3. Supports can be made either to be yieldable or rigid 4. Supports can be used to build a roof beam or to suspend roof material 5. It is cheaper than the resin system and costs about the same as standard bolts.

Jan 1, 1974

By Charles C. Y. Chen, Duane R. Skidmore

Batch leaching of Ohio #1, Ohio #4A and Ohio #5 coals was conducted with the thermophilic. sulfur, oxidizing microorganism: Sulfolobus acidocaldarius. Four different size fractions of each coal, with median sizes of 508, 200, 90, and 49 microns, were subjected for 10 days to leaching in a 5% coal-water slurry at 72°C and a pH of 2. Release rates and extent of sulfate and iron I1 and I11 ions from the coals during the leaching process and distribution of sulfur forms (sulfate, pyritic and organic) in the coal samples before and after treatment were determined. Data indicated that Ohio #1 coal, with an initial sulfur content of 0.6%, showed no significant changes with leaching in total sulfur content or forms of sulfur. The Ohio #4A coal, with initial total sulfur content near 5%, yielded product, for sizes below 200 microns with 90% reduction of pyritic sulfur while the extent of organic sulfur removal varied with coal particle size. Results similar to those for Ohio #4A were observed on the Ohio #5 coal, which had an initial total sulfur content of 3% and a final sulfur content near 1%. The findings were interpreted in terms of basic biological, chemical and physical mechanisms.

Jan 1, 1989

By J. P. A. Hortley

In conventional electrolytic copper production, looped copper starter sheets, on which the copper is deposited, are supported by hard-drawn copper bars. These bars have cross-sectional areas of between 1 and 1.4 in2. The suspension bars serve two purposes: firstly to support the cathode, which can weigh up to 150 kg, and secondly to introduce the electric current. IYI examined these two requirements in detail to see whether a better design could be achieved. Considering firstly the current carrying requirement, it wee noted that under normal refinery conditions, each cathode carries between 400 and soak. If one applies the generally accepted rule that 1 in of copper can carry 1000A4 a suspension bar need theoretically contain only 1/2 in2 of copper. This contention is supported by the fact that the 500A current passed through the cathode also appears to pass quite satisfactorily through the two support loops, which have a cross-sectional area of approximately 0.35 in 2. Turning now to the strength requirements, the cross-section of hard-drawn copper bar required to support a 150 kg cathode is relatively small, and easily met by the present designs. It is not, however, the static load applied by the 150 kg cathode immersed in the electrolyte which causes the damage to the hard-drawn copper, or even the increased static load of a 100 kg man standing on one foot in the centre of the bar; the damage is actually caused by the dynamic loads applied to the bare when they are dropped, thrown into containers, lowered too rapidly into the cell, or otherwise mistreated. The important requirement is therefore that the bar does not permanently bend. Its proof stress of limit of proportionality, rather than the amount that it deflects under static loading, should be the strength criterion. With the hard-drawn copper normally used for the manufacture of suspension bars, it has been observed that the copper becomes annealed during use, particularly at the end of the bar where the current is introduced. Thus, after a relatively short time, the cathodes are in effect being supported by annealed copper bars.

Jan 1, 1978

By J. P. Ramsey

This is a description of the efforts of a research project intended to demonstrate methods of alleviating pollution from coal mine refuse piles and slurry lagoons. These are mainly derelict barren sites. Some are burning and some are vulnerable to wind erosion which causes air pollution. Some occupy valuable land near metropolitan areas. They are an integral part of the landscape of the Appalachian and Midwestern Coal Fields. They are important in the light of growing civic awareness of the great general problem of waste disposal and environmental improvement. In the V-shaped valleys of the Pocahontas Region, they continue to be piled higher and higher. In flatter topography, they tend to form broad, flat ridges. Some contain more metal forms than others and some have a minimum of metal, but weather to a fine talc, which chokes streams with a fine particle suspension. Most are burning or have burned, but burning or weathering, most all are sources of pollution to the atmosphere and to adjacent waterways. This demonstration project is being carried out at an abandoned mine near the town of Du Quoin in southern Illinois. It is jointly sponsored by the Truax-Traer Division of Consolidation Coal Company and by the Federal Water Pollution Control Administration of the Department of the Interior. The site area is a refuse pile and slurry lagoon, each of fifty acres. It is hoped that basic data from this study will be generally applicable to other sites and will provide a basis for rational and efficient engineering design of future reclamation projects. Most refuse piles have extremely long term capabilities to produce highly potent acidogenic oxidation products typifying the more serious aspects of acid mine drainage contamination. Numerous sites remain where the abandoned mine no longer discharges acid waters, but its associated refuse pile continues to generate significant quantities of acid and other oxidation products even after many years.

Jan 1, 1969

By J. Stachulak

This paper deals with theoretical considerations and practical applications of ventilation network calculations, based on mass flow rates and performed by computer simulation in our deepest operating mine - Creighton. The paper also deals with natural ventilation. In the usually accepted air-flow theory, the air is assumed to behave like an incompresssible medium. This introduces considerable error where temperature and pressure changes are great. Therefore, any study of the air flow in deep mines, must take into account compressibility. Basing ventilation calculations on mass flow allows a distinction to be made between air leakage and such quantity changes which occur due to air density changes. The energy which is required to convey one pound of air through a mine can be obtained by adding all head losses hL (ft-lb) of the ventilation paths through which the air flows. However, this total energy will not be correctly expressed in a compressible fluid by summing all pressure losses PL = hL x d (ft-lb/ft3 = lb/ft2) d = density. There is a law of mass conservation, but no law of volume conservation. Natural ventilation is caused by the conversion of heat into mechanical energy and not by the difference in upcast and downcast densities, as often believed. In an existing mine natural ventilation can be determined correctly by plotting a pressure volume diagram and measuring the area ? [ ] vdP = hN, where v = specific volume, or by measuring the sum of all friction losses and work provided by a fan. These procedures are tedious. The natural ventilation head (hN) can be approximated by the equaticn hN =[ ] tdZ. Where T is the average absolute temperature, t air temperature and Z elevation. In Prof. R. Greuer's computer program this determination of hN is automatically done for every mesh of the network.

Jan 1, 1980

By D. W. Park

The Longwall Strata-Control and Maintenance System (LoSCo-MS) is a software and data-communication system developed at the University of Alabama. This system integrates real-time shield monitoring, data presentation, analysis and the forecasting of forthcoming events. The main objective of this system is to provide stability information on longwall panels, including excessive shield load, low setting pressure, leg leakage, poor shield performance and imminent maintenance problems. Analyses of various mining and geological parameters were also performed to determine past and present roof characteristics and to forecast roof loading patterns for the following mining cycles, the next periodic weighting, etc. A local coal mine in the Warrior Coal Basin has adopted this system to provide daily evaluation of ground stability and maintenance problems in their longwall panels. Two years of experience with this system is covered in this paper.

Jan 1, 2000

By N. S. P. Kumar

INTRODUCTION Development work at Carr Fork Mine of Anaconda Copper Company in Tooele, Utah commenced in August 1974. A decision to install an underground gyratory crusher for primary crushing run-of-mine ore and waste was made in 1976. Higher throughput rates, larger reduction ratios and greater flexibility in terms of meeting immediate and expanded production needs were the main reasons for selecting the gyratory crusher over the jaw crusher. UNDERGROUND MATERIALS HANDLING Underground crushing and conveying system was designed for a capacity of 16,300 mtpd of ore and waste on a 2-shift, 5-day week basis. Engineering and design of crusher complex was performed by Anaconda engineers at Carr Fork. Figure 1 represents the longitudinal section of mine showing the general materials handling system. Mine area is trackless except for materials and production haulage which is run on rail track on both 1200 and 970 levels. Ore from stopes and waste rock from development headings are handled by 3.8 cu m (5 cu yd) Jarco scoops and dumped into 2.4 m (8 ft) diameter ore and waste passes at the 1200 level. The material gravitates down to the 970 level where it is loaded into 12 cu m (420 cu ft) ASEA mine cars using side loading chutes. The muck train, consisting of 15 to 18 cars and two 27 mt General Electric trolley locomotives, is hauled over a distance of 2,300 m (7,550 ft) to

Jan 1, 1981

By K. H. Al-Rawahy

Mineral resources comprise of metallic, non-metallic, and fossil fuels. Our civilization, and the associated economic and industrial developments are inherently dependent on the availability and use of minerals. This is evident from historical development and identification of civilization eras throughout human history: the stone age, the iron age, the bronze age, and the current computer age. This paper deals with the depletable fossil fuel sector of minerals; this is represented by crude oil, natural gas, and coal. Fossil fuels provide approximately 80% of total global primary energy supply; the rest being provided by renewables (wind, hydrothermal, solar), nuclear, and biomass. Economic, industrial, and population growth will, inevitably, lead to an increase in demand for energy. In general, per capita energy consumption is correlated with per capita income, with the US showing the highest energy use per capita, and South Asia having the lowest. This paper examines the underlying interrelated issues (factors) of energy reserves, production, scarcity, depletion, economic, and technological factors and impact on long term availability and thus sustainability. Is it possible to extend the time to economic depletion of these resources? This will have an impact, direct or otherwise on total energy availability, and the inter-temporal allocation of the resource. Specific economic and physical parameters relevant to mineral supply and their respective impact on depletion, and inter-temporal welfare are investigated. These variables include own price, substitute price, population, income, technical innovation-both on supply as well demand, and resource substitution.

Jan 1, 2007

By Michael Li

Unsaturated flow and solute transport were studied in three large columns measuring 1.5 m diameter x 2 m height, loaded with up to 3.7 t of oxidised waste rock, which was excavated from the Stratmat pile at Heath Steele Division, Noranda Inc. and contained elevated concentrations of zinc in the pore water. The bottom of each column was partitioned into 37 squares, each of which was drained independently. Following rain simulations at the top of the rock bed, the drainage in each drain port was monitored for volume and physicochemical parameters at pre-determined intervals. This paper describes some of the observations resulting from the experiments. The main conclusion of the study is that unsaturated flows in waste rock are heterogeneous, and flow channelling is ubiquitous. The results imply that the transport of solutes from oxidised waste rock to its toe drainage is subject to various controlling mechanisms, including geochemical equilibrium control and successive pore water dilution control.

Jan 1, 2000

By R. V. Ramani, K. V. K. Prasad

Forecasting mined grade variability from exploration information is a challenging task in mine planning. For effective planning of activities, such as workplace scheduling, ore grade quality control, etc., development of realistic numerical simulation models of in situ variability from exploration information is an essential first step. Geostatistical conditional simulation (GCS) is one of the well known methods to develop such simulations. Recently, stochastic fractal models based on the assumptions of scale-invariance and self-similarity have been used for developing simulations of several natural phenomena. It has been suggested that these models might permit the generation of short-scale variability information from exploration data with greater fidelity when the data satisfies the attendant assumptions. In this paper, stochastic fractal models are reviewed, and their relationship to geostatistical variogram models is examined. A comparison of the two simulation techniques has been performed using coal sulfur data from a mined-out coal property. The results of this comparative analysis are also presented in the paper.

Jan 1, 1993

By Mehmet Maral

Various types of Tertiary (Miocene) lignite occurrences had been formed and alternated with volcano-sedimentary Bigadiç Formation in the field of study, which resides in the middle and eastern parts of Biga Peninsula. The focus of the study is to identify the geochemical and petrologic properties of coal occurrences and the formation mechanism of the deposits. A comparative study of the deposits will also be studied. Biga Peninsula is a very rich zone in terms of both metallic ores and industrial minerals. Most of the metallic deposits and industrial occurrences in the region have been known and mined throughout the history. This richness of the region is related to the volcanic and tectonic activities that have developed during different geological periods. These activities are the main reasons of weathering and alteration phenomenon.

Jan 1, 2005

By M. Kawulak

The necessity to protect the environment can limit mining activities and make some areas less attractive for the prospecting and exploration of mineral deposits. In Poland, the main environmental factors that restrain Irumng are: 1. Regional A Protection of the landscape B. Protection of ground water from contamination and depletion 2. Local A Conservation of fertile soils B. Conservation of forest resources C. Preservation of natural, cultural, and historical monuments The regional factors listed above that can limit mining are presented on a map of Poland. These data, combined with maps of known and potential mineral deposits, make it possible to delineate general levels of limitation for various mining-related activities varying from "no existing environmental limitations" to "no allowed industrial activity" As an example, a compilation of such data is presented for lignite exploration and mining in Poland. Lignite deposits occur within Upper Paleocene to Upper Miocene clastic strata at depths ranging from a few to 300 m. The thickness of the lignite is generally a few meters, but can locally reach over 100 m within grabens. As a result, the overburden-to-lignite thickness ratio varies from less than 1 to over 20. Within the same Tertiary strata, and within overlying Quaternary strata, several aquifers exist that produce good quality water that may be contaminated or depleted during lignite mining. The protection of these ground waters is the main factor limiting lignite mining and should be addressed in mining and environmental policy and planning.

Jan 1, 1996

By A. W. Easton

INTRODUCTION This presentation will address changing trade patterns in lead and zinc from the mid 1980's to the early 1990's. Lead and zinc deposits are developed where they are found in many parts of the world. As many are not in major consuming areas, there is significant international trade in both lead and zinc concentrates and in refined metal. Forecasts of mine production have been analyzed, primary and secondary refining capacity and future consumption levels have been estimated, to arrive at the changes in trade patterns expected during the next half decade. This paper will first address concentrate and metal trade patterns for lead, then for zinc, and finally some remarks will be made on captive mine/smelter agreements, on regional trade agreements, and on barriers to trade. I would like to note that. there is only a small international trade in semi-fabricated products such as zinc die-cast alloy, zinc oxide, lead oxide or rolled lead and zinc. Most of the world's zinc and lead trade is in concentrates or refined metal. LEAD TRADE PATTERNS Lead Concentrates Six countries are exporters of lead concentrates. Three countries are in the Americas - Canada, Mexico and Peru, with two in Africa - Morocco and South Africa (including Namibia), and Australia. Due to the limited growth in lead consumption and consequent minimum investment in new production facilities expected, mine and metal production levels and future consumption levels are not forecast to change much between now and 1990. Accordingly, the tonnage of lead concentrates exported will remain essentially unchanged from these six countries. In total they have exports of 480,000 metric tonnes (metal content)* and by 1990 this figure is forecast to rise only slightly with the only increase taking place in Mexico. The concentrates are exported mainly to Western Europe & Japan. Apart from these six main lead concentrate exporting nations, a significant change is expected in the United States. In the mid * All concentrate trade figures are based on metal content

Jan 1, 1986

By M. J. Shields

There are numerous suggestions in the literature on methods of obtaining representative samples of waste rock or mill tailings. Some suggested methods would result in thousands of samples and very high costs for a large facility. There is no general rule that can (or should) be followed, such as collection of a given number of samples per mass of material, per acre of impoundment, or per foot of drillcore. Each site is different, and the adequacy of sampling must be tailored to the site. A logical approach is to let the variability at the site dictate the number of samples that should be collected and analyzed, and then to quantify and evaluate the results by means of standard statistical methods.

Jan 1, 1998

By T. Vincze

Effective coal mine face ventilation, for remotely controlled and automated mining systems, is essential for the control of methane. The evolution of new mining equipment and methods has required changes and improvements in face ventilation methods. One emphasis today is on the use of remotely operated and automated mining systems that can be used to make continuous cuts of 6 m (20 ft) and deeper. U.S. Bureau of Mines research is studying ways to more effectively ventilate these extended cuts. Two face ventilation techniques that utilize either blowing brattice or a jet fan for deep cutting are examined in this paper. Bureau of Mines procedures for evaluating face ventilation systems are also discussed.

Jan 1, 1992

By J. A. Finch, G. Labonté

The behavior of four different redox sensing electrodes (gold spiral, black platinum, chalcopyrite, and galena) during roughing and cleaning flotation is examined and related to the flotation response. The results indicate that the solution potential (as sensed by the black platinum electrode) is different from that of the pulp potential (gold spiral) and is only weakly related to the flotation response. On the other hand, the potentials exhibited by the gold spiral and the two mineral electrodes are related to the flotation response. The transient responses of the gold and mineral electrodes during the addition of flotation modifiers could indicate the conditioning time required to achieve flotation or depression of selected minerals.

Jan 1, 1991

By A. P. Cook

Methane drainage on a mine-wide scale is a relatively new technology to South African coal mines. Shallow seams and apparently low methane contents have been assumed to result in less methane problems than experienced in other countries. The introduction of deeper mines however, has now resulted in methane drainage taking on a higher priority. Methane contents in the region of 12 m3\t have resulted in one colliery introducing drainage as a ventilation support. Although a low seam permeability initially indicated reduced potential for drainage, early borehole flows of 90 m3\m\year have since increased to 450 m3\m\year. Rapid inflow of methane into goafs and sealed areas from seams surrounding the main production seam at another colliery have warranted extensive evaluation of the methane properties of these seams with the projected introduction of predrainage from surface. Methane pressures in excess of 1000 kPa and contents in the region of 10 m3\t again give methane volumes suitable for drainage. Coal seam drainage ahead of mining is becoming more significant and is likely to see an increase in the near future. INTRODUCTION Methane gas is an everpresent hazard associated with underground coal mining. Safe working levels of methane in the mine atmosphere are normally maintained by ventilation practises, ensuring sufficient dilution of the gas. However in some cases the ventilation must be assisted by methane drainage, either from the mined seam, or from adjacent seams and strata, or from goafed areas. South African collieries have practised only limited methane drainage until now. Relatively shallow mining depths, and apparently low in-seam methane contents have been assumed to result in fewer problems with methane than are the normal for other countries. This is now being shown to not necessarily be the situation. Work carried out by the Coal Mining division of COMRO (Cook and Erwee, 1991) indicates South African production coal seams have very similar methane retention properties to those of coals in other countries, with seam gas contents of up to 12 m3/t. This awareness, as well as greater mining depths, and higher degrees of mechanisation, has resulted in higher priority being given to methane emission problems throughout the industry. Increased levels of safety, as well as possible commercial applications, are the main reasons for the interest now being shown in methane drainage. Not only is there possible applications in the present production coalfields, but South Africa has vast areas of coal reserves which are presently non-mineable, now being seen as possible alternative energy sources. Limited methane drainage is practised within the industry, but only on collieries that have identified specific methane problems that can be alleviated by drainage. Historically this has been restricted to surface drainage of longwall goafs, reducing emissions onto the faces. More recently, horizontal in-seam holes have been drilled, until now for bord and pillar sections, but the results are being evaluated for later application to shortwall faces. Adjacent seams pose problems at some sites and vertical and cross measure boreholes are now being considered.

Jan 1, 1993

By Karl-Heinz Bruemmer, Karl Wollers

1- Importance of Shafts for the Exploration and Extraction of Coal Deposits Coal mining in the Federal Republic of Germany is carried out in a depth between 800 and 1200 m below sea level (Fig. 1). The shortest connections underground in a mine and up to the surface are vertical shafts. Such shafts assume, with ventilation, manriding and the winding of material, the most important functions for the maintenance of mining operations. In the German coal mining industry, a difference is made between the main shafts providing a direct access from the surface to the deposits, and the so-called "blindshafts" which serve as a connection between two or several haulage levels underground. [ ]

Jan 1, 1976

By W. Petruk

Imaging is a fundamental requirement when characterizing minerals, ores and related products. Images are used for presentation, texture analysis, characterization, image analysis, identification, etc. The image mode that is utilized is dependent on the application, mineral properties and available instruments. Different instruments produce images that display different features. In order of increasing complexity they are: hand specimens, a non-polarizing microscope, polarizing optical microscope, scanning electron microscope (SEM), low vacuum SEM, microprobe, secondary ion mass spectrometer, staining, cathodoluminescence, tomography and others. Image analysis uses images produced with either an optical microscope or a SEM, but the SEM images are superior in this application. Key words: Mineralogy, Imaging, Mineral characteristics, Scanning electron microscopy, Optical microscopy, Cathodoluminescence

Jan 1, 2003