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By L. B. Pankratzt

The heat content above 298.15° K of ferroelectric lithium columbate (LiCbO3) was measured to 1,770° K. The Curie temperature was determined to be 1,450° K, the melting point 1,540° K, and the heat of fusion 16.94 kcal/mole. Heat content and entropy increments have been tabulated for the temperature range from i98.15° to 1,800° K. Heat contents are also given in equation form.

Jan 1, 1966

By R. E. Head

[Surveys of the manganese situation conducted by the Geological Survey any other agencies have definitely established the, fact that the tonnage of high-grade manganese or in the United States is relatively small. It is therefore obvious that large-scale production of manganese is possible only through beneficiation of low-grade material. Deposits of low-grade manganese ore are being examined by engineers of the Mining Division of the Bureau of Mines to determine their size and possibilities as sources of manganese on a tonnage basis. The Metallurgical Division of the Bureau is developing and perfecting beneficiation processes with the objective of utilizing such low-grade ores. Microscopic study of these ores represents one phase of the research.]

Jan 1, 1941

By R. E. Head

[Surveys of the manganese situation conducted by the Geological Survey and other agencies have distinctly established the fact that the tonnage of high- grade manganese ore in the United States is relatively small. It is therefore obvious that large-scale production of manganese is possible only through beneficiation of low-grade material. ]

Jan 1, 1941

By Vernon C. Allison

The explosibility of coal dust has long been recognized by competent investigators as constituting one of the dangers of mining coal and in the use of pulverized coal as a fuel in industrial plants. The Bureau of Mines has carried on extensive series of experiments dealing with this subject, and has not only developed methods for the practical prevention of this danger, but in the, course of these experiments has developed a standard method of determining the relative explosibility of coal dusts and other organic dusts.3 Oil shale contains compounds 'of carbon and hydrogen that are either of a petroleum nature and are strongly ,adsorbed upon the incombustible part of the shale, or else are present in the shale as a compound ("kerogen") which has the property of changing into petroleum-like products when acted upon by heat. The oil shales may contain varying amounts of the organic matter, ranging from a trace to more than 66 per cent, depending upon their richness; therefore, it is important to know whether the dusts formed in mining and handling these oil shales are explosive when mixed with air and if so, to indicate remedial measures. This paper gives the results of explosibility tests of several pulverized oil shale's, selected as being typical of those which in the future may be used in commercial shale-oil production test on a sample of typical Colorado oil shale has been., published in an earlier paper.4

Jan 1, 1926

By N. S. Dalal, A. H. Hoffman, X. Shi, D. E. Banks, J. K. H. Ma, Y. Rojanasakul

Excessive production of reactive oxygen radicals by alveolar macrophages is proposed to play an important role in oxidative lung injury. A major product of oxygen radical formation is the highly reactive hydroxyl radical (•OH) generated via a biologic Fenton reaction. In addition to its known ability to induce lipid peroxidation, recent studies have suggested that the •OH may exert its cytotoxic effect through the alteration of [Ca2+], homeostasis. To test this potential mechanism as well as to investigate the relationship between •OH and Ca" overloading in cytotoxic injury, isolated rat alveolar macrophages were exposed to externally generated radical system, H2O2 (0.01 to 1 mM) and Fe (1 mM) and their [Ca2+] levels and cell injury were monitored using quantitative fluorescence microscopy with the aid of the specific Ca" indicator, Fura-2, and membrane integrity indicator, propidium iodide. Electron spin resonance measurements using the spin trap 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) confirmed the production of the .OH radical by this system. Upon the addition of the radicals, the macrophages displayed a rapid initial rise in [Ca2+] which was followed by a slower but more pronounced [Ca2+], elevation that reached a level 3 to 5 times higher than the basal level. This process preceded cell death as evident by nuclear propidium iodide fluorescence. Depletion of extracellular Ca" inhibited both the [Ca2+], response and cell injury. Preincubation of the cells with the Ca" channel blocker verapamil or .0H radical scavenger mannitol similarly inhibited the [Ca2+], rise and loss of viability. Firefly luciferase assay of cellular ATP content demonstrated that the alterations in [Ca2+], following .0H treatment preceded the depletion of ATP. Changes in membrane potential caused by Na* substitution with K* had no significant effect on either the unstimulated or stimulated [Ca"], levels. Taken together, these measurements indicate that .OH-induced injury in alveolar macrophages is associated with the alteration in [Ca2+], homeostasis. The mechanism of •OH-induced [Ca2+] loading is not due to nonspecific membrane damage or energy depletion, but mainly due to an increase in Ca2+ influx through Ca2+ selective channels. This Ca2+ over-load state as well as energy depletion caused by the oxidant may activate certain cellular degradative processes leading to cell injury and death.

Nov 1, 1995

By A. D. Bauer

For several years the Bureau of Mines has conducted surveys to determine the changes in motor gasoline being sold throughout the United States. The present survey shows that far the districts in which samples were collected, the average gasoline is becoming more volatile instead of less so, as is sometimes supposed. This year's gasoline is much more volatile than that sold two years ago, and it has a somewhat better distillation range than last summer's samples. A comparison of the average figures for several years, shows that motor gasoline is also becoming more uniform in character. The large seasonal change is disappearing, but ?winter gasoline', still has a lower initial boiling point than "scanner gasoline". This difference in volatility is made intentionally to facilitate starting the motor in cold weather. The end point shown in the present survey is slightly lower either than that of last winter or of the summer of 1921.

Jan 1, 1922

By Ronald A. Munson

Samples of the naturally occurring zeolites phillipsite, clinoptilolite, erionite, and chabazite have been surveyed for their gas adsorption, ion exchange, and other characteristics. Chabazite and erionite, which are generally more stable, also have higher methane adsorption capacities than do the other natural zeolites. Both natural erionite and natural chabazite are classified as small-port zeolites on the basis of their inability to adsorb chlorotrifluoromethane. In the range of 8 to 100 mesh, the adsorptive capac-ity of natural zeolites is improved only slightly by a decrease in particle size. The capacity of natural clinoptilolite to adsorb methane is increased by cation replacement by the hydrogen ion and decreased by exchange with calcium ion. Natural phillipsite, which is easily decomposed by heat, adsorbed methane to a limited extent.

Jan 1, 1973

By Edward W. Parsons

Conventional rock-bolt anchors often fail when installed in weak formations. The purpose of this work was to develop an anchor that would utilize an explosive charge to secure anchorage in any type of rock. Laboratory work to develop a rock-bolt anchored by explosive forming was initiated using rock-bolt models which had a drilled explosive chamber and were composed of various metals. This was followed by the use of several types of seamless tubing which were expanded with a water-coupled explosive capsule. By attaching a length of solid bolt to the anchor tube, a prototype explosive-anchored rock bolt was made. More than 150 laboratory models were expanded during this phase of development, During two field tests in underground mines (A and B) and one in an open- cut mine (C), 87 explosive-anchored bolts, 9 slot-and-wedge bolts, 2 bolts anchored with expanding grout, and 28 expansion-shell bolts consisting of three types of shells were installed and subjected to pull tests. The field tests were run to determine the effects of variables such as the amount and placement of the explosive charge, design changes in the bolt, and the effect on anchorage of different pull-test techniques. The field tests revealed the following: Mine A. The explosive-anchored rock bolt was feasible, but changes were necessary in bolt materials and in some details of bolt design. Mine B. The design and materials of the bolt gave excellent results in hard fractured rock, but no information was obtained concerning variations in the dimensions of the anchor unit or in the explosive charge. Nine C. Varying the explosive charge to produce a beaded surface on the bolt tube and tightening of the anchored bolt before pull-testing were found to increase significantly the anchorage obtained in soft ground.

Jan 1, 1963

By J. E. Hamak

This publication contains analyses and related source data for 165 natural gas samples from 21 States and 1 foreign country. Of the total samples, 155 were collected during calendar year 1988. The remainder were collected earlier, but releases granting permission to publish were not received until 1988. All samples were obtained and analyzed as part of U.S. Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by mass spectrometer and chromatograph.

Jan 1, 1989

Develop new technolgies and techniques which enable recovery of strategic and critical minerals such as cobalt from domestic resources, thereby easing the U.S. dependence upon foreign producers for these valuable commodities. Approach The Bureau of Mines, through research, developed a process which uses mineral beneficiation techniques to recover cobalt-rich products from Missouri lead ores. Before development of this process, cobalt was lost as an impurity in the copper, lead, and zinc concentrates and in the mill tailings because the technology to recover it with minimum impact on present production did not exist.

Jan 1, 1989

By A. Wahab Khair, S. Jung

"This paper deals with the fracturing process of laterally confined blocks of coal subjected to impact indentation. During the test, blocks of coal with approximate dimensions of 10 in. x 10 in. x 6 in. were laterally confined to predetermined equivalent in-situ stresses and then subjected to an impact indentation by dropping coal cutting bits (various shapes) attached to a known weight from a known height. During the test a number of parameters, namely surface strains (using strain gages), penetration depth (using L.V.D.T.) and acoustic emission characteristics were measured. After the test, the fractured surfaces were photographed with the aid of a camera attached to a microscope. The fracture, its intensity and extended zone within the coal blocks were mapped using sonic techniques. By correlating measured parameters, fractured zones under a given set of test parameters were identified and characterized.INTRODUCTION To improve the understanding of basic failure mechanisms in coal cutting, a better knowledge of fracture and crack regions caused by the indentation in coal is needed. This study reports the detailed experimental procedure used in fracture analysis of indentation experiments on coal specimens using the Acoustic Emission (A.E. hereafter) and sonic techniques. The relationship between microcracking and the inelastic deformation of rock was confirmed by a series of experiments in which the A. E. generated by the cracking in the rock specimen were recorded and the number of events were compared to the strain measurement. (Scholz, 1967).According to fracture mechanism theory, crack initiation in brittle materials such as rocks begins from ""flaws"" either pre-existing or induced by the indentation process itself. Rocks are pervaded by natural cracks and pores, from which numerous possibilities for crack initiation arise (Lindquist, Lai and Alm, 1984)."

Jan 1, 1989

By E. C. Lane

The motor gasoline which is being marketed in the United States this summer is apparently more volatile than the gasoline sold a year ago. In fact the average volatility of this summer's gasoline is almost the same as the average volatility of the gasoline marketed last winter. During the past seven years the Bureau of Mines has made semi-annual surveys of the gasoline marketed in the United States, the survey just completed being the fourteenth in the series. The cities in which samples have been collected have been chosen as representative of the more important marketing territories as it is obviously impracticable to obtain a sample of every gasoline sold in the entire country.

Jan 1, 1926

By R. M. Gammell

"INTRODUCTION The Farmer prospect was examined by W. R. Green, an engineer of the Bureau of Mines, in June 1944. As a result, studies of this property were included in a general preliminary investigation of the Etevens County lead-zinc deposits by the Bureau in 1945. The exploratory work was designed chiefly to supplement the surface examination by determining the nature of the mineralization below the zone of oxidization. The results of the small-scale diamond-drilling program undertaken at the property are presented in the following report.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization our resources to the end that they make the greatest possible contribution to security and economy. It is the policy of the Bureau to publish the facts developed by each exploratory project as soon as practicable after its conclusion. The Mining Branch, Lowell B. Moon, chief, conducts preliminary examinations, performs the actual exploratory work and prepares the filial report. The Metallurgical Branch, R. G. Knickerbocker, chief, analyzes samples and performs beneficiation tests."

Mar 1, 1947

By D. Harrington

Springing or chambering of deep drill holes is common practice in some quarries. It involves definite hazards from premature explosion during placing of the springing charges or the final charge due chiefly to heating of the bottom of the holes by the successive exploding of the springing charges or, in some instances, from burning of paper or other material following detonation of the explosives The danger is either unknown or disregarded in many instances by those who place the charges in the holes. Disregard of this hazard probably is, at least in part, responsible for the far too high fatality and injury rate due to charging explosives and premature slots in quarry work. Awareness of the danger' should result in elimination or at least of material decrease in injuries from this cause.

Jan 1, 1941

By R. K. Clifford

Chalcopyrite (CuFeSz) concentrates produced on the Lead Belt of Missouri typically contain 28 pct Cu and from 0.5 to 1.5 pct each of nickel and cobalt. Most of the nickel and cobalt are present as the mineral siegenite, (Ni,Co)3S4, almost none of which is recovered presently. The Bureau of Mines, U.S. Department of the Interior, has been conducting research on the chalcopyrite to produce a marketable fraction enriched in cobalt and nickel. Ferric chloride leaching of various chalcopyrite (copper) concentrates has yielded residues containing from 10.2 to 16.2 pct Ni and 8.3 to 11.4 pct Co with recoveries of approximately 79 pct. In another approach, laboratory froth-flotation tests have been conducted to investigate the effects of regrinding, roasting, baking, and steaming prior to flotation, with a variety of reagents. The best laboratory results were obtained after regrinding the copper concentrate to 94 pct minus 400 mesh and floating the chalcopyrite at natural pH (6.5) with 0.48 pound of sodium diethyldithiophosphate and 0.01 pound of sodium cyanide per ton of concentrate. This procedure yielded a tailings assaying 20.4 pct Cu, 5.2 pct Ni, and 3.45 pct Co. The tailings contained 67.2 pct of the nickel and cobalt and 15.9 pct of the copper originally in the copper concentrate; the remainder of the values reported to the flotation concentrate, which analyzed 29.6 pct Cu. To verify the laboratory flotation results, a 60 kg/hr process demonstration unit (PDU) was constructed in the Cominco American Magmont mill, Bixby, Mo.

Jan 1, 1978

By T. A. Evans

The Bureau of Mines conducted a Laboratory and pilot-plant investigation of the flotation of iron sulfides from zinc-lead mill tailings near Platteville, in south-western Wisconsin, at the North Central Experiment Station, Minneapolis, Minn. The procedures used and the results obtained in this investigation are described in this report. Samples for laboratory tests were obtained from each mill in the district, namely, Calumet & Hecla, Inc., Eagle-Picher Co., Vinegar Hill Zinc Co., and Tri-State Zinc, Inc. The sample fat pilot-plant work was obtained from the Davis Mining Enterprises mill.

Jan 1, 1957

By Oliver Bowles

"Properties and Uses.Iceland spar is a name given to a pure crystallized form of calcite (CaCo3) which is sufficiently transparent and free of defects to be used in the manufacture of optical instruments. While the actual requirements are small, the degree of purity and physical perfection demanded renders it somewhat difficult to obtain suitable material.The properties of value in Iceland spar are its transparency combined with double refraction. It is used in the manufacture of polarizing microscopes, saccharimeters, colorimeters and photometers. Its most important use is in the manufacture of Nicol prisms, which constitute an essential part of every polarizing microscope. The principle governing the construction of the Nicol prism is as follows:Ordinary light in passing through a crystal of calcite is resolved into two rays of plane polarized light vibrating in planes at right angles to each other and having different indices of refraction. Thus the two rays follow different paths through the crystal. The prism of Iceland spar is cut diagonally and cemented together again with a transparent cement having an index of refraction intermediate between the two rays passing through the prism. Canada balsam is employed for this purpose. The prism is cut at such an angle that the ray having the greatest index of refraction meets the surface of the balsam at an angle greater than the angle of total reflection, and it is thus deflected to the side of the prism, while the second ray passes through. Thus one of the rays is eliminated and polarized light vibrating in a single plane is obtained."

Apr 1, 1920

By L. J. E. Hofer

The Bureau of Mines determined rates of adsorption and desorption of methane as a function of particle size and temperature, using coals from the Pocahontas No.3 seam (lvb) from the Bishop mine of western Virginia, and the Pittsburgh seam (hvab) from the Pursglove No. 15 mine of northern West Virginia. For a given coal sample and temperature, the rate curves for adsorption and desorption are essentially the same when expressed on a fractional approach to equilibrium basis. The rates of adsorption and desorption increased eightfold as the particle size was decreased from 6-8 to 270-325 mesh per inch. The adsorption process appears to be diffusion controlled. Rate of sorption processes increased with increasing temperature; however, the amount adsorbed at equilibrium decreased.

Jan 1, 1966

Although the technology involved in removing material from below the earth's surface has a long history, communication systems in underground workings are relatively new to the industry. Communication equipment did not begin appearing in underground mines until the early 1900's. Figure 1-1 shows a miner using a Western Electric standard telephone set for underground mines in 1913. These early phones were essentially the same as those used aboveground, except that they were enclosed in cast-iron boxes as protection against moisture, acid fumes, and gases.

Jan 1, 1984

In 2007, a total of 4,639 stone mining operations reported employment to the Mine Safety and Health Administration (MSHA).1 Stone mines comprised 31.2% of all mining operations. ? Mines producing the primary commodity of limestone (crushed and broken) comprised the largest number of operations (n=2,051; 44.2%). ? Stone mining operations were located in all states and territories except Delaware and North Dakota. ? Pennsylvania had the most stone mines (n=373; 8.0%), followed by Texas (n=352; 7.6%).

Aug 1, 2009