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Kinetics of bubble-particle interaction, surface hydrophobicity and interfacial phenomena in sulfide mineral flotation are discussed in this paper. Results of the measurements of a bubble and mineral induction time (IT) and detachment force (DF), vacuum of bubble evolution (VE) and mineral floatability are discussed for pyrite, galena, chalcocite and chalcopyrite. Natural wetting and wetting induced by xanthates with different lengths of alkyl chains are examined. Experiments show the existence of several maxima of hydrophobicity on dependences of pH and electrochemical potential. These maxima are attributed as the reflection of mineral surface heterogeneity due to xanthate adsorption and the presence of cationic and anionic centres with uncompensated positive and negative charges. These charges can be neutralised by both regulation pH and applied potential. The aim of this paper is to evaluate a thickness of the rupturing film and to estimate how long the bubble-mineral interactions are according to the experimental values of IT, in order to develop a procedure for comparing of the results of DF and atomic force measurements in the same dimensionality, and to compare the results of the experimental studies on the wettability of sulfides with those predicted by the models of physics of capillarity.

Jan 1, 2005

The weathering of different types of base metal deposits in the semi-arid environment of the Lachlan Fold Belt of western New South Wales affects the geochemistry of outcropping ironstones (gossans) and derived soils. W eathering of the pyrite- and pyrrhotite-rich mineralisation at the Elura Zn-Pb-Ag deposit leads to highly acidic conditions and strong depletion of Cd and Zn throughout the profile. There are local attainments of high concentrations of Ag, As, Ba, Cu, Hg, Pb, Sb and Sn in the profile and As, Ba, Pb and Sb are still highly anomalous in surficial material (ironstone and soil). However, at Parkers Hill, in the Mineral Hill Field, the primary Zn-Pb mineralisation is pyrite-poor and so weathering is not as acidic as at Elura. Thus, although Ag, As, Cd, Cu, Sb and Zn may be concentrated at various levels in the Parkers Hill weathering profile, Cu and Zn (as well as As, Pb and Sb) are retained in surficial ironstones in essentially the same abundances as in primary mineralisation. Thus, variations in the suite of geochemical indicators present in ironstones and residual soils are likely to reflect differences in the original mineralogy and the degree of acidity produced during the weathering of base metal mineralisation. Hence, an understanding of weathering processes is necessary to fully interpret exploration geochemical data.

Jan 1, 2004

By N J. Beukes, J Gutzmer, C Reinke, M Bau

In this study the light sparse phase search (SPL_Lt) mode on the Mineral Liberation Analyser (MLA) was successfully used to identify and quantify the abundance of rare earth element (REE) phosphates in Precambrian iron formations. Monazite (light REE phosphate) and xenotime (Y and heavy REE phosphate) are identified and data from the MLA combined with the mineral chemistry of the two minerals are used to calculate and model the expected REE concentration and distribution in these two REE phosphates. The REE phosphates account for up to 31 per cent of the REEs in the banded iron formations (BIFs) and excellent correspondence is observed between the modelled REE patterns and the whole rock geochemical data available for the same samples. Except for quantifying the mineral weights, the sparse phase search also allows for the localisation of REE phosphate grains and the observation of their association with other minerals using backscatter electron (BSE) imaging. These observations are used to conclude that the REE phosphates were most likely of diagenetic origin, with REEs and phosphate remobilised from primary chemical precipitates. It is demonstrated that automated mineralogical techniques can be used to qualitatively and quantitatively describe the influence of a rockÆs trace mineralogy on its geochemistry.

Jan 1, 2008

This paper will review the experiences of both big and small exploration/mining companies (local and foreign investors), including the impediments to exploration and project development in Indonesia since the Contract of Work was first introduced there (1967 Minerals, 1981 Coal). This is seen through the eyes of a person who has been employed in a managerial capacity in large and small concerns, and more recently as an independent consultant. Comment will be made on the political, legislative and social constraints imposed by the presence of a large group of disparate artisans (illegal miners) who now form a significant component of the Indonesian mining industry; the Bre-X debacle; the impact of the recent Regional Autonomy legislation; and changes to the Mining, Forestry and Environmental Acts. An overall view (including statistics) will be presented as to how recent Indonesian developments have affected international confidence in investing in its mineral sector over the past decade and it will be placed in an international competitive context.

Jan 1, 2004

Application of Agitated Leaching for Iron Removal from Silica Using Sulfuric and Hydrochloric Acid In this research, iron removal from silica used in glass industry was investigated using agitated leaching method. Silica sample was provided from silica concentrate originating from Chalchoog Silica Mine located in Abhar, Iran. The sample contained silica, iron oxides and clay minerals. For characterization of samples XRD and XRF analysis and atomic absorption method were applied. Silica and iron oxide (Fe2O3) grade of head sample was 98.41 per cent and 0.067 per cent respectively. Two inorganic acids (sulfuric and hydrochloric acid) were used in agitated leaching tests. Two series of L9 orthogonal array of Taguchi design with replication were used to determine the effect of parameters including acid dosage, leaching duration, ambient temperature and solid content on iron removal. The statistical calculations and analysis of variance (ANOVA) were carried out by means of DX7.0, Minitab14.0 and Winrobust1.02 softwares and also statistical calculations were checked manually using Excel software. Also multivariate regression was applied in order to forecast Fe2O3 conent of final product. The optimum conditions for leaching tests which sulfuric acid was employed are as follows: 40 minutes leaching time, temperature of 85¦C, 40 g/L acid concentration and solid content of 20 per cent. Under this condition the amount of iron oxide in silica was decreased to 0.042 per cent. The optimum conditions for leaching tests which hydrochloric acid was employed are as follows: 80 minutes leaching time, temperature of 75¦C, 30 g/L acid concentration and solid content of 20 per cent. Under this condition the amount of iron oxide in silica was decreased to 0.035 per cent.

Sep 13, 2010

By L C. Thompson

This paper examines six sites in Northern Nevada where soils and groundwater have been contaminated with petroleum hydrocarbons and/or organochlorine compounds. All six of the sites studied are located in an arid, highly mineralised area of the Great Basin. As a part of the original geochemical investigation to determine the applicability of biodegradation in the remediation of petroleum impacted soils and aquifers extremely high levels of uranium, vanadium and molybdenum were detected in the anaerobic groundwaters associated with some of the hydrocarbon plumes. Some groundwater uranium concentrations exceeded 7 ppm while vanadium and molybdenum concentrations reached almost one ppm. The bioleaching appeared to be most effective under methanogenic conditions and was noted in both high sulfide and low sulfide environments. Background concentrations of uranium in the formation were measured between 6 ppm and 109 ppm and highly dependent upon depth with the highest levels being found in association with evaporites. Unlike uranium, vanadium tended to concentrate in free-floating organic fractions reaching levels as high as 2000 ppm in the layers of jet fuel floating above the groundwater. Molybdenum was the most resistant of the three metals to bioleaching.

Jan 1, 2004

By B Hu, B Zhang, J Wang, H Ma, D Liu, L Han

Zeolites are potential carriers of slow release fertilisers due to their unique phenomenon for salt occlusion. A comparative study was performed on the capacities of potassium nitrate (KNO3) occlusion in molten KNO3 treated synthetic 4A and 13X zeolite molecular sieves with main channel sizes of 0.41 x 0.41 nm and 0.74 x 0.74 nm respectively. The results show that in a laboratory setting, the treated zeolite 4A contained 13.57 per cent of occluded KNO3 and the treated zeolite 13X did not contain any. This was confirmed by the regular release of K+ and NO3- during washing both treated mixed samples with water and by their IR spectra and TG analysis. There are also changes of the relative intensities of peaks in X-ray diffractograms of both treated zeolite samples. K+ release from molten-KNO3 treated zeolites in deionised water and simulated soil solution shows that release of K+ from KNO3 occluded in zeolite 4A are slow and steady. Proper size fit between the channel size of zeolites pore and the size of K+-NO3- ion pair of KNO3 is the decisive factor for zeolites to occlude KNO3.

Jan 1, 2008

By M I. Pownceby, A Torpy, C Johnson, N C. Wilson

To extract uranium from low-grade, calcrete-hosted uranium (CHU) ore is challenging owing to the presence of carbonate and swelling clay gangue minerals that require an alkaline lixiviant to be used. Western Australia possesses ~75 000 U3O8 t in CHU resources. Improvements to alkaline leach extraction practices would improve the economic potential of these deposits.A column leach study of CHU ore was run for 105 days using an alkaline carbonate-bicarbonate lixiviant. The uranium content of the liquor plateaued after 75 days at ~275 mg U/L; the calculated maximum solution capacity was 800 mg U/L. Spiked peaks and troughs were seen in the data set beyond the 60th day, where concentrations ranged from 220 - 290 mg U/L, indicating possible cyclic uptake and loss of uranium from the solution.Pristine and leached ore samples were geochemically analysed and mineralogically characterised at high resolution using a field emission gun-electron probe micro-analyser (FEG-EPMA). Results showed that leached ore samples from the top of the column contained less carnotite than pristine ore. In contrast, leached ore samples from the column base contained regions with more carnotite than pristine ore, indicating precipitation. Three carnotite grain micro-structures were identified in the leached ore; fan-spherulite, granular and core-shell cubes, with evidence for multiple growth phases.Evidence of carnotite precipitation was seen at the edge of and in pore spaces within montmorillonite and dolomite grains. The point of zero charge of both minerals is lower than the pH of the lixiviant (pH 10.8), thus the mineral surfaces are negatively charged and would not attract UO2(CO3)34- ions out of solution. Similarly, the decrease in the uranium content of the lixiviant is not attributed to super-saturation, as this was unlikely to have been achieved. Work is ongoing to understand the reason for carnotite precipitation and the fluctuations in the lixiviant uranium concentration that are seen.CITATION:Johnson, C, Pownceby, M I, Wilson, N C and Torpy, A, 2013. Microscale characterisation of pristine and processed ore - implications for leaching calcrete-hosted uranium ore, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 303-316 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

The aim of this paper is to broadly review the purposes of valuations and the methods used to calculate them. Examples are provided by coal and alluvial gold properties. Important factors are consistency, how to deal with uncertainty, and the selection of discount rates. The purposes of valuation are seen as: 1.  valuations for sale; within this category are sales to third parties, sales between partners, and vendor valuations for prospectuses; 2.  to provide bankable estimates for financing; and 3. to provide values for local body rating. The methods used depend on the purpose of the valuation and the amount of information to hand.

Jan 1, 1988

By Johnson G. D

Confidence in Yakabindie becoming a truly cost competitive nickel project has risen recently because of: ò the emergence of an economically effective contract mining climate; ò the delivery of cheaper energy via the Goldfields Gas Pipeline; and ò the development of the Yakabindie Process for production of nickel cathode and cobalt by-product directly from sulphide concentrates at site, dramatically cutting capital and operating costs compared to the conventional route. Development of the Yakabindie Process was a result of 'necessity being the mother of invention'. Yakabindie can now break out of the trap of relying on existing downstream processors to treat an intermediate, and instead the project can gain direct market access. The very attractive cost advantages demonstrate that hydrometallurgical processing of sulphide concentrates is a worthy prize. Improved cobalt recoveries, and tolerance of higher levels of magnesium and arsenic than allowable by smelters, are further advantages of this approach. Leach residues are combined with much larger quantities of naturally alkaline flotation tailings and remain at site. As a result the process is more environmentally sensitive than the conventional smelt/refine route, with no sulphur dioxide gas emissions and 'metal only out the gate'.

Jan 1, 1996

By C A. Fleming, C J. Ferron, P T. OÆ

A new process is described which allows for direct recovery of base and precious metals (Au and PGMÆs) from sulphide concentrates or other feedstocks. The process was developed initially for application to ores or concentrates that are too low-grade for economic treatment by the conventional smelting and matte leaching process (for PGMÆs). It is now believed that the process may be widely applicable to a variety of materials including PGM concentrates containing high amounts of chromium or magnesium. Operating conditions have been identified under which gold, the PGMÆs and the base metals dissolve simultaneously in a pressure leaching autoclave. The product of this leaching process can then be treated by one of several flowsheets, of which the preferred will likely involve solid/liquid separation, followed by precipitation (or adsorption on activated carbon) of gold and the PGMÆs, followed by copper solvent extraction/electrowinning. Depending on the concentrations of nickel and cobalt, the copper raffinate would either be partially recycled to the autoclave to allow Ni/Co concentrations to build up, or it would proceed directly to a Ni/Co refinery. This paper deals with the pressure leaching process and the recovery of gold and the PGMÆs from the pressure leach product.

Jan 1, 2000

The metallurgical testwork program is generally the most important critical path item for the completion of a bankable feasibility study and hence can become the critical parameter for financing of potential mining projects. This paper presents generic detailed testwork programs suitable for bankable feasibility studies for a gold leaching and polymetallic flotation study. The design of the metallurgical testwork program for each of the two differing processes is discussed and the critical factors that effect the selection of the testwork programs are highlighted. The importance of the metallurgical testwork results in predicting the metal recoveries and cash flow prediction for the project is presented. The detail of the testwork programs costing is broken into activity based methods based on the laboratory and management hours/costs, such that generic rule of thumb costing guidelines can be generated. The scheduling, costing and importance of the metallurgical testwork program to process feasibility studies are discussed in this paper.

Jan 1, 2000

The paper will review the fundamental policy issues and options that have been considered in the determination of the proposed allocation and pricing (ie royalty) regime for minerals under the Crown Minerals Act 1991. It will consider such influences on the new disposal, allocation, pricing and management arrangements for the Crown's mineral estate as the existence of prior ownership claims, exclusivity in access, the requirement for cost recovery and the treatment of contingent liabilities.

Jan 1, 1993

Acid rock drainage (ARD) derived from sulphide oxidation and the associated metal leaching is the most significant environmental issue facing the mining industry today. Under given hydrological and biogeochemical conditions, the local geology and mineralogy largely control the formation of ARD. The involvement of a geologist is therefore essential in minesite ARD assessment and prevention. The relevant tasks that a mine geologist may undertake at three major phases of a mining project are briefly described. Additional knowledge that a mine geologist should acquire in order to achieve proficiency in ARD assessment is also suggested.

Jan 1, 1993

Increasing attention is being focussed worldwide on the strategic environmental assessment of mining projects, including consideration of cumulative environmental effects. In New Zealand there is now an end in sight for inappropriate delays in resource consent approval of responsible mining projects. This paper investigates six case examples of recently consented mining and quarrying projects, whose applications were notified. It also explores the nature of delays that occurred, the factors that contributed to the delays, and whether the consent process delivered fair and effective public participation and desirable environmental outcomes.

Jan 1, 2005

Both blast furnace and steel furnace slags have been used extensively and successfully on main line railroads in the United States for more than 25 years. Annually, these slags are being used as ballast at the rate of about 4 million tonnes of blast furnace slag and 1 mil- lion tonnes of steel furnace slag, much of it on main line with 90 metric tonne car loadings. More steel furnace slag would be used if it was available. Both slags meet all the specification limits of the American Railway Engineering Association. Actual use on high density rail- roads has confirmed the long range economics of their use. Comparison of laboratory tests, such as Los Angeles abrasion, with actual field per- formance has shown conclusively that commonly used laboratory tests can not be used to accu- rately compare the quality of various types of ballast materials.

Jan 1, 1979

A universal grinding circuit model suitable for an arbitrary structure of flowsheet has been suggested. In this model classifiers and mills are described in a most general form. What puts the model in a class by itself is the automatic mass balancing in all streams of the circuit. In order to provide this a special classifier model is adopted. A previously published continuous steady state process model is used as a grinding model. Non-linearity of classifier model leads to a resultant circuit model which is equivalent to a non-linear integral equation. It complicates somewhat calculation algorithm in comparison to that of linear model, but provides a physically meaningful solution.

Jan 1, 1993

Hindustan Zinc Limited (HZL) is one of the leading base metal producers in India. It operates a two-smelter Complex at Visakhapatnam, Andhra Pradesh. At this zinc-lead smelter zinc is manufactured by the conventional hydrometallurgical route and lead is produced by Blast furnace technology generating residues or wastes which contain substantial quantities of metal values. Disposal of such wastes is a problem in any non-ferrous industry. Both the stringent environmental regulations and the changing industrial scenario emphasise the need for industrial research to find economically viable and environmentally friendly technologies to recover the metal values from these waste materials. The in-house R&D Centre at Vizag Zinc Smelter (VZS) thinking globally re-engineered its activities and major thrust was given for converting waste to valuable metals and metal compounds. Basic analytical chemistry with the hydrometallurgical concepts has been adopted in developing these innovative technologies. In this paper attempts are made to provide a clear history of the different waste raw material, the process developed for each raw material and their superiority of over other parallel work. Most of the processes described here are pilot plant tested and under patenting. The process flowsheet, results obtained and advantages of each process are presented. This paper provides a consolidated approach through which the varied smelter waste materials can be processed with cost effective and eco-friendly innovative technologies. In-house R&D efforts at VZS with its contribution and achievement in converting æwastes into wealthÆ technologies are presented in this paper on the following the major thrust areas:recovery of zinc from liquid effluent; recovery of zinc from effluent treatment plant (ETP) gypsum sludge; production of highly pure electrolytic zinc metal powder from zinc bearing gypsum residue/sludge generated at the effluent treatment plant; hydrometallurgical recovery of copper as copper sulphate solution which can be used for CuSO4.5H2O, copper cathode/copper metal powder from copper-cadmium cement; recovery of manganese, lead and silver from anode mud generated at Zinc Cell House and 4-metal extraction/recovery of manganese, cobalt, copper and nickel from Indian ocean bed manganese nodules; recovery of zinc, lead, silver and sulphur values from silver concentrate residue generated at the froth flotation process; recovery of silver and lead as lead-silver sponge/lead-silver sulphide concentrate from lead bearing residues; recovery of lead, silver and copper from copper matte; recovery of antimony as antimony metal or lead-antimony master alloy from antimony bearing dross; and recovery of nickel and dimethylglyoxime from Ni-DMG complex.

Jan 1, 2000

By L McCarthy, B W. Cuffley, O K. Thomas an

The Central Victorian Goldfield is a world-class field located in Victoria, Australia. It is currently undergoing a revival through activities in the Bendigo, Ballarat, Tarnagulla, Maldon, Castlemaine and other fields. Sediment-hosted auriferous gold-quartz reefs that are structurally and geometrically complex dominate the region. To date, no remote methods have been developed to assist in the targeting of the discrete high-grade oreshoots that characterise the mineralisation. An understanding of the structural setting and controls, and thus likely frequency of repetition of oreshoots remains the main exploration tool. Gold within the reefs is generally characterised by both its coarse nature (>100 up to 10 000 microns) and erratic distribution; as a result, most of the Victorian deposits are classed as high- to extreme-nugget effect systems. This characteristic ensures that mineralisation is very challenging to explore, evaluate and exploit. The key issues facing the explorer and miner are related to effective sampling, and definition of geological and grade continuity, and ultimately grade and tonnage. Tonnage can often be estimated to a reasonable level of confidence, whereas the grade estimate generally carries a medium- to high-level of uncertainty. In these deposits, surface diamond drilling alone is generally only able to define an Inferred Mineral Resource, with underground development, closely spaced in-fill drilling and bulk sampling/trial mining required to define Ore Reserves. The extraction of gold from ores is relatively simple, based on the coarse nature and hence amenability to gravity recovery. Ground conditions and the need for in-stope grade control (eg mapping, sampling etc), generally point toward mechanised cut-and-fill as the primary stoping method in the region. To potential investors this style of mineralisation has been viewed as high risk, because of the associated low confidence in the grade estimate, general paucity of Ore Reserves at mining start-up and need for underground development at the Feasibility Stage.

Jan 1, 2004

By D Craw, C Smith, C Martin

The Wangaloa coal mine closed in 1989, and an attempt to grow Pinus radiata on quartz-rich overburden dumps was not successful. The site is currently being rehabilitated with re-profiling and native plant establishment. Plants are being established in a range of substrates that consist of variably disaggregated Tertiary coal measure sediments derived from the mine sequence. This material has low organic matter content (typically <10 %), originating from coal fines or carbonaceous sediment. Substrate samples were collected during December 2003 from a range of sites varying in age, slope, and parent material. Nutrient analysis includes nitrate, ammonia, total N, total P, available P and readily exchangeable base cations. Total nitrogen and phosphorus are low on areas of recently disturbed, quartz-rich overburden, with total N =1200 mg/kg, and total P =200 mg/kg. Background forested areas have total N ranging between 2800 - 3300 mg/kg and total P of 420 - 500 mg/kg. Quartz-rich overburden sites contain available nitrogen levels of less than 6 mg/kg, while background forested areas are generally >20 mg/kg. The soils and water runoff are generally acid, with pH down to three. Water samples have been collected from both ground and surface resources on a monthly basis since December 2003. The main lake on the site had pH of 4.6 in 1999, and this remained relatively unchanged when 850 tonnes of lime were added in 2002. However, the lake pH changed to 6.4 within a one month period in 2004, and has fluctuated since that time.

Jan 1, 2004