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By Kambhampati C. Rao, Cecil Lue-Hing, Nabih P. Kelada, William B. Willborn

improvements in the analytical techniques for cyanide speciation can furnish useful information about the behavior of the different cyanide species in the receiving environment. This could be of help to the environmentally concerned public and the regulatory agencies in the assessment of cyanide limits for effluents, stream quality, and land disposal of cyanide bearing wastes. In addition the ability to distinguish the free cyanide and the weakly bound cyanide from the strong ULTRAVIOLET IRRADIATION UNIT (LAMP, COIU3' HOUSING) FIGURE 1 complexes, as well as transformation to thiocyanate is also needed by different industries, such as mining and metal finishing, etc., to evaluate the efficiency of several processes. Cyanide has been used for the recovery of gold since the late 19th century. Although cyanide leach solutions are mostly recovered and used again, a large quantity of cyanide bearing wastewater becomes unfit for use and has to be treated before it can be released into natural waterways.

Jan 1, 1992

By Bobby C. Carson

INTRODUCTION The National Park Service is entering the seventh year of monitoring caves for the presence of radon and radon daughter products. The purpose of this paper is to summarize the radiation monitoring program at Mammoth Cave National Park, and to present some of the results of this program. Mammoth Cave National Park completed five years of collecting data on May 1, 1981: although Mammoth Cave encompasses approximately 361 km of underground passageways, this paper will concentrate on only a 2.2 km section of the cave known as the Historic Tour. Included in this paper is a discussion of the methods the Nations Park Service uses to protect employees from exposure to alpha radiation. MONITORING METHODS The National Park Service monitors cave atmospheres utilizing the procedures provided by the Mine Safety and Health Administration in their Radiation Monitoring Training Manual (Anon., 1976). This procedure is described as the Kusnetz Method (Kusnetz, 1956) of radon daughter monitoring. Due to the length of the tours at Mammoth Cave, it has been determined to be the most practical procedure. The Historic Tour is a 2.2 km (1.4 mile) loop through passageways ranging in size from 18 m high by 12 m wide, to 0.9 m high by 0.6 m wide. Seven five minute walking samples were taken for this cave tour by drawing at least 10 1 of air through a 25 mm fiberglass filter utilizing a Monitaire Sampler Pump. The radon daughter concentration levels were determined using an alpha scintillation counter to measure the alpha activity on the filter paper. The Monitaire Sampler Pump was calibrated each day prior to monitoring the cave tour and the scintillation counter was calibrated by procedures described by the Mine Safety and Health Administration (Beckman, 1975) at six month intervals. Guidelines established by the National Park Service and approved by the Mine Safety and Health Administration require weekly sampling when the average working level exceeds 0.30 (NPS-14, 1980). A working level is an atmospheric concentration of radon (Rn-222) daughters which will deliver 1.3 x 10 5 MeV of alpha energy per liter of air in decaying through Ra C' (Po-214). The Historic Tour has continually exceeded the 0.30 working level average and has been monitored weekly. Generally, only radon daughter working level data has been collected on the Historic Tour due to limited personnel. However, other special measurements of the uncombined fractions of radon daughters with wire screens, tsivoglou method for radon daughter sampling (Thomas modification, 1970), and thoron daughter monitoring. These special measurements have not been routine due to time limitations involved in radon daughter sampling of other occupied portions of the cave. SUMMARY OF DATA The Historic Tour has been the most consistantly monitored tour since elevated levels of alpha radiation were found to exist at Mammoth. Cave. It is also the only natural entrance to the main sections of the cave and provided an opportunity to study man made actions upon the natural entrance. For these reasons the Historic Tour was isolated for study. Beginning October 10, 1977, and ending November 20, 1977, a pilot project was undertaken involving the Historic Tour and the practice of covering the natural entrance to this tour with sheet metal in the winter months. The purpose was to study radiation levels on the Historice Tour while the covers were on and off the natural entrance. In this pilot project, comparisons were made with incast air with covers on and off the entrance, and outcast air with covers on and off the entrance. TABLE 1 Incast air Mean W.L. Covers on . . . . 1.46 W.L. Increased 54% Covers off. . . . 0.67 W.L. when covers on Outcast air Mean W.L. Covers on . . . . 1.33 W.L. Decreased 5% Covers off. . . . 1.40 W.L. when covers on The natural entrance was artificially covered in the winter months (Yarborough, 1978) to protect the visitor from the extremely cold incast air, in the first four years of monitoring. The data in Table 1, illustrated in Figures 1 and 2, shows that this action increased the radon daughter working levels on the Historic Tour by 54% when the covers were on the entrance and the airflow was incast. While the air flow was outcast at the natural entrance, it made little difference as to whether the entrance was closed or open. Some interesting findings were observed when

Jan 1, 1981

By Peniti Niskanen

Outokumpu metals & Resources (OMR) is a sub-group of Outokumpu Oy. OMR is a Mining and Metallurgy group of about 75 companies in 16 countries. The main activities are exploration, mine development and, mining and metallurgical processing of base metals.

Jan 1, 1996

By Pascale St-Germain, Michael Li, Lionel J. J. Catalan

The oxygen flux into water-covered reactive sulphidic tailings is required for evaluating the long-term performance and predicting the quality of engineered shallow water covers. This information can also serve as an input to the design of water covers for reactive tailings decommissioning. This paper describes some dissolved oxygen (DO) profiles recently measured in the field across the tailings/water interface and oxygen fluxes derived from these profiles. These fluxes are compared with previously reported flux values from similar field measurements. Techniques and pitfalls for measuring DO profiles and calculating oxygen fluxes are also discussed.

Jan 1, 2000

By Larry Lynott

This paper summarizes the benefits ofusing an in-situ analyzer in a sampling and valuation program. The tests and studies cited quantify the problems associated with current conventional sampling techniques and contrast conventionally-obtained results with those obtained through in-situ analysis. Data are presented to show the improved precision in valuation resulting from the in-situ method. Greater precision in estimating the mineral content of unmined ground becomes increasingly important as mines strive for optimum exploitation of their deposits. As the following analysis shows, the variable distribution of minerals within a deposit, along with the difficulty and the cost of high density sampling limits the precision which is currently possible in practice. An inherent problem exists in the conventional method of sampling. The erratic values of ore grade necessitate the collection oflarge numbers of samples for statistically accurate valuation and ore reserve estimation. Owing to the cost of manpower, current sampling techniques do not allow for the collection of sufficiently large numbers of samples. The most common method of sampFng in current practice is chip sampling, although bulk sampling is sometimes used. The intent of sampling is to obtain an estimate of the value of blocks of ground prior to mining. This information is used to plan the rate and sequence of mining, yet the sampling intervals which are possible in practice cause these block estimations to be ubject to considerable uncertainty. This inevitably leads to mcorrect mining decisions which may be vy costly.

Jan 1, 1998

By A. D. Agate

In developing nations, novel mineral processing methods like bacterial leaching are gaining prominence. The principles and practices for isolation and preservation of cultures used in bacterial leaching are discussed with special reference to cultures used in leaching copper from Indian ores. In all, 145 potentially useful microorganisms such as iron- and sulfur-oxidizing bacteria were isolated from various ecosystems of the copper mining areas in the country. The major organisms isolated by enrichment culture technique belonged to T. ferrooxidans and T. thiooxidans species. In addition, thermophilic cultures like Sulfolobus sp. and thermophilic thiobacilli were also isolated. The process of copper leaching was scaled up to the 300-kg level in PVC columns. Since the preservation of efficient cultures in active state was vitally important, a new method was devised that preserved the activity of thiobacilli for a period of more than two years. The novel method of storage in sterile chalcopyrite ore at 8°C can be considered an important advance.

Jan 1, 1987

By K. Deaton

"INTRODUCTION A packaged cooling system is being developed for refuge alternatives (RAs) that meets MSHA qualification guidelines for deployment in coal mines. This system will allow full occupancy ratings of deployed Refuge Alternatives (RAs) to be maintained by keeping the apparent temperature inside the RA from exceeding 95°F. Research investigations sponsored by NIOSH have shown that heat buildup caused by occupants in mobile RAs will result in apparent temperatures that exceed the 95°F limit established in 30 CFR 7.504. Figure 1 shows the temperature rise in an inflatable RA having an occupancy rating of 23 people at an 81°F mine air temperature. This plot shows the need for either heat mitigation or occupancy derating in warmer mines. The RAECS will be designed to provide enough heat mitigation to eliminate occupancy derating due to heat buildup over the 96 hour refuge period.This paper describes testing of a prototype cooling system that uses proven vapor compression technology powered by batteries to keep the RA interior below the 95° limit for a minimum of 96 hours. Testing of this prototype cooling system was conducted in December of 2015 and January of 2016 at the NIOSH test mine in Bruceton, PA. December testing was conducted at the prevailing mine ambient temperature – approximately 60°F. The January testing was done with the mine ambient temperature in the immediate vicinity of the RA artificially elevated to 85°F. Realistic heat gain from RA occupants was provided by human simulators developed by NIOSH. These simulators add sensible heat corresponding to human metabolic processes and latent heat generated by respiration and perspiration. Heat generated by CO2 scrubbers was also added. Results of cooling system performance using these simulated loads at the two ambient conditions are described. A comparison of the apparent temperature in the RA using two different control techniques is also presented. This work documents the ability of the cooling system to meet the established apparent temperature limit at the full occupancy rating of a six person RA. A new cooling system intended for use with existing RA deployments and having greater cooling capacity is currently in development and will be described."

Jan 1, 2017

By Andrzej M. Wala

The determination of the air quality needs to dilute diesel exhaust gases to a safe level must be individually evaluated for particular cases. One such case is when diesel-powered vehicles are working in long dead- end headings with forcing auxiliary ventilation. The vehicles perform specific operations in a cyclic order required by the technical process. The dynamics of this process in certain conditions has a vital influence on environmental conditions in the working area and in the rest of the heading. Recent studies on diesel gas behavior in long headings have shown a zone of increased concentration of pollutants (accumulation) between the face and the mouth of the heading. To be able to control these accumulations of pollutants, use of the concept of planned air discharge by using the Coanda-type ducts is proposed. The main objective of this paper is to demonstrate an application of computer simulation of that process. It is shown that, by planning the additional air discharge, the concentration of diesel gases can meet required limits along the heading.

Jan 1, 1987

By S. P. Liebenberg

During the past fifteen years significant progress has been made on carbon-in-pulp (CIP) technology for the extraction of gold. While most research on the mechanisms and kinetics of CIP sub-processes has focused on the adsorption step only, auxiliary unit operations such as elution have received less attention. The mathematical models which have been developed for elution at the University of Stellenbosch can be used for design as well as process optimisation by incorporation into an overall CIP simulation program. Except for these models, no other comprehensive models for the complex elution process are available. It is the aim of this paper to review recent modelling work on competitive elution from activated carbon.

Jan 1, 1995

By A. E. Hall

The authors are to be commended for their attempt to provide a convenient piece of software for preliminary drum hoist specification. This field has received little attention in recent years and is eminently suited to calculation by computer. Unfortunately, there appears to be an error in the calculation of the required rope diameter. The 66-mm (2 5/8-in.) rope selected is oversized for this application. Wire rope weight and breaking strength are related to the rope diameter. For a round strand rope

Jan 1, 1988

By Zhongxue Li, Baolu Zhou, Yiqing Zhao

"Rare earth elements (REEs) are a kind of new materials which have excellent optical, electrical and magnetic properties, and they play an important role in the development of high technology and green energy industries. With abundant reserves and a wide range of REE type, rare earth industry has a rapid development in China in recent years. However, environmental issues associated with REE exploitation have severely restricted the sustainable development of rare earth industry in China. At present, literatures on the externalities of REE exploitation are very limited, especially in China. This paper builds an evaluation model based on life cycle evaluation to estimate the external costs of REE exploitation at Bayan Obo. The results show that the external costs for producing one metric tonne of rare earth oxides (REO) in Bayan Obo was CNY 34739 in 2013, the external costs of waste gas, waste water, radioactive substance, REE resource depletion, and land occupation are CNY 14945, 12515, 1400, 3199, and 2680, respectively. Waste gas and water constitute about 79% of the total external costs. The internalization of the external costs would reduce the financial profit of Northern Rare Earth (Group) by 18%. This study has taken into account only those externalities whose market values can be estimated, and therefore the external costs of REE exploitation in Bayan Obo is likely to be underestimated. The results fill the gap in literature and provide further understanding on the external cost of REE exploitation.Introduction / Background Along with increasing concern about environmental pollution problems caused by the usage of fossil fuel and the shortage of fossil energy, a transition has occurred where development has moved toward green and renewable energy sources with less pollutant emissions (Stegen 2015). Rare earth elements (REE) are a group of important raw materials for these trends since they have unique magnetic, electronic and optical properties, and thus make them widely used in making high-performance magnets and energy saving lamps (U.S. DOE 2010). In addition, REE are crucial for manufacturing of widespread high-tech applications in medical, defense and electronic industries. Many countries have made medium-term and long-term plans for the development of their REE industries, and the annual growth rate of global REE demand is expected to increase by 6% by 2020, and reach about 170,000 metric tons of rare earth oxides (REO) by 2020 (Rollat et al 2016)."

Jan 1, 2017

By Petr Salak, Adrian St. John, Angelos Gakis

"INTRODUCTIONCrossrail will provide London and the South East of England with a world class, high-capacity railway to ease congestion on London’s public transport system and enable better access between business, residential and entertainment districts. At the heart of this £14.8bn scheme lies Farringdon Station, which will form a major interchange between Crossrail, Thameslink and London Underground. The £400m Farringdon Crossrail station was awarded to a joint venture of BAM Ferrovial Kier (BFK) in 2011, and comprises two ticket halls, two platform tunnels and a multitude of connecting tunnels all constructed using open face sprayed concrete linings (SCL). BFK appointed Dr. Sauer & Partners (DSP) as their specialist SCL designer. As the main contractor for both C300/C410, the Western Running Tunnels and Station Caverns, and also for C435 Farringdon Station, BFK were in a unique position to develop strategies to reduce cost, time and risk for the Client. One such innovation involved the continuation of the TBM drives for the running tunnels right through the length of the new Farringdon platform caverns. This created large diameter precast concrete pilot tunnels for the subsequent platform enlargement using SCL. The benefits of such an approach are described in detail by St.John et al 2015. BFK also introduced another alternative strategy to reduce cost, time and risk, by proposing to abandon the TBMs in the ground (“Turn & Bury”) permanently rather than recovering them through the ticket hall shafts. This de-risked the programme, enabling critical ticket hall construction to proceed unhindered. However, one consequence of this revised strategy was an area of increased underground congestion, with two SCL tunnels (RTE2 and ES2) and a bored tunnel (complete with abandoned TBM) in close proximity to a ticket hall excavation (see Figure 1) and a sensitive, listed railway structure. Faced with this complex geometry, and combined with challenging geotechnical conditions (Gakis et al 2015), the team chose to install enhanced monitoring to study the behavior of tunnel RTE2 and provide additional assurance that the tunnels were performing as predicted. Applying advanced 3D numerical modelling and taking into account the residual tensile strength of the SCL helped avoid unnecessary reinforcement installation in primary lining and/or early installation of a secondary lining in RTE2 prior to ES2 construction."

Jan 1, 2016

By M. D. Attfield

During 1992 a number of papers were published on aspects of respiratory disease in US underground coal miners. These included reports on trends in prevalence of coal workers' pneumoconiosis, the risks of developing coal workers' pneumoconiosis in relation to dust exposure, and the relationship between lung disease other than pneumoconiosis and dust exposure. The intent of this paper is to provide a summary of the essential findings from these investigations. PREVALENCE AND INCIDENCE OF COAL WORKERS' PNEUMOCONIOSIS Coal workers' pneumoconiosis (CWP) is usually detected in living miners through use of the chest x-ray. Deposits of dust in the lung, and the fibrotic tissue reactions to the dust, are manifested on the x-ray as small and large opacities. These abnormalities are quantified into degrees of severity using a standardized classification scheme (the International Classification of Radiographs of the Pneumoconioses of the International Labour Office). For small opacities, the scheme provides for a four-point scale of abnormality (0, 1, 2, 3), reflecting increasing profusion of the opacities on the x-ray. In this report, category 1 or greater small rounded opacities (CWP 1+) represents the earlier radiographic stages of pneumoconiosis. Large opacities, indicate the later and often disabling stage of pneumoconiosis, usually referred to as progressive massive fibrosis (PMF). Information collected in a national surveillance program for underground coal miners (the Coalworkers' X-ray Surveillance Program (CWXSP)) and a large epidemiologic study (National Study of Coalworkers' Pneumoconiosis (NSCWP)) provide a means to assess trends in CWP prevalence over the years following the reduction in dust levels mandated by the 1969 Federal Coal Mine Health and Safety Act (FCMHSA). These programs are operated by the National Institute for Occupational Safety and Health (NIOSH), and are described in detail in Attfield and Althouse (1992) and Attfield and Castellan (1992). Both studies were divided administratively into distinct time periods, and the results shown here reflect that division. Figure 1 shows the prevalence of CWP 1+ as determined from data from the CWXSP, plotted by time period and years in mining. There is evidence of a temporal reduction in prevalence. (The lack of an obvious decline in the early 1970s may be an artifact arising from use of different versions of the standard classification.) Figure 2 provides information in the same format for PMF, and shows a similar trend [ ]

Jan 1, 1993

By Charles S. Robinson

The Henderson ore body is east of the Continental Divide in the Front Range of the Colorado Rocky Mountains about 50 miles west of Denver. The ore body is being developed for mining by workings that extend more than 3500 feet below the topographic surface. During construction of the mine workings, ground water in fractures in crystalline rocks has been encountered. From 1969 to 1973, Charles S. Robinson & Associates, Inc., in cooperation with the engineering and geologic staffs of the Climax Molybdenum Company, a division of Amax Inc., studied the ground water geology of the Henderson mine development area. Detailed geologic records of the Henderson mine were available as a result of the exploration, evaluation and development of the mine. Records of the flow, chemical composition and temperature of the ground water at and near the surface, from the entire mine, from portions of the mine, and from exploration holes drilled in the mine, were kept as the mine was developed. Where possible, ground water pressures in drill holes and changes in pressure with time, were recorded. The geologic, hydrologic and chemical data were correlated. The following conclusions were drawn from the correlations: The ground water in the Henderson mine occurs in fractures in Precambrian igneous and metasedimentary rocks and in a series of Tertiary intrusive rocks. Two zones of ground water were recognized; an active zone, in which the fracture systems are recharged and discharged annually into the surface water system, and a passive zone, in which the fractures were filled with water in the geologic past. Discharge from the passive zone is through mine workings that intersect the fracture systems. Discharge from a fracture or fracture system is initially high but decreased with tire!. The rate of decrease in flow (or pressure) is exponential. By measuring the change in flow with time, it is possible to calculate the amount of flow at some given period of time in the future. Based on changes in rate of flow and pressure, and the geology, and assuming rates of mining of the ore, it will be possible to predict the volumes of water that will have to be handled during the life of the mine and the area around the mine that will be drained by the mining operation.

Jan 1, 1976

By H. Wen, X. Zhai

"The Jurassic coal fields which lay in west China are the major energy base and contain half of coal resources in China. Due to the gather and degeneration rules, the spontaneous combustion characteristic of Jurassic coal is distinguished with permo-carboniferous coal, which needs to be studied deeply. Programmed heating experiments of five Jurassic coal samples and three permo-carboniferous coal samples from different primal coal fields in West China were conducted to identify the characteristic parameters in the low temperature stage of oxidation and spontaneous combustion. The experiments were carried out under non-isothermal heating conditions up to 180? at the heating rate of 0.33?/min in an air atmosphere. The result showed that oxygen consumption rate, CO gas production rate and heating intensity of all coal samples increased with the rising of the temperature, which of the Jurassic coal was higher than that of Permian-carboniferous coal. The C2H4 gas of Jurassic coal generated earlier, more than that of Permian-carboniferous coal in the process of oxidation and spontaneous combustion. It indicated that the Jurassic coal was easier to be oxidized and spontaneous combustion and the index parameters of spontaneous combustion were different between the Jurassic coal and permo-carboniferous coal.INTRODUCTION Coal was the foundation of industry development, and occupied 70% of primary energy production and consumption structure in China. According to the data of the 3rd coalfield prediction, 39.6% of the total coal resources were located in northwest Jurassic coal field in China [1], where the quality of coal was excellent. The study of northwest Jurassic coal already dated from the 80s of the 20th century, about coal rock composition, coal metamorphism [2], coal-derived hydrocarbons, coal structure [3], etc. The results of these studies showed that the composition and properties of Jurassic coal was obviously different from Permian-carboniferous coal, as well as the characteristic of spontaneous combustion [4]. As a result, the spontaneous combustion characteristic of Jurassic coal particularly needed to be studied. Now more and more methods could be conducted to test the characteristics of coal spontaneous combustion, for example, thermal analysis technology [5-7], programmed heating experiment [8-10] and coal spontaneous combustion experiment [11,12]. In these methods, programmed heating experiment could be conducted to determine the oxygen consumption rate, CO gas production rate and heating intensity quickly."

Jan 1, 2015

By J. E. Gebhardt, H. Toro, K. Y. Lee

Industrial-scale test results indicate superior metallurgical performance of column flotation compared to conventional cell flotation for copper cleaning. A technical comparison of bubble generation systems for column flotation is made. Two types of bubble generation systems are considered: the filter-cloth type spargers and the Turbo-Air® sparger, which utilizes an air-water mixture fed to the column through injection tubes. Examples of the improved technical performance available with an external sparger system are presented using data from plant tests conducted for specific applications with several different mineral ores. INTRODUCTION Column flotation is now a valuable unit operation which mineral processing engineers employ in the design and operation of flotation circuits in nearly all mineral applications. The acceptance of columns in the mid- 1980s by the minerals industry was paralleled by a rigorous approach to developing a scientific understanding of the design, scale- up, and operation of column flotation units (Finch and Dobby, 1990). Since then, column flotation has become a standard unit of the cleaning stage in many new mineral concentrator projects and has replaced older mechanical cells to improve process efficiency. The size of column cells has continued to grow from the initial 0.9- to 2.1 -meter diameter range, and it is not uncommon to find column cells today being 2.7- to 3.6-meters in diameter. With the success of the smaller units, the scale-up to larger cells has been proven and demonstrated by the performance of the large-diameter cells (Murdock and Wyslouzil. 1991). The use of columns in flotation circuits has also been accompanied by developments in modelling. control, and optimization of column performance (Lee et al, 1991). The bubble generation system is the heart of the operation of column flotation cells. The most common methods for generating bubbles can be divided into two types: the internal and external spargers. Internal spargers are typically a porous material, such as sintered glass, porous rubber or filter-cloth, or maybe a single- or multi-nozzle sparger. External spargers implies that a gas and a liquid (either water or slurry) are brought into contact outside the column and that mixture is then introduced into the column. Several types of external spargers are available today, and innovative designs for externally mounted air sparging systems have been a significant factor in the successful application of columns. Early types of bubble generation systems.

Jan 1, 1993

By Ted H. Eyde

The Bowie chabazite deposit has yielded the most mined tonnage of any natural zeolite deposit in the United States. Since 1962 the deposit has yielded about 12,000 tons of crude chabazite, with an estimated market value of S30 million when sold as an activated molecular -sieve product. Between 1,000 and 1,500 tons of high-purity crude lump chabazite is now produced annually by stripping and selectively mining the lower, massive, half-foot-thick, "high-grade" bed. All of the chabazite is still shipped out of State for grinding prior to extrusion and activation. Zeolite minerals were discovered at the Bowie deposit in 1875, when Oscar Lowe identified a hydrous silicate related to chabazite or stilbite from a tuff bed that cropped out in the San Simon Valley. It was not until 1959, however, that chabzite, erionite, and clinoptilolite were positively identified as the principal constituents of an altered vitric-tuff horizon that crops out in the area originally described by Lowe. Shortly after the rediscovery of zeolite minerals in the San Simon Valley, several of the major producers of synthetic zeolites acquired land positions covering the outcrops, including projected extensions, and began exploration drilling. By 1980 all of the known chabazite reserves had been acquired by five companies and two individuals. The more than 3,000 holes drilled to explore the deposit and the excellent exposures provided by the strip-mined areas indicate that the chabazite-bearing horizon (known as the marker tuff) is confined to a flat-lying lacustrine section known to the operators as the Green Lake Beds. The deposition of the parent airborne vitric ash and subsequent zeolitic alteration was controlled by many factors, including the lake-bottom topography, depth and cation content of the saline-alkaline lake water, and proximity to post-depositional erosion surfaces. Zeolitic alteration was complete when an extensive system of younger paleochannels deeply eroded the Green Lake Beds. This left only a few erosional remnants of the marker tuff and the lower "high-grade-bed" that constitute the present deposit. Both the channel gravels and the Green Lake Beds are overlain by a section of halite-bearing brown mud-stones, known as the Brown Lake Beds. The bowie chabazite deposit can be used as a model to guide the exploration and development of other zeolite deposits that formed in saline-alkaline lacustrine environments.

Jan 1, 1987

By E. D. Gálvez, L. A. Cisternas, A. López-Valdivieso, F. Lucay

"The floatability of molybdenite fines in saline solutions was investigated through microflotation studies using a modified Hallimond tube. In addition, the effect of pH and gypsum precipitation from calcium ions (Ca2+) and sulfate ions (SO4 2-) ions in saline water on the recovery of the molybdenite was analyzed. It was found that the floatability of molybdenite fines significantly increased with the ionic strength of the saline solutions and is independent of pH above 0.5 mol/L ionic strength. The high floatability of molybdenite in saline solutions is explained as being due to the low electrostatic repulsion between bubbles and the edges of molybdenite particles, which is exceeded by interactions due to van der Waals and hydrophobic forces. The precipitation of Ca2+ and SO4 2- ions as gypsum had a detrimental effect on the natural floatability of molybdenite because of gypsum crystal attachment on the faces of the molybdenite particles. This precipitation phenomenon may be initiated in copper–molybdenite flotation circuits that use recycled saline water, like seawater containing Ca2+ and SO4 2- ions.IntroductionWater availability is a significant factor in mining projects. Water, particularly fresh water from rivers and underground water, is becoming a scarce resource for mining operations and new projects. Under these circumstances, the use of water with high concentration of salts in flotation plants is becoming increasingly important (Cisternas and Moreno, 2014). The use of seawater has been studied as a sustainable solution for many mining companies in dry areas located near the sea. Notably, using seawater in mining operations is how mining companies in Chile have coped with the problem of water resources (Cisternas and Gálvez, 2014). In 1930, small plants in Chile used seawater to float chalcopyrite from high-copper-grade ores. In 1975, the results of tests in pilot plants for the flotation of copper minerals with seawater were reported. It was found that froth formation in seawater at pH 9.5 was suitable to make the rougher circuit work properly, even without frothers. The Cenizas mining group successfully floated chalcocite, bornite and chalcopyrite in the Las Luces plant in Taltal in Chile using seawater (Moreno et al., 2011). Minera Centinela (Antofagasta Minerals S.A. Chile) is currently processing porphyry copper ores using a seawater mixture consisting of 20 percent fresh seawater and 80 percent recycled water. Lower consumption of flotation reagents was reported in both seawater and salt water. In addition, studies performed with synthetic seawater showed that certain frothers increase the froth volume, whereas others decrease it. Additionally, the froth produced with seawater carries a high amount of gangue, and low-quality concentrates are obtained, requiring more cleaning stages."

Jan 1, 2015

By Z. Kowalski

In the defunct Gorka quarry, there are situated both a waste disposal site of an area of 6.7 ha and containing approximately 1 million ton of high aluminium wastes and a pond of an area of roughly 3 ha, up to 15 m deep, with about 400000 m3 of polluted water. The reservoir is fed with the filtrates arriving from the disposal site mentioned, at a rate ~130 m3/day. An alarming phenomenon is the subsidence of the pond bottom and the infiltration of solutions into the Triassic and Jurassic water resources, assessed at ~40 m3/ day. The basic problem related to the effluents in the Gorka pond is their high alkalinity (pH 12-13.4) and variable pollutants whose level increases appreciably with the pond?s depth. The solution offered provides pumping out and treatment of about 500000m3 of effluents retained in the Gorka reservoir in an about yearly time. Effluents would be treated in a reverse osmosis plant, according to a process so far verified on a quarter-commercial scale. The treatment process by-product would be discharged into the Ropa stream. The brine solution (containing about 25% NaCl), whose amount may reach up to100000m3, might be supplied to the Debiensko Mine which produces technological salt from salt-bearing mine waters. Similarly, there would be provided an intake of underflows of infiltrates (by means of deep wells, and possibly girdling ditches) arriving from the high aluminum site, and such effluents would be subject to ongoing dilution in water courses. It would be possible to test the system of underflows reaching the Gorka reservoir by means of geochemical identification, previously performed. The next stage following the pumping, would be the utilization of approx. 50 000m3 of bottom slurry. Highly alkaline slurries would be utilized in the production of self-solidifying mixtures. Slurries would be pumped out and temporarily dumped on drying beds, located nearby the Gorka reservoir, and later on used successively for making self-solidifying mixtures in a plant similar to a concrete making seat. Those mixtures would be applied for sealing the bottom of the Gorka reservoir and the necessary part of the edges of the defunct quarry. An alternative solution is the utilization of slurries in the facilities of the Trzebionka Mining Works and the application of self-solidifying mixtures, made in the Trzebionka Works, for sealing the reservoir bottom.

Jan 1, 2006

By David R. Quigley, Patrick R. Dugan

First reports of microbial coal solubilization appeared in the early 1980's (Fakoussa, 1981; Fakoussa and Truper, 1983; Cohen and Gabriele, 1982). These degradations, which occurred at ambient temperature and pressure, resulted in a dark brown to black viscous liquid and required days to weeks to occur. Rates and degrees of coal biodegradation varied from coal to coal. Hard coals were not extensively degraded (5-7%) while low-rank coals such as Leonardite, a sublignite, were completely solubilized. A correlation between degree of weathering or oxidation of coal and the coals susceptibility to biological attack was observed. This led to oxidative pretreatments as a method to enhance microbial degradation of coal (Strandberg and Lewis, 1986). Products of microbial degradation of coal are water soluble solids that do not have significant solubilities in organic solvents (Wilson, et. al., 1987; Quigley, et. al., 1987; Quigley, et. al., 1988a). Solutions of solubilized coal did not separate or form precipitates which suggested that they were true solutions and not colloidal suspensions. Biosolubilized coal contained more oxygen than starting material suggesting that microbial attack of coals involved oxidative cleavage of carbon-carbon bonds. This small change in oxygen content was the only change observed in coal structure during the biosolubilization process. Many coal solubilizing microorganisms have been isolated. Some are lignin degrading organisms such as Phanerochaete chrysosporium and various Streptomyces species (Gupta, et. al., 1988; Wilson, et. al., 1987). This was not unexpected since the structures of lignin and low-rank coals are similar. These organisms produce an enzyme complex, ligninase, that utilizes hydrogen peroxide to oxidatively cleave the bond between a and ß carbons of an aliphatic chain bound to an aromatic nucleus. Another important organism is Trametes versacolor (syn. Coriolus versacolor, Polyporus versacolor). Even though this organism produces a ligninase (Dodson, et.al., 1987), coal solubilization has been attributed to the enzyme laccase (Pyne, et. al., 1987). Laccase utilizes molecular oxygen to oxidatively cleave a - ß bonds using a mechanism similar to that observed for ligninases (Kawai, et. al., 1988). Other coal solubilizing microorganisms have been isolated from coal outcrops (Ward, 1985; Ward, 1988), but enzyme activities responsible for coal solubilization have not been identified. Research at the Idaho National Engineering Laboratory has focused on those mechanisms involved in coal biosolubilization. An

Jan 1, 1989