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By V. ?. Chanturiya, I. Zh. Bunin, M. V. Ryazantseva

"Surface changes in naturally occurring metal sulfides (pyrite, arsenopyrite, sphalerite, chalcopyrite, galena, and molybdenite) due to treatments from high-power electromagnetic pulses (HPEMP) at varying times were studied using X-ray photoelectron spectroscopy. Analysis of the obtained results revealed common patterns and differences in surface transformations. The transformations were found to include two main stages. The first stage was observed at low treatment intensities (up to n ~103 pulses). At this stage, formation and accumulation in the surface layer of the nonstoichiometric sulfide phase, oxides and hydroxides, as well as elemental (polysulfide) sulfur and/or metastable sulfur species (thiosulfate, sulfite) was observed. The second stage (N = 3·103 pulses) is characterized by thermal removal of sulfur species and renewal of the mineral surface (sulfidization).It was found that the chemical changes of the sulfur on the surface layer of pyrite, arsenopyrite, chalcopyrite included accumulation/formation of S0 (Sn 2-) at the first stage of the transformation, followed by its removal. An increase in the surface concentration of elemental sulfur for pyrite and chalcopyrite was 10–12% while arsenopyrite was approximately 5%. A more complicated chemical change was observed for sphalerite and galena, that included formation/accumulation of metastable sulfur species (thiosulfate, sulfate) at the initial stage (up to 103 pulses) and during longer treatment times, the sulphur is reduced back to its initial state (sulfide or disulfide). The increased concentration of S0 sulfur, compared to the original sample, was only 3% in galena and sphalerite.The application of HPEMP treatment to improve flotation selectivity is supported by singlemineral flotation tests. Changes in flotability as a result of HPEMP treatment are principally explained by surface phase changes that resulted in higher adsorption activity."

Jan 1, 2016

By Yongquan Zhu, Zhengguo Zhu, Zhichun Liu, Chao Kong, Xinqiang Gao

"The aim of the study is to have a good understanding of the change in the seepage field during and after the tunnel excavation in weathering alteration rock. Field tests are used to monitor the changes of the water table and the numerical model is used to analysis the influence of the seepage filed with different operation conditions during and after the tunnel excavation. Results indicate that the depth, diameter and pumpage of precipitation well are the main factors that have a great influence on the drainage effect. Results also indicate that different operation conditions had various effects on the decrease in water yield during tunnel construction and the recovery in groundwater level after construction.INTRODUCTIONAs a potential disease during tunnel construction, Gushing water not only affected construction schedule, increased construction cost, as well as affected tunnel stability and safety during operation, but also decreased ground-water level. What’s more, the fall of water table caused by gushing water in tunnel would have influenced surrounding residents’ living water, agricultural water and ecological environment around tunnel. In recent years, enough emphasis has been paid to the influence on environment due to the construction of tunnel as a result of the reinforcement of people’s environmental protection awareness.As a result of water collection and drainage after excavation, groundwater was discharged into the tunnel, which caused a loss of water resources in the adjacent mountain mass. Furthermore, during tunnel operation, it was difficult for groundwater level to resume its original condition, which caused a bad ecological environment, because drainage system during tunnel construction destroyed its original hydrologic dynamic balance.In order to study whether decreased groundwater level resulting from tunnel construction could be restored during operation to its original condition, this paper gave a field monitoring on tunnel displacement during construction and simultaneously, generalized model of regional hydrogeology was created according to field hydrogeology to carry out a calculation of stable seepage flow and draw comparisons between recovery conditions of various water levels."

Jan 1, 2015

By Xiaoqiong Wang, Daobing Wang, Fanbao Meng, Jianbo Wang, Hongkui Ge

"Shale gas has become an important unconventional oil and gas resources. Its effective development relies on comprehensive and accurate understanding of shale gas reservoirs. Rock mechanical properties is one of the important components of reservoir evaluation. Two adjacent black shale samples, which are cored from the depth of 1145 meters in Chongqing, southwest China, are subjected to acoustic emission(AE) test under uniaxial stress and compared with coarse grained granite. The results of synchronous AE, stress-strain and ultrasonic velocity experiments show that shale has weak anisotropy. Compared with granite sample, two shale samples are similar, but their strength, velocity and brittleness are quite different, indicating that shale has strong microscopic heterogeneity. TOC, XRD, SEM microstructure analysis show that total organic content, mineral composition and natural fractures are the main impacting factors for mechanical heterogeneity. INTRODUCTIONShale gas is a typical low-grade marginal resource, which is characterized by ultra-low matrix permeability and small single well control volume. In order to enable commerical development, complex hydraulic-fracture networks must be created in the shale to allow gas to escape from the micro/nano-pores and natural fractures where it is trapped in the rock (C. Clark et al.,2013; Ge et al., 2013). The development of shale gas requires accurate evaluation methodologies to evaluate shale reservoir properties and predict production. (Jarvie et al., 2007). Rock mechanical properties are an important part of the reservoir evaluation. It is significant for efficient drilling, completion and hydraulic fracturing to understand mechanical behavior of shale gas play (John, 2011; Wei, 2013).Rock mechanical properties mainly include heterogeneity, anisotropy, brittleness and acoustic emission activity (Lockner et al., 1992; Jerome et al., 2009; He et al., 2010; Liang et al., 2012). Shale mechanical properties are evaluated from laboratory tests following a complex workflow that covers tasks from sampling to testing (Md. Aminul Islam et al., 2013). It is common to include various experimental methods such as stress-strain curves, ultrasonic velocity and acoustic emission when evaluating the mechanical properties (Rao et al., 2006). Because of the presence of organic-rich matter, mineral composition orientation and natural fractures, shale tends to have strong anisotropy and heterogeneity (Deng et al., 2004; Wang et al., 2013; Hathon et al., 2013)."

Jan 1, 2015

By O. Hall

STOPING at Noranda" is a sequel to "Mining at Noranda". "Mining at Noranda", presented in 1937 (1), sketches Noranda's history, metallurgical problems, exploration, mining methods, mining details, pillar extraction, and costs. "Stoping at Noranda" deals in greater detail with our stoping, the use of sub-level drifts instead of benches, and the drilling out of the stopes with jointed rock drill steel and diamond drills. Sun-LEVEL DRIFT STOPING: Sub-level drift stoping is almost universal throughout the mine and is the standard sroping method in both sulphide ore and rhyolite flux ore. The features that have led to the adoption of this standard are: (1) Continuous symmetrical drilling in sub-level drifts with no delay for blasting. (2) Large-tonnage blasts Saturday night after the drillers have left. (3) Comparative freedom from gas and smoke during the working days. ( 4) The daily safety achieved by having all stope drilling done in drifts. (5) The safety and security achieved by drilling out stopes, floors, and pillars before there is any weighting or cracking.

Jan 1, 1939

By Chris G. Dobson

Introduction The Britannia mine is at Britannia Beach, on Howe sound, approximately thirty miles from Vancouver. The first claims were staked in 1898, and a local company was formed at that time to develop them. In 1904, Mr. Grant B. Schley became actively interested in the property and in the following year the Britannia Mining and Smelting Company, Limited, was incorporated to operate it. This Company was taken over a few years later by the Howe Sound Company, Limited. The mine comprises five more or less separate ore-bodies, which have produced approximately 20,000,000 tons of ore to date. The East Bluff ore-body, with which the present paper deals, is well suited to large-scale mining by means of carefully placed powder blasts. It covers approximately an acre and lies in the slate footwall, in a bay produced by a fault. The hanging-wall side, on the west, forms the face of the Bluff glory-hole, which extends to the 1,200 level. A portion of this ore was available for breaking into this old glory-hole, below which four bulldoze chambers could quickly be built. Mining of this block is complicated by a very soft footwall, which 'runs' badly when broken. In stoping, care is taken to guard against the hazard of dilution by deliberately leaving a small portion of ore on the footwall. Some of this will undoubtedly be lost, but it is hoped to recover a fair amount of it after the major drawing is completed. The deposit occurs in a greenstone which has been highly silicified following brecciation. The chief minerals are chalcopyrite, sphalerite, and pyrite. Concentrates of copper, zinc, and pyrite are made at the mill. The average grade of ore runs 0.7 per cent copper, 1.5 per cent zinc, and 0.03 oz. gold per ton. The rock, which is practically a chert, is extremely hard, but shatters well. Both in stoping and drifting, holes must be closely spaced and powder used generously. Development When development work started in the East Bluff, there were no raises and only one drift on each level in this section of the mine. After blocking out the ore by thorough diamond drilling, a production of two thousand tons per day was set as a goal. To obtain this tonnage from so small an area required a great deal of carefully planned and well timed development work.

Jan 1, 1935

By J. Doucet, C. Price

In an industrial setting, operational changes are continually introduced, driven by new technologies or changing economics. Because of day-to-day variability, quantifying the impact of these changes based on metallurgical performance requires long trial periods to achieve statistically significant results. Tools and techniques developed by the mineral processing group at McGill University have allowed for direct measurement of process variables (e.g., bubble size, gas and solid holdup). Two case studies are described where direct measurement techniques were used to evaluate: a) a new rotor stator mechanism; and b ), the introduction of a new frother type. Application of these methods has accelerated the evaluation of process changes and improved confidence in results.

Jan 1, 2009

By George Langford

Introduction The manufacture of ductile beryllium is one of the most interesting problems confronting the metallurgist today, and one which becomes more acutely in need of resolution as the uses for beryllium increase. Beryllium belongs to the hexagonal group of metals along with zinc, magnesium, and cadmium. The melting point of the metal is about l,280°C. ± 5°C. Due to its brittleness, the metal's chief use is as an alloying agent in copper and iron. The very low absorption coefficient of beryllium for x-rays makes the metal ideal for x-ray windows, and, similarly, because of its low capture cross-section for neutrons, the metal holds a preferred position in the field of nuclear physics. Modern x-ray diffraction methods were responsible for explaining the mechanism whereby zinc metal, although brittle when cast, could be made ductile at room temperature. The diffraction patterns of zinc and magnesium indicated the importance of the parts played by recrystallization and preferred orientation in this mechanism. It was with this in mind that an Investigation into the recrystallization and preferred orientation of beryllium was undertaken. The investigation, after a series of experiments were conducted involving cold-working and annealing, yielded the recrystallization temperature curve for beryllium. Both the texture of preferred orientation and the effect of recrystallization on this texture when subjected to compressive stresses were also determined. W. A. Alexander, J. K. Swinton and L. M. Pidgeon, in their investigation on The Recrystallization Temperature of Beryllium (C.I.M., Trans., Vol. L, 1947, pp. 657-664), utilized the Brinell ball as a means of cold straining the metal. Sufficient strain was developed to estimate the recrystallization curve for the metal. However, in order to determine the lowest recrystallization curve, as well as to develop a preferred orientation structure, larger deformation than that possible with a Brinell ball was required. The plastic deformation of beryllium can be carried out at an elevated temperature above 700°C. Above 850°C., the metal is quite ductile and can be readily compressed or extruded.

Jan 1, 1948

By M. E. Holter

"Five main lignite seams occur in the Tertiary Ravenscrag Formation in the Eastevan area, at depths of 100 feet or less. They are named, in ascending order: the Boundary, Estevan, Souris, Roche Percee and Short Creek seams. A total sequence of approximately 250 feet is represented by the coal beds and interstratified clays, silts and sands. Strata dip to the southeast at 25 feet per mile or less and trike northeast. Large areas underlain by coal seams at shallow depths are delineated. Reserve calculations are dependent on detailed information on seam thicknesses and feasible stripmining depths. The stratigraphically higher seams are thinner on the average than lower seams and this, together with the increase in elastic size fractions in higher strata, suggests a retreat of a Tertiary marine margin to the south during the closing depositional history of coal seams and associated strata."

Jan 1, 1972

By Shintaro Takamiya, Kazunari Yoshida

"Recently, small sized micro-needles for medical are required more frequently by patients. The biggest reason is that it presents great burden on the patients, due to the size of the needle injection. People need to use a very small needle to lower the pain, but the downfall is that it makes them more expensive due to their complicated manufacturing method. Therefore, we need to fabricate a needle by wire-drawing to decrease its price. Tube-drawing is beneficial for its production value; however, in conventional tube-drawing it is difficult of control the wall thickness of the tube and makes it 1mmor lower in diameter. That is why, we propose fluid-mandrel drawing for new tube drawing. This method allows fabrication of a fine tube by using the pressure of the fluid in the tube. In this research, the goal is the fabrication of a fine tube by fluid-mandrel drawing and its evaluation. Finally, the fabrication of a fine tube by fluid-mandrel drawing was conducted and in result a tube with a diameter of 0.2mm, high strength and thin wall and fine inner surface was drawn, which can be used as a lesser pain micro-needle.INTRODUCTIONThe main manufacturing method of the current medical needles is roll forming. With this method, it is difficult to make a tube with a diameter lower than 1mm. Deep drawing has been proposed and used as method to further reduce the diameter, but this method is costly and the injection needle obtained by this method is several times more expensive.Therefore, we need to obtain a fine medical needle by drawing process that can be mass-produced and inexpensively manufactured. However, with the conventional drawing process, it is not possible to obtain a syringe needle with a reduced diameter easily, that is why, a fluid-mandrel drawing has been proposed which can reduce the diameter without damaging the inner surface. The methodology of the method is, a fluid is filled in the sealed tube and the pressure inside the tube during drawing is responsible for the good inner surface and wall thickness. It is also expected that the fluid can be easily discarded and that the tube can be manufactured on a long scale."

Jan 1, 2017

By M. Mbonimpa

Field experimental cells were constructed in 2007 to assess the performance of different cover scenarios for the reclamation of the Parc 1 tailings disposal facility at the Westwood-Doyon Mine site (Abitibi, Quebec). Three configurations of cover with capillary barrier effects (CCBEs) with different thicknesses and material types for the moisture retention layer (MRL) were studied. MRL with 80 cm till, 40 cm till, and 40 cm clayey silt were used for cell nos. 2, 3, and 5, respectively. The capillary barrier layer (CBL) and drainage and protection layer (DPL) of the CCBE consisted of 30 cm gravel. A reference cell without cover was also constructed to compare the geochemical performance of the CCBEs. Due to an unexpected flooding in the leachate exit area of the cells in spring 2008, the cell instrumentation for hydrogeotechnical monitoring was postponed to spring 2009. Changes with time in volumetric water content, suction, soil oxygen concentration, and temperature were measured at different depths. This paper presents and discusses preliminary results obtained from spring 2009 to autumn 2010. In all cases, the degree of saturation Sr is lower in the CBL than in the MRL, indicating the presence of capillary barrier effects at the interface of these layers. Cell nos. 2 and 5 showed hydrogeotechnical behavior typical of an effective CCBE, with Sr maintained above 85% in the MRL and lower than 30?50% in the DPL and CBL. Based on the obtained results, and as expected, MRL thickness and the type of construction material used appear to affect the hydrogeotechnical behavior of the CCBE. Oxygen concentration profiles through the CCBEs were used to estimate the oxygen flux, and results indicate that cell nos. 2 and 3 performed better than cell no. 3. CCBE performance is currently being investigated using the geochemical monitoring data.

Aug 1, 2013

By C. R. Larsen, R. G. Bradburn, A. L. Mular, B. C. Flintoff

"Following the acquisition of grinding- circuit data at Brenda Mines Limited for simulation purposes, various methods to mass balance the circuit were evaluated. Unfortunately, different answers were obtained for different balancing methods. A data-adjustment procedure was therefore developed. The procedure assumes that all ""best-fit"" criterion. A search is conducted with the minimum set of water masses and narrow size ranges of solids around the circuit (called search variables), which permit the computation of any of the measured data points. Search variables are used to calculate measured values for an objective function of the form: [ ] where W, is a weighting factor•, M1 is a measured value and M. is a corresponding . value calculated from search vanables. The best values of M, are those which minimize R. The above method is compared with others that have been utilized for mass balancing circuits."

Jan 1, 1976

By A. Rodriguez-Prado, R. L. Legge, W. C. Lennox

ABSTRACT It is possible to adequately describe chemical reduction of hexavalent chromium, Cr(VI), in industrial and mining wastewater in constructed wetlands by applying different kinetic models (e.g., halforder, second-order). Accounting for hydraulic transport of contaminants in reduction equations can also improve such description. The authors developed an explicit advection-dispersion bulk flow equation and applied it to model Cr(VI) reduction in laboratory wetland mesocosms. The results indicated that the model adequately described wetland exit Cr(VI) concentrations and Cr(VI) reduction, representing an improvement over the commonly used graphic method and potentially improving the wetland design.

Jan 1, 2014

By B. D. Pandey, M. S. Kim, B. S. Kim

The recovery of Sn from used Pb-free solder (Sn, 3~4 % Ag, < 0.9 % Cu, < 1.2 % Pb) has been investigated by electrorefining in sulfuric acid solutions containing small amount of hydrochloric acid. This involved preparation of the anode material by melting and casting the used solder followed by refining. During electrorefining, dendritic tin was deposited on stainless steel cathode. Increasing the amount of hydrochloric acid up to 0.3 mol /L in the electrolyte enhanced the current efficiency to 92.2 % and the enrichment ratio of silver to 94.3 % in the anode slime which was otherwise 84.7% and 81.6 % in absence of HCl, respectively. The electrolyte containing hydrochloric acid has also prevented the precipitation of tin oxide in the bath. In the scale-up experiment using 1.6 kg anodes, 84.3 % current efficiency and close to 100 % Ag enrichment ratio were obtained, while the purity of electro-refined tin was over 99.9 %. The energy consumption of the winning process was found to be 0.151 kWh /kg-Sn which is competitive as compared to commercial tin electrorefining processes.

Jan 1, 2014

By G. Song

Magnesium has excellent bio-compatibility in terms of its density, strength, elastic modulus and toxicity. However, due to its poor corrosion performance, so far magnesium has not been successfully used in the human body as a permanent implant material. Nevertheless, there is a possibility to utilize the low corrosion resistance of magnesium to make magnesium into a temporary implant component that can gradually dissolve in the human body after surgical region heals. This will avoid the secondary operation to remove the temporarily implanted component and the chronic inflammatory discomfort caused by the implant. This paper is aimed at exploring the possibility of using magnesium as a degradable bio-material through investigating the corrosion behaviors of pure magnesium and surface treated magnesium in a simulated body fluid (SBF) solution. It was found that magnesium corroded rapidly in the SBF solution, resulting in vigorous hydrogen evolution and a strong alkalization effect. Hence, it is impractical to use magnesium as a permanent implanted material or even a degradable implant. However, a proper anodizing treatment can significantly improve the corrosion resistance of magnesium, and hence slower down the hydrogen evolution and alkalization processes, which will allow to control the corrosion or degradation of magnesium at a desired rate in the human body. With a controllable corrosion rate, it is believed that magnesium as a degradable implanted material will be eventually achievable.

Jan 1, 2006

By A. Longval, Q. Jiao, T. Shannon

In 2000, Xstrata Zinc (former Falconbridge Ltd.) Brunswick Smelter commissioned a modified lead blast furnace. Since then, efforts have been made to improve its operation in order to achieve optimal operation in terms of coke consumption, lead loss to slag, and improved environmental and hygiene conditions. This paper will review the important step changes in operational philosophy, undertaken since 2004, for the control of the blast rate, oxygen enrichment in blast, slag chemistry and charge level. Furthermore, a review of the improvements made in secondary materials consumed at the blast furnace will be made. This paper will also discuss the significant reduction of the frequency of accretion removal as a result of improved furnace operation.

Jan 1, 2008

By S. Parkash, A. J. Szladow

Vigorous agitation of suspensions of coking coals in water (or light mineral oils) will often result in catast rophic loss of caking properties. It is shown that this deterioration is not a consequence of oxidation of the coals (by dissolved oxygen), but that it can be qualitatively connected with internal "solid-state" reactions which appear to derive their activation energies from cavitation of the liquid.

Jan 1, 1971

By P. A. Bahri, D. G. Dixon, T. M. Woodward

A comprehensive mathematical model of the Sherritt-Gordon ammoniacal pressure leaching process at K winana Nickel Refinery has been constructed. The process is comprised of six autoclaves functioning as a three-stage leach circuit, operating over the temperature and pressure ranges of 85-95°C and 750-1000 kPa, respectively. The process chemistry forms a complex series-parallel reaction network, characterised by: (1) the gas-liquid mass transfer and reduction of oxygen, (2) the oxidation of eight distinct minerals, (3) the oxidation of sulphur, and successive reactions involving various intermediately oxidised sulphur species, and (4) the oxidation of Fe(II) to Fe(III), and subsequent precipitation as a hydrated ferric oxide. Material balances were developed for species in all three phases, and an energy balance to account for all reactions and phase conversions. The multiple convolution integral (MCI) statistical reactor model was employed for the scale-up of particle kinetics. The model has been validated against plant data, and simulation results are in agreement with plant performance.

Jan 1, 2005

By Q. Chen, J. H. Zhang, M. Zhang, F. M. Zheng, Y. J. Zhang

The characteristics of air bubbles and gas dispersion in KYF flotation cell are studied using the method of the point conductivity probe and CFD simulation. With increasing of speed, the velocities of air bubbles increase slowly and the distribution of diameters exhibits little change. With increasing of aeration rate, the gas holdup is increased. However, the velocities and diameters of bubbles have no great change. The CFD predictions on gas holdup have good agreement with the experiment results. The gas holdup distribution in the center section is revealed. The gas dispersion in the middle and upper part of flotation cell is uniform. It would be helpful for bubbles and solid particles collision. The gas holdup of the lower part of flotation cell is scarce, and it agrees with the observation in experiment. The gas would accumulate at the suction side of impeller blades, and it would decrease the power consumption. The rotating speed and aeration rate have great effect on gas dispersion. With increasing of aeration rate, the gas holdup of flotation cell will increase. The increasing of speed would improve gas dispersion. The results are expected to help to optimize the performances of KYF flotation cell.

Jan 1, 2015

By Leroy C. Stewart

Owing mainly to the use of ethylene dibromide in the production of tetraethyl lead for gasoline treatment, there has been a tremendous increase during the past decade in the demand for bromine. In the United States, production, derived mainly as a by-product from the treatment of brines from salt wells, rose steadily from about two million pounds in 1924 to nine million pounds in 1931. In 1936, production amounted to between 20 and 21 million pounds. Much of the increase during the past four or five years has been due to the operation of the Ethyl-Dow Chemical Company&apos;s plant, which extracts bromine directly from sea water. The process employed by the Ethyl-Dow Company is somewhat similar to that in use on salt-well brines at their plant at Midland, Michigan, but whereas these brines contain around 1,300 parts per million bromine, sea water contains only 65 to 70 p.p.m.-about as much as the waste effluent in the brine process. By intensive research, however, a process was developed whereby a very considerable percentage of the bromine content of sea water could be recovered, and at a satisfactory operating cost. In its essentials, the process consists in liberating the bromine from the sea water by treat-ment with chlorine, blowing the bromine out of the water by a current of air, and finally absorbing it in a solution of soda-ash.

Jan 1, 1938

By P. Belley

Prior to 2006, the filtration unit for leached sludge treatment (filter press) permitted the filtration, washing and drying of cake to 17% (w/w) moisture. That year saw moisture content abruptly increase to 20% (w/w), drastically changing the rheological properties of the cake. The cake became sticky and agglomerated. This led to major disruptions of operations and plant capacity (cake release and cake conveyor problems, complicating the subsequent steps of the process). The conditions for the filtration, washing and drying, were simulated to ease cake unloading without aggravating dust emissions (moisture about 17% (w/w)). All of the laboratory tests yielded a moisture content above 17% (w/w). Therefore, we concluded that the moisture problems were not due to a recipe change in primary material, but to an operational problem in the filter press. Through the laboratory results, the filter press operating conditions (washing ratio, drying pressure and drying time) were optimized to enable a reduction in cake moisture to 17% (w/w).

Jan 1, 2007