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By S. W. Asihene, K. Osseo-Asare

The leaching and solution treatment operations used in the ammoniacal treatment of laterites depend on the ability to establish and maintain close stability relations between soluble metal ammine complexes and solid phases such as oxides, hydroxides, basic carbonates, sulfides and ammonium double salts. This paper presents a quantitative treatment of heterogeneous equilibria in ammonia/laterite hydrometallurgical systems, by means of several.types of hydrometallurgical phasedia- grams (e.g., Eh-pH, log [NH3 + NH4+] - pH, log [C02] - pH, log SO42-] - pH, log [Metal] - pH). Dissolution/precipitation phenomena associated with nickel and cobalt recovery and with magnesium scaling are discussed in the context of the phase diagrams.

Jan 1, 1979

By M. Abdel-latif, R. W. Bartlett, P. R. Taylor

A cyclone reactor system for the partial reduction and melting of taconite concentrate fines was designed and operated. A nontransferred arc plasma torch was employed as a heat source. Taconite fines, carbon monoxide and carbon dioxide were fed axially into the reactor, while the plasma gas was introduced tangentially into the cyclone. The average reactor temperature was maintained above 1673 OK (1400°C), and reduction experiments were performed under various conditions. The influence of the following parameters on the reduction of taconite was investigated: carbonmonoxide to carbon dioxide inlet feed ratio, carbon monoxide inlet partial pres- sure and average reactor temperature. The interaction of the graphite lining with carbon dioxide and taconite were also studied.

Jan 1, 1995

By Eleanora I. Robbins, Motoaki Sato

Many problems associated with acid mine drainage (AMD) are caused by the complex way molecular oxygen (O2) oxidizes reduced matter at surface temperatures. In aqueous solution, O2 kinetically "prefers" to go through the formation of hydrogen peroxide (H2O2) as an intermediate. Being innately unstable, H2O2 is quickly decomposed back to water and oxygen in the presence of dissolved Fe and Mn, both catalysts for the decomposition. Direct addition of H2O2 to AMD produced similar results. Ozone (O3) is a much faster and stronger oxidizer than either O2 or H2O2. In the laboratory, O3 rapidly precipitated Mn, Fe, Ni, Co, Pb, and Ag even in acidic solutions. The experiments indicate that AMD can probably be processed with ozone and metal oxides/hydroxide recovered in flow systems using only septic-tank-size reactors and small sedimentation ponds.

Jan 1, 2000

By J. A. Herbst, K. N. Han, P. B. Queneau, S. W. Asihene

As hydrometallurgy matures as a technology, more of its existing process knowledge will continue to be summarized in the form of detailed mathematical models. This development is happening at a time when major improvements in computer hardware have reduced the cost of computing. The opportunity then exists, through the solution of these process models, to design, control, and optimize hydrometallurgical plants on the basis of the physics and chemistry of its processes and less on empiricism. In this paper, a review of the current capabilities of sensors and phenomenological models for selected hydrometallurgical processes is presented. Future trends, in terms of the control and optimization of hydrometallurgical plants, are then explored. The possibility of simultaneously optimizing plant design and associated process control system performance is discussed.

Jan 1, 1993

By Kenneth N. Han, Xinghui Meng, A. J. Monhemius, G. W. Warren, E. Peters

The leaching of gold in ammoniacal solutions containing various oxidants in an autoclave has been investigated. Also studied are thermodynamic and kinetic aspects of the ammonia leaching of gold and silver. The variables studied included stirring speed, temperature, concentration of ammonia, ammonium, and various anions. Arrhenius activation energy values were found to be between 47.1 kJ/mol and 86.2 kJ/mol depending upon the kinds of oxidants used. An electrochemical reaction controlling mechanism has been proposed for the dissolution reaction. The leaching behavior of gold and silver from various ores in ammoniacal solutions containing various oxidants has also been investigated. The samples tested included sulfidic as well as carbonaceous refractory ores. The recoveries of gold and silver from these refractory ores were better than 96% within 2-3 hours of leaching time.

Jan 1, 1993

By Raymond E. Krauss

The McLaughlin Mine is based on a world class epithermal gold deposit located in the coastal thrust fault of northern California, about 1 12 air km (70 air miles) north of San Francisco. Owned and operated by Homestake Mining Co., the McLaughlin deposit contains about 18 Mt (20 million st) of gold ore at an average grade of 5.2 g/t (0.152 oz per st), or about 93 t (3 million oz). The area was identified as a gold target by Homestake in early 1978. Drilling confirmed it to be a commercial deposit by 1980. The mine was then planned, engineered, built and brought into production by March of 1985. The deposit was historically a part of the Knoxville District. It was mined for cinnabar, which was used to produce mercury for use in recovering gold and silver in the Mother Lode and Comstock districts. At that time, the mine was called the Manhatten and later the One Shot Mine. It was worked for more than 100 years, producing about 76,000 flasks of mercury without any awareness of the presence of economic concentrations of gold. By 1978, the site was largely disturbed and entirely unreclaimed.

Jan 1, 1990

By R. R. Klimpel

The efficiencies of plant-scale comminution processes are often evaluated by various indices calculated and/or measured somewhat independently of the performance of any associated downstream froth flotation processes. To compare specific comminution factors, such as energy utilization, media consumption and equipment utilization time, comparisons of comminution efficiency independent of flotation behavior are appropriate. However, as increasingly detailed plant-level information is gathered on the joint and highly interactive nature of comminution and froth flotation, it is becoming even more obvious that knowing and using simple efficiency indices are not enough. What is needed are more performance-related measures of the efficiencies of the combined size reduction froth flotation system for effective plant-level economic optimization to occur. The purpose of this paper is to present examples of some of the important interactions that influence the joint efficiencies of size reduction and froth flotation processes.

Jan 1, 1999

By Cheryl M. McInnes, Graham J. Sparrow, James T. Woodcock

Three composites, assaying about 3 g/t Au and 0.75% Cu, were investigated. Each contained oxide copper minerals, iron oxides, and silicates. One composite also contained copper and iron sulphides. Maximum gold extractions by thiourea leaching were obtained after copper removal by acid pre¬leaching at pH 1.5 and redox potentials of 400 mV (Pt versus SCE). Best thiourea leaching conditions were pH 1.5, redox potentials over 200 mV, and 0.4% thiourea. This gave 90% gold extraction in 2 h with thiourea consumptions of 25 kg/t. Lower potentials gave poorer extractions. Ferrous iron additions before leaching halved thiourea consumptions. Longer leach times and the presence of sulphide minerals sometimes resulted in reprecipitation of gold.

Jan 1, 1989

By R. L. Grayson, S. S. Peng

Sampling of respirable dust and analyses of samples have been partially completed for a longwall panel. Physical and compositional properties which have been characterized include: 1. Respirable mass concentration, 2. Mineral composition, 3. Particle size distribution by mineral, 4. Particle shape distribution by mineral, 5. Particle angularity distribution by mineral, and 6. Respirable size distribution. Analytical techniques used in the characterization of samples are described, and results are reported with emphasis placed on relationships between the various characteristics and worker locations. Details of existing mining conditions, equipment arrangements, dust control methods and operating system parameters are presented.

Jan 1, 1986

By Solomon S. Katz

As more and more computer software is written for geological mapping applications, the users of the software are discovering the problems of transferring data between the programs, maintaining correct data and integrating maps produced last week with those produced today. One way to deal with these situations is by using a geographic information system (GIs). Last September the USGS and National Academy of Science held a 5-day GIs symposium on integrating technology and geoscience applications (USGS, 1988). It was followed in October by GEOTECH '88 (Peters and Krajewski 1989) which had a session exclusively for GIs applications in the Geo-Sciences. Editorials in Geobyte (Leonard, 1986, 1988) suggested that geographic information systems will be the next major computer programs to be adopted by the mineral industries. As far- back is 1985, the Computer Oriented Geological Society (COGS) printed An Introduction to GIs in their newsletter (Katz, 1985). About 20 years ago, a revolutionary idea occurred in the world of business data processing. It was the idea that all related data be stored in a standard format, in a single place and that all related computer application programs would use the same data.

Jan 1, 1989

By Haydn H. Murray

The three major catalyst markets that utilize industrial minerals as raw materials are petroleum refining, chemical processing, and emission control. Because of economic, competitive, and regulatory pressures, catalyst producers are pushed to develop products with improved performance to meet changing environmental standards. Also, refiners are demanding new families of cracking catalysts that will crack residual fuels. In 1987, worldwide cracking catalyst sales amounted to $457 million (Occelli, 1988a). Recently enacted federal and state laws to improve air quality have prompted strong growth for environmental catalysts, which in 1989 accounted for more than a third of the $1.9 billion catalyst market in the United States (Farrauto, Heck, and Speronello, 1992). A catalyst is a material that promotes or enhances a chemical reaction but does not itself enter into the reaction. One of the more important mineral groups used as catalysts is clays. The first recorded use of clay as a catalyst was its use in the dehydration of alcohol (Bondt et al., 1797). Clay minerals that are used as catalysts are kaolinite, halloysite, smectite, palygorskite, and sepiolite. Minerals used as catalysts, catalyst supports, or as a raw material to make zeolites are kaolinite, halloysite, sodium montmorillonite, calcium montmorillonite, hectorite, palygorskite, sepiolite, talc, calcined kaolinite, gibbsite, chlorite, and titanium dioxide.

Jan 1, 1994

By Hasan Sevim

A computerized heuristic model for an efficient and economic design of belt haulage networks in underground coal mines is discussed. The model is versatile, easy to use, and is valid for all mining methods singly or in combination. It may be used to design new networks or to analyze existing networks. The input data required are 1. maximum production rates from a section, 2. probabilities of production rates, 3. equipment costs, and 4. data necessary for network coding to represent different cases. The objective function is the "expected minimum cost per ton of coal hauled" while meeting production requirements. The output includes belt width, motor horsepower, bin size etc. and also values of operating parameters for each belt such as belt speed, effective tension, power consumption etc. A detailed account of the cost involved is also provided for each unit as well as for the entire network. Description of the model and an example of the design of a belt network in a mine with two longwall and four development sections are presented.

Jan 1, 1986

By C. Steiakakis

Over recent years large construction projects have taken place and will be taking place in complex geological environments. In order to reduce costs and increase safety, a detailed geotechnical evaluation of local conditions is very important. This issue has been addressed in much detail for soils and hard rocks but there is a gap in intermediate geomaterials such as soft or altered rocks. In order to overcome this problem geotechnical engineers usually adopt principles and methods meant either for soil or hard rocks. The rock mass classification systems such as RMR, GSI etc. are the ones predominantly used. The users of these systems are of-ten unaware of the theory, limitations or the data behind these systems. The aim of this paper is to demonstrate problems or misuses of rock mass classification systems in intermediate geo-materials. The main focus is on the GSI classification system since it is widely used in Greece. Complex geological environments, altered, weathered or poor rock materials are addressed and suggestions on how they should be evaluated with the use of rock mass classification systems are discussed. Situations where the use of these systems produce erroneous results not due to their limitations but rather due to lack of experience and incorrect use are also discussed. Finally, recommendations are made for better use of these systems in practical problems

Jan 1, 2005

By Jon Y. Kaneshiro, Gregory E. Korbin, Stephen J. Navin, Larry J. Stout

Sewage presently being discharged into the Tijuana River Valley pollutes the valley as well as the beaches in the South Bay of San Diego, making the beaches unusable nearly year round. The SBTO will convey flows down a 8.5 m (28 ft.) by 58 m (190 ft.) deep drop shaft, through a 3.35 m (11 ft.) by 5.8 km (3.6 mile) long tunnel, and up a 46 m by 2.7 m (150 ft. by 9 ft.) riser shaft connecting to a 1.5 km (0.95 mile) of seafloor pipeline and 1.2 km (0.76 mile) of diffusers on the ocean floor. The drop shaft will be sunk through 38 m (125 ft.) of saturated sands and gravels and 20 m (65 ft.) into the dense fine sands of the San Diego Formation. The tunnel liner has been designed as a five piece, single pass, gasketed, bolted, reinforced concrete liner designed to withstand an external head of 76 m (250 ft.) of water and internal operating head of up to 27 m (89 ft.) and to accommodate movement at the numerous fault crossings. The tunnel is contemplated to be driven with a state-of-the-art Earth Pressure Balance Machine (EPBM) or slurry shield machine through a wide range of conditions from clay to gravel with boulders.

Jan 1, 1995

By J. R. Stoltz, E. Thompson, S. Pattee

On May 15 and 16, 1999, a mine ventilation survey was performed in the 705-m- (2,312-ft-) deep Cayuga Mine, Cargill Salt Division, Lansing, NY. The purpose of the survey was to develop a numerical model of the existing ventilation system and to perform a computer simulation study for long-term environmental and ventilation planning. Because the natural ventilation pressure (NVP) has significant effects on the ventilation system at the Cayuga Mine, there was a need to assess the NVP acting in the mine. Due to the ventilation arrangements in the Cayuga Mine, the authors decided to use the direct-measuring method to determine the NVP by measuring differential pressure across the automatic fan door. This difference in pressure was measured immediately after the fan was stopped and the automatic door was closed to stop the flow throughout the entire mine. To show seasonal changes in NVP, two additional measurement for NVP were performed, one on Aug. 22, 1999, during the hot (summer) season, and another on Feb. 6, 2000, during the cold (winter) season. The mutual interaction between the natural ventilation pressure and the main fan at the Cayuga Mine is also discussed

Jan 1, 2003

By 1980, the US mining community had reached a broad consensus regarding coal pillar design. The pillar load could be estimated from tributary area theory, and the pillar strength could be estimated from empirical formulas and laboratory coal strength testing. Then the growth of longwall mining required new thinking. Recently, powerful design methods have emerged from analysis of large databases of real-world pillar successes and failures. These include the analysis of retreat mining pillar stability (ARMPS), the analysis of longwall pillar stability (ALPS), the Mark-Bieniawski rectan¬gular pillar strength formula and guidelines for preventing massive pillar collapses. Sophisticated numerical models have also helped transform the pillar design landscape. In the process, the understanding of pillar mechanics has been greatly enriched. A new paradigm identifies three categories of pillars according to the types of failure that are associated with them. These categories are slender pillars (w/h < 3.0), which are subject to sudden collapse; intermediate pillars, in which pillar squeezes seem to be the most common failure mode; and squat pillars (w/h > 10), which are dominated by entry failure (rib, roof or floor) and coal bumps.

Jan 1, 2000

By D. Borrowman

Attrition of activated carbon in either the carbon-in-pulp (CIP) or carbon-in-leach (CIL) method of gold extraction can lead to, at the least, loss of expensive carbon that has to be made up, and at the worst, loss of both the carbon and any gold that was attached to it. Carbon attrition therefore represents a significant factor in both the efficiency and cost of the extraction process, and efforts to reduce attrition through process and equipment selection pay dividends. In evaluating carbon attrition potential, one would note that an individual carbon particle is in jeopardy virtually any time it is in motion. Since the motivators of this motion are primary centrifugal pumps, the purpose of this paper is to review the current styles of these pumps now in use and to examine their performance in minimizing carbon attrition.

Jan 1, 1992

By Randal J. Barnes

The nonlinear network optimization algorithm developed in this paper solves the following mine ventilation design problem: find the location and size of all fans and regulators which minimize the overall system power consumption while satisfying all physical, legal, and operational constraints. This work includes the formulation of the problem within the framework of mathematical optimization, the development of the computational theory, and the creation of an efficient solution methodology. The algorithm has been implemented on a microcomputer, and a small but representative example is included. The algorithm presented in this paper has four limitations. First, the optimization process is for a single point in time: the dynamic nature of a mine ventilation system in an evolving mine is not directly addressed. Second, the topology of the ventilation network is required input information. The mathematical algorithm does not optimize the size or location of the mine ventilation airways; however, the post optimality analysis techniques can be used to aid in topological decisions. Third, the problem is formulated using volumetric flow; thus, heat and moisture transfer are ignored. Fourth, the capital cost of ventilation equipment is not included in the formulation.

Jan 1, 1989

By J. F. T. Agapito, J. B. Page

This paper describes part of a geotechnical study based on stress determinations and convergence measurements conducted to assess the long-term stability of an experimental room-and-pillar oil shale mine. A rock mechanics program was initiated in 1971 at the Colony Mine as part of a large study conducted for the design of a commercial operation. The Colony Development Operation is a joint venture currently consisting of four active members; Ashland Oil Inc., Atlantic Richfield Company (Operator of the project), Shell Oil Company, and The Oil Shale Corporation. Although oil shale commercialization plans are presently suspended, rock mechanics instrumentation has been continued as part of Colony&apos;s policy in maintaining readiness to proceed with a commercial shale oil plant when national energy policies became better defined. The property is located in the southern edge of the Piceance Creek Basin in northwestern Colorado, approximately 200 miles west of Denver. Experimental mining operations were conducted from 1965 to 1972 with one of the major objectives of the pilot mine being the assessment of opening and pillar sizes for the determination of extraction ratio and life of the property. Mining was conducted in a 60 foot thick portion of the Mahogany Zone in the Parachute Creek Member of the Green River Formation, at depths of 600 to 850 feet by a one-bench system. Pillar dimensions were 58 feet by 58 feet and rooms were 55 feet wide.

Jan 1, 1977

By F. K. Letowski

Leaching of zinc sulphide concentrate by nitric acid which is simultaneously regenerated by oxygen in the reactive froth has been investigated. The reactive froth was formed by a recycled zinc sulphate electrolyte containing nitric acid, a mixture of gaseous 02 and NOx, entrapped in the foam and particles of the zinc concentrate suspended in the foam. In the reactive froth the multiple regeneration of nitric acid proceeded owing to the encapsulated oxygen and amount of nitric acid used can be considerably lower than in the continuous liquid phase. 93 to 97% of zinc was extracted to a solution containing 30 to 409/1 HNO, during 40 to 60 min of leaching in a batch reactor without regeneration of nitric acid. 50 to 100% of the consumed nitric acid was regenerated during continuous leaching in froth carried out in the ‘flotation column’-type reactor at 80 to 90°C and under pressure of 100 to 200kPa. The rate of HNO, regeneration in the froth was proportional to oxygen pressure and inversely proportional to nitric acid concentration in the froth. A two-stage process flowsheet is proposed. In the first, the reduction stage, removal of nitric acid from the leach solution directed to standard purification and electrolysis is carried out by its reduction to nitric oxide using fresh concentrate in the froth. In the second, the oxidation stage, nitric acid is continuously regenerated by oxygen in the froth.

Jan 1, 1995