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By M. Zaki El-Sabban

Tables of chemical thermodynamic properties for the ideal gas state from 0° to 1,000° K are reported for eight alkanethiols, three cycloalkanethiols and arylthiols, six thiaalkanes, two dithiaalkanes, three thiacycloalkanes, and three thiophenes. They are based on current physical and thermochemical constants and definitions, reliable vibrational assignments, and the latest insights into molecular structure and energetics.

Jan 1, 1970

By P. Talonen

Since the last Iron Control in Hydrometallurgy Symposium in Montreal in 1996, the Kokkola zinc plant has increased its capacity from 175,000 t/y to 280,000 t/y by installing an atmospheric concentrate leaching process, which has also affected iron control in the leaching circuit. Major changes have been made at the jarosite residue pond; a subterranean plastic wall reinforced with bentonite and cement has been built around the pond. A new water collecting system that is used for groundwater level control in the pond area was installed. With these two investments in the pond area, it is now possible to prevent any seepage flow from the pond into the surrounding environment. Water pumped from the residue pond is treated in the water treatment plant. This paper describes the behavior of iron in Kokkola's current leaching processes. The treatment of the jarosite, the improvements to the residue pond and the water treatment process are also described.

Jan 1, 2006

By Seib W

In cut-and-break rock excavation use is made of the fact that breaking rock in tension towards a free face requires a specific energy of excavation which is small in comparison with that required for rock excavation using conventional tools operating by a process of indentation of the rock.The process of cut-and-break excavation comprises firstly a cutting step in which a groove is cut into the rock surface, followed by a breaking phase in which a tool is inserted into the cut in order to break the rock adjacent to the cut.

Jan 1, 1992

By Charles Janin

(San Francisco Meeting, October, 1911.) THE first successful bucket-elevator dredge to operate in California was put in commission at Oroville in March, 1898. There had been numerous previous attempts at dredging, but none of the earlier boats proved a success. The gold-miners in California early conceived the idea of a machine to dig gravel from the beds and bars of auriferous streams that were inaccessible by the methods then employed, and it was only a few months after the discovery of gold in California that such a machine was. shipped around Cape Horn from New York to San Francisco. This was, however, but the forerunner of many failures in gold-dredging, and was soon at the bottom of the Sacramento river. During succeeding years many other unsuccessful attempts were made, and it was not until 1897 that a dredge of the single-lift bucket-elevator type was floated on the Yuba river. This dredge was built by the Risdon Iron Works for R. H. Postlethwaite, and would probably have been a success if it had been operated on some of the rich Oroville ground instead of in a turbulent stream, where the dredge was wrecked during a flood, and was not repaired. Fig. 1 is a sketch-map of California, showing gold-dredging areas. It is not my intention to narrate in detail the history of the early failures in gold-dredging, and the various steps in the development of the modern boat, but merely to touch upon this in a general way, and to call attention to the wide difference in capacity and operating-cost between the first successful dredge, with an actual capacity of 600 cu. yd. per day-though its rated capacity was in excess of this-and the present modern dredge with 15-cu. ft. buckets, and an average capacity of 250,000 cu. .yd. per month. Even this enormous capacity has several times been exceeded on monthly runs. The first successful dredges

Mar 1, 1912

By J Lyall Workman, Peter N. Calder

"Large hole rotary drilling is one of the most common methods of producing blastholes in open pitmining. Large hole drilling generally refers to diameters from 9 to 17 inch (229 to 432 mm), however aconsiderable amount of rotary drilling is done in diameters from. 6% to 9 inch (165 to 229 mm). Thesesmaller diameters are especially prevalent in gold mining and quarrying."

Jan 1, 1996

By A. G. Jackson, S. J. P. Laube

"Control of thin films during the growth process is dependent on several parameters that are difficult to monitor, including flux of film material, pressure, substrate temperature, composition, and thickness. One means for easing this difficulty is to take advantage of emission spectra associated with the process and the film. For pulsed laser deposition (PLD), the ion cloud generated by the laser has characteristic emission spectra that can be used to control the flux and, hence, the film. For chemical vapor deposition, the species present can be determined using mass spectroscopy and specific peaks can be used to control the deposition. Raman spectroscopy affords the possibility of real-time control by sensing characteristic peaks associated with film composition and thickness. These spectroscopic methods offer a real-time alternative to process control that is very attractive, because of the ability to accurately control films to achieve the engineered structures and properties sought. Examples are presented to illustrate the capabilities of these methods for thin film preparation.IntroductionThe drive to reduce costs and improve efficiencies of operation sets the tone for much of research, basic or applied. Basic research is limited by the ability of sensors and associated instrumentation to measure parameters accurately and reproducibly. Applied research has the same limitations and also the added constraints of time and costs. Hence, there are strong incentives to explore means for refining existing sensors with respect to performance and cost, as well as finding new sensors and techniques for more accurately and rapidly measuring quantities of interest in experiments and in various processes."

Jan 1, 1997

By Robert M. Becker

Particle mixtures were sampled in the laboratory, using ordinary sampling procedures, to determine whether or not the compound-multinomial probability distribution and other developments of part 2 agreed with experimental results. The objective was accomplished by the Bureau of Mines by comparing the moments and moment relationships of the appropriate probability models with their corresponding experimental values over a fairly wide range. The overall agreement between the corresponding theoretical and experimental values is both good and complete. The results demonstrate that sampling to a constant amount, such as weight, of items per sample is not the same, in general, as sampling to some constant number of items per sample. The results seem to confirm all the developments of part 2 and the application of the compound-multinomial function to bulk sampling.

Jan 1, 1965

By V. K. Kakaria

As you know most of the gold and silver is produced by one of the following processes: (1) Agitated Leaching - Carbon adsorption or Merrill-Crowe (2) Heap Leaching - Carbon adsorption or Merrill-Crowe The figure 1 shows a typical flowsheet for recovery of gold and silver using Agitated or Pachuca Leaching Operation. The ore is crushed and ground and then leached in cyanide tanks solution using either Pachucas with air agitation or tanks with mechanical agitation. The soluble metal values are separated from the pulp by counter-current washing. The precious metals from cyanide solution are either recovered by zinc dust (Merrill-Crowe Process) or by loading on carbon and stripping with hot caustic cyanide solution. Gold and silver are electrowon on steel wool cathodes.

Jan 1, 1981

By George A. Morgan

The production and processing of crude petroleum and natural gas are the dominant economic sectors of the Middle East. The IS countries that constitute the region accounted for 26% of world crude petroleum output, 17% of world natural gas plant liquid production, and almost S% of world dry natural gas production. About 66% of total world crude petroleum reserves and 31 % of total world natural gas reserves are in the Middle East. Transportation and port facilities in the region are geared to expediting efficient and rapid shipment of these materials. U.S.-dollar-denominated export sales of these fuels, estimated at $120 billion in 1989, provide funding for further diversification of the mineral industry. This is usually through development of downstream facilities for producing energy intensive metals such as aluminum and byproducts of the fuels such as petro-chemicals and fertilizers. Earnings from the industry are also channeled by sever-al Governments in the region to mineral industry projects in Africa and elsewhere. A fairly wide range of nonfuel minerals is produced in the region. However, the variety of minerals produced, output levels, and the size of the overall nonfuel mineral economy is dominated by Iran and Turkey. Turkey, with a diverse mineral production and strategically situated between Europe and the Middle East, ranked among the top three world producers of boron, chromite, pumice, and strontium. It was also a significant world producer of magnesium com-pounds, mercury, and sodium sulfate. Iran had generally lower output owing to 9 years of neglect to the mining sector between 1979 and 1988. It was a significant producer of gypsum and fifth in world production of strontium. Despite a very small domestic mineral industry, Israel was second in world production of bro-mine and a significant producer of phosphate rock and potash. Jordan ranked fifth in world production of phosphate rock. Iraq ranked about eighth in world production of sulfur, a commodity of major importance in the metallurgical, petrochemical, and fertilizer industries.

Jan 1, 1992

By Wu Jian-tao, LI Guo-wei

"The Cement Mixing Pile (CMP) quality assurance assessment is an important programme in evaluating the efficiency of foundation improvement. Coring is the current specified method of quality assessment in China which has the shortcomings of long cycle, high cost and low efficiency. The field and laboratory test show that the regular cone penetration test can only detect maximum of 4m of effective detection depth in CMP. In contrast, the method of cone penetration test in the reserved hole can detect the quality continuously along the pile at any depth. The tip resistance of reserved hole penetration in the 7th day has good linear relationship with unconfined compressive strength in the 28th day. The slope of linear relationship decreases with the increasing of clay particles content.INTRODUCTIONThe method of Cement Mixing Pile (CMP) is often used to improve soft soil foundation in highway construction, with the major purpose of reducing settlements under embankments (Bruce et al., 2000),which is a form of what is known as the Deep Mixing Method (Bruce et al., 2013). The CMP technology spread quickly in China in the 1980s. CMP quality assurance assessment is an important programme in evaluating the efficiency of foundation improvement. Coring is the current specified method of quality assessment in China (China Academy Of Building Research, 2002). The method of Coring is perceived in some quarters that samples will provide lower strengths given the distress caused to the core during drilling and extraction (Bruce et al., 2002).The cone penetration test CPT can provide continuous measurements of the penetration resistance, sleeve friction at the tip of the probe, which has advantages of simple operation, low cost and high efficiency compared with coring. However, CPT tests have not been established to assess CMP in Sweden because of difficulties in maintaining verticality (Larsson, 2005). In Finland and Norway, however, CPT tests are commonly used (Halkola, 1999). One of the disadvantages of CPT is the tendency of the cone to steer out of the column (Porbaha et al., 2003). Darya Mokrousova (2010) states this tendency to deviate can be overcome by pre-boring and starting the penetration test from the base of the pre-bored hole. Sheng Haiyang (1999) found that probes may be deflected out, sometimes even at small penetration depths, and may not give a complete inspection of the pile. Liu Songyu et al. (2003) suggested that the Standard Penetration Test (SPT) is an effective way to evaluate the strength and quality of stabilized soil-cement columns. In general, Regular CPT can’t test the full length of CMP, and SPT still needed drilling which causes discontinuous detection. From the existing standard of China, core sampling compressive strength test is the main method, evidently, coring displays a longer test cycle, high cost and low efficiency. Therefore, an improvement of CMP quality assessment, by conjuring a fast and reliable detection and evaluation method, is necessary. The aim of this paper is to research the feasibility of using CPT in assessing the quality of CMP and presents an improved CPT method."

Jan 1, 2015

By C. G. Wilson

DURING the course of some experiments on the plastic deformation of gallium a standard stereo-graphic projection was prepared with (001) at the center and it was felt that this might be useful to others working with single crystals of gallium. The stereogram, given in Fig. 1, was made using the following crystallographic data (Bradley, 1935):

Jan 1, 1962

By S J. Neethling and, S J. R Simons

In this paper the effect of humic substances (natural surfactants), electrolytes and solid particles on bubble coalescence, and as a consequence on froth stability, have been investigated. In this study two bubbles of equal size were formed and forced to collide using a novel experimental apparatus. The interactions were recorded by a high-speed camera, the images of which helped to determine the coalescence frequency and the coalescence time, as well as the mechanisms of the interactions. Two types of humic substances were used, along with three different electrolytes. Humic substances appeared to have a considerable effect on bubble coalescence, while the effect of electrolytes was minimal. Moderate and high hydrophobic glass spheres were used between two bubbles. Very hydrophobic spheres promoted fast bubble coalescence, while moderate hydrophobic spheres had no effect. Data of coalescence frequency and time is presented, as well as images of the coalescence events. The coalescence frequency was used to validate a parameter, Pf, known as the film failure frequency, used in a simulation model to predict foam height in a gas-sparged vessel. Predictions determined using Pf were then validated by experimentation.

Jan 1, 2005

By Albert E. Long

During the summer and fall of 1948 the Bureau of Mines, in cooperation with the U. S. Geological Survey, conducted 6xperiments in diamond core drilling in the Phosphoria formation in southeastern Idaho and southwestern Wyoming. Nearly all of the diamond core drilling in the Phosphoria formation has been done by mining companies interested in finding and developing phosphate-bearing beds amenable to stripping. The recovery of sludge; and enough core (usually 30 to 60 percent) to identify certain marker beds produced by current drilling practices meets both the primary requirement of mining companies in determining depth of overburden and their secondary need to determine the phosphate content of relatively thick minable units whose general composition and nature are already fairly well established.

Jan 1, 1949

The polymerisation of silica is found to interfere with thickening of leach pulps at Risdon. Hydroxyl ion and fluoride ion are catalysts for this reaction. Stability may be obtained by the presence of aluminium or ferric iron.INTRODUCTIONAt Risdon it has been a matter for satisfaction that, although the concentration, of silica in leach solutions is appreciable, it has ,given relatively little cause for anxiety.However the margin of safety is small and some intermittent difficulty in thickening leach residues during the last few years has prompted a further investigation, certain parts of which are described here since they may be of general interest.Leaching and ClassificationThe method of leaching which is practised at Risdon has been described in, two previous articles, by W. C. Snow (1936) and S. W. Ross (1949) to whiCh the reader is referred for detail. Continuous leaching is practised, the circuit solution flowing through five air agitated pachucas in series, to tlie first of which calcine is added. The circuit solution, which also enters the first pachuca, consists of spent electrolyte from, the electrolytic cells and contains 90 -gm. of free sulphuric acid per litre. About 80 per cent of the solublezinc oxide is extracted from the calcine in the first pachuca, at a pH value of 1-1 (7 gm.H2S04/1 at 55 to 60°C. In the later pachucas the leaching rate decreases sharply. The leach pulp which leaves the 'last pachuca contains an average of 17 gm. of free acid per litre, corresponding to a pH of 1.7; but, owing to variations in extraction, the end point fluctuates between 2.5 and 0·3 gm. free acid per litre (pH:> 1·5 to 2.5). The average flow through the plant is 1,250,000 gallons per day, which corresponds to a production of 300...

Jan 1, 1958

By Cheng Fang, Zhou Lie-xing, Peng Jin-hui, Guo Sheng-hui

This article discusses the behavior of temperature and microwave thermo gravimetric analysis characteristic of ammonium paratungstate in a microwave field. Experimental results show that when 12g of material is place in a microwave with 900W of power, paratungstate’s temperature rises at 70°C/min. This results in paratungstate’s temperature being 980°C after 14 minutes. Compared with thermo gravimetric analysis characteristic, former two-step process of paratungstate microwave calcined completed ahead of schedule, after two-step process reaction is more intense,Paratungstate warming is more rapidly, the reaction time is much shorter; According to XRD and SEM, the product is high purity, the crystal particle size is uniform, and the grain size is fine.

Jan 1, 2015

By Leonhard Weixler, Jean Wehbe, Gordian Ulrich, Franz-Werner Gerressen

"As alternative energy industries pick up speed internationally, and as government regulation and restriction limit the use of impact hammers due to environmental limitation from construction induced noise during pile driving operations, unconventional solutions for more complex offshore foundation installations have become a necessity. Manufacturers and equipment suppliers race to develop alternative techniques to accommodate for offshore foundation construction in various soil conditions and at greater water depth. The FLYDRILL, and the Seabed-Drill BSD are two innovative systems for the installation of offshore monopiles with reduced environmental impact.INTRODUCTIONThe FLYDRILL and the Seabed-Drill were born from techniques in the design and construction experiences gained from land based foundation drilling systems over the past 25 years. As the alternative energy industry ventures into uncharted territory of deeper water for offshore wind farms, fast current regions for tidal energy, and increasingly challenging soil conditions and project complexity, the advancement and development of new innovative equipment system and drilling techniques have become a necessity.The systems described herein show the development of the so called “FLY-Drill” system, and the all new “Seabed-Drilling” equipment applied at the first ever made job using a seabed drilling rig.FLY DRILLThe FLY DRILL method is a completely new concept for bored piling. The drilling unit with rotary head, Kelly bar, and drilling tool is suspended by the hoist rope of the base carrier crane. The hydraulic power for the drill unit is provided from the base crane.The drill head is fixed on the casing with a hydraulically operated clamping system during the drilling operation. When emptying the drilling tool, the clamp cylinders are opened and the complete unit is swung sideways."

Jan 1, 2017

By F. E. Joyce

The Bureau of Mines studied copper-nickel minerals (mainly sulfides) of the Duluth Gabbro Complex in north-eastern Minnesota to determine their response to selective high-temperature sulfatization techniques. The gabbro, containing 0.44 percent copper and 0.13 percent nickel, was ground to minus 325 mesh and sulfatized in a heated, rotating, stainless steel bench-scale retort. Tests demonstrated that over 95 percent of the copper and 80 percent of the nickel can be converted to water-soluble sulfates, depending upon the roasting conditions employed. Yield equations were developed using regression analysis for predicting the extraction of copper and nickel between the temperature limits of 520° to 670° C, the roasting time limits of 3 to 7 hours, and S02 limits of 10 to 40 percent in S02-air mixtures.

Jan 1, 1971

By J. Alexis, G. Ye, E. Burström

Over the past twenty years the 3 MW DC arc furnace at MEFOS has been frequently used for development of new processes. These processes include recovery of valuable metals from slag, sludge and dust from steel and other metallurgical industry, treatment of ashes from power plant and incinerators, smelting reduction of minerals and zinc recovery from EAF dust. The process characteristics of the DC arc furnace operation in terms of: ? selective reduction, ? total reduction, ? process stability and flexibility, ? dust carry-over, ? thermodynamic conditions provided in the hot spot area, ? precision in composing slag products These are analysed and described in this paper based on technical results from selected test campaigns over the years and thermodynamic considerations. The electromagnetic properties of DC arcs beneath the electrode have been studied by CFD simulation. The calculated result enables us to understand some interesting technical phenomena observed. The heat balance has also been considered based on data obtained from test campaigns and heat balance calculation.

Jan 1, 2004

By Edward H. Jr. Boyle, Paul R. Thomas

Introduction It is estimated that nearly 40% of all the gold ever mined in free world countries has been produced by South African operations. There is concern that this immense productive capacity will soon decline. Such a decline could reduce world gold supply and lessen the ability of market economy countries (MEC) to exert the major influence upon the world gold market. This paper addresses three general issues concerning South African gold production: • How much gold remains to be recovered from the demonstrated resources of the 44 evaluated South African mines; • How long can production at current levels continue; and • What will be its cost. Table 1 provides production data on the world's 10 largest producers for the years 1971, 1981, and 1983. As shown, South African gold production declined significantly from 1971 through 1981. As of 1981, annual South African gold production had dropped by more than 311 t (10 million oz) in 10 years. Despite this, its mines still produced 656 t (21 million oz) that year, about half the world total. From 1981 through 1983, this trend was reversed. Annual South African gold production increased by more than 21.8 t (700,000 oz). The trend reversal was also evident in the US, Canada, and Australia. This illustrates the general, inverse relationship between gold price and gold production. In South Africa especially, as gold prices increased substantially during the 1970s, the average grade of ore mined (pay limit) was lowered as new, lower grade areas and materials were exploited. Gold production declined in volume. But gold revenues increased, and the lives of the operations were extended. The 1981-83 period was one of declining (US dollar-based, average annual) gold prices that resulted in increasing South African production as average ore grades were raised. South Africa currently accounts for 50% of world production (Fig. 1). Figure 2 illustrates South Africa's contribution to total MEC production in 1971 and 1983. Although South Africa's relative share of production has declined, it still represents the single most important source of new gold supply. In 1983, it supplied more than 65% of total MEC production. South Africa currently produces more than twice as much gold as the Soviet Union (ranked second in world production), and 11 times more gold than the US (ranked fourth in world production). Barring major discoveries, South African gold production is expected to peak in 1987 and begin to decline again throughout the 1990s. The rate of decline is ex-

Jan 11, 1984

By Thien Sok, Yaojun Lu, Craig Gilbert, Jeremy Scott

Feedwells play a pivotal role in gravity thickeners, governing flow distribution, feed dilution, and flocculation condition during solid–liquid separation. This study presents an optimized design and digital prototyping framework for FLSmidth’s E-volute and E-Duc Feedwell systems, integrating advanced computational fluid dynamics (CFD) with quantitative criteria introduced at SME2024. Building on established FLS technologies, a series of novel configurations were developed and systematically assessed under full-scale and site-specific conditions. CFD provided quantitative insight into flow distribution, feed dilution, and flocculation efficiency, enabling iterative refinement of design parameters. The optimized feedwell demonstrated superior hydraulic performance, enhanced mixing, and improved flocculation outcomes. Beyond the specific design advances, the work highlights CFD as an effective and economical tool for digital prototyping, facilitating early identification of design limitations, reducing dependence on physical trials, and accelerating innovation. The methodology underscores the value of simulation-driven design in advancing feedwell performance and improving thickener technology.

Feb 22, 2026