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By Charles "Chick" Rodgers, Anthony Sarion

"With declining feed grade and increased production targets, it became necessary to upgrade Key Lake's eight stage counter current decantation (CCD) circuit. Following laboratory trials, mill operations recognized that dilution of the feed slurry and buffering of the feed density variations would improve thickener throughput. Plant testing resulted in the installation of Outokumpu's Supaflo ""Floe-Miser"" system. The circuit's flowsheet, instrumentation and control strategy were also upgraded along with the thickener feedwell modifications. The paper will also discuss these modifications and the implementation of the current control strategy.IntroductionCameco Corporation's Key Lake operation is the largest single uranium producer in the world. Current production is fourteen million pounds of uranium oxide (U 308) per year. It is owned 2/3 by Cameco and 1/3 by Uranerz Exploration and Mining with Cameco as the operator.The mine is 570 kilometres north of Saskatoon on the southern edge of the Athabasca basin. Access to the mine is by an all-weather road and a private airstrip.Process DescriptionThe Key Lake milling process consists of five individual plants: crushing and grinding; leaching and counter current decantation (CCD); solvent extraction; yellowcake precipitation and ammonium sulphate crystallization; and bulk neutralization (Figure 1 -Simplified Mill Flowsheet). A detailed mill flowsheet can be found in the appendix."

Jan 1, 1998

By S. Ivanova

The results presented in this paper show that the gold solution dilution is a key parameter to control the dispersion of gold on ?-Al2O3 the selected support. The variation of concentration leads to changes in pH which modify the nature of gold complexes from HAuCl4 formed in the solution. These complexes are presented. Some of them (AuCl3(OH)- and AuCl2(OH)2 -) react with the surface of alumina and give interesting interaction. AuCl2(OH)2 complex has been considered as an ideal complex because of the strong anchorage of a bidentate species on the alumina. This complex is formed mainly in a solution of gold with a concentration of 10-4 M giving a pH of 3.5-4.5. The nature of the anchorage and the amount of chlorine, has an influence upon the formation of Au-Cl bridges which modify the dispersion of the gold on alumina of the final catalyst as shown by TEM.

Oct 1, 2003

Thermal barrier coating (TBC) systems provide thermal insulation to high temperature for aero¬propulsion. A fracture mechanical model developed earlier for multilayer systems is applied on TBC to realize superior performance by enhancement of fracture resistance. Functionally gradient materials (FGM) solution concept is the basis of approach followed here. A few realistic FGM TBCs are considered in the analysis in addition to a conventional TBC as the base case and a hypothetical worst case with YSZ-YSZ interface. Parameters like number, composition and thickness of graded layers and elastic modulus are considered for the analysis and quantitative improvement of fracture resistance of TBCs. The analysis is confined to deep crack with crack size to width ratio as 0.5.

Jan 1, 2010

By Zhibao Li, Lanmu Zeng

The behavior of dicalcium silicate in NaOH-NaAl(OH)4-Na2CO3 solution is of significance for controlling the silica level in the production of alumina via the sintering process. Dicalcium silicate samples were obtained through a twostep approach: coprecipitation of calcium and silicate from CaCl2-Na2SiO3-NaOH solutions; and calcination of the hydrated precursor at 1200°C for 4 hours. The optimization of the synthesis parameters including temperature, solution concentrations and aging time was also investigated. Xray diffraction (XRD) and chemical analysis show that the calcined solids include dicalcium silicate with trace amounts of wollastonite. The solubility of the synthesized dicalcium silicate in HCl, NaOH, mixed NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was determined. It was found that the solubility increases with increasing HCl and NaOH concentration. The effect of temperature on the solubility in HCl solutions is limited, but the solubility decreases with increasing temperature in NaOH solutions. The solubility of dicalcium silicate in NaOH-NaAl(OH)4 and NaOH-NaAl(OH)4-Na2CO3 solutions was shown to increase with increased temperature, Al(OH)3 and Na2CO3 concentration. The BromleyZemaitis model for the aqueous electrolyte system was selected to predict the solubility of dicalcium silicate. The model’s predictions yielded certain success compared with experimental solubility data.

Jan 1, 2014

By D H. Sharp

The Quebec Cartier Mining Company produces iron concentrate for twelve months of the year from Port Cartier. This J>Ort is designed to handle ship varying in size from 3,000 to 100,000 d.w.t., requiring 50 feet of water at low tide. The harbour was built on shore for reasons of economy and layout, after considering many more conventional offshore designs. It provides for heavy oil bunkering, tanker off-loading, a heavy lift derrick and freight handling, besides ship loading and mooring. The weather for the previous fifty years was studied to enable wind and wave conditions to be accurately assessed for design purposes, and to determine probable lost time due to adverse weather conditions through-out the year. The first ship to be loaded was 60,000 d.w.t.; the second, 20,000 d.w.t. The latter entered the harbour after dark, under its own power, following a tug through the partly dredged narrow entrance. Large ships use tug assistance. Ships may leave the loading berth with the other berths occupied.

Jan 1, 1963

By H. Saari, D. Y. Seo, J. Beddoes, T. R. Bieler

Prior work on effects of lamellar orientation on creep rates and other mechanical properties have shown that having lamellae parallel to the tensile axis provides optimal creep resistance and good strength. Consequently, a directional solidification system was used to examine the effect of solidification rate on the development of crystals with lamellae parallel to the growth direction. The nominal chemical composition of TiAl ingots was Ti-46A1-2Mo-2Nb (at%) and the ingots were 20 mm in diameter and 180 mm long. The master alloy bars were placed in a high purity yttria mold on a copper chill plate and raised into the hot zone of a Bridgman furnace. The alloys were melted and then directionally solidified at withdrawal rates of 4, 8, and 12 mm/min. As-cast specimens were sectioned at positions of 4, 22, 66, 111, and 155 mm from the bottom of the ingot to evaluate microstructure and crystallographic texture as a function of distance from the bottom of the ingot. The directionally solidified microstructure consists of continuous columnar grains with fully lamellar structure, a network morphology of primary 13, yttria particles, and interlocked columnar boundaries. For all three ingots, the texture at 4 mm shows many peaks, with isolated strong peaks, and a slight tendency toward <111> plane normals within about 20° of the cylindrical axis. At 155 mm, all specimens showed substantially stronger clustering of <111> orientations near the cylinder axis, with the strongest clustering of poles occurring for the 8 and 12 mm/min specimens. Analysis of diffraction peaks indicates that strongly compressive residual stresses in the radial direction are present in the casting. The combined microscopy and texture analysis provides more complete understanding of the processes of directional solidification of TiAl alloys.

Jan 1, 2004

By M. Bouchard, B. Cadieux et F. Goutier

Five phases of ice movement were r es pons ible f or glacial dispersion in t he study area. I ce fl ow directi on changed prog r es s ively from SE to SSW and then to the S. All observed glacial sed iments are associated with a south-southwest to south movement; t hey are grouped, on the basis of their texture, structure, morphology and composition, into four distinct lithofacies. A lithological study of the coarse-grained fraction (4-128 mm) of these lithofacies shows systematic compositional differences. These are: 1) variations in the proportions of local bed rock fragments; 2) variations in the horizontal displacement of the maximum abundance peak of a given lithology relative to its source area, and 3) variations in the length of dispersion trains associated with each lithofacies. Although dispersal trains can obviously be mapped without differentiating li thofacies, studies based on the consideration of lithofacies should give more reliable results than conventional methods.

Jan 1, 1984

By O. G. Olvera, E. Asselin, D. Rival

Particle concentration distributions in a leaching tank have been estimated using a novel experimental approach that takes advantage of the galvanic interactions that occur between pyrite (FeS2) particles and a Pt electrode. The collision of FeS2 particles with Pt changes the open circuit potential measured with the electrode due to galvanic interactions. To discern particle collisions with the Pt electrode from experimental noise a simple analytical procedure was first adopted although the use of techniques involving frequency domain analysis is also briefly presented and discussed. Although this method is still under development, it is simple to implement and can yield valuable information regarding the hydrodynamic behavior of solid particles in stirred tanks in very short times. Finally, the advantages and drawbacks of the technique are discussed.

Jan 1, 2014

By G. Viramontes-Gamboa, A. Encinas-Oropesa, S. Velázquez-Roque, L. A. Ibarra-Bracamontes

Some industrially relevant applications for pyrite nano/micro-particles have been proposed in the literature, such as the catalysis of chalcopyrite leaching, the removal of As(III), As(V) and Cr(VI) from solution, as photovoltaic devices, and others. Even though pyrite can be recovered from solution by flotation, for some applications it may be beneficial to provide pyrite with magnetic properties. In this work, a methodology to synthesize magnetic shell/core composites made of pyrite as the shell and either natural or synthetic magnetite as the core is presented. The size of the magnetic composite may range from tenths to hundreds of microns. The synthesis is basically made by stoichiometrically mixing iron nano/micro-particles with sulfur microparticles with magnetite particles, and bringing the mixture in an oxygen free atmosphere from 200 to 300 °C for 4 h. The composites were characterized by optical microscopy, Scanning Electron Microscopy and X-Ray diffraction.

Jan 1, 2014

By F. P. Hassani, M. Hefni, M. F. Kermani

"This study is part of large and an ongoing investigation into the development of a light-weight and highly fluid mine fill for various applications in mining and civil operations. Foam mine fill is the new material proposed for backfilling mines, and is fabricated by mixing stable foam into a mixture of tailings, binders, and water. This paper investigates the effects of both binder dosage and the amount of foam used upon the mechanical and physical properties of foam fill, mainly in regards to compressive strength, porosity and density.Samples were prepared using tailings from a copper mine as the inert material, Normal Portland Cement as the main binding agent, and a foaming agent with a foam generator. Samples were cured for 7, 14 and 28 days and were then subjected to unconfined compressive strength (UCS) testing. Select samples were subjected to mercury intrusion porosimetry, so as to study the microstructural properties. An empirical model was then developed, using a response surface methodology to establish a relationship between the investigated parameters. INTRODUCTION AND BACKGROUNDThe disposal of mine tailings is a significant issue in the mining industry, particularly as mine production increases. Many mines re-use mine tailings for backfilling, which is a method for reducing environmental exposure to tailings, maintaining underground stability, and increasing ore recovery (Benzaazoua, Belem & Bussière, 2002).This paper introduces a new type of backfill called ‘foam mine fill’. This proposed backfill material is similar to cellular concrete, as air bubbles are entrained in cement or lime mortar, resulting in a cellular structure (Narayanan & Ramamurthy, 2000). Air voids can occupy up to 70% of the volume of concrete, which makes it light- weight, and thus can be used for a wide range of civil applications, including backfilling (Tarasov et al. 2010; Panesar, 2013). Unlike cellular concrete, the incorporation of air bubbles into a mixture of tailings, binder and water makes foam fill a potential new backfilling material. Furthermore, a preliminary investigation on foam fill samples found that pulp densities should be optimized before adding the foam, in order to produce consistent samples without foam segregation or losses (Hefni et al., 2014)."

Jan 1, 2015

By C. J. Simensen, R. Østhus, H. J. Roven, K. G. Skorpen, H. Kalager

"This work encompasses co-extrusion of alloy Al4.5Mg at the core and rapidly solidified Al4.5Mg1Ag forming the surface layer. The goal is to produce a multi-material by co-extrusion having a relatively hard surface as compared to a softer core. At the same time, work hardening in both alloys is expected to be significant due to Mg in solid solution. Precipitation hardening at 160°C is studied by applying solution heat treatments at 560°C. The hardness increased from 80 to 130 VH in the surface material after 236 h. Surprisingly, the Al4.5Mg alloy also shows pronounced aging at this temperature, i.e. from 70 to 90 VH. The relatively high solution heat treatment temperature introduces grain growth in the core, but this is insignificant for the RS surface alloy. Blisters forms at the surface and cracks follows large portions of the interface. However, the tensile ductility is significant in all conditions due to very pronounced work hardening, i.e. for the as co-extruded, T6, under- and over-aged. The elongation at fracture ranges between 40–45% and the tensile strengths 240–275 MPa. The tensile properties increase linearly with the thickness of the RS alloy, i.e. following the rule of mixtures.INTRODUCTION Al-Mg alloys in 5xxx-series are classified as non-heat treatable wrought alloys (Polmear, StJohn, Nie, & Ma, 2017). The formation of the binary ß-Al8Mg5 does not give a substantial increase in the strength of the alloys (Mondolfo, 1976). When a third element like Ag, Cu or Zn are added, G.P.?zones are formed at low temperatures and intermediate, partial coherent phases are nucleated somewhat higher temperatures and finally a ternary, equilibrium phase is formed (Auld, 1968; Cousland & Tate, 1986; Mondolfo, 1976). Both the formation of G.P.?zones and intermediate phases increase the hardness and strength of the materials. An intermediate, hexagonal T´?phase is formed in Al-5 wt%Mg-1wt%Ag, and finally the equilibrium, cubic phase (Al,Ag)9Mg5 is nucleated (Cousland & Tate, 1986; Mondolfo, 1976)."

Jan 1, 2018

By Nicholas J. Welham

"The effect of extended ball milling has been studied for two industrial processes: (1) the processing of metal sulphide concentrates; and (2) the carbothermic reduction of ilmenite to synthetic rutile. The plant concentrates were a gold ore with 128 g/t Au of which 8% was non-refractory and a zinc concentrate with copper impurities.The gold concentrate showed complete dissolution of the gold bearing minerals after milling giving almost complete gold liberation. The zinc concentrate showed almost all of the sulphides had solubilized leaving the gangue and elemental sulphur. A study of pure pyrite and arsenopyrite shows that selective dissolution should be possible by a simple leaching process directly after milling.The milling of ilmenite and coal together results in a temperature decrease of 150°C in the subsequent carbothermic reduction of ilmenite, in addition to improving both the rate of reaction and the selectivity of reduction to rutile. IntroductionAlmost all mineral processing plants use mills for the size reduction of particles prior to physical and chemical processing. When continuing beyond size reduction the energy transferred causes deformation, breakage and realloying of particles giving a steady-state particle size. The breaking also causes increasing damage to the crystal structure by formation of smaller grains giving an increasing number of grain boundaries and increasing crystalline defects due to deformation. The increasing number of grain boundaries and defects leads to increased reactivity, which can be seen directly by a reaction within the mill, or indirectly, via a decrease in the subsequent annealing temperature required for reaction."

Jan 1, 1997

By J. P. Messervey

Dr. K. A. Clark: No one will doubt the statement of fact that, during drilling operations through the bituminous sand beds in the Mildred-Ruth Lakes area, the core-barrel was found to contain bitumen with minor amounts of sand instead of bituminous sand. But many will doubt the interpretation of this fact as meaning that beds of bitumen occur interstratified with the bituminous sand beds. They will prefer to hold faith in the laws of physics, which deny that sand will float on oil or that fluid under pressure will not flow away through a permeable medium, until it is proved that the appearance of the oil in the core-barrel was not due to circumstances surrounding the drilling of the bituminous sand beds. The implication of the interpretation that sand is floating on oil is clear and it is unacceptable. Bituminous sand is unconsolidated sand more&apos; or less saturated with a viscous oil. It is as difficult to conceive of bituminous sand lying on top of a body of the viscous oil as it is to conceive of unconsolidated sand more or less saturated with water lying on top of a body of water. The only difference between the two concepts is that the oil is viscous whereas the water is fluid. Oil-soaked sand placed on viscous oil would, when released, sink through the oil slowly, whereas water-soaked sand would sink through the water quickly.

Jan 1, 1947

By M. J. deBastiani

The uranium producing division of Denison Mines Limited operates a 6,000-ton-per-day integrated mining unit in the Algoma area of Ontario. The property is located approximately one and one-half miles from Highway I 08, eight miles north of the town of Elliot Lake. The property was staked in 1953, diamond-drilled in ?late 1954 and 1955, and put into production in 1957. Since that date, the operation has produced $250,000,000 worth of uranium oxide from approximately 11,000,000 tons of ore milled, and paid $18,000,000 in dividends to its shareholders. The operation employs about I000 people, and monthly operating costs are approximately one million dollars. From these figures alone, it is obvious that it was necessary to develop and institute an adequate set ?of controls for effective management at all levels of supervision over a period of four years, a system of production and cost control was developed that enables us to effectively measure the pulse of the various phases of the operation at any given time.

Jan 1, 1963

By S. Yadav, T. G. Murthy, C. Saldana

"An experimental study has been carried out in order to study the deformation of porous brittle materials under plane strain indentation. Gypsum, which is well known model system for understanding the behaviour of soft rocks, is used in this study. The effect of wedge angle is investigated in this research through this series of experiments, using wedges of 3 different apical angles. High-speed, high-resolution images are captured using a CMOS camera during the experiment. The images obtained are analyzed using a Particle Image Velocimetry (PIV) algorithm in order to obtain the evolving velocity, strain-rate and strain fields.INTRODUCTIONThe problem of indentation, which is usually referred to in the context of hardness testing is ubiquitous as a material characterization technique for a large class of solids. Mechanical properties of materials such as yield stress, flow stress, fracture toughness, elastic moduli etc. can be related to the hardness of a given solid. The indentation problem involves a given material or solid (whose properties are to be determined) indented by a relatively harder material (indenter) allowing the solid to undergo plastic deformation, which is then related to the yield stress of the material. The problem of indentation and its variants see many applications ranging from mining and petroleum industry, infrastructure industry, manufacturing, and biomedical sectors. Indentation has been extensively studied in metals, with accurate measurement of deformation parameters, stresses and comparison with analytical solutions. On the other hand, understanding of indentation in other class of solids such as cellular solids, porous solids, rocks, and soft solids is still nascent. In case of rocks, a comprehensive understanding of the indentation problem is very crucial because of the obvious applications in mining, petroleum and infrastructure sectors. The inherent porosity, the brittle nature of the rocks, adds to the complexity of indentation in these porous brittle solids. Various theoretical models with degrees of simplifying assumptions have been proposed to study the indentation in rocks. The most common model used in the study of indentation in rocks is a cavity expansion model, wherein a blunt indenter indenting into a rock is approximated with the expansion of cylindrical or spherical cavity in an elastic-plastic material. Complementary studies in understanding fracture initiation and propagation due to indentation has been largely based on the studies of traditional brittle materials such as glass."

Jan 1, 2015

By Kilmar Mine

The Kilmar dolomitic magnesite deposit~ in sourhwesr Quebec lie in Grenville Province sedimentary rocks that strike north and dip steeply west. The sediments comprise quartzitic, carbonate and argillaceous members. The middle or carbonate member hosts the magnesite and, like the two other members, has been intensely mewmorphosed. Magnesite occurs as lenticular shaped zones of altered limestone and is mixed with 5 to 30% dolomite crystals. Diopside, serpentine and mica are common accessory minerals. Magnesite appears to have formed from merasomarism of all or part of the carbonate member due to intrusion of hot magnesia-rich solutions. Magnesite is mined from a 490 m vertical shaf1 and is milled and burned into clinkers, which then are shipped 10 pyroprocessing industries around the world.

Jan 1, 1984

By Ruan Chi, Zhenyue Zhang, Zhengyan He

In order to understand what governs the leaching of exchangeable rare earth (RE) and impurities and enhance the RE leaching process, the effects of the concentration of ammonium sulfate, pH and leaching temperature on the migration of RE and aluminum (Al) during the leaching of weathered crust elution-deposited rare earth ore was studied. The elution curves for ammonium ion (NH4 +) were also studied to reduce the consumption of the leaching agent. It was found that a high concentration of leaching agent can enhance the leaching process of RE and Al, reduce the breakthrough volume of NH4 + and more rapidly obtain the equilibrium of NH4 +. However, excessive leaching agent can both increase the cost and the burden on the environment. There is almost no variation on the elution curves of RE and Al in the pH range of 4-8 and control of the pH of the leaching agent can be omitted. It is better for the leaching work to be done in summer since higher temperatures can enhance the RE leaching process and improve the use ratio of ammonium. Using 0.1 mol/L ammonium sulfate for leaching 250 g RE ore, 95.42% RE extraction can be obtained when the volume of leachate is 102.6 mL. At this moment, only 18.17% of NH4 + is used to exchange RE and 49.22% of NH4 + is left in the leachate that can be reused as leaching agent by replenishing ammonium sulfate. The results of our studies can provide theoretical guidance for high efficiency and low consumption exploitation of RE ores.

Jan 1, 2016

By K. Kawagishi, J. Ang, A. Sato, H. Harada

"We have recently proposed a new ""EQ Coating"" bond coat system to solve the problem of secondary reaction zone (SRZ) formation caused by bond coats applied on the hot section components of modem jet engines. A viable EQ coating alloy was previously found for a representative znd generation superalloy, TMS-82+. It would be ideal if the same could be done for a representative 5th generation superalloy, TMS-173. In this paper, we will show that the coating with the best oxidation resistance in the EQ system of TMS-173, although possessing considerably better resistance than TMS-173, did not have sufficient oxidation resistance. In order to improve the oxidation resistance of the EQ coating for TMS-173, we have ventured into ""Pseudo-EQ coatings"". A diffusion couple between the Pseudo-EQ coating and TMS-173, after 300hrs at 1100°C, had a 0-15µm IDZ, but no SRZ. A diffusion couple between a conventional coating and TMS-173 formed a 80-150 µm SRZ. After a 1 hr oxidation test at 1100°C, the PseudoEQ coating formed a thinner oxide layer than the EQ coating, but still contained NiO and spinel. Aerospace"

Jan 1, 2006

By B. K. Mishra, Subrat Kumar Padhy, B. C. Tripathy, I. N. Bhattacharya

Manganese is a difficult metal to electrodeposit due to its high electronegativity and continues to possess unique process challenges. Manganese deposits of high quality are electrodeposited on 316 grade stainless steel from sulphate solutions in the presence of organic additives such as tetra ethyl ammonium bromide (TEABr), tetra propyl ammonium bromide (TPABr), and tetra butyl ammonium bromide (TBABr). The concentrations of these additives were examined over a relatively broad range to evaluate their effect on current efficiency, specific energy consumption and deposit morphology of the electrodeposited manganese metal. A maximum current efficiency of 68% was achieved in the presence of TEABr in the bath. X- ray diffraction studies revealed that (330) (411) planes were the most preferred planes of crystal growth during manganese electrowinning at a current density of 500 A/m2 resembling alpha-manganese irrespective of the nature of additive. Scanning electron micrographs showed smooth and uniform deposit morphologies when manganese was electrodeposited in the presence of TEABr.

Jan 1, 2014

By Samuel B. Rombeger

The behavior of gold in hydrothermal systems is evaluated as a function of pH and oxygen and sulphur activities at temperatures to 250°C. Under conditions of stability of pyrite and argillic alteration as emblages, gold will be transported as bisulphide complexes. In systems containing significant amounts of arsenic, thioarsenide complexes may be important. Oxidation, dilution and reduction in sulphur activity would cause gold deposition from saturated solutions under these conditions. Gold chloride complexes will predominate under oxidized conditions where hematite or other oxides are stable and depo ition would result from increase in pH and/or reduction . Absorption and coprecipitation are po sible mechanisms of deposition for gold in certain low grade depo it . Low concentrations of gold in the transporting solution combined with the ignificant solubility of gold as bisulphide complexes, sugge t hydrothermal solutions rarely may be saturated with gold and coprecipitation with sulphides may be an important initial depositional process. Recrystallization of the sulphides in the presence of the hydrothermal solution would be re ponsible for release of gold to more table ite . Thi mechani m i supported by the close association of gold with pyrite in many hydrothermal gold deposits.

Jan 1, 1986