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Titanium dioxide (TiG ) is produced 2 commercially by two methods generally referred to as the "sulfate" route and the "chloride" route. The SCM Corporation, in supplying 15% of the world's demand for TiO 2, uses both of these processes. Of the two processes the sulfate route is generally regarded as the older and more established technology. Worldwide the sulfate route accounts for some 70% of total Ti02 production. However, in the U.S.A. the chloride process accounts for 80% of production. The processes vary in chemistry and raw material requirements. In the "sulfate" process finely ground ilmenite or titanium slag is digested with sulfuric acid to produce a porous "cake" vrnich is extracted with water and recovered liquor. The solution is treated with scrap iron to reduce any ferric ions to the ferrous state which is then crystallised and removed as ferrous sulfate heptahydrate. The liquor is concentrated by evaporation and hydrolysed to form the insoluble hydroxide which is filtered and washed free of impurities. This is converted to the dioxide by calcination at 800 - 1000¦C and milled to break up any aggregates. The "chloride" process uses a higher quality feedstock of natural or synthetic rutile and/or high grade titania slag. The feedstock is mixed with ground high-purity coke and chlorinated at 950¦C in a fluidised bed. The resulting crude titanium tetrachloride is purified by distillation and chemical treatment. The purified titanium tetrachloride is burned with oxygen or oxygen enriched air to give titanium dioxide and chlorine, which is recovered and recycled to chlorination. Titanium dioxide pigment from both processing routes undergoes similar finishing techniques. It is subjected to further stages of wet and dry milling, then coated with layers of inorganic oxides in order to enhance its properties for specialist applications.

Jan 1, 1986

By A Nixon

The Australian mining industry has changed dramatically over the past 20 years in terms of mining methods, mining equipment and human resource policies. The industryÆs approach to safety and health in terms of attitudes, style of legislation, and risk management techniques has also changed significantly. These changes have had and continue to have major impacts on the design of underground mine ventilation systems. In some areas, trends are clearly emerging. In other areas, mine ventilation planning remains very æreactiveÆ and is performing poorly in terms of providing a safe and healthy work environment at a reasonable cost. New concepts involving the role of ramps and shafts, the provision of refrigerated air, æventilation on demandÆ and newe gress and entrapment approaches are likely to be incorporated into mine planning and operating practices over the next ten years. This paper discusses these and other trends and identifies some likely future developments in the area of hardrock mine ventilation.

Jan 1, 2005

Bougainville Copper Limited (BCL) ships about 600,000 dry tonnes of copper concentrate per annum to Japan, Germany and Spain, with some spot sales to other countries. Concentrate sales value for 1984 was 335 million US$, representing almost half of PNG exports. Contained metal determination is based on physical and chemical measurements on representative samples. The entire procedure is subject to statistical uncertainties and possible systematic errors; losses as high as several percent of contained copper or gold are common and frequently are regarded as unavoidable. In this context, the function of the chemical laboratory is to identify and eliminate such errors and recommend correct technical procedures for possible inclusion in sales contracts. BCL's marketing management has encouraged this approach and the close buyer versus seller agreement is beneficial for all parties involved. BCL participates in the respective technical committees of the Standards Association of Australia (SAA) and the International Standards Organisation (ISO). Standard methods for sampling and analysis of copper, lead and zinc ores and concentrates are in course of preparation, some being due for publication shortly.

Jan 1, 1986

The Pacific Rim and its environment involves a vast array of natural phenomena, and a vast array of situations which show the impact of man. Almost half the world's population of over five billion live in nations" which border the Pacific, but the concentration is focussed in the North. Great experiments are occurring in this region, the industrialization and energy development in- Japan and China, the growth of Indonesia, (now 168 million - soon 368 million; Brown and Jacobson, 1986), the enormous developments of agriculture and the metals resource base in Australia and China. At the same time, the Pacific Rim does not project images of hopelessness, the mood is upbeat. Over the past decade, incomes have increased substantially in most of the major countries of Pacific Rim (e.g. over the period 1980-86, + 58% in China, + 21% in Japan, + 34% in South Korea; Brown and Jacobson, 1986). In September, 1986, at the general assembly of the International Council of Scientific Unions (ICSU) in Bern, Switzerland, representatives of over 50 nations approved a new initiative, "The International Geosphere Biosphere Programme: A Study of Global Change". The focus of this new program is "To describe and understand the interactive physical , chemical , and biological processes that regulate the total Earth system, the unique environment that it provides for life, the changes that are occurring in this system, and the manner in which they are influenced by man. The IGBP will be a tightly-defined programme of research, directed at providing fundamental knowledge that will serve as a basis for assessing likely future changes on the Earth in the next 100 years" (ICSU, 1986). For the earth scientist, and all resource scientists, there is an emerging agenda; new priorities are appearing, new questions are being asked. The recent report of the World Resources Institute (1986) focusses on this emerging agenda. Topics which are at centre stage in this report include the following: The environment and human health Tropical deforestation The atmosphere as a shared resource and climates Soil-degradation Rural-urban migrations Food and agriculture The diversity of species-ecosystems Freshwater as a finite resource Coastal areas and resources

Jan 1, 1987

By Y Potvin

Risk assessment in the mining industry is currently a topic of great interest with risk methodologies being increasingly applied beyond the traditional areas of finance and feasibility to analyses of risks due to various physical hazards including chemical, electrical, mechanical and geotechnical sources. The application of risk analysis and evaluation techniques to the management of personnel safety is being promoted by both industry and regulators but, particularly for geotechnical hazards, often there are inadequate databases for a meaningful quantitative calculation of risk. In Western Australia over the decade 1987 - 1997, the annual fatality rate for underground mining has averaged at approximately 1.3 in 1000 employees with rockfalls/rockbursts accounting for over half of these deaths (Prevention of Mining Fatalities Taskforce, 1997). Recent improvements have been made since this time, perhaps halving the annual fatality rate, mainly due to industry improving ground control measures and implementing various recommendations from the Prevention of Mining Fatalities Taskforce (1997). However there still remain a large number of unknowns when trying to address the complex area of geotechnical risk in mining. Risk calculations require information about the source of the hazard, the people or assets exposed to the hazard (the æelements at riskÆ) and the effects on these vulnerable elements if the hazard actually occurs (the potential consequences). To date, little information has been available on the exposure of mining personnel and equipment to underground hazards other than occupational safety studies on chemicals, heat, dust, etc. This paper concentrates on underground geotechnical risks and presents a data collection and rating system for the exposure of both the underground workforce and equipment to rockfalls and rockbursts. The methodology considers exposure times, personnel protection levels and hazard proximities to give exposure ratings for the major underground mining activities and hence rate different locations within a mine. This exposure methodology is then applied to the workforce and production/ development cycles in an actual WA underground mine, creating a snapshot map of differing levels of personnel exposure across the mine.

Jan 1, 2003

By R J. Everett

The mining industry is beginning to adopt quality systems based on the requirements of International Standards for quality assurance, such as the ISO 9000 series. Indications from similar industries are that considerable benefits are to be had from their adoption. This paper describes the use of the International Standard ISO 9001 for quality assurance within BUKA Minerals Limited. This provided guidance for the development of a clear statement providing agreement on the processes to be followed and the outputs required when dealing with outside service providers. Discussion focuses on the interaction with BUKAÆs consultants and contractors during the specification stage, resulting from the application of quality assurance techniques. Risk analysis was used to identify and manage the risks associated with the companyÆs contract for geotechnical and mine design services and the tender for a mine development program of work during the feasibility stage of the project. Setting acceptance controls for the deliverables from such contracts is traditionally fraught with difficulty. BUKA used Failure Mode and Effect Analysis for exposing underlying risks that were not effectively being countered. The briefs were reviewed and additional controls were developed to manage the risk. These controls have provided clearer instructions to the consultants and contractors, indicated audit points for the company and defined the deliverables. There exists within the company, and among its outside service providers, a clearer understanding of what is to be achieved and how it will be measured. The process has imparted considerable confidence to both parties on how the work will proceed and what outputs are to be provided. Some discussion is provided on how quality principles are being applied throughout industry and commerce, generally, and how they may apply to the mining industry. The paper argues that, far from being an appendix to the tendering process, Risk Management should be a mandatory step integrated into the definitions of the work.

Jan 1, 1998

Rocks of all geological ages are present on the Australian continent. As a result of its geological heritage, Australia is richly endowed with mineral and energy resources. Due in part to its enormous mineral wealth, the nation is in the position of being a wealthy country surrounded by less developed countries of the Asian and Pacific region. Over many years Australia has developed and gained valuable experience in the exploration, mining and processing of a wide range of mineral and energy resources. In an interdependent world community, it is obviously in Australia's interest to cooperate and provide assistance in geoscience education and training to developing countries of the region.

Jan 1, 1986

I propose to speak today about our mineral heritage. In common usage "heritage" refers to the past. It means the discoveries, the developments, the mines and the processing plants, the benefits, the consequences, and the human experiences flowing from these. The history of the industry, inseparable from the history of the countries in which The Institute operates, is a rich background of which we can all be proud.But there is also a much wider meaning to mineral heritage. Our past has left us with the ab\lity to create and operate world scale enterprises generating wealth for the community, the ability to offer satisfying and challenging careers in a wide range of skills to our young people, and the willingness to follow adventurous and challenging vocations in remote areas, away from the big cities, at a time when the mentality of many is to get the most for the least effort and at the least inconvenience to themselves. The industry continues to be the repository of the pioneer spirit and a vital contributor to improving the life of the people in our countries.Thus, while our mineral heritage has much to do with the past, an essential part of it is how we use this rich past to build and shape our future. It is in this broader context that I am speaking today.

Jan 1, 1990

By A E. Annels, M NoppT

Ore Reserves are key mining company assets and their reliable estimation is crucial for both feasibility studies and the day to day operation of a mine. The reserve is based on the Mineral Resource after the application of certain technical and economic parameters. Engineering aspects of reserve estimation can be accurately determined to ¦10 per cent, however the majority of project risk will revolve around the resource. A final Ore Reserve generally contains a set of figures quoted without reference to its potential errors. Rarely are overall confidence limits quoted and, if they are, they often do not take into account many of the factors that cause uncertainty in the grade and tonnage estimates. There is thus an unquantifiable risk, which the operator should be aware of. This paper presents a review of the possible sources of error that might occur during the various phases of an exploration and estimation programme which are carried through into the Ore Reserve and hence mine design.

Jan 1, 2002

The Copper Concentrator at Mount Isa Mines Limited treats approximately 6 Mt of chalcopyrite ore annually. The ore is currently sourced from the 1100 and 3000 orebodies at Mount Isa. Chalcopyrite is the only significant copper bearing mineral, with pyrite, quartz and dolomite being major gangue minerals. Ore is typically 10% chalcopyrite, 11% iron sulphides and 79% non-sulphide gangue. Copper ore is treated through two autogenous mills, two ball mills and a flotation circuit. The autogenous mills replaced a crushing plant, two rod mills and two primary ball mills during 1991. For routine analysis of concentrator performance, composite samples of mill feed, final concentrate and tailings are generated every 4 week period. All samples are sized and size fractions are assayed. Recovery of mineral species to the concentrate are then calculated for each size fraction. Sometimes liberation analysis was also performed by QEM*SEM (Quantitative Evaluation of Material by Scanning Electron Microscope).

Jan 1, 1990

By C Fountain

It is commonly known that copper smelter terms include penalties if the concentrations of elements, such as arsenic, mercury and fluorine, exceed stipulated limits. It is less commonly known that the behaviour of these elements in the smelters can depend on the processes used to treat the concentrate. The principle behind the penalties is to compensate the smelters and refineries for additional costs caused by the presence of the penalty elements, but these costs will vary depending on the process used and the location of the smelter.The issues caused by the minor elements include effects on the occupational health of smelter workers, increased environmental disposal costs, increased operating costs and reduced cathode copper quality.The effects of minor elements can be surprising. High levels of arsenic in concentrate are considered undesirable, but some smelters add arsenic to anode copper to improve the performance of the refinery.Excess concentrations of some elements will result in rejection of concentrates by smelters. China has blanket import bans on copper concentrates with concentrations of lead, arsenic cadmium, fluorine and mercury exceeding specified levels.This paper will review the behaviour of minor elements in smelters and refineries, explaining the deleterious effects of each of them, to provide a greater understanding for people and organisations wishing to market copper concentrates.CITATION:Fountain, C, 2013. The whys and wherefores of penalty elements in copper concentrates, in Proceedings MetPlant 2013 , pp 502-518 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

The energy input requirement to produce the molten slag associated with iron production to the modern Australian blast furnace, is estimated to be 2.OMJ/kg. In converting blast furnace slag to products of higher commercial value, advantage should be taken of this energy content by transporting molten slag from the furnace for beneficiation and processing in the molten state at an "off furnace site". The refined slag melt may then be converted into a variety of products for use in the building and construction industries, e.g. slag cement, slag sand and slag aggregates, insulation wool and various slag ceramic products. Some results of studies into slag melt beneficiation and conversion processes involving both molten and cold granular slag raw material, are presented.

Jan 1, 1979

The paper reviews the majority of associations and institutions which operate in support of the Australian mineral industry. The review covers historical aspects of each organisation and the current activities and management structure. The linkages between the organisations through membership are briefly discussed. The paper comments on the evolution of the formation of the organi- sations and the networks between them that do exist and operate regu- larly. Rationalisation or a process to consider formation of new groups to fill gaps in the network are recommended for further research.

Jan 1, 1988

There have been many developments in recent years in pipeline transport to enable them to be more widely used in industry. Substantial tonnages of materials that are not affected by water, such as coal and other minerals, aggregates and wastes, can be moved over considerable distances in quite small diameter pipes. Where there are no existing road or rail facilities, long-distance pipelines are usually cheaper to install, and this advantage increases in difficult terrain. Pipeline operators all over the world assert that hydraulic lines pay for themselves in a relatively short time, in spite of the heavy capital outlay, and this is equally true for lines convey-ing slurries or pastes within a plant complex.'This paper reviews some of the more important investigations in the hydraulic transport field. Although reference to systems carrying a wide range of materials is made, the majority of recent published data centres on coal transport.The paper looks at the application to a wide range of particle sizes, the development of non-aqueous slurrying media and coal/water fuels. The review also looks at some of the equipment being proposed to provide more reliable operation and in particular the range of solids-handling pumps now available.-The paper goes on to identify areas where further research and development is required and some of the many organisations undertaking this work.

Jan 1, 1985

The investigation of Noapara glass sand deposit in Sylhet district of Bangladesh is performed to beneficiate the sand for the manufacture of colourless glass. For the ease and efficient removal of the colour bearing impurities, the physical and mineralogical investigations of the sand deposits is carried out first. The sand is then treated with the standard beneficiation procedures to reduce the impurity level to an acceptable level. It is found that the Noapara glass sands are of medium grained and moderately sorted. They contain 0.15 - 0.30 per cent Fe2O3 and 0.001 -0.008 per cent Cr2O3 as major colour bearing impurities. The heavy mineral fractions containing most of the impurities can be grouped into five types of associations:stable or ubiquitous minerals (tourmaline, zircon, rutile); metamorphic species (staurolite, kyanite); amphibole minerals (hornblende, tremolite); the micas (muscovite, biotite); and discrete minerals (magnetite, ilmenite, etc). It is also seen that, the use of mechanical separation process in combination with water washing, attrition, and magnetic separation can remove a maximum of only 70 per cent of total Fe2O3 present in the deposits. This is insufficient to produce the specified grade of sand to manufacture colourless glass. Among the various chemical treatment processes used, sodium dithionite method is found to be the most effective, although the discrete minerals are not removed. Using the specific reagent group during froth flotation, the iron and chromium contents are reduced to 0.03 and 0.001 per cent respectively which are very near to the specified colourless glass composition.

Jan 1, 2000

Several coal preparation plants are presently "automated" to the extent of automatic sequencing and interlocking via digital means, together with closed loop control on various level and density circuits. This paper will explore the potential for second generation automation utilizing on-stream ash analysers and other measuring elements so as to optimize the total metallurgical process. This would enable maxim-ization of recovery, improved product homogeneity and minimum reagent consumption.

Jan 1, 1985

By Pandey A. K, Srivastava A, Das A

Drilling and blasting constitute important activity in mining operations and account for around 20% of the total excavation cost. The utilization coefficient of energy for explosions of the fragmentation type is hardly 15 to 2035 and an enhancement in this is possible only through optimization of blast design. Designing a 'blast is a complex planning task, which for optimum results calls for matching the energy level of the explosive, rock properties and bench geometry. Optimum blast design needs a comprehensive study and an objective analysis of the intersecting elements. A cost optimised approach is often adopted with due consideration for all the cost sectors viz., drilling, blasting, loading, hauling dumping, and primary crushing, contributing to the overall miring cost. The present study deals with a performance prediction model which predicts the optimum burden for an explosive system in a given rock type to produce a certain desired fragment size. The model is framed on the inputs : shovel size, drill size, unit cost of drilling, bench dimensions, rock density, bond index, unit cost of explosive, maximum work potential. The model has been extended to compute the drilling and blasting costs for an assumed size of the bench to be blasted per round, so as to arrive at the overall cost optimization from a number of explosive systems. A comparative cost calculation with different explosive systems has been presented for a typical iron ore mine in India.

Jan 1, 1990

By H Höft

Today tunnel segment liners are sealed with corner-vulcanised gaskets made of extruded elastomeric compression profiles. The profile geometries and the elastomeric materials have been further developed in course of time to meet the steadily increasing water-proofing requirements. After 40 years of using such compression gaskets, a wide range of proven standard profile geometries and well-known brands can be found on the market. Even so, there is still potential for further developments and improvement, not only with regard to the water-proofing performance. Permanently increasing cost pressure in the segment production plants demands further developments and new solutions with regard to application techniques. This is an abstract only. No paper was prepared for this abstract.

Mar 8, 2011

By Ryan CG, Cousens DR, Sie SH, Suter GF

Proton microprobe analyses of trace elements have been carried out on a wide variety of ilmenites, garnets and chromites, to improve diamond exploration methods. The results so far show the potential to discriminate between barren and diamondiferous source rocks, and to distinguish multiple sources within single Drainages.

Jan 1, 1989

By Swift D. G

For some time the Electricity Trust of South Australia (ETSA) has been investigating the application of new mining methods and equipment to minimise the cost impact of the steadily increasing depth of mining brought about by the 20¦ dip of the coal seams at the Leigh Creek Coalfield. Exhaustive examination of all suitable mining systems showed that highly mechanised systems involving belt conveyors displayed no eco- nomic or operational advantages over shovel and truck methods. However, the configuration of the Leigh Creek coalfield allows for two quite different approaches to mining by shovel and truck. The current strip mining method involves removing overburden from the highwall in 60 m to 200 m wide strips to progressively expose the coal down dip, and requires all waste to be hauled to the surface. The alternative ter- race haulback method involves opening a boxcut to full depth at one end of the coalfield, then mining the full section along strike and placing the spoil in the mined out area. On a strictly economic basis, the latter is clearly advantageous, but the former has significant less tangible advantages. In deciding between the two methods ETSA is faced with the need to examine the applicability of each method under a wide range of possible future demands on the coalfield, and to assess the importance of many intangible factors.

Jan 1, 1989