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By Lucas L. Costa, Luiz F. Lopes, Ludy C. Motta, Felipe P. D. Lopes, Sergio N. Monteiro, Lara S. Vasconcellos

"Environmentally correct materials like the lignocellulosic natural fibers, which are renewable and biodegradable, are being extensively investigated as possible substitutes for synthetic fiber in polymeric composites. Several natural fibers have never been thoroughly investigated as possible composite reinforcement. The fiber obtained from the leaves of the buriti (Mauritia flexuosa) palm tree is one example. Therefore, the objective of this work was to study the properties of buriti waste fibers, in amounts of up to 30%, reinforcing polyester composites.IntroductionIn the past century, the technological development gave priority to new synthetic materials with energy intensive methods of production. Today, there is a concern that conventional energy source such as petroleum, natural gas and coal are the main responsible for global warming. Therefore, the use of natural materials is gaining attention not only for the saving in process energy but also the renewable and biodegradable characteristics that make them environmentally correct. The lignocellulosic natural fibers extracted from cultivated vegetables like jute, sisal, hemp, coconut, flax, ramie and many others are typical examples. This type of fiber is being extensively investigated as a possible substitute for synthetic ones, especially the glass fiber, as composite reinforcement [1].A relevant example of lignocellulosic fiber substitution is nowadays occurring in vehicles. The automobile industry is applying composites reinforced with natural fibers to replace parts such as panels and seat cushions made of fiberglass or polymeric foams [4], as illustrated in Fig. 1. The practical reasons for this preference are that natural fiber composites present less damage to tools and molding equipments as well as relatively better finishing and less abrasive surface than corresponding parts made, for instance, of glass fibers. On top of these advantages, low cost is probably the main motivation for the industrial interest for natural fiber composites, especially in the case of residual fibers [5] or post-used fabrics such as jute sackcloth [6]. Natural fibers, however, are hydrophilic and will not form strong bonding with a hydrophobic polymer, normally used as composite matrix [1-3]. Another disadvantage is the heterogeneous characteristics of a natural fiber, which is typical of biomaterials. This results in a relatively great dispersion of dimensions and properties values such as the mechanical strength [1-3]."

Jan 1, 2008

By M Grinceri

The New MetroRail City Project was completed in 2007 in Perth, Western Australia. The project included construction of two underground stations, twin bored rail tunnels of 1.4 km combined length and cut-and- cover tunnels and dive structures of about 1 km total length. It is the first major underground construction project within the Perth central business district (CBD). This paper provides an introduction to the project and describes the geology and hydrogeology of the area. Ground conditions varied significantly along the alignment from soft estuarine muds in an area of reclamation to very dense cemented sands and very stiff to hard clays. Deep foundations for the project extend down into the bedrock below the CBD, a Tertiary siltstone/sandstone. Key geotechnical hazards encountered during the project are discussed. The building protection methodology on the project is described, including damage assessment, condition surveys, monitoring and protection of key structures.

Jan 1, 2008

By A H. Bagherieh, S Mesroghli, H Jorjani, S Chehreh Chelgani

The rare earth elements (REEs) assay and recovery in leaching processes is being determined using expensive analytical methods, ICP-AES, and ICP-MS. This paper presents a neural network model to predict the effects of operational variables on the lanthanum, cerium, yttrium, neodymium recovery in the leaching of apatite concentrate. The effects of leaching times: ten to 40 min, pulp densities: 30 to 50 per cent, acid concentrations: 20 to 60 per cent and agitation rates: 100 to 200 rpm were investigated and optimised on REEs recovery in laboratory at a leaching temperature of 60¦C. The obtained data, on the laboratory optimisation process were used for training and testing of a neural network. A feed-forward artificial neural network with 4-5-5-1 arrangement, was capable of estimating the REEs leaching recovery. Neural network predicted values were in good agreement with the experimental results. The correlations of R = 1 in training stages, and R =  0.971, 0.952, 0.985 and 0.98 in testing stages were results for Ce, Nd, La and Y recovery predictions respectively and that theses values are considerably acceptable. It was shown that the proposed neural network model accurately reproduces all the effects of operation variables, and can be used in the simulation of a REEs leaching plant.

Jan 1, 2008

By James G. McKelvey

Owners have seen several major tunnel projects in recent years fall victim to a general reduction in the number of bidders as well as an erratic range of pricing. It should be noted though that this is not a universal trend and some projects have seen good competitive bids. Contractual terms and conditions are an important factor in attracting good competition. The Front End documents of tunnel projects have come under increasing scrutiny as tunneling contractors in the U.S. industry are looking much more closely at their risk exposure in the contract terms and conditions. Considering the amount of tunnel construction work upcoming in North America, it is important that General and Special Conditions are put together in a way that provides a reasonable basis to execute the Contract and also provide a fair, balanced and swift way to resolve disputes.

Jan 1, 2008

By Nadir Plasencia, Rogerio: Neves Mota

The evaluation of vibrations induced to build structures is one of the main concerns when dealing with blast works. EDP, the main Portuguese producer of electricity is presently incrementing energy production in some old hydropower dams by installing new production plants. The need for not disrupting production during the upgrading works causes some concerns related with vibrations induced to the production engines. Vibration estimation was performed in two of these dams, constructed in a granite environment, by performing controlled blasts. For each dam site, some vibration transmissivity laws were developed with the fitting process.

Jan 1, 2008

By D. Rutledge

Discrete (digital) signal processing techniques are proving to be very valuable tools for miners using the block cave method. Waveform analysis of different measured signals associated with active mining provides valuable information on production dynamics and safe operation of the mine. For example, correlation of the 3D surface displacement velocity waveform and the production output waveform reveals a remarkably predictable time-varying physical process. Studying the geometrical and temporal relationship between these two signals opens a broad window through which new management techniques become apparent. In this paper we discuss the signal processing techniques used to study these relationships, as well as the related implications for mining. This research was carried out in association with the Chevron Mining underground molybdenum mine in Questa, New Mexico. Some of these new techniques will be integrated into the decision management process at the mine and will provide insight on ore production, draw control, and safe reclamation. The science of signal processing involves the analysis and interpretation of physical processes that vary with time. Two general categories of signals1 are recognized. A continuous signal is a waveform of varying amplitude that is continuous in time (such as a sine wave). A discrete signal is a sequence of quantized values. The independent time variable and amplitude are sampled periodically such that we only know the value and shape of the waveform at the sampling frequency. Displacements measured by a Global Positioning System (GPS) receiver are an example of this. Discrete signals may be studied in the time, frequency, autocorrelation, or wavelet domains. In this paper the amount of ore extracted from the mine and the measured surface displacements are analyzed in the time domain.

Jan 1, 2008

By Thomas V. Falkie

In bygone days, the mineral engineer spent most of his/her time on the technical aspects of designing, building, and managing mineral operations. In the last few decades, mostly since the 1960s, increasing amounts of engineering man power and time are spent dealing with federal, state, and local government agencies, laws, and regulations. It is not possible to plan, design, build, or operate mines, mills, smelters, or even office buildings without detailed consideration of government regulations and permitting requirements dealing with environment, worker health and safety, etc. The four chapters of this section provide an overview of the social, legal, political, environmental, and health and safety aspects of mineral enterprise. The section sets the stage for the working engineer/geologist in industry, government, consulting, or academe and points the direction for more detailed study in each of these areas.

Jan 1, 2008

By Jewel A. G. Gomes

Lead has long been an USEPA priority pollutant and an important environmental and health concern because of its toxicity at ppb levels. In light of health and exposure data for lead, the EPA has set standards for Maximum Contaminant Level (MCL) and a MCL Goal (MCLG) as 15 ppb and 0 ppb, respectively. An accurate and rapid measurement of lead in the field remains a technical challenge. In this work, a relatively new method of deploying a nanoband electrode system using anodic stripping voltammetry has been optimized by changing deposition potential, electrolyte, and plating time used for the measurement of Pb(II) in water samples. Green rust has been proven to be an efficient intermediate matrix for removal of lead contaminants. We also report here the removal efficiency of lead using green rust produced by electrocoagulation, both directly and indirectly. Lead containing floc was also characterized through XRD, SEM, and EDAX techniques.

Jan 1, 2008

By P F. Knights, P Boniwell

This paper investigates the causes of low effective utilisation of the production drill fleet at the Telfer Underground Gold Mine, as measured by the percussion hours per shift. The first part of this paper focuses on a site time and motion study conducted to accurately identify shift time allocation and optimal drilling parameters (manual versus automatic, and suitable flushing mediums for varying ground conditions) as well as quantifying the business potential for automated or remotely operated production drilling. The second part of the paper focuses on the rate of successful hole completion for automated production drilling during shift changes. Two main areas of drill optimisation were identified. Firstly, a site-specific drilling procedure was established so as to ensure that all operators were drilling using optimal parameters. Total production metres per rig increased by 10.7 per cent as a result of the implementation of this standard. It was observed that a 25 per cent faster overall drill cycle was achieved using air mist flushing, and that manual drilling achieves a 19 per cent faster overall drilling cycle in comparison to automated drilling. Secondly, routine provision to the maintenance department of automation reliability reports that outlined the principal causes of unsuccessful hole completion led to an increase in production metres of a further 4.1 per cent, measured between January 2007 and August 2007. First hole automation reliability increased from 39 per cent to over 77 per cent over the same time period. Second hole automation completion was increased to 74 per cent, leading to a higher proportion of production achieved through automated technologies.

Jan 1, 2008

By V. Iordachita

In the beginning of the third millennium, the world mining industry has to cope with many challenges; the continuous need for mineral resource deposits and the mostly unsolved economic efforts should be accompanied with ecologic measures mankind has to take in order to avoid self-destruction. The present paper analyses the possibilities of using underground mining spaces in Romania for storing dangerous waste and suggests viable solutions. The characteristics of dangerous wastes and their disposal in suitable underground spaces are analyzed. Also, some methods for deactivating dangerous solid wastes as well as the importance of monitoring underground spaces in order to eliminate environmental impact risks are presented.

Jan 1, 2008

By Chris Curfman

Sustaining Business in a Rapidly Changing Environment Topics: ?Sustainability @ Caterpillar ?Workforce Management ?Regulatory Environment & the Reality of living in a Carbon Constrained World

Jan 1, 2008

In this study, the flotation performances of ethoxycarbonyl thionocarbamate (ECTC), dialkyl thionocarbamate (DATC) and xanthate copper sulfide collectors are compared by the structure-reactivity relationship using generalized perturbation theory and density functional calculation at the B3PW91/6-31G(D) level. The electron-donating power of xanthates is strong and, therefore, xanthates can strongly react with metal cation on the surfaces of copper and iron sulfide minerals through the formation of normal covalent bonds. This explains the poor selectivity of xanthates and also the high pH levels (above 13) required for the flotation separation of copper/iron sulfide minerals. DATCs are more selective for copper sulfide flotation, particularly against gangue iron sulfides. Although less powerful than xanthates, DATCs can perform copper/iron flotation separation at lower operating pH (commonly at pH levels below 11.5). ECTCs use an ethoxycarbonyl replacing an alkyl N-substituent in DATCs. The presence of the ethoxycarbonyl group effectively changes the functional group of collector from -C(=S)NH- to -C(=S)NHC(=O)-. The strong electron-withdrawing ethoxycarbonyl group adjacent to the C=S group decreases the electron density of the sulfur atom, which improves ECTC?s selectivity against iron sulfide minerals at slightly alkaline conditions. The lowest unoccupied molecular orbit (LUMO) of ECTC, which is constituted by the pz-orbit of every atoms in the conjugate -O-C(=O)-N-C(=S)-O- group and which is pleased with accepting richly d-orbital electrons (feedback electrons) from the (t2g)6(eg)3Cu(II) or t6e4Cu(I) configuration of copper cation on the surfaces of copper sulfide minerals, resulted in the formation of dative p-bond. The iron atom, which has a (t2g)6Fe(II) or (t2ga)3(ega)2 Fe(III) configuration on the surfaces of iron sulfide minerals (Fe(III) is the predominant composition at alkaline conditions), has difficulty in offering its d-orbital electrons (feedback electrons) to ECTC?s LUMO. ECTC collectors are powerful for copper sulfide minerals and very selective against iron sulfides, which has been further confirmed by UV spectra and bench-scale and industrial-scale flotation tests.

Jan 1, 2008

By Christopher Haycocks

Self-supporting, open stoping underground mining methods are some of the earliest, starting with the prehistoric flint mines of Europe and the Egyptian gold mines of Nubia in the time of the pharaohs. When the early miner created an opening, it had to be inherently stable and self-supporting to enable him to continue. Therefore, as mining progressed beyond simple gophering, self-supported open stoping methods were devised to meet the needs of individual ore bodies. Timber for support appears in mines as early as 1000 BC, but this was for no more than local ground control. The ingenuity of mining engineers through history has so refined open stoping methods that today they produce more tonnage than any other mining system. Self-supported open stoping finds its application in moderate to strong rocks that exhibit little jointing or fiagmentation. Good back, hanging wall, and footwall conditions that require no more than incidental support are an essential part of these mining methods. Open stoping methods find applications in all inclinations of ore body from flat to vertical, and where ore movement may be either mechanical or under the influence of gravity. Table 18.0.1 demonstrates the range of ore bodies suitable for open stoping, with particular reference to their dip and the deposit thickness. Most of the flat-dipping applications use ore pillars for overall support and ground control that may be recovered under some conditions after completion of normal stoping practices. In steeper ore bodies, rib, crown, and sill pillars used to block out the ore may be recovered subsequent to the completion of stoping. Open stopes are frequently filled to facilitate pillar recovery. Two of the methods, vertical crater retreat (VCR) and shrinkage stoping, utilize fragmented ore for temporary support in the stopes. In these two cases, the stope is not strictly open until after drawdown.

Jan 1, 2008

By Clay Haynes

In 2005, Black & Veatch Corporation began designing a raw water conveyance system for San Luis Obispo County from Lake Nacimiento to the city of San Luis Obispo. The first element of the water transfer system will be a raw water pump station and lake tap. The wet well of the pump station will consist of a concrete lined shaft approximately 180 feet deep constructed in the very incompetent sandstone of the Vacqueros Formation. The lake will be wet tapped at approximately 172 feet below grade using a slurry earth pressure balance tunnel boring machine. The 48 to 72-inch finished diameter microtunnel will be approximately 500 feet in length. Construction is scheduled to begin in the winter of 2007.

Jan 1, 2008

By Antonio de Lucas, Juan Francisco Rodríguez, Ignacio Gracia, Mª Teresa García

"The amount of waste of Polystyrene (PS) foams is increasing in last years due to their use in insulation, protecting and, storing many different food products. Conventional methods of recycling such as crushing and shrinking by heated air or frictional heat have the disadvantages of molecular degradation, resulting in a reduction of the quality of the recycled polymer. Dissolution and shrinking with suitable solvents is one of the cheapest and more efficient ways of polystyrene recycling but in the process of the solvent recovery by distillation a certain degree of molecular degradation is produced. In this way, CO2 supercritical technology appears as an interesting alternative for the elimination of solvent. This work proposes a global process to polystyrene recycling in two steps: a polystyrene dissolution with a suitable “green” solvent followed by its elimination by supercritical tecnologhy. In order to develop a “green process” the constituents of essential oils, limonene, terpinene, cymene, and phellandrene, are selected as the most appropriated solvents. Introduction In the last years, disposal of the non-biodegradable plastic wastes has been recognized as a serious environmental problem. Recycling these wastes has great interest in order to prevent the environmental pollution and to preserve natural sources (1, 2, 3). Since the Polystyrene foams (PS) is one of the most used foam in isolation, protecting and food storage most of recycling work is concerned with this polyolefin (4). The two main alternatives for treating polymer wastes are energy recycling, where wastes are incinerated, and mechanical recycling (5). Environmental argumentations such as toxic emissions are building up a public resistance against incineration process (6). Mechanical recycling is a popular recovery path for manufacturers and is carried out on single-polymer waste streams. Any way, the market for recycled products can only be found if the quality is close to that of the original. Unfortunately the process of classification and further recovery of these wastes makes them often more expensive than virgin plastic (7, 8). Solvent extraction is one of the cheapest and more efficient ways for PS recycling. If it is done in house of waste producers the separation between plastics could be easy and effective and the transport costs would be eliminated."

Jan 1, 2008

By Scott M. Doehla

A proposed rehabilitation of a 200,000 sf, 75-foot high steel-frame building at the former U.S. Navy Yard in Brooklyn, New York required the review of existing foundation data and an investigation of the foundations with respect to their condition. The building was constructed in stages between 1856 and 1933, including several expansions and interior equipment with isolated foundations. The building has clear spans on the order of 50 feet and at one time supported cranes allowing transport of heavy equipment through the building. The proposed rehabilitation is to include a food manufacturing center and office space having multiple stories. Original construction drawings, available from the Brooklyn Navy Yard Development Corporation?s drawing archive, were reviewed to determine the foundation system supporting the structure. The original drawings provide a window into the methods utilized during late 19th and early 20th century pile foundation construction. The review revealed that the building is supported by pile foundations ranging from timber to concrete-filled steel pipe (depending on the year of construction). Annotations including pile driving records were available on some drawings indicating the design and as-built capacity (using the ENR formula for driving resistance). An investigation consisting of test borings was performed to identify the subsurface conditions underlying the building for evaluating theoretical capacity of the piles. A test pit investigation was performed against existing columns within the structure to expose the piles and pile caps for inspection pertaining to pile condition. The test pit investigation revealed methods utilized during original construction to integrate new columns with existing floor slabs, the use of below-grade brick arches to support a floor slab, and the condition of timber piles which were likely installed up to 120 years ago. The observations made within the test pits were compared with original drawings to evaluate the accuracy of these drawings.

Jan 1, 2008

By Jurgen te Kook

State-of-the-art for subsidence calculation are stochastical models. Although these models were successfully used all over the world they have their limitations due to the fact that they are not based on mechanical laws. For example the models did not take the rock mass structure and the rock mass characteristics into account. Therefore in a research program the skills of geomechanical numerical models for subsidence calculation were investigated. A case study shows that numerical models which are in principle based on the elastic theory are suitable for subsidence prediction. Due to the principles of these models the results are not sufficient in the case of multiple seam extraction. More extended geomechanical numerical models like FLAC and UDEC were investigated in further steps of the research work. Up to now large area geomechanical models require unrealistic long calculation times if the level of detail is similar to that of small scale calculations. Due to this it was necessary to implement a simplified description of the rock mass structure and characteristics. Different case studies show that this approach is successfull for subsidence calculation by numerical geomechanical models even for multiple seam extraction.

Jan 1, 2008

By F. Raupp-Pereira, G. G. Cunto, J. A. Junkes, D. Hotza, V. P. Della

"The present work investigated the valorization of wastes as alternative raw materials for ceramic industries. Different industrial wastes based on the SiO2-Al2O3-CaO system and classified as non-hazardous were selected: sludge from varvite cutting process, sludge from gneiss breaks processes, sludge from filtration/clarification of potable water and a clay classified also as waste. All as-received residues were characterized by X-ray fluorescence, differential thermal analysis, thermogravimetry and particle size distribution. The applicability of these materials in ceramic formulations was then evaluated. The formulated mixtures were subjected to forming by pressing and extrusion followed by thermal treatment. After optimization of the processing conditions, the properties of the samples sintered at different temperatures were also evaluated. The waste materials studied proved to be alternative raw materials to natural mineral resources for the ceramic industry.IntroductionOne of the most important problems that have accompanied the humanity in recent decades is the environment’s degradation. In the same context, the natural resources exploration and technological development are phenomena which, if aren’t controlled, can cause ecological disequilibrium with unpredictable consequences [1]. It is in this perspective that recycling of various wastes assumes relevant importance.The recycling, understood here as the waste process reuse, is a common practice in the First World countries, where the raw materials have strategic aspects and the disposal techniques of solid wastes have considerable economic costs. In Brazil, the ecological conscience begins to be aroused due to, in the last ten years, the implementation of stricter laws for environmental control, in general, and licensing of waste generating from industrial activities, in special. The terms “residue” or “waste” are normally used to describe what remains of a production process; when an application for this material is not found. When wastes or residues are susceptible to be incorporated as raw materials or energy sources in a new material production, they can be understood as by-products [2].The valorization of industrial wastes is important, due to the need to pollute less and give an ecologically correct destination for wastes. The waste recycling, independent of its kind, presents several advantages in relation to using primary natural resources, such as reduction in the volume of raw materials extraction, lower energy consumption, lower levels of pollutant emissions and improvement of the health and safety of the population. The most visible advantage of recycling is the preservation of natural resources, extending its life and reducing the destruction of landscape and ecosystems [3]."

Jan 1, 2008

By Asok Kumar Das

"In steel making ferroalloys occupies a commanding role for production of varied quality of steel. Ferroalloys enable alloying elements such as chromium, silicon, manganese, vanadium etc to be safely and economically introduced into metallurgical processes thus giving certain desirable properties of the alloyed metal. Their importance grew with the progress of the steel metallurgy which implied more diversified alloying elements, in better controlled quantities, in purer steel. The ferroalloy industry became a key supplier to the steel industry. Production of ferroalloys generally involves the use of Electric Arc furnace(EAF) into which raw materials(e.g. various metal ores, quartz, coke, lime etc ) with relatively fluctuating physical compositions are loaded. Due to this, one of the major environmental impacts of producing ferroalloys is the emission of dust and fume from the smelting process. INTRODUCTIONFerro Alloys are essential ingredients used for refining, de-oxidation, desulphurization and alloying addition in the production of different types of steel and hence Ferro Alloy industry forms a back bone of iron and steel in the world. Indian ferro alloy industry is more than 45 years old. It produces most of the bulk ferro alloys and a large number of special ferro alloys. The present installed capacity of the Indian ferro alloy industry is sufficient to meet the requirement of existing level of indigenous steel production of about 46 million tonnes. Revised National Steel Policy – 2008 envisages production of more than 100 million tonnes of steel by the year 2011-12, at proportionate annual growth rate per annum. The focus of the policy is to achieve global competitiveness not only in terms of cost, quality and product-mix but also in terms of global benchmarks of efficiency and productivity. In order to achieve the objectives of National Steel Policy and also to meet the requirement of ferro alloys, the Indian Ferro Alloy Industry has to gear up in terms of enhancement in production capacity, sourcing of raw materials, up gradation of technology, improvement in productivity, automation / mechanization, customer satisfaction etc."

Jan 1, 2008

By B. Nebreda, I. Vegas, R. Vigil, O. Rodríguez, M. I. Sánchez de Rojas, M. Frías, R. García, J. Urreta

"This paper shows the possibility of reutilize paper sludge waste as supplementary cementing material for the cement manufacture. This industrial waste consists essentially of a mixture of organic matter (30%) and inorganic compound, such as calcite and clay minerals. The raw paper sludge does not present pozzolanic properties, but once calcined at 650ºC during 2 hours, exhibits high pozzolanic activity, similar to silica fume at 28 days, as a consequence of the transformation of kaolinite into metakaolinite. Calcined paper sludge was used as partial Portland cement replacements of 0, 5, 10 and 20%. Enhancement in compressive strength was appreciably obtained for 10 and 20% substitution levels from 7 days on. Furthermore, calcined paper sludge slightly reduces the initial and final setting times of cement paste. Introduction Natural pozzolanic materials have been ordinary used in different aspects of construction, mainly for their influence on the microstructure and durability of blended cement matrixes [1, 2]. Due to the regulations of environmental protection, many researches are focusing on the possibility of obtaining pozzolanic materials from industrial wastes and not from natural materials (ceramic wastes, silica fume (SF), activated clays) [3–5]. One of the most used pozzolanic products is the metakaolin (MK) obtained from the activation of natural clay (kaolinite). The positive effect that MK has on blended cement performances [6,7] and also the influence that curing temperature and matrix nature have on the reaction kinetics and stability of hydrated phases produced during the pozzolanic reaction, according to the studies carried out by Frías et al. [8,9] are well known. However, there is a worldwide trend towards the use of recycled products in cement industry. In this line, some authors have reported an alternative way of obtaining MK from waste paper sludge [10-14]. The raw paper sludge (PS), once calcined under controlled conditions (700-800ºC), produces a MK with pozzolanic properties [15-20]. The present research is part of an experimental study about alternative source for MK from the Spanish paper recycling industry and its use as supplementary cementing material. This contribution pays special attention to the option of reducing activation temperature below 700ºC. This fact has a positive effect in reducing the energy consumption, as well as in reducing environmental impacts associated with decarbonation of calcite. The chemical and mineralogical characteristics of raw paper sludge and derived calcined product are described. In addition, the influence and behavior on blended cement properties (setting times and mechanical properties) are also discussed."

Jan 1, 2008