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By David Lunt, Evan Kirby, Peter Mason, Ian Ritchie

The treatment of refractory gold ores, in particular the "competing" technologies and their relative advantages and economics, has become a major segment of most mineral technology oriented conferences in recent years. A common theme is the increasing refractory nature of gold ores being treated. This is despite ores such as those at Kalgoorlie having required roasting for liberation since the last century. Papers on refractory gold treatment have examined the characteristics of refractory ores and the causes of reduced recovery (eg La Brooy 1994), the available technologies and their relative economics eg Litz 1990), and the selection of a suitable process route (eg Nicholson 1993, Weston 1994). The most comprehensive collation of data on such processes is provided in the different editions of Randol. A variety of classifications and definitions of "refractory ore" have been published. Due to the many factors which can impact on the recovery of gold it is perhaps not feasible to develop a universal characterisation that can be applied to all gold bearing rocks. La Brooy et al have provided the framework for characterisation shown in figure 1.

Jan 1, 1995

By Brad C. Lewis

The coal mining industry has experienced a general trend toward longwall operations. An increasing percentage of underground coal is being mined by longwalls. And productivity in longwalls is likewise increasing. Operators of longwalls, however, have not yet reached a state of mining euphoria. Competitiveness within the industry and from alternate fuel sources is forcing continued pursuit of higher productivities and lower costs. [Figures 1, 2 and 3] present trends in the industry. Longwall mines, as defined here, are those reportedly having longwall installations in each of the respective years. Production from both the continuous miner and longwall units is included in the longwall mines. Nonlongwall mines are all other underground mines. Productivity calculations are based on total employee-hours associated with the operation. Annual percent increases in productivity appear to have peaked in the 1985-1987 time frame. This was due, in part, to implementation of technological advancements and improvements in management-labor relations. The results shown in [Fig. 3] aroused the author's curiosity. The first question was "Have technological advancements to increase productivity peaked?" It does not appear so.

Jan 1, 1990

By B. J. Arnold

Coal blending inherently means homogenizing a mixture of coals so that the properties of the blend meet some specifications for maintaining power plant performance and emission requirements. In practice, however, coal blending is, at best, coal mixing. The degree of blending sophistication required depends on the reason for coal blending in the first place. If it is to maintain fuel characteristics that will diminish the chance of slagging and fouling, then some swings in variability may be tolerated at some power stations. However, if emissions limits are the issue, then more sophistication may be needed. Emissions limits are becoming stricter with requirements to meet averages for shorter time frames (hours and days instead of weeks and months). These restrictions require closer control over the quality of the blend being fed into the bunkers at the station. Even scrubbed units should have a consistent quality of fuel as feed so that sorbent additions can be minimized. To meet these challenges, engineers must consider available equipment and control techniques and the properties of the parent coals when evaluating new blending systems.

Jan 1, 1994

By I. Nishkov, L. Alexandrova

The kinetics of froth flotation and the three-phase contact (TPC) parameters are studied at temperatures varying from 20°C to 40°C. The material floated consists of glass spheres and a quartz particles with various diameters. Dodecylamine hydrocloride (DDAHCI) is used as a collector. The equilibrium three-phase contact angle is measured with a microscope technique using the modified Mingins-Scheludko method. Using a Wilhelmy method, the temperature effect on the surface tension of the DDAHCI solution is determined. The formation of the thin film on a polished plate of vitreous silica and the expansion of TPC is monitored by means of a metallographic microscope and recorded on a attached camera at different temperatures. The experimental data show an intensification of the flotation kinetics at 30 and 40°C in the case of small particles. Such an intensification is not observed with the larger particles. The cause for intensification of the flotation kinetics is sought for in the dependence of the TPC rate of expansion and induction time on temperature.

Jan 1, 1995

By Kelly F. Bailey

Introduction On June 20, 1986, the Occupational Safety and Health Administration (OSHA) published revised asbestos exposure standards for general industry and construction. The standards reflect OSHA's attempt to adequately control workplace exposures to minerals it considers carcinogenic - minerals capable of causing or contributing to cancer. These standards specifically identify asbestos as: chrysotile, an asbestiform serpentine mineral; and the amphibole minerals amosite, crocidolite, tremolite asbestos, actinolite asbestos, and anthophyllite asbestos. Each of these has a more common nonasbestos mineral analog that exists in nature in a crystalline, blocky shape rather than the hair-like or fibrous shape of asbestos. The mineralogical names for three of these nonasbestos minerals are unique: antigorite for chrysotile, cummingtonite-grunerite for amosite, and riebeckite for crocidolite. The other three nonasbestos analogs do not have unique mineralogical names. They are simply designated as actinolite, tremolite, and anthophyllite without the word asbestos following their names. The 1986 OSHA standards not only cover exposure to the six asbestos minerals, they also cover specifically the nonasbestos forms of actinolite, tremolite, and anthophyllite (AT&A). The new standards regulate these minerals exactly like asbestos (OSHA, 1986). The construction aggregate industry views this as a major problem because these nonasbestos minerals are common amphibole rock-forming minerals in the earth's crust. They exist in small quantities over large areas of the United States (Kuryvial et al., 1974). These minerals, unlike asbestos, are not mined for a specific commercial purpose. They are unavoidable components in much of the aggregate used for construction throughout the US. They are also common in the gangue material of metallic ores. There are areas of the US where amphibole-bearing bed¬rock is common. Not every rock mass in these areas contain amphiboles, however. It does mean, though, that amphiboles are physically compatible with many of the rocks in those areas. And given the correct geochemical conditions, they will be present primarily in the nonasbestiform variety. In addition, these amphiboles will probably exist in the natural drainage system, sand and gravel deposits, stream sediments, lake shores, valley basins, or ordinary beach sand within these areas. There has been little quantification of nonasbestiform AT&A in dusts and soils in the US. This is not surprising since these nonasbestiform minerals are not commercially valuable. However, an example of the pervasive nature of these minerals can be found in a 1981 Geological Society of America publication where about 0.7% tremolite-actinolite was found in the desert dust in and around Tempe, AZ (Pewe, 1981). Since OSHA standards treat these common nonasbestos minerals as carcinogens in the same way as asbestos, large natural areas in the US are implicitly being labeled as hazardous by OSHA. When a substance is identified as a carcinogen, another OSHA standard comes into play, the Hazard Communication standard. There are also right-to-know laws in 9 states that essentially duplicate this federal standard. These standards require that a product containing 0.1% or more of an OSHA-designated carcinogen be labeled as such (OSHA, 1983). This means that much of the stone and sand gravel products occurring naturally and mined in the US could be labeled a carcinogen when, in fact, they are not. The National Stone Association (NSA) and the domestic construction and mining industries believe that OSHA has seriously erred. The NSA has studied the health, mineralogical, technical, economic, and legal basis for OSHA's action. These studies concluded that there is no justification for the agency regulating nonasbestos minerals as if they were asbestos. Health issues The preamble to OSHA's 1986 asbestos standard states that evidence for asbestos-like health effects from exposure to nonasbestiform varieties of AT&A is inconclusive (OSHA, 1986). The fact is, not only are the data inconclusive, they are nonexistent. During 1986-1987, NSA's occupational health and epidemiology consultant, Environmental Health Associates (EHA), reviewed all available health studies related to AT&A. EHA found evidence that malignancies in both experimental animals and humans are associated with the asbestos forms of these minerals. No experimental or epidemiological evidence was found that indicated such pathogenic effects occur from exposure to nonasbestiform varieties of these minerals. There are relatively few scientific studies of the health effects of exposure to nonasbestiform varieties of AT&A. In three different animal studies, exposure to either nonasbestiform tremolite or actinolite did not result in pulmonary fibrosis on in excess tu-

Jan 11, 1988

By R. Torbin

The degree to Which automation/remote control/robotics has been utilized in the mining industry is far less compared to general industry because of several factors. These factors include the adverse working environment, the difficult work operations, and the generally lower incentive for capital investments in new mining equipment. Foster-Killer has been actively involved in the development of advanced mining and underground construction equipment. This equipment is designed to be remotely operated to improve both productivity and worker safety. Many of these machines employ advanced electronics and robotic features. Other types of Foster-Miller developed robots will also be described Which could be applied to special mining problems. The types of machines that will be discussed include the following: remote shaft lining/placement. remote excavation/mining operations, automated conveyor system, and robotic surveillance.

Jan 1, 1989

By H. H. Hughes, J. G. Dunn, P. G. Fernandez, H. G. Linge

Dissolved Arsenic (As) is stabilised primarily as As(III) and As(V) and enters ground water streams from sources such as the increasing metallurgical processing of As - containing ores [1]. As(III) is more toxic than As(V) and is less effectively removed from solution by oxide precipitation. Even for dilute As(III) solutions, skin contact or ingestion can cause dermatitis or cancer and there are stringent effluent control standards in place for As containing effluent from mining operations [2]. Chemtronics (Perth, Australia) has manufactured a compact digital voltamme­ter, based on anodic stripping voltammetry (ASV) and suitable for use in the laboratory or field. In this paper we demonstrate the utility of this equipment for measuring As(III) concentration with a detection limit of ca. 10 ppb.

Jan 1, 1995

By P. Riveros, J. Binvignat, V. M. McNamara, D. Koren

The feasibility of recovering cyanide and copper from a gold mill barren solution was evaluated in a small A VR pilot plant. The campaign lasted 64 hours, during which time about 4,000 L of gold mill barren solution were processed. The results showed that A VR is an effective technology for recovering cyanide and copper from barren solutions. Under the best conditions, the copper precipitation and the cyanide volatilization attained 94% and 98%, respectively. Using 5 MNaOH as the absorbent, practically all the HCN gas was recovered in the form of a concentrated NaCN solution containing 70 g/L free CN. Basic engineering design parameters applicable to a large-scale operation were obtained, including the Henry's Law constant and the mass transfer coefficient for HCN gas.

Jan 1, 1997

By R. J. Rice, K. F. Denning

Effect of iron on the removal of arsenic, mercury and selenium from gold mining effluents. Arsenic, mercury and selenium are common trace elements in gold tailing effluents that require removal before the water is either recycled or returned to a receiving body. One of the better methods of removal of these elements is the use of iron salts whereby, the metal is trapped on the freshly precipitated hydrolyzed iron oxides either by adsorption or enmeshment of the fine particulate and hence, removed from solution. The metal removal is effected by iron to metal ratio, pH, temperature etc. Pilot plant tests have shown that mercury can be reduced to < 5 ppb Hg, while full scale tests on arsenic and selenium have achieved levels of < 50 ppb As and < 10 ppb Se in well controlled systems.

Jan 1, 1993

By T. Yegulalp, K. S. Lackner

Zero emission coal plants capture their own CO2 emissions. Since they have no smoke stack, they emit no pollutants to the air. Zero emission plants circulate a gas stream, to which fresh fuel is added and from which spent fuel and impurities are removed as solids or liquids. Coal is gasified via hydrogenation, steam reforming or CO2 gasification (Boudouard reaction). The gas is oxidized in a fuel cell and the resultant water and CO2 are partially removed before returning the remaining gas to the gasifier. The high conversion efficiency of zero emission power plants, which exceeds 70% even in realistic designs, stems from combining fuel cells with careful heat management. The paper generalizes the concepts and outlines the thermodynamic basis of zero emission power plants.

Jan 1, 2004

By Schebek, J. Warsen

"Data and information from sustainable development (SD) reports can be seen as a promising and easily accessible source for an Life Cycle Assessment (LCA), i.e. for generic Life Cycle Inventory (LCI) data in particular. The reliability and comparability of LCA results crucially depends on the quality of LCI data, that is defined by specific normative requirements. In parallel the GRI (Global Reporting Initiative) provides a set of guidance documents for enhancing the quality, rigor, and utility of SD reporting with specific reporting principles that address similar issues on a company level comparable to LCI data quality requirements on the process level. In order to assess the general suitability of the fundamental reporting principles for LCI data quality purposes selected reports from mining and minerals (M&M) sector are assessed within a detailed analysis."

Jan 1, 2005

By B. Yarar, R. Buchan

Mineral-processing techniques were adopted for use in the separation of various plastics used in beverage bottles. A complete flowsheet, which utilized size reduction, heavy-media separation and flotation, was developed to separate PE, PVC and PET. In addition, the mixtures contained cellulose fibers (from labels) and aluminum (from bottle caps). It was demonstrated that, while heavy-media separation allows for the separation of a PVC/ PET mixture, froth flotation can be used to separate PVC and PET. For this purpose, the differential action of a pH 11 alkaline aqueous solution containing methanol and MIBC as surface-tension control agents, has been found to be a suitable flotation medium. This paper reports on some aspects of a flotation flowsheet that was developed for the separation of plastics contained in municipal solid wastes.

Jan 1, 1997

By Venkata S. Vutukuri

Assuming a number of discrete leakage paths and treating the airflow through leaky duct line as a series-parallel combination of airflows along the duct and through leakage paths, exact solutions for auxiliary ventilation problems can be obtained. A computer program "SEGMENT&apos;&apos; has been written to solve problems using this method. However, most of the investigators have treated the duct lines with a uniformly distributed leakage and many have derived formulas assuming various boundary conditions and levels of simplification for the design of a simple auxiliary ventilation system An appraisal of accuracy of the various formulas has been conducted using the results from the program "SEGMENT&apos; as benchmark and the formulas which give accurate results have been identified. The ranges of application for all the formulas have also been determined for 5 %error.

Jan 1, 1993

By E. D. Goddard, D. S. Murphy

Acid resistance, zeta potential and ESCA (electron spectroscopy. for chemical analysis) experiments were performed on emperador marble and four calcium carbonate samples (onyx calcite, travertine calcite, Iceland spar calcite and aragonite). Six fluorine-containing reagents were used to treat the surfaces of these materials: magnesium hexafluorosilicate, zinc hexafluorosilicate, sodium fluoride, zinc fluoride, strontium fluoride and stannous fluoride. The acid resistance of treated samples proved to be much higher than that of their untreated equivalents. The isoelectric point of treated samples approaches the isoelectric point of fluorite. Also, the fluorine content, as measured by ESCA, of a marble surface treated with magnesium hexafluorosilicate is much higher than that of an untreated sample. The binding energy off of fluorine and calcium the treated marble is consistent with the formation of calcium fluoride.

Jan 1, 1994

By D. Tao, B. K. Parekh

Fine coal particles are difficult to separate effectively from liquids or other solids. Ultrasonic energy may be used to enhance the efficiency of the conventional fine-particle separation processes widely used in the coal and mineral industries. Flotation, settling and dewatering tests were conducted using several fine coal samples to study the effects of ultrasonic treatment on these processes. Process variables such as particle size, ultrasonic treatment time and solids concentration were investigated for their impacts on ultrasonic treatment effectiveness. The results obtained from this study showed that ultrasonic treatment is an effective approach for enhancing solid/solid separation in flotation and solid/liquid separation in sedimentation and dewatering of fine coal. SEM microphotographs demonstrate that ultrasonics cleaned particle surfaces, which is, in part, responsible for the observed improvement in fine coal separation processes.

Jan 1, 2000

By S. M. Hsiung, Wen H. Su, Syd S. Peng

This paper examines the interaction problems of multiple seam mining by combining underground investigation, laboratory testings, and numerical modeling. One case of multiple seam interaction that occurred recently in West Virginia was carefully studied. Causes for the interaction problems were identified and the corresponding mining recommendations were proposed. The principle of pillar columnization and the effect of a remnant pillar on mining operations in the underlying and over- lying seams were also carefully examined. Considerable attention was given to the effect the pillar size, the pillar width, the coal stiffness, the extraction ratio, the degree of inhomogeneity in the interburden, the overburden thickness, the mechanical properties of the interburden rocks, the strata inclination, the interburden thickness, and the in-situ horizontal stresses have on the pillar load transfer mechanism.

Jan 1, 1986

By Graeme Lyall, Oy Leuangthong, Clayton V. Deutsch

There are many variables to consider in the evaluation of nickel laterite deposits including the concentrations of nickel, iron, silica, and magnesia. These variables show complex relationships with each other such as mineralogical constraints, non-linear correlation, and heteroscedasticity. The complex multivariate relationship between the variables cannot be reproduced by conventional Gaussian or indicator geostatistical techniques. We introduce the stepwise conditional transformation method as a pre- and post-processing multivariate transform for the stochastic simulation of a nickel laterite deposit. Transformed data are multiGaussian and independent at h = 0; thus, cosimulation can be avoided after verification that variables are independent at all lag distances. Back transformation restores the features of the input multivariate distribution to the simulated realizations. The complex multivariate correlations are reproduced and sensitivity issues are addressed.

Jan 1, 2002

By James D. Reilly

The time-worn adage "an ounce of prevention is worth a pound of cure" was never more applicable than when used in reference to coal mine safety. Many individuals have dedicated many hours to developing effective accident prevention programs, and much has been accomplished. Each production escalation, however, creates new hazards and safety problems which need special study and research. It is a never ending cyle. To study the progress of coal-mine safety is to raise memories of many individuals who have been dedicated to removing the hazards that have developed with increased productivity and deeper penetration into the earth for coal. Some vivid examples of this dedication are the works of the men who pioneered the use of the safety lamp and the use of rock dust in mining.

Jan 1, 1968

By Gary L. Simmons

Aqueous pressure oxidation at low temperature, although desirable from a process engineering and operations point of view, presents unique problems when temperatures approach 160°C (320°F). In developing the pressure oxidation process for the Lone Tree Mine, elemental sulfur formation and agglomeration with pyrite proved to be a problem. This paper discusses some of the unique mineralogical and chemical characteristics of the Lone Tree sulfide deposit that make it amenable to low temperature pressure oxidation. Problems encountered during pilot plant operation and their solutions are also discussed.

Jan 1, 1993

By Juergen Loroesch

Since the introduction of Peroxide Assisted Leach, PAL™, in the gold mining industry three years ago, seven plants in Australia and South Africa have successfully employed this process. Significant increases in the gold extraction rate are often accompanied by savings in cyanide. These applications are summarized in an overview which helps to define the requirements for a technically and economically successful PAL operation, based on mineralogical composition, operating parameters, and various design and plant features. PAL has a well-defined field of application which has to be differentiated from competitive oxygen leach techniques.

Jan 1, 1990