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By J. W. Jang, I. Iwasaki

Introduction Grinding ball wear in wet grinding is due to a complex combination of abrasion, corrosion, impact and their interactions. The ball charge is continually falling from a height greater than half of the ball mill's diameter, and contact is made with ore particles or other balls. Abrasive wear occurs through penetration and plowing of media materials from the ball surface by hard ore particles (Gangopadhyay and Moore, 1985). Electrochemical interactions between the abraded and unabraded areas of the ball surfaces, as well as between the grinding media and the minerals, occur in grinding mill pulps (Adam et al., 1986). The wear depends on the media composition, the hardness and the corrosive/abrasive characteristics of the slurry. The marked-ball-wear test method was used to evaluate the performance of grinding media under nitrogen and oxygen atmospheres. Also, the wear mode was studied by observing the grinding media surface under a scanning electron microscope. In general, grinding media of high hardness and high chromium contents were found to have better corrosive wear resistance than those of low hardness and low chromium contents (Jang, Iwasaki and Moore, 1988). The purpose of this investigation was to determine the size distribution and the shape of wear debris in a study of the wear rates and wear behaviors of grinding balls. Experimental Materials The grinding ball alloys used in this investigation were: •martensitic stainless steel (MSS; 0.96% C and 16.2% Cr), •high-carbon, low-alloy steel (HCLA; 0.89% C and 0.53% Cr), and •mild steel (MS; 0.22% C and 0.09% Cr). The mineral used in this study was synthetic corundum, because it was on hand and contained no magnetic impurities. Debris A 203- mm (8-in.) diam porcelain mill was used for grinding the corundum. The mill charge consisted of: •1200 g of 12-grit synthetic corundum, •770 mL of 0.05 mole/L Na2SO4 (61% solids), and •125 steel balls of nominally 25-mm (1-in.) diam. To minimize the debris corrosion, nitrogen was introduced into the mill. Grinding with MSS, HCLA-steel or MS balls was conducted for 2 hr at 51 rpm. The grinding time using the MS ball was varied from 0.5 hr to 2 hr in an attempt to study the debris amount and shape as a function of time. The debris was collected with a hand magnet from the ground slurry and separated from the corundum particles using a Davis magnetic tube. After the separation, the debris particles were immediately washed with acetone and then filtered and dried. Debris size analysis Buckbee-Mears 3-in.-diam, micro-mesh sieves and an electromagnetic shaker were used for determining the debris size distribution. In sieving, isopropyl alcohol was used. The debris fraction collected from each sieve was washed with acetone, dried and then weighed on an analytical balance. [ ]

Jan 1, 1993

By L. M. Bigler, J. L. Dobra

With the passage of Mexico's Mining Law in 1992, the tax treaty with the US in the same year, and the passage of the North American Free Trade Agreement, gold mining for non-Mexican mining companies in Mexico has changed dramatically. The statutory changes have created an opportunity for non-Mexican precious metals' producers to own 100% of a Mexican gold concession. This paper examines the financial feasibility of a hypothetical gold mine and processing plant in Mexico. The analysis includes the operational consequences of the recent weakness of the peso, as well as tax and employment issues.

Jan 1, 1996

By E. R. Braer, C. J. Bise

The trend in underground room-and-pillar coal mining is to employ remote-controlled, continuous-mining machines and extended cuts to depths of 12 m (40 ft) or more. This system of coal extraction, adopted by more than 435 mines, can create additional worker safety hazards. To address the ground-control-related safety hazards, a combination of statistical analysis and numerical modeling was used. Initially, the reported roof-fall incidents and fatalities were reviewed to delineate the ground-control hazards. Then, the application of the coal mine roof rating (CMRR) for estimating safe extended-cut depths was evaluated. Finally, computer modeling was completed to predict roof displacements during extended-cut mining. This paper describes the results of these studies and their impacts on the safety of extended-cut mining.

Jan 1, 2000

By D. R. Nagaraj

The chemistry and structure-activity relationships for four new classes of sulfide mineral and precious metals collectors developed recently are discussed in this paper. These collector classes are alkoxycarbonyl alkyl thionocarbamates and thioureas, dialkyl (or diaryl) monothiophosphates and dialkyl monothiophosphinates. The main emphasis will be to highlight the differences between collectors and their affinities for various minerals on the basis of data on kinetics of adsorption on pure minerals, natural ore flotation and microscopy of flotation concentrates. The mechanism of interaction of these collectors with sulfide minerals is also discussed with the available data on the FTIR and solution chemistry studies.

Jan 1, 1989

By Richard M. Michaels

In considering the use of underground space for civil works functions, there are several criteria that must be met if transfer of any of them is to occur. It is important to recognize that these criteria involve social and political as well as conventional engineering and economic considerations. It is the purpose of this report to identify certain of these criteria and develop a set of measures that will permit the evaluation of the potential benefit of transferring civil works functions underground. The work reported here was completed for the ASCE and is contained in the report, Undergound Space, 1973. If one examines the total direct and indirect economic return from the location of civil works in subsurface rather than surface space, sizeable benefits accrue. This occurs largely because design, construction, operating and maintenance costs of these systems are highly dependent upon the forces exerted on these systems by the surface enviroment itself. Transferring of these facilities to underground space would eliminate a large segment of those costs. It is equally true that civil works functions compete with other uses for surface space and generate significant conflicts with these competing uses. Highway construction takes land from other productive uses. Electrical transmission lines conflict in terms of safety and aesthetics with adjacent social activities. Assuming that construction costs can be made equivalent, the analyses in the previous report indicate that the locating of all civil works functions underground would yield an annual net savings to the society of the order of 60 billion dollars. It may be added that the benefits in terms of improved social perfromance would also be substantial. However, it is clear that the benefits from utilization of subsurface

Jan 1, 1974

By Julius Rubinstein, Victor Badenicov

The development of column flotation is the most significant achievement in the area of mineral processing in the last few decades. The high efficiency of column flotation allows a reduction in process time, a decrease in the number of cleaner stages and in the volume of the circulating load in the flotation circuit, and, as a result of this, an increase in consistency and reliability of operations. Unique multisectional column flotation apparatuses were developed. Such designs have a number of essential advantages as compared to monocells. A change from monocells to multisectional column allows to provide favourable conditions for separation of particles of various floatability. To attain that aim particular hydrodynamics and aeration regime is established in each section of the column, operational variables being adjusted according to the floatability of the material. Therefore in multisectional column machines the material-apparatus feedback can be established, process variables optimized depending on the characteristics of the floated materials. This concept forms the basis of column designs we have developed. For the first time column cell with alternating slurry Rows (combination of co- and counter-current flows) were developed and commercialized . Successful operation was reported of the new generation of columns with cell volumes of 10 to 80 m3 and the height of 4-6 m in copper, molybdenum, antimony, tungsten and nickel ores and coal slurry processing at different plants. Operation experience of these cells showed their considerable design and operational advantages and verified the proposed options and relationships. The new apparatus is provided with a pneumohydraulic aerator allowing to control bubble size distribution, the service life of the aerator is not less than two years. A multilevel flotation model was developed and used to work out a technique of column design and process parameters calculation. A method of the apparatus design parameters calculation based on laboratory test results (scaling up) was worked out. The method is based on flotation macro and micro-hydrodynamics simulation.

Jan 1, 1995

By R. C. Berry

The Environmental Impact Statement (EIS) has become a routine requirement for mining operations on federal lands. A similar document is being required in developing countries. Baseline studies are needed prior to writing an EIS and these studies involve surface water, groundwater, air quality, and wildlife/ native plant evaluations. The required baseline hydrology and geochemical studies are often the most expensive and lengthy evaluations. This paper summarizes the hydrology and geochemical baseline studies required for .An EIS and presents suggested methods to expedite these studies and to shorten the time and the cost to complete the studies and the EIS.

Jan 1, 1999

By Patrick Corser, Mitch Usibelli

Introduction Coal mining in Alaska's interior, specifically in the Healy area, began as early as 1918 with the construction of the Alaska Railroad. Mining was originally limited to underground operations but has expanded to entirely surface operations. In 1943, the Usibelli Coal Mine was formed and started developing Alaska's first surface mine east of Suntrana (Usibelli Coal Miner, 1984). Production from the local coal deposits has steadily increased and, in 1978, surface mining of Poker Flats was initiated (Fig. 1). Currently, a 25-m3 (33-cu yd) walking dragline strips two coal seams, using an extended bench on the second pass. In addition, a fleet of trucks and shovels are used for coal removal and some limited overburden stripping. In 1984, a contract was signed between Usibelli Coal Mine and Sun Eel Shipping Co. in 1984. Since then, production has nearly doubled to more than 1.3 Mt/a (1.5 million stpy). This article will discuss geotechnical constraints on mining within the steeply dipping coal deposits that exist within the Poker Flats mining area. Specifically, the article will describe how the mining operation retriggered an historic landslide on the No. 5 coal seam (Fig. 2). And the article tells how a mine plan was developed that allowed the coal to be safely removed without inducing additional movement. Regional geology The coal-bearing group in the Nenana coal field is of Tertiary Age. It is overlain in some areas by several thousand feet of Tertiary gravels - the Nenana Gravels. In areas mined by surface methods, the Nenana Gravels have been eroded off, and up to 30 m (100 ft) of quaternary outwash gravels overlay the coal-bearing formations. The coal-bearing group is divided into five formations: Healy Creek, Sanctuary, Suntrana, Lignite, and Grubstake (Wahrhaftig, 1969). Lignite Creek lies on the north limb of a west plunging anticline. This has brought the Suntrana coal-hearing formations near enough to the surface to allow surface mining. Mining is presently in progress on the south side of Lignite Creek in the Poker Flats area. The coal-bearing formation is cut off to the south by a fault having perhaps several thousand feet of vertical displacement, with the upthrust side to the north. South of this fault, Nenana Gravels are exposed on the surface. The Suntrana Formation contain the minable reserves at Poker Flats. This formation is a repeated sequence of poorly consolidated pebbly sandstone near the bottom, grading through a silty fine sandstone to a footwall clay unit immediately below a coal seam cap. The footwall clays are high plasticity clays to silty clays. It has been reported that they contain 30% to 50% montmorillonite (Usibelli Coal Mine Inc., 1982). There are six coal seams in the Suntrana Formation, No. I (the lower seam) through No. 6. Only the top four seams are currently exposed. No. 3, No. 4, and No. 6 seams are the only mined seams. The No. 5 seam is very thin or not present. Portions of the undisturbed Suntrana Formation are overlain by up to 15 m (50 ft) of Quaternary outwash gravels or recent landslide rubble. The surface is overlain by a very thin layer of muskeg and isolated areas of permafrost. In many areas, the outwash gravels are found immediately below the surface muskeg. Numerous landslides have been documented along the north facing slopes of Lignite Creek (US Geological Survey, 1970, and Wahrhaftig, 1958). These appear to be surficial solifluction or skin flow types of landslides. In addition, deep-seated structurally controlled slides are also evident on both the north and south sides of Lignite Creek. Structural features Premining aerial photographs (Fig. 3) of the Lignite Creek slopes in the Poker Flats area indicate substantial evidence of deep-seated landsliding. The landslides noted in Fig. 3 are both inside and outside of the current mining area. Surface mapping and geologic exploration indicate that the coal seams are dipping out of the slopes within the noted slide areas. It is suspected that, historically, these landslides were triggered by undercutting of the toe of the slopes by Lignite Creek. And sliding it thought to have taken place on one or more of the clay beds underlying the coal seams (Golder, 1985). The slide areas are characterized by semicircular head scarps and slumped topography. Based on the premining photographs, these slides do not appear to have been recently active. However, they are expected to be in a state of only marginal stability. Extensive coal exploration indicates that the primary structural feature within the

Jan 1, 1989

By Gerhard Sauer, Heimo Gold

The main advantage of the New Austrian Tunneling Method over conventional drill and blast techniques, TBMs and shields is its outstanding flexibility. Many different support concepts help to cope with all but the most adverse conditions. A considerable variety of unique additional support measurements provide a functional tool when dealing with particularly difficult conditions or restricting requirements. The resulting adaptability of NATM with respect to geometric and geologic changes is a cornerstone to providing an economic design and to a safe and unhindered execution of the tunnel work. To take best advantage of this flexibility and to emphasize its cost-saving capacity, NATM explicitly extends the design period into the construction phase. In accordance with corresponding ground classes or other anticipated conditions, a number of basic support categories and an array of additional support measurements are established during the actual design phase. The decision for applying a particular support category at a specific location and for necessary additions to the given support scheme, however, is regularly made on site after each advance, and is determined by the key persons involved in the construction. Contract documents must reflect this approach to facilitate the execution of the work and to curtail construction costs. Biased distributions of risks, however, can adversely effect the envisioned benefits. Consequently, the respective responsibilities of engineer, contractor, and client need to be redefined.

Jan 1, 1989

By J. C. Watts

Ball mill grinding circuit control has received increasing emphasis in the past few years due to such factors as declining ore grades, increasing production costs, and advances in analytical devices and minicomputer technology. Since ball mill circuits have been a traditional bottleneck in mineral processing plant throughput, control systems often improve through- put without requiring additional processing equipment. In addition, much of the variability of the grinding product size and consistency is often removed, allowing better process operation downstream. Among the problems which arise in designing and implementing a process control strategy for ball mill circuits are circuit constraints imposed by processing equipment and local management, proper instrument selection, installation and maintenance, and use of calculated or inferred variables for process measurements. This paper discusses these problems and attempts to identify valid approaches to their solution.

Jan 1, 1979

By P. R. A. Andrews

Areas of bubble contact were delineated for topaz and tourmaline in the presence of chloride, fluoride, sulfate, phosphate, oxalate, and citrate ions using dodecylamine hydrochloride collector. The limits of pH and the minimum collector concentration were established using the bubble pick-up technique. Bubble contact did not occur below the p.z.c. (point of zero charge), estimated to be 5.6 for topaz and 6.6 for tourmaline, in the presence of chloride ion. Flotation below the p.z.c. was, however, extended by citrate, oxalate, phosphate, sulfate, and fluoride ions. Oxalate, citrate, and fluoride ions displayed the greatest pH range of activation, followed by phosphate and sulfate ions. Chloride ion acted as an indifferent electrolyte. Topaz was selectively activated with respect to tourmaline by fluoride and phosphate ions. Topaz was activated by fluoride ion between pH 2.4 and 5.6. Tourmaline flotation in this pH range was virtually insignificant. Topaz was activated by phosphate ion between pH 4.9 and 7.4. Tourmaline flotation in this pH range was only partial. Activation appeared to be strongest when anionic protonated species were in maximum concentration. Strong activation also corresponded to very stable metal ion species thought to be formed on the surface of each mineral.

Jan 1, 1991

By R. L. Pozzo, A. S. Malicsi, I. Iwasaki

The electrochemical nature of mineral-grinding media interaction in the wet grinding of one and two sulfide mineral ores was investigated with regard to the flotation behaviors of the minerals. Two iron sulfides (pyrite and pyrrhorite) and mild steel were used to represent the sulfide minerals and the grinding media, respectively. Galvanic currents in two- and three-electrode combinations under abrasive and non abrasive conditions were correlated with the floatabilities of these minerals under corresponding conditions.

Jan 1, 1991

By C. G. Cunningham

The Marysvale volcanic field of west-central Utah contains large areas of argillically altered rocks (fig. 1) that, in turn, enclose smaller areas of fine-grained, medium-grade, replacement alunite deposits and coarsely crystalline, high-grade vein-type alunite deposits. The largest replacement alunite deposits are [ ] located peripheral to a 23-m.y.-old monzonite stock called the Central Intrusive (fig. 1). The deposits formed in near-surface, highly oxidizing environments at the tops of hydrothermal plumes that were spaced irregularly around the stock. The deposits are horizontally zoned from alunitic cores through kaolinitic to propylitic envelopes. Vertically, characteristic alteration minerals progress from a pyrite-propylitic alteration assemblage at the base, upward through alunitic, jarositic, and hematitic assemblages to a flooded silica cap as shown on figure 2. The silica caps are cut by hydrothermal explosion breccias. d34Sso4 values of + 11.5 to + 15.4 permil indicate that sulfur in the hydrothermal plume was derived from underlying Mesozoic evaporites. The sharp upward transition from pyrite- propylite to alunite probably marks the paleowater table, and the top of the flooded silica cap represents the paleoground surface. Basin-Range extensional tectonism began shortly after alteration, and buried the replacement alunite deposits in basins beneath sediments eroded from uplands. The deposits were only recently exhumed.

Jan 1, 2013

Acid mine drainage is still a common problem in the northern Appalachian high sulfur coal region despite mining and reclamation practices applied to control it. Mining companies must treat water with alkali to raise pH and precipitate metals in order to discharge the water into receiving streams. Common chemicals used to treat drainage are limestone, hydrated lime, soda ash briquettes, caustic soda, and ammonia. Each chemical has advantages or disadvantages under specific conditions. A simple spreadsheet program was developed to evaluate costs of treating acid mine drainage across several specified water quality parameters and time horizons. Caustic soda and soda ash were shown to be cost effective for treating low flows and low acidity over short time periods. However, as quantity of water increased, quality decreased, and time horizon increased, the ammonia and hydrated lime systems were found to be much cheaper than caustic soda.

Jan 1, 1991

By John Ralston, Rossen Sedev, Nicola Richards, Quinn Anthony, Geoffrey Reynolds

Derivatised 2,4-diketopyrimidine groups have been anchored to planar gold surfaces as self¬-assembled monolayers (SAMs) for chemical and photochemical studies. Three derivatives, 5-methyluracil (thymine), 5-trifluoromethyluracil and 5-nitrouracil, were chosen for the specific moiety present at position C-5, which can exert strong or weak inductive effects on the adjacent aromatic ring. The measured acidity constants decrease from 5-methyluracil to 5-nitrouracil as the inductive properties of the group at C-5 position increase. When grafted to the surface the acidity constants increase, albeit still adhering to the expected inductive trend. The functionality also exerts an influence on the surface wetting properties. Surface wettabilities indicate that the orientation of the pyrimidine groups at the surface occurs so that the C-5 position has a direct effect upon the surface chemistry. Upon dimerisation the surface contact angles increase signifi¬cantly. At pH 11 the contact angle changes reflect that the dimer has a higher pKa than the monomer. The monomer surface is deprotonated at this pH while the dimer surface is partially deprotonated, leading to changes in contact angle of up to 22 degrees. Large changes in contact angle were observed for 5-nitrouracil which were independent of surface charge and were appar¬ently due to conformational changes alone. Electrowetting of three fluoropolymer surfaces by electrolyte solutions was studied with the sessile drop method. The electrowetting curve (contact angle/potential) is analogous to the elec¬trocapillary curve (surface tension/potential) and may be described by a combination of the Young and Lippmann equations. We demonstrate that for some specific surfaces a systematic deviation occurs at positive potentials. This departure is attributed to double layer effects, namely the adsorption of hydroxide and halide anions. pH, ionic strength and polymer composi¬tion can all influence electrowetting behaviour.

Jan 1, 2003

By M. A. Mahtab, N. M. Cruickshank, M. T. Wane

Gas outbursts occur as sudden eruptions of gas and minerals from the face of a mine heading as the heading approaches potentially burst prone (or anomalous) zones of rock. Such outbursts have resulted in considerable damage to equipment, and in some cases lives have been lost. Characterizing these anomalous zones and detecting their presence is therefore vital to safe mining. Certain significant characteristics associated with the outburst-prone zones are: (1) the presence of fluid inclusions, (2) unstable stress conditions, (3) characteristic geologic structures, (4) certain physical properties of the rock, and (5) microseismic activity. Geophysical and engineering methods for detecting these characteristics are discussed and are considered with respect to their past success and future potential for predicting gas outbursts.

Jan 1, 1987

By J. A. Herbst, C Lo. Y, Z. Rogovin

The identification and quantification of incipient overload conditions in mills have recently been found to be very significant in the design of tumbling grinding mills. To investigate these phenomena, a series of experiments was conducted in a Plexiglas mill operated in both dry and wet modes. For on-stream measurement of the mill charge weight, volumetric filling, dynamic angle of repose, and mill power, an electronic system was developed. The mill was filled to various levels with 19.1-mm (3/4-in.) ceramic balls as grinding media. As feed material, grindable limestone or 3.2-mm (1/8-in.) nongrinding ceramic balls were fed at various steady-state rates to determine the incipient overload conditions. The prediction of overload has apparently been reduced to predicting the feed rate that results in 50% mill filling.

Jan 1, 1988

By Lawrence J. Connelly

During the last decade, use of freeze conditioning agents (FCA) to ease unloading and handling of both run-of-mine and washed coal during periods of cold weather has become an accepted practice by the coal industry. This paper reviews some of the mechanical means of easing the handling of coal during periods of cold weather, as well as their use in conjunction with FCA's. Factors required to promote a successful cold weather handling program are also covered. Mechanisms by which FCA's function and the influence of various substrate characteristics on the ultimate response to freeze conditioning agent performance are discussed. A modified approach to freeze conditioning is presented.

Jan 1, 1986

By R. Velkova, D. Bojinova

The objective of the present investigations is to establish the effect of the preliminary mechanical activation of phosphates on the degree of phosphorus extraction by bioconversion of Bulgarian and Tunisian phosphates using A. niger fungi and T: thiooxidans microorganisms. The influence of the phosphate concentrations, the type of the nutritive medium and the incubation times on the process of biological mobilization of the phosphates was studied. When the concentration of phosphates in the medium is twice as high, an equal and/or higher degree of phosphorus extraction can be achieved through the bioconversion of mechanically activated phosphates compared with non- activated phosphates under similar conditions. A maximum degree of 90+% phosphorus extraction in utilizable form was achieved at definite conditions.

Jan 1, 2002

By R. D. Miller, D. W. Steeples

Seismic reflection is a powerful geophysical exploration method that has been in widespread use in the petroleum industry for more than 60 years. This paper addresses some basic principles of the method and its application at depths shallower than 30 m (100 ft). Since 1980, the shallow reflection technique has been increasingly used for engineering and environmental problems, such as mapping bedrock beneath alluvium and delineating intra-alluvial features near hazardous waste sites, detecting voids in coal and karst, defining the top of the saturated zone and mapping shallow faults. New applications will be added with improved resolution and increased cost-effectiveness.

Jan 1, 1994