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By K. Hanumantha Rao, K. S. E. Forssberg, A. Vidyadhar

Using pure albite and quartz minerals, the separation of albite from quartz using mixed cationic/anionic reagent schemes is assessed through Hallimond flotation, zeta potential and diffuse reflectance FTIR studies. The reagent schemes are tested in bench-scale flotation for the separation of albite from Greek Stefania feldspar ore. The single mineral flotation tests showed the feasibility of selective albite flotation from quartz at around pH 2 using a mixture of cationic diamine and anionic sulfonate collectors or a combined cationic-anionic collector of diamine-dioleate. In contrast to the selective flotation response of albite at pH 2, where albite is slightly negatively charged and quartz possess zero charge, the zeta potential and FTIR studies elucidate similar adsorption behavior of mixed collectors on both of the minerals. The infrared spectra not only showed the co-adsorption of anionic sulfonate or oleate with diamine on the surface but also showed that the diamine adsorption increases with the presence of anionic collector. The intrusion of anionic collector in between adjacent surface alkyl ammonium ions decreases electrostatic head-head repulsion, thereby increasing the diamine adsorption by increasing the hydrophobic tail-tail bonds. The discrepancy in the flotation and adsorption results at pH 2 is attributed to the coarse and fine size particles employed in these studies, respectively. The comparable adsorption on fine particles of albite and quartz at pH 2 is explained by the interaction of ammonium ions on silanol groups by hydrogen bonding besides electrostatic interactions. The bench-scale flotation results indeed showed that selective albite flotation takes place only after desliming the feed material. An albite concentrate exceeding 10% (by weight) Na20 is produced from a material containing about 6.5% (by weight) Na20, where an albite product of more than 9% (by weight) Na20 is considered to be valuable. Key words: Flotation, Adsorption, Zeta-potential, FTIR

Jan 1, 2003

By Jean-Pierre Nossereau, Allen J. Hulshizer

The main thrust of this paper covers the design, installation techniques and experience associated with the installation of eleven 1.5 m (4'-11") and three 2.87 m (9'-5") diameter shafts in 15 to 23 meters (50 to 75 ft) of water over 1.6 Km (a mile) out in the Atlantic Ocean. The approach implemented, permits the use of pre-fabricated shaft linings and incorporates a safe dry-tap method for connecting the offshore shafts to tunnels driven blind from deep land shafts over 4.8 Km (3 miles) away. This tunnel-shaft system is a unique venture employed at the Seabrook Nuclear Power Station to meet plant cooling water requirements.

Jan 1, 1981

By L. K. Lepley

A marine sonic sub-bottom profiling system and a hovercraft were used in an engineering geophysics survey of the tailings being deposited at the Mercur gold mine. Detailed density sections with vertical resolution of one meter were desired for computations of strength, permeability and potential self-compaction. The logistical problems of conducting a geophysical survey and in collection of geotechnical soil samples from an active tailing impoundment was solved by using the amphibious hovercraft for towing and transport on the impoundment. The "chirp" sonic system produced continuous, real-time geophysical cross-sections with vertical resolution of ten centimeters showing possible trapped gas. The hovercraft provided a platform over water, ice, slurry, and solid beach for collection of geotechnical information and physical samples.

Jan 1, 1994

By Claus Becker

Waterbearing, cohesive or non-cohesive grounds with glacial stone deposits are found very often in Europe. The problem consists of destroying the boulders and supporting the face simultaneously. At the example Grauholztunnel Bern ( outer diameter 11,60 m ) the theoretical attempt of solutions for the big machines is described: destroying of the boulders with roller discs, hydraulical support of the front. The problem of coming out of stones of a certain size from the surrounding matrix will be discussed. Further diminishing to the size that can be handled by pumps is executed by a crusher, situated in the center of the machine. At the same example the theoretical attempt for headings in cohesive soil with stone deposits are shown. Surface structure of the cutting wheel and working chamber as well as controllable current movements are the solution here. The danger of clogging discs and stone crusher has to be encountered by right positioning of the tools and jetting nozzles. At the example Sewer MoosstraBe Salzburg the same problems are discussed for the Mikro-Tunnels. The pipe-jacked sewer lines have outer diameters from 485 and 805 mm. With this method, the stones have to be holed through. The wear of the cutting tools determines the [ ]

Jan 1, 1989

By R. V. Ramani, S. Skankar

Available literature on the effect of re-entrainment on overall airborne dust concentration in mine airways or the fundamental mechanisms of coal dust re-entrainment in mine atmosphere is scant (Shankar and Ramani, 1991). Therefore, as part of the Respirable Dust Center's ongoing research, the following three-part study was undertaken: •a study of the re-entrainment phenomena of anthracite and bituminous coal dust particles in a wind tunnel under the influence of varying air velocities; •a study of the same in the Lake Lynn Laboratory Mine of the USBM with both air flow and walking by personnel causing re-entrainment; and •the mathematical modeling and computer simulation of the re-entrainment phenomenon. In this paper, results from the re-entrainment studies in the wind tunnel and the Lake Lynn Laboratory mine are presented. Comparing the results from the two studies, it was observed that increasing the air velocity increased the rate of re-entrainment (Shankar and Ramani, 1994a) and the rate of re-entrainment decreased with the time of exposure of the source dust to the flowing air. In addition, when the source dust was composed of particles of different sizes, the airborne dust concentrations due to re-entrainment were higher than when the source dust was composed of particles of the same size. The contribution of airborne dust concentration due to airflow was negligible compared to the contribution due to walking.

Jan 1, 1996

By Allan E. Hall, Kuda R. Mutama

Jet fan (ductless fan) ventilation in underground mines and tunnels is a subject requiring further attention. At present there are no accepted procedures or guidelines for this type of ventilation. The main reason has been the absence of sufficient general data, which has hampered the development of rules. There is great potential for using jet fans in terms of both effectiveness and economics because they eliminate the need for ventilation tubing. In the present studies a procedure is described and results are presented from a jet fan modeled in a square section wind tunnel. The major purpose of the studies was to provide fundamental data on jet fan performance after it was realized that previous work had been limited and too site specific. The jet fan position in relation to the tunnel walls was varied in order to study the influence of confining walls on entrainment rates and the resulting aerodynamics. A clearer understanding of the fundamental principles of jet fan applications was obtained.

Jan 1, 1995

By W. R. Hopkins

Over 95 percent of the world's refined copper is now produced by electrolytic processes. The bulk of this electrolytic copper comes via the conventional route for sulfide ores of concentration, smelting and electro-refining. A rapidly increasing percentage of world production is now achieved using hydrometallurgical routes involving dissolution of the copper values from minerals, purification of the resultant leach solution by solvent extraction and finally deposition as cathodes by electrowinning. The technology can now be considered mature and this paper endeavors to summarize recent developments which, from the authors' perspectives, are important.

Jan 1, 1989

By Slobodan Vujic

Production of building materials such as are stones, sand, gravel etc., is characterized by a relatively low economic value and requires reasonable transport costs. That is why we are often faced, in our practical work, with the fact that within the framework of a relatively small area several open pits of building materials are, developed side by side while neither ecological, urban and spatial nor location factors have been taken into consideration. Numerous locations together with heterogeneous factors. point undoubtedly to the problem of planning the open pits locations for building mateials as a very serious and complex one. Even when certain localities are in question, it is rather a difficult task to present a real state and encompass all the, important location factors by mathematical model ling. This paper presents one of such models for solving the problem of selecting a location for building materials open pit.

Jan 1, 1992

By S. Chander

A comparison of gold, platinum and sulfide ion selective electrodes was made for determination of Eh in solutions containing hydrosulfide ions as a model system. The comparison was made in terms of the accuracy of the measured response, response time, pH dependence, and reproducibility of measurement. The sensitivity of each electrode towards changes in hydrosulfide ion concentration was measured in terms of the change in measured Eh per decade change in concentration. On the basis of a detailed investigation of the electrode processes occurring at the surface of gold and platinum electrodes, it was postulated that within the pH range investigated these electrodes respond to changes in the hydrosulfide ion concentration in solution. In comparison, the sulfide ion selective electrode is known to respond to changes in the sulfide ion activity in solution. Although the potentials measured with gold and platinum electrodes were mixed potentials, pretreatment procedures can be used to obtain a signal suitable for process control. For control of hydrosulfide ions in flotation pulps, the use of a gold electrode pretreated at 1.0 V with respect to a standard hydrogen electrode is recommended.

Jan 1, 1992

By Numan Elmas

This paper presents detailed information on the genesis, formation, and industrial utilization of Yaylacik magnesites. Tectonically, the study area is located within the Tavsanli Zone, immediately south of the Izmir-Ankara suture in western Turkey. The geologic setting mainly comprises ophiolitic melangks basics, and ultrabasics associated with very rich magnesite deposits and lacustrine sediments. The ophiolitic unit tectonically overlies the schists and carbonate rocks. The presence of glaucophane and lawsonite indicates a low-temperature/high-pressure metamorphism. The ultra- basic rocks, which exhibit cumulate composition, have been mostly serpentinised and represent the oceanic floor of the Yaylacik ophiolite. Basic intrusives consist of dolerite and diabase, and they show the characteristics of within-plate dolerites. The magnesite occurrences are commonly observed in block, stockwork, lens, and vein forms and were deposited within the serpentinites. In most magnesite samples, secondary quartz/chalcedony formations are observed as fracture fillings due to the highly effective tectonic movements. Field surveys and microscope studies reveal that magnesites had been formed by the metasomatic alteration of serpentinites. Chemical analyses show that, although MgO content of the magnesites varies from 43.41% to 50.48%, Fe203 and CaO are lower than 1%. Silica contents are as high as 5.52% in a few samples. Although Yaylacik magnesites are not suitable for making basic refractory bricks, they are widely used as caustic-calcined magnesite in a variety of applications, including animal food, artificial fertilizer, chemical (acid neutralizer), medical and pharmaceutical, and water treatment.

Jan 1, 1999

By W. Petruk, D. B. Sikka

Lithium-bearing lepidolites from three deposits in the province of Goias, Brazil, were investigated to determine whether there is a correlution between the lithium content of the mineral and the color of lepidolite and associated tourmaline. Such a correlation can be a useful guide to field geologists for outlining high-grade lithium ore zones. It was found that mauve-pink lepidolite associated with pink tour-maline, and brownish lepidolite associated with black tourmaline have high lithium contents, but that the color of lepidolite is not due to lithium. The pink color of lepidolite and tourmaline is likely due to Mn3+, and the brownish tint of lepidolite and black color of tourmaline to Fe3+. Lepidolites appear to be lithium- rich when the lepidolite and associated tourmaline contain relatively high amounts of Mn3+ and/or Fe3+.

Jan 1, 1988

By Dan G. Wasyluk, Meryl J. Klassen, Tony J. Morris, Clive H. MacKay

The Rogers Pass Project in British Columbia has involved the construction of two railway tunnels totalling 16.6 km and a 345 m deep shaft. Systematic geological mapping was carried out at four headings during construction. The paper discusses the procedures used to record the geology, structure, rock mass characteristics and excavation performance. Coded data from the geological mapping and shift inspector reports was entered into a computer data base. The rock mass quality was evaluated for both the Geomechanics and Q classification systems. Continuous computer generated graphic logs were produced showing the excavated perimeter map, geological parameters, installed support and construction activities. The tunnel logs were updated on daily basis and used during construction by project staff for evaluating support requirements and monitoring excavation progress. The specific requirements, difficulties and advantages in mapping tunnels using a computer based system are compared to those of a conventionally mapped tunnel excavation with hand drafted tunnel logs.

Jan 1, 1987

By R. A. Jankowski, R. Gong, R. Bhaskar

Full-scale laboratory studies were performed to evaluate the effect of passive barriers and spray airmovers on airflow patterns at a continuous miner face and in reducing underboom boilout and operator exposure to dust. Tasks included baseline data collection, smoke trace tests, detailed performance testing using tracer gas, and data analyses. Data collection was performed using a state-of -the-art gas analysis system and custom-developed software. The data were used to calculate operator exposure at various locations and to develop gas profile maps to analyze airflow patterns. The effects of the proposed underboom airflow modification devices on operator exposure and airflow patterns were examined. Based on the results obtained from the study, the base case condition, with no barriers, appears to result in the lowest operator exposure.

Jan 1, 1992

By Shailesh K. Patel, Shaaban Ben-Poorat

In order to ascertain the environmental fate of flotation reagents (fatty acids, fuel oils, and amines) associated with phosphate rock processing with confidence, it was necessary to first establish laboratory methodologies to identify and quantify flotation reagents. This approach was necessitated by the fact that the reagents used in the flotation process are either reclaimed or by-products of other industries and is dictated by their cost. Initially, several blind performance evaluation samples were prepared by spiking water samples with known amounts of either single reagents or reagent mixes and then analyzed. Reagent recovery for the blind performance evaluation samples was within acceptable limits for similar compounds established by the US Environmental Protection Agency. Averification process involving the use of standards and the refinement of analytical methods was utilized to develop standard operat- ing procedures (SOPS) and method detection limits (MDLs) specific to the identification and quantification of the flotation reagents used in the phosphate industry. These procedures and MDLs were critical to support the project's primary goal of assessing the fate of selected flotation reagents in the environment.

Jan 1, 1999

By E. Woodburn, R. P. King, R. Putman

Flotation plant simulation, a relatively recent methodology in mineral processing, is defined and corresponding uses are discussed. Typical simulation structures are compared. Current problem areas exist although these are not insurmountable. Following a brief state of the art discussion, the N. I. M. simulation program is reviewed. In general, digital plant simulation is expected to be of substantial benefit in the near future.

Jan 1, 1976

By V. C. Kelessidis

Demand for multifunctional drilling fluids continuously increases. In the quest for more hydrocarbons, drilling has extended to deep water areas (now in excess of 2.000 m) and to very deep wells (now in excess of 6.000 m). In these extreme conditions, low temperatures, as low as 1-5°C on the sea bed, high temperatures, in excess of 200°C, and high pressures, more than 1.000 bars, in the bottom of the well, are frequently encountered. In these harsh environments, synthetic oil and oil based drilling fluids are used, but the former are expensive while strict environmental requirements have limited the use of the latter. Thus, drilling industry has turned back to water based drilling fluids which use bentonite as primary viscosifier and as a fluid loss control additive. However, in conditions of high temperatures, bentonite suspensions gel and loose their exceptional low temperatures properties, thus, additives are needed to overcome such problems. In this article we review these challenging drilling environments and establish the requirements for the multifunctional drilling fluids. Our research indicates that demand for continuing use of bentonite by drilling fluid industry is strong. Furthermore, we bring forward the opportunities for new additive development which can expand the operational ranges of bentonite suspensions.

Jan 1, 2007

By Vi-Duong Dang

Lithium requirements in the next few decades for batteries and controlled thermonuclear fusion reactors (CTR) may exceed the availability of the current mineral and brine reserves. It is thus prudent to search for new reserves and resources to satisfy these and future lithium applications. The lithium content of the waters from the Smackover oil field. located in the Gulf Coast region of the United States, ranges from 100 to 500 mp/l and could represent a substantial new reserve. Experimental evidence described in the literature indicates that a specific chelating agent dipivaloylmethane (DPM), of the diketone type, has a specific selectivity toward lithium in the presence of other metal ions in aqueous solutions. Based in part on this unique property of dipivaloylmethane, a conceptual design of a full-size plant to extract lithium from the Smackover brine is presented in this paper. This study includes alternate flow-sheet development, design information on the major units of the process, energy requirements, and an economic analysis of a facility capable of producing 106 kg of lithium per year. The economics of three different process concepts depend primarily on the amount of water needing to be evaporated from the initial oil-field feed waters in concentrating the brine. The results, as a function of production rates, are indicated only in a general manner.

Jan 1, 1978

By Jay Jones, William D. Rech

The Henderson Mine developed a water treatment system in 1985 to meet the NPDES requirements for its mine water discharge. Unacceptable levels of Zinc and Manganese formed the basis for the design and operation of the treatment system. Since initial start up, this system has reliably removed metals from the mine water and facilitated low cost compliance with water standards. The potential addition of a bio- monitoring requirement to the NPDES Permit in 1990 has added a second dimension to the metals removal process. This paper will review the history of Henderson's success at developing a low capital treatment system for metals removal and the anticipated effects of bio-monitoring upon this system based upon preliminary bio-monitoring screening.

Jan 1, 1991

By Timms. Greg P., John W. Bennett

A field-based method for measuring the diffusive oxygen flux through covers placed on sulfidic waste rock dumps has been developed and applied at a number of mine sites. The technique provides a means of quantifying oxidation rates in dumps and can thus be used to assess the effectiveness of cover systems. Two instruments can be used. The first is portable and easy to set up, enabling a picture to be built up of the overall diffusive flux into a dump by making measurements at a sufficient number of locations. The second is installed beneath a cover and is preferred in situations where oxygen is consumed in the cover since it provides a direct measurement of the oxygen flux into the underlying waste rock.

Jan 1, 2000

By L. J. Altenburg

There are a lot of key factors involved in achieving a successful Safety Program. I would like to discuss some of these factors and how they have played a major part in our success at Jacobs Ranch Mine. The areas I will cover concern: 1) Facility Standards (Corporate/Minesite), 2) Communication (Employee/Management -"Teamwork"). 3) Proper Training (Employee/Management). 4) Employee Attitude. 5) Incentive Programs. 6) Health Programs. 7) Results/Benefits.

Jan 1, 1994