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By Bo Feng

The development of surface charge of serpentine mineral and implications for sulphide ?otation have been studied through flotation tests, sedimentation tests, zeta potential measurements and optical microscope photos. The results show that the serpentine mineral was positively charged at an extensive pH range, with an isoelectric point (IEP) of 11.9. The magnitude and sign of the pyrite particles were pH dependent and were negative for pH values above 2. At pH value 9, where ?otation of nickel sul?de ores is routinely performed, serpentine and pyrite particles attract through an electrostatic mechanism. Slime coatings of serpentine adhere to the surface of pyrite, reducing pyrite flotation recovery. The removal of magnesium ions from the serpentine surface by acid leaching results in a decrease of serpentine IEP and eliminates the adverse effect of serpentine on pyrite flotation. Therefore, it has been clearly established that the surface charge value developed in the serpentine/aqueous electrical interface is a function of the serpentine surface incongruently dissolution. As a result of hydroxyl dissolution, the magnesium ions are left in serpentine surface, which is responsible for serpentine surface charge. The methods, which can remove magnesium ions from serpentine surface, can be used to eliminate the adverse effect of serpentine on pyrite flotation.

Sep 1, 2012

By Jack E. Fraley

In this Bureau of Mines study, sealants containing mineral wool, cement, etc, were sprayed through dry-process equipment that propels dry material pneumatically to the water-adding nozzle. Advantages over slurry applications include no mixing, no extensive cleanup, and freedom from hardened cement in equipment should power be lost. Sealants with large mineral wool nodules (>l-inch) were sprayable at rates to 900 square feet per hour for 1/2-inch thickness with little dust and smooth material flow through equipment, but they were weak for mine use, Materials containing small wool nodules (1/4-inch) were stronger but tended to plug lines because the nodules were inadequately separated in the shredder. Increasing the dedusting oil also increased line plugging by holding the nodules together in larger lumps. Best results were obtained using a 3/4-inch-nodule wool with cement binder, which provided both smooth flow through the machine and adequate strength.

Jan 1, 1977

By R P. Varden

This paper looks at the design of the Bentayga raisebore with subsequent back analysis using a LiDAR survey. A search for LiDAR raisebore assessment publications shows little work has been done on this subject. The paper examines the empirical design and RS2 modelling assessment with the bored condition. The high resolution of the LiDAR enabled mapping of weak structures that were located on the geotechnical investigation hole the orientations of which could not be determined. In addition, the scan showed were water ingress was occurring, potential stress overbreak and structural controls on stability. The LiDAR results were able to confirm no additional support work such as a shotcrete liner is necessary. The LiDAR results have been analysed in one metre increments as volume of overbreak against the empirical stability criteria (McCracken & Stacey 1989). The future use of LiDAR mapping over a range of rock mass conditions will provide quantification of the established empirical assessment improving its reliability. It is also a useful and accurate tool to monitor long term stability of a raisebore due to stress change or ore pass due to wear.

Mar 15, 2021

By M. Bryson, A. E. Brady, W. Dawes, G. Beer, N. Sehlotho

Mkango Resources Limited is developing the Songwe Hill Rare Earth Element Project in southeast Malawi. Since being awarded the exclusive exploration licence for the project in January 2010, Mkango has completed an extensive work programme including detailed mineralogical studies, geological mapping, geochemical sampling and trenching, environmental and social studies, two phases of diamond drilling, and extensive metallurgical test work. In October 2012, the company announced a NI 43-101 compliant mineral resource estimate comprising an Indicated resource of 13.2 million tonnes grading 1.62% total rare earth oxides (TREO) and an Inferred resource of 18.6 million tonnes grading 1.38% TREO. The Indicated mineral resource estimate formed the basis for commencement of the Preliminary Feasibility Study (PFS). The mineralogical program identified the fluorocarbonate mineral, synchysite, and the phosphate mineral, apatite, as the primary rare earth element (REE) bearing minerals. Extensive flotation testwork conducted at Mintek in South Africa has resulted in an effective regime to increase the REO grade 2.6 times. Initial leaching testwork by Mintek identified that a selective hydrochloric acid (HCl) leach can target the gangue minerals with minimal REE dissolution. Recent testwork undertaken at Nagrom in Western Australia has expanded on this work to develop a two stage HCl leach process incorporating HCl recycling. A downstream processing route of purification and cerium rejection to produce a cerium depleted high grade REE concentrate suitable as feed to a separation facility is proposed.

Jan 1, 2014

E. G. Spilsbury, New York, N. Y.:—Do I understand correctly that the rolls are at first simple cylinders, one longer than the other, and that flanges are subsequently formed on the longer roll as the result of wear only ? Mr. Payne :—The flanges are formed by the wearing of the shorter roll into the other, which is about an inch longer. When the roll-shells are new, the longer one has machined at each end a ridge about 1/8 in. or 0.25 in. higher than the face. These slight projections help to center and steady the rolls, by locating the flanges in advance. Possibly they might be left off at the start; but Mr. Frazee has found it better, in machining the new roll-shells, to turn such small flanges upon the longer one. In his practice the feed-stream is extended a short distance beyond the two ends of the shorter roll-shell. This allows a small amount of crushing to be done between the flange-ftices and the vertical ends of the shorter roll-shell, which prevents any ridges from forming at the ends of the shorter roll-shell.

Jan 1, 1913

By Henrique Hipolito, Caio Alves

Waelz process is a method applied in the zinc oxide production and is one of the largest sources of carbon emissions within the zinc industry. The solid carbon used for heating and for reduction reactions is provided mainly by the coke fed with the EAFD in the Waelz kiln. Both chemical composition and physical properties of the coke are important to transportation and to the process. Decarbonizing the Waelz process by replacing the traditional fuel source using alternative biogenic fuel, for example, offers a potential solution to reduce the carbon footprint, which is aligned with the ESG perspective.

Sep 29, 2023

By Yi Luo

In a shearer longwall mining operation, the longwall bits are responsible for breaking into and chip-ping the broken coal blocks away from the coal face. However, underground observations have found that a large number of longwall bits are always working under various degrees of wear. Reduction of the bit wear could be realized by using better designed longwall bits and properly selected shearer operating parameters. A computer program has been developed to simulate the performance of the longwall bits. The shape of the bit head, the installation of the bits on the drum and the operation parameters are the information required by the program. Through the simulations, the main factors affecting the bit wearing process are identified. Suggestions are also made for improving the design of the longwall bits.

Jan 1, 1996

By Dunlop A. C

A brief study from the Mt. Bulga prospect com- pares the chemistry and mineralogy of different soil fractions and other materials to suggest a sequence of surficial metal dispersion from adjacent gossans, which may have relevance for geochemical exploration in semi-arid terrains. v v v v v JIV-- v v v v a o v o/ v v v v 1 v v lv ./v '' 1 v 16400N ..I v 1635014 v 1630014 .:1 ò.t SILURIAN sillstone " lelsic volcanic sillstone -sandstone ORDOVICIAN Eandesite o quartz float gossanò pits doOP Iv o shalt v _--'fault v 1---1 soil traverse v v v v 0 100 200 mm e Fig. I Local geology and location of soil traverses, Mt. Bulga (compiled from Chisholm, 1976). The Mt. Bulga prospect in central New South Wales is a small but well documented volcano- genic massive sulphide occurrence (450,000t of 0.8% Cu, 1.3% Pb, 5% Zn and 0.45 g/t Au) Cambrell and Kirk (1974), and Chisholm, (1976). Mineralization is localised near the interface of felsic pyroclastics with overlying silt- stones and along adjacent faults (Fig. 1). In this area with a Koeppen type cf6 climate, soils are thin and skeletal along ridges with thicker and better differentiated profiles with a colluvial component up to 2m thick developed

Jan 1, 1988

By D. A. Rice

As part of its mission, the U.S. Bureau of Mines continues to develop technologies that will enable cost-effective compliance with environmental requirements. To this end, investigations to improve the kinetics of chalcopyrite dissolution by simultaneous grinding-leaching in ferric sulfate solution were conducted using the Bureau-designed turbo mill. The development of such a hydrometallurgical process would provide a nonpolluting alternative to conventional smelter technology. The effects of mill rotational speed and volume percent solids on the leaching time and energy required for copper extraction from chalcopyrite were evaluated. The results of this laboratory study have shown that the simultaneous grinding-leaching of chalcopyrite concentrate using the turbomill is technically feasible with essentially 100 pet extraction of copper being possible at 90° C. An optimal energy consumption of 1,153 kW?h/st of copper leached was found in batch testing with the mill operating at 400 rpm with a slurry containing 35 vol pet chalcopyrite. This energy consumption, while higher than other proposed leaching processes (about 600 kW?h/st), is of the same order of magnitude. Further refinement of the energy requirements would require additional testing using a continuous circuit. Leaching times of less than 1 h, for 80 pct copper extraction, are achievable using the turbomill grind-leach process.

Jan 1, 2010

By D. Marcotte

The Rock Quality Designation (RQD) is a standard scalar measure of rock quality used in common rock mass classification systems (e.g. RMR, Q system). RQD is measured along diamond drill holes. RQD interpolation between holes is nontrivial. Despite the inherent limitations of drill hole data and the local complexities of structural geology, it is often the only information available for mining and major civil engineering projects. Therefore, maximizing the usefulness of this data is warranted. We derive a correction for directional effects that help reduce the bias and improve the accuracy of the estimations. The correction is derived with the aid of numerous simulations. It relies on simple information, the angle between the joint normals and the borehole axis (JO). A reference direction is identified as the borehole direction with smallest JO. A multiple linear regression model based on JO statistics in the various boreholes defines the correction model. The corrected RQD values are then interpolated. It is shown the method enables reducing the bias on RQD estimation by 50% and improves the accuracy of the estimates by 30%. The corrected RQD values show stronger spatial continuity than the raw values. The benefits of estimating the RQD indirectly by using joint frequency measures are also assessed.

May 1, 2003

By Edwin S. Johanson, Ronald H. Wolk, Clarence A. Johnson, Harold H. Stotler, Katherine C. Hellwig

The H-Coal process, an ebullated bed reactor system for converting coal to liquid fuel, is described. Results from long-duration continuous flow bench-scale operations with Wyoming Wyodak, Arizona Black Mesa, and Utah Kaiparowits Plateau coals are presented. Economic data on the conversion of these coals to liquid products are given. The potentials of the H-Coal process in regard to coal from western producers is stressed.

Jan 1, 1974

By Tristan Worsey, Brad Gyngell, Todd Buschjost, Gus Diehr

This paper highlights the opportunities provided by integrating MWD data and drone generated 3D model to industries that use explosive energy to perform useful work as an integral part of their rock extraction process.

Feb 1, 2020

Despite the strange names given to its parts, the eye is not a very complicated organ. If you think of the eye simply as a detector of light, you will be able to understand the mechanics of central vision, peripheral vision and adaptation described below. These three processes of seeing are basic, not only to mining, but also to everyday activities. A number of simple experiments are described In this chapter to demonstrate different types of seeing processes. Try the experiments. They really make the point. Light rays reflecting from objects enter the eye through a lens and fall on the back surface called the retina. The retina 1s lined with millions of tiny light sensors called "rods" and "cones." These sensors, in turn, are connected to the brain by the optic nerve.

Jan 1, 1976

By R. W. Parsons, P. R. Chaney

Oil recovery by the imbibition mechanism can be important in fractured carbonate reservoirs with a bottom water drive. Laboratory experiments were performed on water-wet carbonate rocks to model this process. The results are interpreted in light of the applicable scaling laws. The imbibition production behavior of a pillar of rock subjected to a slowly rising water table can be synthesized from data on total immersion experiments on small rock samples. If the rate of water table rise is slow enough and if the physical properties are such that the imbibition zone is of a small vertical extent, then only the final oil recovery on the small samples need be known. Applying laboratory imbibition data to a real reservoir should be done with caution because of possible wettability problems and the unknown behavior of two-phase flow in fractures. INTRODUCTION The spontaneous taking up of a preferential wetting fluid into a porous medium with the simultaneous expulsion of the contained fluid is termed imbibition. One of the many physical imbibition processes is the production of oil by the taking up of water into a water-wet reservoir rock. In certain types of heterogeneous reservoirs, e.g., fractured, it is realized that imbibition alone may be the dominant mechanism. Theoretical studies of imbibition oil recovery have followed several lines of attack. The behavior of certain mathematically tractable and conceptually simple models have been analyzed. Birks1 considered a bundle of vertical capillaries model, while Perotti et al.2 and Kelemen3 used a model of a series of vertically oriented fractures. If the oil production behavior from a block of reservoir rock is known, then the cumulative behavior of a vertical stack of these blocks subjected to a rising water table can be determined by a method outlined by Aronofsky et al. 4 Knowing the capillary pressure and relative permeability functions should uniquely set the imbibition behavior for a given sample. Solutions of the partial differential equations describing the process, however, present some formidable problems. Digital computer techniques have been applied to displacement processes in which the capillary pressure has been included.5"8 More recently, similar techniques have been used by Blair 9 to calculate countercurrent imbibition behavior. The fact that imbibition behavior is described by the usual fluid flow equations (Darcy's Law and continuity equation) implies that the derived scaling laws should apply equally to this situation. Use of model experiments to study imbibition has been employed by Graham and Richardson 10 and Mattax and Kyte,11 who actually tested the scaling law applicability. This study is concerned with scaled model imbibition experiments on water-wet carbonate rocks. Of particular interest is the slowly rising water table experiment. This simulates a highly fractured reservoir with the water table rising uniformly through the vertical fracture system. Experiments were performed on different sized samples and with different rates of rise of the water-oil interface surrounding the rock pillar. Total immersion imbibition experiments on smaller rock samples were performed to test the basic linear scaling laws and to see if these simpler tests could be used to synthesize the rising water table experimental results. THEORY IMBIBITION SCALING LAWS Scaling laws for the flow of two incompressible immiscible fluids in a porous medium have been presented by Rapoport.12 These are derived directly from Darcy's Law for the individual phases and the continuity equation. Results from a laboratory model experiment will duplicate those from some reservoir prototype if a constant proportion is maintained among the three forces acting on the fluids — the capillary pressure gradient, the gravitational gradient and the flowing pressure gradient. Operation of the model (i.e., fluid injection or withdrawal) must be conducted in accordance with specific equations. If the

Jan 1, 1967

By P. Keller, T. E. Lister, G. G. Clark, L. A. Diaz

As electronic technology continues to evolve there is a growing need to develop processes which recover valuable material from antiquated technology. This need follows from the environmental challenges associated with the recovery of raw materials and fast growing generation of electronic waste. Although present in small quantities in electronic devices, the availability of raw materials such as rare earths and precious metals becomes critical for the production of high tech electronic devices and the development of green technologies (i.e. wind turbines, electric motors, and solar panels). Therefore, the proper recycling and processing of electronic waste presents an opportunity to stabilize the market of critical materials, providing a proper disposal and treatment of a hazardous waste stream. This paper describes the development and techno-economic assessment of a comprehensive process for the recovery of value and critical materials from electronic waste. This hydrometallurgical scheme aims to selectively recover several value streams (base metals, precious metals, and rare earths) present in electronic waste. The economic feasibility for the recovery of rare earths from electronic waste is mostly driven by the efficient recovery of precious metals, such as Au and Pd (ca. 80 % of the total recoverable value). Rare earth elements contained in magnets (speakers, vibrators, and hard disk storage) can be recovered as a mixture of rare earth oxides which can later be reduced to the production of new magnets.

Jan 1, 2016

By James E. Mauser

This report deals with the investigation of a continuous process for producing pure zirconium. It covers the construction, operation, and maintenance of the semicontinuous reactor. The report covers a study of test variables, such as reactor temperature and reluctant charge weights, and evaluates the results, such as billet metal hardness, residual billet salt content, and suitability of a purified billet as a consumable electrode for arc melting. The purpose of this project was to develop an inexpensive and continuous process for producing pure zirconium. The process developed, termed the semicontinuous reactor process, produced billets of compacted zirconium sponge. The metal was produced by reducing zirconium tetrachloride with sodium and magnesium beneath molten byproduct salt. Hydraulic rams at each end of a vertical reaction tube compacted the sponge and ejected it as a billet. These billets were purified by heat under vacuum to remove entrapped salt. The goal was to utilize the purified billet directly as a consumable electrode for arc melting.

Jan 1, 1961

By G. Fazel Jahromi

Enargite, known as one of the major arsenic containing copper minerals, with approximately 19% arsenic, introduces challenges to typical processing options. In most hydrometallurgical processing methods, arsenic remediation occurs after the copper recovery in an autoclave or in a stepwise neutralization process. In this study, the in situ precipitation of scorodite was investigated during an atmospheric leaching process in the presence of carbon-based catalysts and chloride media. The effective parameters of initial ferric addition, temperature, catalyst addition, and oxygen sparging rate were studied and the ferric behaviour was monitored during the scorodite precipitation. The most influential parameters on efficient scorodite precipitation are found to be: initial ferric addition, catalyst to concentrate ratio, and temperature. A 99% scorodite precipitation yield was achieved in this process.

By D. Mukerjee, Ramen Datta, Sanak Mishra, R. Veeraraghavan, K. L. Rohira

"Recent efforts at Steel Authority of India Limited (SAIL) has led to the successful development of atmospheric and marine corrosion resistant high tensile Thermo Mechanically Treated (TMT) bars with minimum specified yield strength of 50 kg.mm-2. These rebars are increasingly being used for a wide range of end-applications, namely, concrete reinforcement structures, bridges, flyovers, dams etc. Welding is an important processing tool for each of the above applications. In view of the importance of welding, a comprehensive evaluation of the weldability properties has been carried for the two grades of steels using Submerged Metal Arc Welding (SMAW) process; the most popularly used technique of welding of reinforcement bars (re bars).Implant tests were conducted to assess the cold cracking susceptibility of the steels. The static fatigue limit (SFL) value, determined for the atmospheric corrosion resistant (Cu-TMT) rebars under no preheat and no rebalcing conditions was found to be 63.8 kg mm-2, which was significantly higher than the Minimum Specified Yield Strength (MSYS) (50 kg.mm-2). This indicates adequate resistance to hydrogen induced cracking (HIC). On the other hand, the SFL value obtained for the marine corrosion resistant rebars (Cu-Cr TMT) under no preheat, no rebaking conditions was found to be inconsistent. Repeat of the test with fully rebaked electrodes (350°C-2h) resulted in a high SFL value (60.3 kg mm-2)_The rigidity of the structure or restraint influences the susceptibility of the weld joint to cracking. The cracking tendency increases with restraint intensity (K) of an assembly. The critical restraint intensities determined for the two steels were found to be· in excess of 1680 kg/mm.mm, indicating good welding behaviour with the following welding conditions : for Cu-TMT rebars with no preheat and no rebaking and for Cu-Cr TMT rebars with no preheat and fully baked electrodes; that is under low hydrogen levels."

Jan 1, 1998

By Ruiling DU, Jiazhi Zhang, Yong Zhao, Keng Wu

Reaction kinetics of metallurgical physical chemistry which was successfully applied in metallurgy (as ferrous metallurgy, non-ferrous metallurgy) became an important theoretical foundation for subject system of traditional metallurgy. Not only the research methods were very perfect, but also the independent structures and systems of it had been formed. One of the important tasks of metallurgical reaction engineering was the simulation of metallurgical process. And then, the mechanism of reaction process and the conversion time points of different control links should be obtained accurately. Therefore, the research methods and results of reaction kinetics in metallurgical physical chemistry were not very suitable for metallurgical reaction engineering. In order to provide the definite conditions of transmission, reaction kinetics parameters and the conversion time points of different control links for solving the transmission and reaction equations in metallurgical reaction engineering, a new method for researching kinetics mechanisms in metallurgical reaction engineering was proposed ,which was named stepwise attempt method. Then the comparison of results between the two methods and the further development of stepwise attempt method were discussed in this paper. As a new research method for reaction kinetics in metallurgical reaction engineering, stepwise attempt method could not only satisfy the development of metallurgical reaction engineering, but also provide necessary guarantees for establishing its independent subject system.

Jan 1, 2015

By Philip Arthur

The ISASMELT process is making a significant contribution to the global metals industry. ISASMELT furnaces are now operating successfully in eight different countries and treating approximately 3 million tonnes of concentrates and secondary materials per year. The process is currently used in both lead and copper smelting. The most recently commissioned plants were in Germany and China, one for treating scrap copper and the other treating low-grade copper concentrates. The Copper ISASMEL T furnace ("CIF") at Mount Isa Mines Limited ("MIM") has continued to set new operational records, with throughput of more than I million tonnes of concentrate per year and very low operating costs. This paper summarises the latest operational data from the Mount Isa Copper ISASMELT plant and outlines the successful approach to industrial R&D taken by MIM in the development of the ISASMEL T process.

Jan 1, 2003