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By Vijaya Thangavelu

Biological leaching of low-grade nickel laterite is based on a non-traditional leaching of oxide minerals using heterotrophic micro-organisms. The organisms solubilise metals by excreting organic acids; these acids then form complexes with heavy metals. High salinity of water supplies and soils in the vicinity of nickel laterite ore bodies is a major abiotic stress to fungi and represents a major challenge in the application of bioleaching process in-situ. Salinity exposes fungi cells to Na+ toxicity and osmotic stress. This study examined the salt tolerance development of Aspergillus foetidus based on gradual acclimatization of organism, its salt threshold and the salinity effect on its metabolism. The biological leaching of weathered saprolite ore with the resulting halotolerant organism under saline conditions was assessed. It was observed that salinity stress affected the organism?s growth and energy utilization

Jan 1, 2006

By J R. Goff, R Carver, D S. Sheppard

The REGCHEM (Regional Exploration Geochemistry) stream sediment geochemistry database of open file mining company data, managed by GNS Science, was recently made accessible via the internet (http://maps.gns.cri.nz/website/minmap/). REGCHEM provides coverage of selected elements in mineral rich areas of New Zealand. Analysis of REGCHEM data highlights problems with inconsistencies between different surveys in terms of sampling methods, number and types of elements analysed, analytical techniques and detection limits. New, consistent multi-element geochemical surveys with national coverage are required. To test sampling, analytical and data treatment techniques for the new surveys, a pilot stream sediment geochemical survey was carried out in the Thames area, Hauraki Goldfield. Seventy samples were collected in an area of 220 km2 representing about one sample every 3 km2. The samples were analysed for 50 elements, mostly by XRF.   Regional patterns are apparent in the concentrations of some elements. Several elements, such as As, Cd, Cu, K, Pb, Sb, Se, and Zn exhibit anomalous concentrations mainly in the western part of the study area, related to Au-Ag-Zn-Pb-Cu epithermal quartz veins and porphyry Cu occurrences in hydrothermally altered andesitic terrane.   Mercury is anomalous in southern samples, reflecting cinnabar occurrences in the Kauaeranga valley (eg Mangakirikiri), and the occurrence of cinnabar as a late stage mineral in some of the Thames epithermal veins. Ba and U are anomalous in the eastern samples, and these anomalies are probably related to the presence of rhyolitic rocks in the eastern part of the project area.

Jan 1, 2006

By K. [Muthukkumaran

An extensive program of laboratory model tests was undertaken to study the effect of slope on p-y curves under passive loading in dry sand. The paper concerns the method developed in a series of laboratory model tests to experimentally determine p-y curves. Bending moment curves are differentiated by using curve fitting method of cubic polynomial function. The study includes effect of slope angle and relative density on bending moment and non-dimensional p-y curves. The non-dimensional p-y curves for piles on sloping ground under passive load are developed modifying API method by including a Reduction Factor (R) using the experimental results.

Jan 1, 2006

By A. Deepatana

Bioleaching of nickel laterite ores is based on the use of heterotrophic fungi organisms and their metabolites (organic acids) to dissolve nickel and cobalt from oxide minerals to form metal-organic complexes. Metal recovery from this process using an aminophosphonic acid based chelating resin (Purolite S950) was investigated as a function of metal concentrations, complexing agent including citric, dL-malic and lactic acids. Batch adsorptions were conducted using synthetic leachate solutions of nickel and cobalt with concentrations from 15 to 2000 mg/L prepared in 0.01 and 0.1 M organic acids. Adsorption equilibrium data were interpreted using the Langmuir, Freundlich and Dubinin-Kagner-Radushkevich (DKR) models. The results showed that equilibrium adsorption data for nickel-organic complexes followed the Freundlich model and those for cobalt agreed with the Langmuir model. It was observed that the maximum adsorption capacities of nickel and cobalt were 3.26 and 10.48 mg/g resins respectively. These were achieved in metal complexes prepared from 0.01 M lactic acid. Metal elution was conducted using 2 M nitric acid. High metal recoveries were achieved from low metal concentrations but were found to decrease with increasing metal concentration. The results suggest that effective recovery of nickel and cobalt from low concentration of metals, such as those generated from bioleaching operations, can be achieved suitably using chelating resins.

Jan 1, 2006

By Raj P. Singh Gaur

Due to high concentration of NaOH in the digested slurry after scheelite digestion, it is diluted to about 4N before filtration to separate sodium tungstate solution from the sludge (residue). However, in practice there may be deviations in the normality of NaOH present in the slurry. There may also be variations in the temperature of the slurry and filtration time. Slight variations in these parameters could cause tungsten losses in the sludge via the back reaction: Ca(OH)2 + Na2WO4? CaWO4 + 2NaOH This paper pertains to the effect of normality, temperature and time on the tungsten losses in the sludge that is separated from ?diluted-scheelite-slurry-in-NaOH? via filtration. Results indicated that tungsten losses in the filtered residue (sludge) were quite significant when the slurry temperature was kept at 70°C or higher. The effect of high temperature was less significant at the slurry normality of 3.6 or higher. Combination of low slurry normality (<3.6) and high temperature (>60°C) resulted into large W-losses in the sludge.

Jan 1, 2006

By Sadegh Firoozi

Experiments measuring the kinetics of oxidation and making visual observations of the oxidation of approximately 6 g static lead baths containing arsenic, antimony and tin were conducted in the temperature range from 500 to 600 oC. A range of repeatable behaviours were observed, notably: the formation of a coherent, solid oxide layers on pure lead and lead-tin alloys; the formation of liquid oxide droplets during the initial oxidation of lead-arsenic and lead-antimony alloys and the eventual formation of a complete oxide layer covering the entire free surface of these alloys. Thermogravimetric measurements revealed that the rate of oxygen uptake was strongly influenced by the form of oxides being generated at the melt/gas interface. Compared to the rates of oxidation of pure lead, arsenic increased the rate of oxygen uptake throughout the temperature range via the formation of liquid oxidation products. The presence of antimony resulted in a moderate increase in the rate of oxygen uptake as compared to arsenic. Tin was effective in lowering the rate of oxidation even in the presence of arsenic because the oxidation product was always a coherent layer that acted as a physical barrier to oxygen transport to the underlying alloy.

Jan 1, 2006

By Johnna Muinonen

"The Thompson Mill processes ores from the Thompson and Birchtree Mines. While the Thompson ore has very little magnesium containing gangue, the Birchtree orebody consists of veins of massive sulphide in a rock matrix that contains a high proportion of magnesium silicate minerals. A significant fraction of the magnesium is floatable, which lead to MgO levels varying from 3-11 wt% in the Birchtree concentrate. The magnesium in the concentrate causes a higher operating temperature in the smelter, reducing furnace life.Birchtree ore represented 20-30% of the mill ore receipts prior to October 2003. Since then the fraction of Birchtree ore has increased to 50%. A reduction of the MgO in concentrate to less than 3% in the total mill concentrate was required to allow safe and economic smelter operation.In October of 2002 a miniplant was set up to simulate the Birchtree plant circuit. Several flow sheet modifications were tested that led to a proposal for a circuit having increased cleaning capacity for the scavenger concentrate and a recleaner on this concentrate. Addition of CMC in rougher cleaner feed was also found to be required. The solution was confirmed through pilot plant testing in the mill in December of 2002. A full-scale installation was designed, engineered, and installed between February and September of 2003 with commissioning in September and October of 2003. Target metallurgy was achieved one week after start-up on slurry to coincide with the Birchtree Mine tonnage increase. This paper highlights the development, design and commissioning stages of the project.The new MgO rejection circuit has successfully allowed the processing of Birchtree ores producing concentrate consistently below 3% MgO. In addition, the new circuit increased overall nickel recovery in the mill.INTRODUCTIONThe Thompson Nickel Belt located approximately 700km north of Winnipeg was discovered in the early 1950’s. Inco first produced nickel from the area in 1960. Over the years the mill has processed several ores from different ore bodies in the area. Currently the Thompson Mill processes two significantly different ores from two mines, Thompson and Birchtree. The Thompson ore is a massive sulphide orebody hosted in schist, containing feldspars, quartz and biotite. Thompson Ore is characterized by high nickel recoveries and clean, low MgO containing concentrates (<2.5% MgO). The Birchtree ore is ultramafic and contains a high percentage of Mg-silicates such as serpentine, chlorite, biotite, amphiboles and talc. Some of these Mg-silicates report to the nickel concentrate and prior to commissioning of the MgO rejection circuit the Birchtree nickel concentrate typically contained 5-8% MgO"

Jan 1, 2006

By Sergio Neves Monteiro

This work had as its objective the characterization of a waste material, steel slag, generated from an integrated steel plant, with a view to its recycling and incorporation into red ceramics fabrication. The characterization was performed in terms of chemical composition by X-ray fluorescence (XRF), particles size distribution, X-ray diffraction (XRD), thermal analysis (DTA/TG) and scanning electron microscopy (SEM). The results indicate that the steel slag presents high amount of Ca, Fe, Mg and Si. The weight loss of the steel slag at temperatures above 800oC is associated with calcium carbonate decomposition. The coarse particle size of the steel slag is inadequate for its direct recycling into red ceramic fabrication. It is necessary to screen or to grind the waste. As a possible solution, it is suggested that screening or grinding the steel slag to a convenient particle size distribution would allow its successful industrial incorporation into red ceramics products.

Jan 1, 2006

By J. C. W. M. de Wit

An excavation, within which a tunnel is sunk as a part of the Centraal Station underground station (platform section) of the Noord/Zuidlijn (&apos;North/South Line&apos;), is to be created beneath the Amsterdam Centraal (&apos;Amsterdam Central&apos;) station. The section beneath Amsterdam Centraal Station is characterised by the application of a particular technology in the form of, inter alia, the so-called &apos;sandwich wall&apos;. This is a composite wall consisting of two rows of Tubex piles with a body of jetgrout columns in-between. This wall acts both as an excavation support wall and also provides vertical bearing. The installation of the wall, including both Tubex piles and jetgrout columns, within these specific conditions (limited height, sensitive historical building), within the design requirements set in terms of construction tolerance and water and soil retention, may be regarded as being a pioneering achievement. The environmental constraints are that the trains should continue to run, the inconvenience to passengers should be kept to a minimum and the historic station should not suffer any damage. Because of the complexity of the working conditions, the project is being overseen by a steering group of experts in the specified construction processes. In order to manage the project risks, jet grouting trials were initially carried out, in order to highlight and control execution problems; the practicability of the design is then tested. Work commenced on the sandwich wall in 2003, when the wooden piles were extracted at the locations where the sandwich wall was to be constructed; in 2004, the steel Tubex piles for the southern wall sections were installed. From May 2005, the construction of the sandwich wall got under way; in addition to the described process supervision, an extensive measuring programme was established, so that the process could be adjusted as necessary and the quality of the finished product determined. This applied to both individual columns and for the end product, the sandwich wall. The measurement results were processed for each column, interpreted and the effect on the work still to be conducted was assessed for each future column. Preventative and corrective measures were, if necessary, taken in order to control or counteract the measured defect. In addition to the process-oriented and qualitative measurements, various independent measurement systems at the station building served as a further control in order to prevent damage to the building.

Jan 1, 2006

By Willie M. NeSmith

Cast-in-place piling are a staple of the deep foundation industry, and are used (in various forms) worldwide. In assessing the application of cast-in-place piles, it is of value to reflect on the development of the various systems, in order to understand how the current processes and equipment came to be. This paper traces the evolution of the cast-in-place industry. Emphasis is on developments in the United States; however, since there has been a substantial fusion of US and European processes, notable European developments are also discussed.

Jan 1, 2006

By M. Gous

Namakwa Sands is a heavy minerals mining and beneficiation business in the Anglo Base Metals Division, and operates along the West Coast of South Africa. The business encompasses mining, mineral concentration, separation, and smelting operations. The smelting process comprises the carbonaceous reduction of ilmenite to produce titania slag with a TiO2 content of 86%, and iron with a carbon content of 2.5%. The Namakwa Sands smelter, situated near the Saldanha Bay harbour, commenced smelting operations in 1994, when a 25 MW DC-arc furnace was commissioned. The smelting operations were expanded in 1999, with the commissioning of a second 35 MW DC-arc furnace. Despite the fact that ilmenite smelting poses a technical challenge in terms of the high temperatures required, the physical characteristics of the slag, the constraints placed on the feedstock, and the tight product specifications, Namakwa Sands has continually increased slag production since 1995. High furnace feed-on utilization and furnace stability, complemented by continuous improvement drives, will be thevehicle to drive performance in the short-term, with longer-term performance enhancements due to strategic process development. Keywords: Pyrometallurgy, Namakwa Sands, ilmenite, DC-arc furnace, titania slag, pig iron

Jan 1, 2006

By H. Boghosian

This paper presents the design and construction of a deep basement in a steeply sloping site in glacial till in Glasgow city centre. Existing foundations, adjacent structures and services, in tandem with asymmetric loading, presented particular challenges in the planning, execution and design of the project. The construction methods and temporary works, analysis by the Finite Element method and monitoring carried out are all described.

Jan 1, 2006

By S. Thorley

In engineering design of operator?s compartments, in underground mining equipment, ergonomics principles are often neglected or not given the full recognition they deserve. This paper defines ergonomics, applies it to machinery in an underground mining environment and describes the ergonomics analysis undertaken during the design phase of an EJC extra-low-profile mining loader. Encompassing the design of the operator?s compartment of this new loader, this paper illustrates the importance of ergonomics principles within the collective design process, ensuring that it is fully integrated into the design approach. An ultimate aim of this study is to ensure that all future designs follow this route to guarantee not only the outcome of a highly efficient, cost-effective and productive machine but that it is also takes the human factor into account, not only in maintenance but also in operation. Maximizing comfort will have the ultimate outcome of actually increasing productivity.

Jan 1, 2006

Pillars with width to height ratios of less than 1.0 are frequently created in underground hard rock mines. The strength of slender pillars can be estimated using empirically developed equations. However, the equations can provide variable results when the width-to-height ratios approach 0.5. This paper investigates some of the issues affecting pillar strength at low width-to-height ratios in hard brittle rock. The investigation includes an evaluation of empirical pillar strength data presented in the literature and observations of pillar performance in underground limestone mines in the eastern United States, supplemented by numerical modeling in which failure processes and sensitivity of slender pillars to variations in rock mass properties are evaluated. The results showed that the strength of slender pillars is more variable than that of wider pillars. The numerical model results demonstrated the increasing role of brittle rock failure in slender pillar strength. The absence of confinement in slender pillars can result in a fully brittle failure process, while wider pillars fail in a combined brittle and shearing mode. The onset of spalling in slender pillars occurs at or near the ultimate strength, while this is not the case for wider pillars. Slender pillars are shown to be more sensitive to the presence of discontinuities than wider pillars, which can partly explain the increased variability of slender pillar strength. Two examples are presented, which illustrate failure initiation by brittle spalling and the sensitivity of slender pillars to the presence of discontinuities.

Jan 1, 2006

By Elli Nurminen

In this work the thermodynamics of the metallic sulphate decomposition reactions were studied through thermodynamical calculations and thermogravimetric methods. The decomposition temperatures and mechanisms were determined for cupric sulphate, ferric sulphate and also for industrial flue dust from a copper flash smelting process. The aim was to determine the thermodynamic conditions for sulphate decomposition and to estimate whether the reactions are kinetically likely to take place in the flash smelting process heat recovery equipment. The information is essential in CFD-modelling of the reactions taking place in the boiler and for optimising the process.

Jan 1, 2006

By C. Pelley, S. Kelebek, G. Kunzel, S. Gregersen, M. Pollanen

A series of small-scale tests was conducted to evaluate the effect of micro-fracture development, imposed by blasting, on the material properties of the rock as well as its resistance to crushing and grinding. The uniaxial compressive strength, tensile strength, Poisson’s ratio, Pwave, S-wave velocity, point load test index, crushing, and grinding work indices were evaluated for samples without any blasting load and for samples which had received a variety of blast loads ranging from a single impact with a lowstrength detonating cord to a combination of impacts at different times and significant impacts with powder factors close to those used in practical blasts. It was shown that the rock mechanics parameters change even at low impacts, suggesting easier crushing of the rock. Damage values appear to be affected by timing as stress wave superposition affects the damage process. Fragmentation is achieved at higher impact levels while work index modification of the fragments is also observed when high powder factors are used, suggesting improvements in grinding.

Jan 1, 2006

By V. Coetzee

In 1992, a paper was compiled highlighting a common-sense approach to electric smelting at Impala Platinum. Since then, the smelter complex has undergone considerable changes. Mineral economics, UG2 exploitation, and changing environmental legislation have enforced numerous process upgrades, yet a common-sense approach has always been adopted. This document details the major changes in the smelter complex at Mineral Processes (Minpro) over the past 15 years, and provides the rationale for the changes. Keywords: Pyrometallurgy, furnace, PGM, platinum, nickel, copper, electric smelting, six-in-line, Peirce-Smith, Impala Platinum.

Jan 1, 2006

By P.J. Terbrugge

Open pit slope design has conventionally been effected as a bottom-up function utilizing available geotechnical information. This results in a decision criterion based on probability of failure and factor of Safety with a risk assessment being carried out on the proposed design slopes. The design approach recommended reverses the process using fault event tree decision methodology. The consequences of this approach are that acceptable risk criteria have to be determined by mine owners. Slopes are then designed by the technical staff to achieve these corporate goals. Benefits that arise from the process are that the owners take a proactive decision on the risk-benefit relationship allowing the technical staff to optimize the geotechnical exploration programme and design.

Jan 1, 2006

By C. Samson, R. S. Smith, S. W. Hefford

"Abstract - Time-domain electromagnetic systems are most sensitive to highly conductive targets during the transmitter on-time. Data collected during the on-time is highly influenced by the geometric relationship between the transmitter and the receiver. Unless corrections can be applied for these geometric variations, the ability to correctly detect and identify highly conductive targets can not be fully realized. Variables affecting the relative position between the transmitter and receiver include changes in the position of the receiver with respect to the transmitter, variations in transmitter attitude, and transmitter loop deformation. The level of accuracy in the determination of the relative geometry required to permit complete removal of the effects due to geometric variations is different for each of the variables and is dependent on the depth of the target. The most influential geometric variation involves changes in the relative position of the receiver with respect to the transmitter along the direction of flight; this variable, therefore, requires the highest degree of accuracy. The accuracy required for receiver motions along the vertical direction is roughly one order of magnitude less, and in the lateral direction, several orders of magnitude less. The objective of this paper is to relate the sensitivity of the response to transmitter-receiver geometry to the ability of an airborne, time-domain electromagnetic system to resolve a highly conductive vertical target. This is achieved by a detailed analysis of the effect of the individual x, y, and z distances between the transmitter and the receiver, the transmitter attitude (roll, pitch, and yaw), and transmitter deformation.Sommaire - Les systèmes électromagnétiques en domaine temporel sont particulièrement sensibles aux cibles à forte conductivité durant le temps d’excitation. Les données collectées durant l’émission du transmetteur sont fortement affectées par les relations géométriques entre le transmetteur et le récepteur. Si un facteur de correction n’est pas introduit pour tenir compte de ces variations géométriques, la capacité de ces systèmes à détecter et identifier correctement les cibles fortement conductrices ne peut pas être pleinement réalisée. Les facteurs affectant les positions relatives du transmetteur et du récepteur comprennent les changements de position du récepteur relativement au transmetteur, les changements d’altitude du transmetteur et la déformation de la boucle du transmetteur. Le degré de précision requis pour déterminer la configuration nécesaire pour compenser complètement l‘effet des changements géométriques est différent pour chacune des variables et dépend de la profondeur de la cible. Les changements géométriques qui ont le plus d’influence sont ceux qui font varier la position du récepteur relativement au transmetteur dans l’axe de la ligne de vol; c’est donc cette variable qu’il faut contrôler avec le plus de précision. La précision requise pour le suivi des mouvements du récepteur le long de l’axe vertical est moindre d’environ un ordre de grandeur, tandis que selon l’axe latéral elle est diminuée de plusieurs ordres de grandeur. Le but du présent article est d’établir comment la susceptibilité de la réponse à la géométrie transmetteur-récepteur affecte la capacité d’un système électromagnétique en domaine temporel aéroporté à reconnaître une cible verticale fortement conductrice. Cet objectif est atteint par l’analyse détaillée de l’effet individuel des distances x, y, et z entre le transmetteur et le récepteur, l’attitude du transmetteur (lacet, roulis, tangage) et la déformation du transmetteur."

Jan 1, 2006

By Edward J. Chuhta, Joseph E. Chilton, Robert J. Timko

in underground mines to measure worker exposure to various gases such as methane, carbon monoxide, and nitrogen dioxide (NO2). Even in relatively small concentrations, NO2 can produce harmful side effects in underground workers. Mines using equipment powered by diesel engines, carrying out explosive blasting operations, and performing extensive arc welding and/or cutting work will have measurable quantities of NO2 released by these processes. Workers in these areas often use gas monitors to warn of excessive gas concentrations and to help them determine when to increase ventilation air that will dilute these gases, thus minimizing exposures to this gas. Portable gas monitors, used to measure NO2 levels, must be calibrated before each use. Calibration is typically performed using a small portable pressurized cylinder containing a certified gas mixture. The certified NO2 standard mixture, usually 10 ppm NO2 concentration, is diluted with either air or nitrogen gas. To determine the stability of commercially available portable gas standards, two different cylinders containing NO2 in nominal 10-ppm concentrations were examined. One cylinder was diluted in air, the other, in nitrogen. Baseline NO2 mixtures were generated using a standard liquid NO2 permeation tube operated at a constant temperature. Final dilutions of the test gas mixtures were made with air or with nitrogen using a mass flow-controlled gas dilution system. This study showed that, when a permeation-type NO2 generator is used, the electrochemical sensors in portable NO2 monitors provide identical results for gas mixtures whether they are diluted with air or with nitrogen. Two different gas monitors, one with a two-electrode sensor and one with a three-electrode sensor, were used to measure gas concentrations in the two commercially available cylinders. One month after the cylinders were delivered, the NO2-in-nitrogen cylinder, stated to contain 10 ppm NO2, measured 8.13 ppm. The NO2-in-air cylinder, also stated to hold 10 ppm NO2, measured 6.88 ppm. Therefore, before using NO2 gas cylinders to calibrate monitors, it is recommended that their concentrations be verified either by manufacturer recertification or by comparing the stated cylinder gas concentrations to a laboratory-based permeation tube-generated standard.

Dec 1, 2005