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By O N. Antzutkin, W Forsling, K J. Pike an

The adsorption mechanism of three different O,OÆ-di-alkyl-dithiophosphate (dtp) collectors, K[S2P(OR)2] with R = Et, i-Bu and i-Amyl, on the surface of synthetic chalcocite (Cu2S) was studied by means of solid-state 31P CP/MAS NMR spectroscopy. The morphology changes on the conditioned Cu2S surfaces, in the collector concentration range 0.1 - 10 mM, were also monitored with scanning electron microscope (SEM). In order to assign Cu(I)-dtp species on the surface of Cu2S, the corresponding bulk Cu(I)-dtp compounds, which are clusters of the monovalent copper containing either Cu6(antiprismatic) or Cu8(cubic) cores, were synthesised, and characterised by means of solid-state 31P CP/MAS and static 65Cu NMR. Further investigations on the crystal habits of the bulk systems were carried out by powder x-ray diffraction and SEM. A comparative analysis of the 31P chemical shift and chemical shift anisotropy (CSA) data estimated from the experimental NMR spectra of the polycrystalline bulk Cu(I) dialkyldithiophosphate complexes was used for assigning the 31P resonance lines in the NMR spectra of the collector treated Cu2S powder samples. The species formed on the synthetic Cu2S surfaces were assigned to polycrystalline phases of: Cu6L6 with L = Et2dtpû, Cu6L6 and Cu8L6(S) with L = i-Bu2dtpû, and Cu8L6(S) with L = i-Amyl2dtpû. A heterophase autocatalytic step process of both formation and growth of solid CuxLy (L = R2dtp, x = 6 or 8 and y = 6) complexes on the collector treated Cu2S surface is proposed. A possible role of the oxidised form of dithiophosphate collectors, bis[di-alkyl-thiophosphoryl]-disulfane (disulfide), is discussed in terms of a specific self-redox reaction. The second order quadrupolar lineshapes in 65Cu NMR spectra were simulated and the interaction parameters, CQ and hQ, for the bulk dialkyldithiophosphato-copper(I) complexes were obtained.

Jan 1, 2005

Longwalling has reached a high standard both in Germany and Australia and most improvements should be expected in planning, monitoring and control. Double drum shearer have electric drives to 1000 kW and automatic height control is under development. Conveyor pans to 40mm thickness and chains to 2300 kN breaking load are in use with controls for pretension and load compensation under test.Trends in support are towards two leg shields with loads to 3850 kN per leg and electrohydraulic controls. Expert systems have been devised for planning and diagnosis tasks. With increases in technical standards, staff qualification standards at rising too, drawing attention to training requirements for modem personnel.

Jan 1, 1991

By Lockhart D. A, Gleeson P, Lang S. C

The Glenrock Group forms the uppermost part of the Early Devonian to Early Carboniferous Burdekin Basin sequence in the Townsville hinterland, north Queensland. As redefined, three formations make up the Glenrock Group. The Percy Creek Volcanics (base), the dominantly epiclastic Mount Douglas Formation, and the Horse Pocket Volcanics (top). The Ellenvale beds unconformably overlie the Mount Douglas Formation and Percy Creek Volcanics and have been excluded from the Glenrock Group as defined by Wyatt and Jell (1980). Three facies associations are recognised in the Mount Douglas Formation: Alluvial Plain facies, Alluvial Fan facies and Lacustrine facies.Deposition of the Glenrock Group, began with the eruption of massive basalt and basaltic andesite lavas, probably in a volcanic arc setting. With time, the volcanism evolved to become more dacitic to rhyolitic in composition. Waning of the volcanic activity appeared to coincide with uplift of source areas (probably to the west). Deposition on an alluvial plain during this waning volcanic cycle, gave way to alluvial fans at the margins of the uplifted terrain. As the uplift ceased and the system became more mature, the alluvial fans gave way to widespread lakes. Rhyolitic ignimbrite and airfall tuff, interbedded with the alluvial plain, alluvial fan and lacustrine facies, indicate that some volcanism continued, probably vented in the uplifted terrain to the west.

Jan 1, 1990

Coal is of tremendous importance for the Czechoslovak econ- omy. The current annual primary energy demand being about 109 million tons of standard fuel (1 ton of standard fuel - 7,000 coal = 29,308 GJ), coal satisfies almost two thirds of our fuel consumption. If compared with the distribution of resources in the world's fuel and energy pattern, the situation in Czechos- lovakia is significantly different, as shown in Fig. I. One of the causes behind the difference is that the Czechoslo- vak oil and natural gas reserves and, hence, their production are insignificant, so that it is necessary to import them. Brown coal will continue to play an important role as a prin- cipal domestic source of primary energy even in the future. While the share of nuclear power is increasing, brown coal represents strategic reserves in the fuel and energy balance.

Jan 1, 1989

By W Dodson

Major ions, d18O and d2H and Carbon-13 concentrations in groundwater from 30 bores near an open pit iron ore mine were used to better understand the chemical evolution of groundwater in the aquifer. The relatively depleted d18O and d2H isotopes of groundwater from various depths suggest that groundwater is recharged from intense rainfall events, with little evaporative effect. The 300 to 500 mg/L increase of major ions relative to that of rainfall is due to evapotranspiration of rainfall during recharge. Geochemical mass balance modelling suggests that the evapotranspiration of rainfall during infiltration through the unsaturated zone varies over six fold from 20 to 130. This coupled with the dissolution of CO2 from the unsaturated zone and partial dissolution of carbonates and gypsum from Tertiary sediments and carbonates from the Wittenoom Formation accounts for the current major ion, d18O and d2H distribution in groundwater. Despite the relatively dissected morphology and steep hydraulic gradient the results of this study highlight the dominance of vertical flow relative to horizontal flow. The study also shows the dominance of rapid recharge by significant rainfall events as an important component of the water budget for east Pilbara aquifers.

Jan 1, 2009

Since the introduction of the Neil George Five Point Safety System, to the underground sections of The Zinc Corporation, Limited and New Broken Hill Consolidated Limited mines in March, 1969, the Disabling Injury Frequency Rate has been halved and shows signs of contin- uing to fall. The total accident frequency rate has also fallen, although the decrease has not been as significant. Before the introduction of the Neil George Safety System, analyses of the direct causes of accidents showed that approx- imately 25 per cent were caused by "unsafe conditions", while 75 per cent were attribu- table to "unsafe acts". Within twelve months of introducing the system, these percentages had significantly changed to 7 per cent unsafe conditions and 93 per cent unsafe acts. Today, the figures are 3 per cent and 97 per cent respectively, and these figures clearly show that the main emphasis in the current programme must be directed towards making the operating men safety conscious. The effort must be focused on changing the minds of men.

Jan 1, 1975

By M Simpson, K Brodie, J L. Mauk

Subaqueous water-rock reactions that occur at the pit wall/lake water interface can affect the pH of pit lakes. Many pit lake water chemistry models neglect subaqueous reactions, which may create inaccurate predictions over time. A mineral quantification method is presented that defines the wall rock mineralogy of active open pit mines, using samples collected from the Martha Mine, a low-sulfidation epithermal Au-Ag deposit in Waihi, New Zealand. The mineral quantification method has five components: field observations and sampling, X-ray diffraction analyses, selection of representative samples, geochemical analyses, and mineral accounting. Predicted mineral concentrations closely match observed mineral concentrations visually estimated using petrographic techniques. Results of the method can be incorporated into a geochemical model of long-range pit lake water quality resulting from subaqueous water-rock reactions.

Jan 1, 2003

A Study on Process Mineralogy and Mineral Processing of Complex Carbon-Bearing Cu-Pb-Co-Ni Multi-Metal Sulfide Ore by Bulk Flotation

Sep 13, 2010

By Allen RL, Clifford BA, Wright JV, Bull S

The Bunga Beds of the Late Devonian - Boyd Volcanic' Complex is a well exposed succession of rhyolite, sedimentary rocks and minor basalt outcropping along the south coast of New South Wales. The sedimentary rocks vary from shallow water basin margin facies, to deep-water basin centre facies, and the majority of .the volcanics are associated with the deep water facies association. The volcanics are dominated by rhyolite domes, lavas and cryptodomes, whose margins are extensively autobrecciated and quench fragmented. In situ pyroclastics represent a very minor volcanic component and are restricted to the remnants of two small doors- top tuff cone successions. Pyroclastic debris is common in the sedimentary succession enclosing the volcanics and was clearly derived from shallow to emergent basin margin areas through mass-flow redeposition. The succession has bearing on the origin of the fragmental component of, the volcanics that host Kuroko- type massive sulphide deposits. The characteristics of these fragmental volcanics are not well documented. We suggest that based on the Bunga Beds,'Kuroko-type volcanic successions are dominated by coherent rhyolite/ felsic lavas and intrusive domes, autobreccias and hyaloclastites, that in situ pyroclastics are rare or lacking, and that redeposited volcanic debris is abundant. Pyroclastic debris is most likely to have been derived from shallow areas marginal to the deep-water volcanic centre that produce the Kuroko-type volcanics and sulphides.

Jan 1, 1987

By Binns RA, Murao S

The PACMANUS and Jade deposits are two active hydrothermal fields that are forming massive sulfide deposits at the Pacific rim margin. Both are associated with felsic submarine volcanic rocks and both occur in back-arc settings. However, PACMANUS is associated with almost sediment-free dacites and lies on the crest of a volcanic ridge, whereas Jade occurs in a heavily-sedimented tectonic depression associated with a basement of pumiceous rhyolite. The PACMANUS deposit is richer in Cu and Au, and Jade in Pb. Zinc, Ag, As and Sb contents are similar. Sulfide textures at PACMANUS suggest formation of Cu and Zn sulfides by simultaneous double-diffusion involving inwards-moving seawater mixing with outwards-moving hydrothermal fluid. By contrast, at Jade there is a more complex history of formation where initial growth of barite on the sediment surface, probably associated with microbial activity, formed an impervious cap which trapped higher temperature hydrothermal solutions.

Jan 1, 1995

This paper describes some experiences in the design of flotation reagent schemes for the efficient flotation of complex gold ores containing free gold and/or gold associated with easily flotable sulphide minerals such as chalcopyrite and bornite. Historically, the design of gold flotation reagent schemes has been based primarily on experiences using high dosage levels of water soluble charged collectors such as xanthates and dithiophosphates and carefully controlled regions of pH. This approach has been effective with gold associated with complex sulphide minerals, in particular gold associated with iron sulphides such as pyrite. An alternative two-stage reagent approach is presented that is applicable to certain types of gold ores. This approach involves using very small dosages of uncharged water insoluble collectors at natural ore pH followed by a modified bulk flotation reagent approach for the second stage. The reasons for utilising this approach, when applicable, are discussed and illustrated with examples.

Jan 1, 1997

Since 1865 when Congress moved to create a Federal Mining Bureau, successive legislations have given rise to the current '!Federal Coal Mine Health and Safety Act, 1969. Coal beds from 22 feet to 20 feet thick are mined under covers from 50 to 2800 feet with full and partial pillar recovery equally popular and accounting for a total of 54% of the mines. Pillar recovery and roof support practices vary, and each operator must submit an overall roof control plan (within specific guidelines) for approval before undertaking any development. The guidelines relate to dimensions of openings, details of support, sequence of extraction, limits of extraction and caving details. Experienced and professional staff of M.E.S.A. provide roof control plans and make inspections and grant-approvals of principles of support and minimum support in pillar extraction, with provision for modifications with time. Guidance is given with training programmes and standards of supervision. All of these aspects are approached in the spirit of the Congress declaration that the first priority and concern must be the health and safety of the miner.

Jan 1, 1974

Oxy-ACETYLENE system of welding and cutting is at present practised in two forms, which may be described as the high and lowpressure systems. In the high-pressure system the two gases, oxygen and acetylene, are delivered. to the blow-pipe under pressure from properly constructed trade cylinders. Oxygen cylinders are in two sizes, each containing 100 and 200 cub. ft. of gas respectively. These cylinders are charged to a pressure of 120 atmospheres, or 1800 lb. per sq. in. approximately. The acetylene cylinders are made in one size as far as the writer knows, and contain 200 cub. ft. of acetylene gas at a pressure of 10 atmospheres. Each cylinder is provided with a valve and connection for attaching a regulator to "break down" the high pressure in the cylinders to the necessary low working pressure of the blow-pipes, and to deliver the two gases at a constant pressure irrespective of the variable pressures in the cylinders. These regulators can be adjusted down to as low as 1 lb. and are provided with two pressure gaugesone reading the contents of the cylinder in atmospheres, and the other the working pressure in lb. per sq. in. The high-pressure, or "two cylinder" system is compact and can readily be transported from place to place in the works. For this purpose the two cylinders are mounted on an easy-running 4-wheeled truck, which the operator and assistant find no difficulty in manipulating. In the low-pressure system the two gases are delivered to the blow-pipe, one from the oxygen cylinder and the other from the acetylene gas generating plant, which consists of the following:Generating cylinder, half filled with water, into which the cathoide is plunged. The generated gas is passed through a filter to the gasometer, then through a water washer on to the hydraullic seal...

Jan 1, 1922

By Y B. Kang, Y J. Park

Ti-added ultra-low carbon (ULC) steel is produced by adding Al and Ti during the secondary refining process to deoxidise molten steel and to bind C and N which are detrimental to the deep drawing quality of the steel product. However, the production of Ti-added ULC steel faces challenges, including submerged entry nozzle clogging and surface defects on cold rolled coils. The troubles were often attributed to ‘Al-Ti complex inclusions’ in the molten steel. However, the evolution of oxide inclusions including their stability has been still unclear. In the present study, the evolution of these inclusions in Ti-added ULC steel was investigated by phase diagram measurement, CALPHAD thermodynamic modelling, high-temperature stability test for the oxides, and observation of transient behaviour of oxide inclusions in the steel. The phase diagram of the Al-Ti-O system was elucidated with an emphasis on oxygen potential, which significantly controls the stability of the oxides. CALPHAD thermodynamic models and a self-consistent database were developed. The transient behaviour of Al-Ti complex inclusions in Ti-added ULC steel was observed in situ using a confocal scanning laser microscope. This was additionally validated by the new thermodynamic model. The equilibrium phases of the oxide inclusions were investigated using a high-temperature resistance furnace, and were analysed using a secondary electron microscope, energy dispersive spectrometer, and electron back-scattered diffraction. By considering the morphology and crystal structure of these inclusions, the evolution of Al-Ti oxide inclusions was elucidated. Various behaviour of Al-Ti inclusions and their influence on steel cleanliness are discussed.

Aug 21, 2024

By Gray J, Krouse HR, Changkakoti A, Kwak TAP

The Dachang tin field with more than one hundred million tonnes of ore at 1% tin and 3% Zn is one of the largest tin fields in the world. It comprises five carbonate replacement tin deposits, of which the Changpo deposit containing about 80 million tonnes of ore at about 1% tin is the largest deposit. The deposit, hosted by middle Devonian limestone, argillaceous limestone and black shale, is genetically related to the Longxianggei granite.The oxygen, hydrogen and carbon isotope data of minerals, rocks and fluids suggest a magmatic fluid which evolved during the crystallization of the Longxianggei granite. Mass balance calculations show that the depletions observed in 180 and 13C values of calcites from the ore bodies to the country rocks were due to continous isotopic exchange reactions between the magmatic fluid and the marine limestones at different W/R ratios and between 300 and 600¦C.

Jan 1, 1990

By S Miller, A Neale

As part of a long-term acid rock drainage (ARD) mitigation study, PT Freeport Indonesia has completed the construction of a highly instrumented, full-scale, experimental, overburden stockpile to further evaluate the behaviour of the waste rock system at Grasberg mine. A total of 24 lysimeters, 30 sets of thermistor strings and 48 oxygen-sampling ports were installed at select locations during stockpile construction. ARD flow rates and chemistry have been recorded since the start of overburden rock placement in April 2000. Measurements of in situ temperatures and oxygen concentrations quantify reaction rates and the oxygen pathways that control oxidation kinetics deep within the waste rock profile. Direct field observations show the significance of advective oxygen flow with respect to the onset of oxidation kinetics. Oxygen measurements show that the rubble zone that forms at the base of a waste rock bench provides a critical pathway for oxygen entry to the waste rock profile. Furthermore, rapid oxidation as evidenced by measured temperature increases deep within the panels of waste rock is observed to occur. The observations presented in this paper provide critical insight for understanding the mechanisms and behaviour of full-scale waste rock stockpiles with respect to ARD generation. The results of this program will assist in the future selection, testing and evaluation of appropriate mitigation measures with respect to surface and face treatments to reduce long-term ARD generation. This project is a work in progress, and at least another two-years will be required to fully understand site-specific ARD generation and ARD mitigation mechanisms. This paper will discuss various design and construction considerations, provide an overview of results achieved to date, and some preliminary interpretation of what is happening within the overburden stockpiles.

Jan 1, 2003

High pressure (-1.2 GPa) Early Cretaceous granulite facies orthogneisses in Fiordland, New Zealand are in tectonic contact with a cover sequence comprising mid-Palaeozoic amphibolite facies metasediments, subordinate metavolcanic rocks and syntectonic granitic orthogneisses. This cover sequence and the underlying granulites constitute upper and lower crustal plates of a mid-Cretaceous metamorphic core complex whose emplacement was linked to continental rifting and the Late Mesozoic breakup of the Pacific margin of Gondwana. Exhumation of the lower plate granulites occurred in two stages. The first stage was associated with extreme attenuationand tectonic denudation of the cover sequence accompanying emplacement of the core complex, leading to rapid uplift of the granulites but without generating the large volumes of Fiordland-derived sedimentary detritus normally expected if uplift and erosion were the only factors involved in unroofing the granulites. Final uplift and exposure of the granulites at the surface occurred mainly during the last 10 Ma in response to transpression across the mid-Tertiary Alpine Fault and/or the obduction of Fiordland continental crust over oceanic crust of the Tasman Sea.

Jan 1, 1990

By Mason P, Waller C

The Phase I electrowinning system at KCGM's Fimiston Operation utilised the well proven technology of electrowinning precious metal values onto steel wool followed by calcining and direct smelting to bullion. The above process, while reliable and successful, was to some extent labour intensive. The Williams Mine in Ontario, Canada had published conditions under which precious metal values are electrowon onto woven stainless steel and directly removed using high pressure sprays. The current paper describes the testwork which was carried out to check the applicability of the Williams criteria to KCGM eluates arising from the elution of highly loaded carbon from the calcine circuit and lowly loaded carbon from the float tails circuit. Information is also given on the commissioning and operational experience which occurred.

Jan 1, 1996

In 1976, The Zinc Corporation Limited Broken Hill set up a plant to re-process a hill of tailing (Mt. Keast) from the original treatment operations. With the likely disappearance of this source of feed in 1985, an investigation was initiated to determine what other feed sources might be available. This involved searching through old records and photographs as well as a subsequent drilling campaign. The paper briefly covers the history of treatment operations and describes, as a result of the information obtained, the likely future sources of feed.

Jan 1, 1983

Recent data contributions to New Zealand Mesozoic terrane geology confirm the consensus interpretation that New Zealand grew by the progressive addition of material by plutonic and accretionary processes along the Gondwana margin. The data also (1) emphasise the discontinuous but inter-related nature of these processes of continental growth, (2) better establish a direct Gondwana correlation of the Western Province and probable Gondwana provenance of at least some of the Eastern Province, (3) suggest specific times and places when passive or strike-slip rather than subduction regimes are recorded along the south Gondwana margin, and (4) potentially lead to interpretations emphasising parautochthonous rather than far- travelled relationships between many New Zealand terranes.

Jan 1, 1995