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By Vladimir Lobanov, Pritchinm Alexander, Nikifor Ageev

"Sulfuric anhydride is one of the most voluminous technological emissions. The possibility of high-temperature SO2 oxidations without catalyst in presence of calcium-bearing filling materials (CaO, Ca(OH)2 and CaCO3) with obtaining of binding material on the basis of waterless calcium sulfate is studied. Due to application package HSC-4 the thermodynamic analysis of the specified interactions is made and following conclusions are drawn: 1) Reactions are feasible in the all range of investigated temperatures (400 – 1000 °?); 2) The best results should be expected at use of ???; 3) The heat of reaction does possible autogenous behavior of process. The researches have shown: 1) Practical possibility of the process; 2) SO2 oxidation without the catalyst is feasible in presence of ???, Ca(OH)2 and CaCO3; 3) The optimum temperature range is 600-800 °?; 4) The content of waterless calcium sulfate in a product reaches 48% that makes it possible to use as the binding material; 5) At excess of ??? the degree of SO2 collection is nearer to 100%. Introduction At processing of sulfide raw materials in metallurgical furnaces the significant amount of sulfur, mainly in the form of sulfuric anhydride is escaped. Rich gases (SO2>3 %) are used for the sulfuric acid or element sulfur production. Chemism of sulfuric acid manufacturing is based on catalytic high-temperature oxidation of anhydride. Poor gases of metal works (SO2 =2,5 %) and power combustion units (SO2 =0,5 %) after clearing discharge into the atmosphere. Commonly, to recovery of weak sulfuric anhydride the chemical and physicochemical methods are applied. A few chemical ways of recycling sulfur dioxide are applied practically. In a number of methods for SO2 recovery a pulp of metals oxides (magnesium, zinc, etc.) with formation of sulfites is used. In other case sulfuric anhydride is catch by weak sulfuric acid in the presence of an oxidizer (pyrolusite ore). Methods of absorption SO2 by solid sorbents, (carbon fibers, silica gels, zeolites) are known and put into practice. Regeneration of the saturated sorbents is realized by thermal decomposition or extraction. Obtained as a result high-concentrated solutions are a commercial product."

Jan 1, 2008

Water retention, water loss and delay in tailings storage rehabilitation are major challenges for many Coal Mines. Work by Stewart, Backer and Busch in the early 1980s suggested that there were improvements to be made in tailings dewatering and density by the addition of flocculant. This prompted ACARP, in cooperation with Bulga Coal Management (Xstrata), to initiate a research project investigating the impact of flocculant addition on tailings deposition density, water retention and the tendency for tailings to form surface crusts suitable for subsequent rehabilitation. A polyacrylamide-based flocculant (200 - 250 g/tds) was injected into the tailings line immediately prior to disposal into the impoundment area. The flocculated slurry rapidly released clear water and created a beach due to the immediate increase in deposition density. The deposition density increased from 35 per cent w/w to 61 per cent w/w solids within 24 hours and continued to increase to 75 per cent, seven days after treatment. The water capture at the tailings storage facility improved by more than 90 per cent; water which would otherwise be lost from the circuit through retention and evaporation. The impoundment capacity had nearly tripled due to the improvement in initial deposition density from 420 kg/m3 up to 1163 kg/m3. Four weeks after disposal surface crusts were forming on the storage facility, suggesting that there would be less delay between cessation and tailings storage rehabilitation.

Jan 1, 2008

By G Lind

Bridging of production stopes in narrow vein gold deposits contributes to significant financial losses and production delays. Bridging is caused when underbreak in the stope production blast occurs, resulting in less than the designed stope blast volume breaking out during blasting. Jundee Operations in the Northern Goldfields of Western Australia extracts ore from its expansive narrow vein orebodies utilising longhole open stoping. In 2006 it experienced bridging in ten panels, or 8.77 per cent of all panels, as well as multiple bridging in 30 per cent of these bridged panels. The Jundee orebodies are west dipping with the bridged panels dipping between 44¦ and 62¦. This paper examines some solutions from the drill and blast design perspective to minimise bridging occurrences. It was found that the then current drill patterns and number of holes were adequate from a longhole stope design perspective. However, changes to the blasting design, specifically modifications to the blast delay initiation sequencing, primer positioning and blasthole dump combined with timely stope surveying and back analysis, were implemented with the aim of preventing bridging in this narrow vein operation.

Jan 1, 2008

By G Partington

A regional scale prospectivity model was developed for Papua New Guinea (PNG) to identify areas of porphyry Cu-Au mineralisation. Weights of evidence modeling techniques were used to determine spatial correlations between porphyry Cu-Au mines and predictive maps created from available spatial data. These predictive maps were then combined into a final prospectivity map. Despite limited regional scale data the model has successfully identified areas of known porphyry mineralisation as prospective and has also identified areas where new mineralised systems may be discovered with further exploration. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Paul J. Axtell

The results of in-situ geophysical cross-hole tests on improved soil by soil mixing (SM) and jet grouting (JG) are described. This testing was conducted on soil improved by SM and JG columns constructed in the downstream free-field of Tuttle Creek Dam near Manhattan, Kansas as part of the seismic retrofit. Results of similar geophysical testing performed on untreated soil in the vicinity of the Downstream Test Program (DTP) area, as well as beneath the embankment at several locations, are also described and used for comparison purposes. In-situ shear moduli are also compared with those determined in laboratory resonant column tests. The increase in stress wave velocities and associated shear moduli by SM and JG treatment are presented for use in liquefaction potential and seismic deformation analyses of SM or JG treated soil. This data is required to determine the decrease in liquefaction potential and earthquake-induced permanent deformations due to SM or JG with respect to that of untreated soil.

Jan 1, 2008

By H P÷llmann

Calcium aluminates, calcium aluminate ferrate and calcium aluminate sulfate were synthesised by solid-state reaction, sol-gel method, a self-combustion method and by a polymeric precursor process. For chemical sintering methods the base chemicals CaO, CaSO4, Al2O3 and Fe2O3 were used. As precursors for sol-gel synthesis metal nitrate hydrates and Al2O3-Sol were used. In order to synthesise pure phases by a self-combustion reaction glycine was used as fuel and nitrates as metal components. In the polymeric precursor process metal nitrates and diluted H2SO4 were used as metal components and the resin was made using citric acid (C6H8O7) and ethylene glycol (C2H6O2). Precursor phases synthesised by these different methods were sintered step-by-step in order to investigate the crystallisation. Further on single phases were hydrated and their hydration behaviour was studied by heat flow calorimetry, X-ray diffraction and cryo-transfer scanning electron microscopy. Due to the different synthesis procedures different hydration reactions and microstructures of the phases will be shown.

Jan 1, 2008

By Miquel Lamadrid, Changshow Sun, Chris Johnson

To reduce blasting overbreak and improve stope stability, several new blast designs were proposed for current and future stopes. Based on the analysis of the powder factor, and the extent of damage zone, the appropriate new blast design was selected. Excellent results were achieved from the new blast design. Comparing the new blast design with the old one, the largest of the overbreaks decreased more tan two times and average overbreak reduced more than two times. The new blast design is currently applied in all mining zones in Leeville underground mine.

Jan 1, 2008

Limestone formations in the United States can be subject to relatively high horizontal stresses due to the existence of tectonic loading of the limestone strata. Underground limestone mines use the room-and-pillar method, in which 12- to 18-m-wide rooms are typically excavated. The stability of these excavations can be compromised by the horizontal stress, resulting in a rockfall hazard. Rockfalls are the cause of 15% of all reportable injuries in underground limestone mines. Horizontal stress related damage can occur in the form of guttering along one or more sides of an excavation, roof beam buckling or oval shaped roof falls, with the long axis perpendicular to the major horizontal stress. Numerical analyses show that the pillar layout and orientation of the mine workings have an effect on the horizontal stress distribution within the roof. The effects of high horizontal stresses can be mitigated by orientating the heading development direction parallel to the maximum horizontal stress, reducing the number of cross-cuts and offsetting the cross-cuts to limit the potential lateral extent of horizontal stress related roof falls. The modeling approach described in this paper can be used as a tool to evaluate potential roof failure and optimize the stability of room and pillar layouts.

Jan 1, 2008

By R K. W Merkle, E Whiteman

The anorthosite complexes and related rock types of the Indian Precambrian shield are primarily associated with either cratons or mobile belts. They were metamorphosed under amphibolite to granulite facies conditions. The major rock types are chromite-bearing meta-anorthosites, amphibolites, basic granulites, pink granites and gneisses. This study was carried out on chromitite bearing samples from Sittampundi Anorthosite Complex (SAC), Tamil Nadu, to evaluate the nature and textural settings of platinum-group minerals (PGM), using state-of-the-art technology. The structure and petrology of SAC were well studied by earlier workers (Subramanian, 1956), but only scanty data on geochemical, petrology and mineralogy of PGM are available. The mineralogy of the samples is dominated by chromite (>70 mass per cent), plagioclase (An90) and chlorite-actinolite with orthopyroxene (En85). Details of the petrological evolution of the Sittampundi complex will still have to be studied further, but indications of magma replenishment at the level of chromite formation and the elevated PGE values associated with the chromitite samples make the Sittampundi complex a promising target for future exploration activity.

Jan 1, 2008

By Fabio J. Esper, Guillermo R. Martín-Cortés, Francisco R. Valenzuela-Díaz, Cassio P. Carvalho, Giorgio Grotti, Reginaldo B. Santos

"Rejected sands from smelting metallurgical process because contain lead and others heavy metals are a problem to dispose as waste in all the countries. A procedure that is being proposed for it is to incorporate it on common clay bodies in the fabrication of structural ceramic products as bricks, blocks and roof tiles. The main goal of this paper is to present the results obtained with mixtures of sands from smelting metallurgical process with common clay from Jundiaí, São Paulo, Brazil. Preliminary incorporation tests (1,0% in weight) were made with hand formed spherical samples. With the higher compression strength of the spheres after drying and firing (950ºC) experiments on bricks production were made for quality technological test. Seven hundred hallow blocks containing 1,0% waste were produced and presented ceramic properties similar to those without sand incorporation. Introduction In last the fifteen years the LMPSol - Raw Materials & Non-metallic Solids Laboratory – Metallurgic Eng. & Materials Depto. – Polytechnic School - University of São Paulo comes studying the possibilities of incorporate industrials waste materials to the production of bricks and other products of construction aiming at to remove pollution products of the environments and to user the properties of the same ones in the structural ceramics products. Examples are the study of the influence of rejected steel furnace dusts in structural ceramic [1], another example is the main subject of the present paper: use of rejected sand from smelting metallurgical process in the production of bricks an other products of structural ceramics. Antecedents More or less one year ago, specialist and members from the direction board of METALÚRGICA GROFE LTD. Company contacted researchers and professors of the LMPSol – PMT – EPUSP seeking for a solution to their concern with the disposal of rejected sand from smelting metallurgical process."

Jan 1, 2008

By St. E. Deák

There is a large preoccupation concerning the development of expert tools (ET) in the mining industry, in order to minimize the impact from waste dumps and processing residues on the environment. In this paper, the authors present a new approach for the development of an expert tool for each area under study, in order to minimize production and disposal of mining wastes on the environment, by taking into account the DKRControl method as well as the Ecomining principles, regarding among others hazard identification, impacts and monitoring. Due to the complexity of this topic a reliable ET requires input from a number of interested stakeholders. The design and management of a mining waste disposal site over its entire life cycle is also considered very important.

Jan 1, 2008

Longwall mining is a commonly used method of coal extraction that involves the complete removal of large, rectangular panels of coal. Longwall mining causes the immediate seam roof to break and fall into the void created by mining. The convergence of the surrounding strata towards the mining void causes subsidence on the surface. The subsidence magnitude is related not only to the mining depth, the topography, the geological features and the overburden materials, but also to the sequence of the strata overlying a coal seam. In additional to the vertical subsidence which is evident at the surface, there are also horizontal movements inwards toward the centre of the void, which cause the surface to tilt, bend, stretch and com-press. This paper presents a parametric investigation of the influence of the overburden stratigraphy to surface deformations due to longwall mining using 2D finite element models. Models simulate rock movement by applying equivalent edge load to the open roof.

Jan 1, 2008

The utilization of computer assisted tomography (CT or CAT-scan)as general non-destructive examination (NDE) technique and as research tool for scientists in South Africa, is limited due to the relative unavailability or nonexistence of such specialized analytical equipment. Many medical hospitals are equipped with X-ray CT scanners for the diagnostic examination of patients but do not easily allow paleontologist or other scientist to utilize their very expensive equipment. As from 2003, Necsa hosts the South African Neutron Radiography (SANRAD) and tomography facility where neutrons from the SAFARI-1 nuclear research reactor and their penetrating power as well as X-rays as a complementing tool, are utilized in many R&D applications. This facility is being made available to HEI and specifically utilized by postgraduate students as part of their studies and/or by industry on an ad hoc commercial basis. The capability of these radiation imaging facilities at Necsa will be demonstrated in areas such as paleontology, geosciences and specifically the physical properties of rock and the distribution of minerals in borehole cores, petrophysics to predict the percentage tar/oil/water content within sandstone samples and others. The penetration capability of neutrons through specimens with a matrix of high atomic number (dense materials) and their ability to be attenuated by low atomic number material (light density) makes neutron imaging complementary to X-ray imaging. The capability of X-ray and gamma radiation for relatively easy penetration through specimens of low atomic number allows for viewing of imbedded high atomic number materials and density variation. X-ray micro focus radiography is capable of resolving objects of micro scale size that are micro distances apart whereas X-ray phase contrast radiography utilizes the wave properties of the electromagnetic spectrum of X-rays to clearly define edges of the specimen under investigation. Many applications with neutrons as imaging probe are successfully applied at several facilities across the globe such as at NIST in USA, Neutra at PSI in Switzerland, and ANTARES at FRM2 in Germany, etc, are documented 4?9, through world conferences on neutron radiography, for example. This is achieved through very well thought through and implemented instrumentation from the production of neutrons to their detection and interpretation of the images. The need arose at Necsa to upgrade the current facility from 42-year-old technology, which was successfully applied in neutron imaging over the past 10 years, to state-of-the-art technology found at European facilities. This initiative started under the auspices of an IAEA-TC programme for the period 2007?2010.

Jan 1, 2008

By T. W. Beck

Overexposure to respirable dust remains a widespread health hazard to roof bolter occupations in underground coal mines. Recently implemented mist drilling technology was evaluated for its effectiveness in controlling respirable dust exposures for roof bolting personnel. This work presents the findings from NIOSH field and laboratory studies comparing respirable dust levels on mist drilling roof bolter machines to dust levels measured on machines using a conventional vacuum drilling system. Gravimetric and instantaneous respirable dust samples were collected for multiple drilling cycles. These dust measurements were used to assess the potential dust control capabilities relative to conventional drilling. Controlled laboratory tests found 0.3 mg/m3 more respirable dust with mist drilling than with the conventional vacuum method. A separate field investigation of the two techniques observed higher dust levels around the mist bolting machine.

Jan 1, 2008

By L. Nichols, H. Keele, K. Czajewski

"The oil sands industry in northern Alberta disposes of the by-products of bitumen extraction into tailings ponds. The mix of tailings sand and mature fines, with gypsum added as a flocculent, constitute a waste stream called consolidated tailings or composite tails (CT). The two main challenges of the tailings disposal process are a chronic shortage of economical containment and the potential mobility of CT deposits in the event of breaching by, for example, long-term erosion, which makes abandonment of tailings ponds more complicated. Thick deposits of CT do not consolidate in adequate time to provide reassurance for abandonment of the CT containment facilities and that is why the containment must be adequately robust or the properties of CT improved for long-term stability. This paper addresses potential solutions to these problems by applying the gravity drainage of CT and quasi-homogeneous construction for containment facilities.Gravity drainage is suggested as a mechanism to facilitate the consolidation of CT in critical areas of the ponds by inserting internal sand layers within the body of the deposit. Critical CT areas are defined as areas around the perimeter of containment. The advantages of this solution are longterm stability of the disposal area by creation of stiff deposits around its perimeter and facilitation of reclamation efforts on its surface.The present solution for containment of CT deposits is not favourable from a materials balance point of view. In general, sand has become a valuable resource as it both forms the primary component of the CT matrix and becomes the containment building material. If sand is required for CT, less is available for dyke construction. This puts additional pressure on the industry as a whole to maximize the use of overburden and interburden for construction of tailings containment structures. Typically, only 50 percent of dry mine waste (overburden + interburden) is incorporated into dyke construction. The remainder of dry waste is stored either in waste dumps or in tailings ponds, consuming valuable in-pond space originally allocated to CT material. Quasi-homogeneous dykes are proposed to contain CT deposits rather than traditional minimum cross-section dykes built of overburden and/or cell sand. The quasi-homogeneous dyke may change the unfavourable material balance and lessen the construction constraints that are presently imposed on the mine/waste disposal process."

Jan 1, 2008

By Keith Best

It has been said that when a person does something right no one remembers but when they do something wrong no one forgets. This statement, when applied to the explosives industry, has never been truer. Think about it.How many times have you seen a news crew reporting on how well a blaster is doing his/her job? Normally, all you will see is how bad things are going and how much “damage” is being done.

Jan 1, 2008

The Mine Safety and Health Administration (MSHA) defines an independent contractor as any person, partnership, corporation, subsidiary of a corporation, firm, association or other organization that contracts to perform services or construction at a mine. Contractors that perform specific types of work are required to report the number of employees who work at coal mines and noncoal mines.

Jan 1, 2008

By K. J. Heale, G. G. Richards, D. J. Rioux, R. L. Stephens

Slag fuming has remained a key process for the recovery of Zn, Pb, and minor elements in the integrated flow sheet at Teck Cominco's Trail Operations for more than 75 years. Since the start-up of the KIVCETTM process and the #3 slag fuming furnace in 1997, a range of process intensification projects have been completed to improve metals recoveries and throughput based on improved process control, mechanical modifications, and, most recently, the implementation of oxygen enrichment of the blast air. This latter project, initially named 'nitrogen depletion' and now 'nitrogen oxygen performance enhancement' (NOPE), is the primary focus of this paper. NOPE reduces the amount of heat required to heat the inert nitrogen gas, and therefore more of the energy input can be used for reduction. It also frees up boiler capacity because the inert nitrogen gas does not then have to be cooled down. A dynamic METSIMTM model was developed to determine the opportunities to improve the process capacity and heat balance to both assist with justifying the project and to verify the observed furnace behaviour. Several process safety management issues were also addressed and a few key minor mechanical modifications were made to allow the project to proceed to commercial implementation at 25% blast air oxygen enrichment. Short term plant trials have confirmed the model predictions. The first three months of a long term, continuous trial showed a 6% increase in zinc fuming rate from average furnace performance despite the implementation of a KIVCETTM fluxing change to assist with minor element recovery that was expected to negatively impact the zinc fuming rate by 3 to 5%. This encouraging result is also in line with the model predictions.

Jan 1, 2008

By M. Olper

The zinc recycling is assuming more and more importance. A lot of zinc secondaries and wastes are ready to be collected and converted to zinc metal. The impurities present in these materials and the technical and economical problems that some traditional ways of treating these materials are facing, call for new technologies. The EZINEX Process, a fully hydrometallurgical process industrially proven to convert oxidised zinc bearing materials directly to zinc cathodes, is an innovative process that can deal with any kind of zinc waste/secondaries in a very powerful way. In this paper the highlights of this process will be shown and discussed to demonstrate the robustness of the process and its economic viability.

Jan 1, 2008

By M. I. Al-Wakeel

Nile sediment was collected as a waste from one of the water treatment plants in Cairo, and subjected to petrographical investigation and granulometric, chemical, and mineralogical analyses. It was expected to find diatomite in that sediment but it was a surprise to find that the diatomite content amounted to about 52.01% by volume in addition to quartz, orthoclase and clay minerals. The latter are represented by montmorillonite and illite minerals. The sediment is light gray in color, soft and has low density and high surface area, such density and surface area generally decrease with temperature. The sediment absorbs 317% of its weight in water. The diatomite skeletons are the main factor responsible for its high porosity producing microporosity and low density, and these particles are concentrated in the very fine silt size fraction (11x2µm). The common diatoms in such sediment include Cyclotella ocellata Pant, and Melosira granulata (Ehr.) Ralfs. It seems that this Nile diatomaceous sediment has many advantages over the fossil diatomite, such as Fayium diatomite in Egypt, with the absence of carbonate minerals that require grinding and calcination those cause destruction of the cellular structure and energy consumption. This Nile diatomaceous sediment can be processed using sequential classification to obtain diatomite concentrate of 88.8% grade at 90.6% recovery, and a middling product of 19.4% grade and 5.8% recovery. The suggested flow sheet is quite simple to produce diatomite product for different industries at a low cost. The unusual particulate structure and chemical inertness make diatomite an ideal mineral to be used as functional filler in a wide range of industries, and as catalyst carriers and insulating material. Key words: Egypt, Nile sediment, Diatomite, Beneficiation, Sedimentation, Classification.

Jan 1, 2008