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By M. Hitch, M. B. Lytle

Resource development conflicts arise largely due to differences in worldview between those who support and those who oppose development. This paper illustrates how societies and civilizations with different worldviews produce different levels of creative and economic energy. A questionnaire was created to build a database of responses to test whether worldview and resource development are correlated. Factor and multivariate regression analysis determined correlations for respondent groupings. Results showed a positive correlation between the respondents\u2019 worldviews and their attitudes toward resource development. Correlations became stronger as the homogeneity of the sample subgroups increased.

Jan 1, 2017

By D. T. White

"Metallurgical extraction processes often call for the heating of aqueous slurries. Indirect heat exchangers are generally not feasible for service with high yield stress slurries because of low heat transfer rates. It is more appropriate to heat the slurry by direct contact, typically with steam as the heating medium. Although having a long and successful history, direct-contact heat transfer to aqueous slurries has been used without the support of pilot plant research. This paper provides results of the needed research, the work being done at a scale large enough to enable direct scale up to commercial operations. A pilot plant heater was constructed and tested to develop an understanding of the slurry heating process and to ensure that commercial scale heaters were appropriately sized.INTRODUCTIONPressure Leaching OperationsPressure leaching operations are often used to oxidise sulphide gold ores, or for extraction of nickel and cobalt from laterite ores with sulphuric acid. Where there is sufficient sulphur available, the exothermic pressure oxidation reactions can be self sustaining at temperatures as high as 225 ºC, without having to preheat the feed slurry. At lower sulphur levels, slurry preheating is required. This is typically achieved by utilising the flash steam released from the slurry letdown stages and contacting this directly with cold incoming slurry ahead of the autoclave. The vessels where this slurry-steam contact is made are known as heaters or condensers, with the number of pre-heat stages varying, depending on how much heat is evolved in the oxidation reaction (Mason, 1990).In nickel laterite pressure acid leaching processes, which operate between 245 and 270 ºC, the only significant exothermic reactions are those associated with dilution of sulphuric acid in the leach. As a consequence, slurry preheating with flash steam is always used commercially. In practice the number of flash steam preheating stages required varies from 1 to 3, driven by a number of factors, including other uses for flash steam and the upper temperature limit at which preheated slurry can be pumped. A diagram of a typical pressure acid leach train is shown in Figure 1.For pressure acid leaching operations and at low sulphur levels in pressure oxidation, boiler generated direct steam addition to the autoclave is required to sustain the reaction temperature. For this reason it is imperative that the flash steam – slurry heat transfer is efficient and the slurry temperature approaches that of the flash steam closely."

Jan 1, 2012

By Silvana Costa

The quality of life in remote mining communities is a significant factor that impacts the mining industry?s ability to attract and retain high quality workers in remote areas. The rapid growth of mining development, along with the shortage of skills and training globally are reflected in an increasing need to identify the ideal conditions for employee wellbeing and investigate ways to improve quality of life of miners and their families in remote locations.

May 1, 2007

By P. J. Adams

Environmental regulations require means for controlling emissions of SO2 NOx and particulate when burning coal. The combustion of coal in limestone fluidized beds is one of the most promising techniques for the necessary reduction in emissions. Fluidized-bed firing, furthermore, offers potential economies in capital equipment. The world's largest steam generator applying fluidized-bed techniques was built under the sponsorship of ERDA and installed in Rivesville, West Virginia. This paper describes the design and discusses the start-up and development difficulties which were experienced during the period from initial operation to current readiness for commercial operation. Other developments leading to utility and industrial fluidized-bed steam generating equipment are reviewed. The future potential of this promising technique is discussed.

Jan 1, 1979

By A. H. Lang

Introduction Tin continues to be as much a strategic metal as it was during the war. This situation is due to the fact that the tin mines in the major producing areas of Malaya and the Netherlands East Indies have not yet reached their pre-war production. Moreover, the world requirements for tin in certain fields, particularly in the food pack industries, are steadily increasing. At present, tin is still under International allocation by the Combined Tin Committee, of which Canada is a member nation. This Committee reviews periodically the availability of refined tin for export from the producing countries and makes allocations of tin to ensure equitable distribution to the consumer countries. In 1947, availability permitted an allocation of only 70 per cent of stated requirements. From 1935 to 1938 the price of tin in New York averaged 49 cents a pound and during the war the price in Canada was controlled under a subsidy programme at levels from 60 to 70 cents per pound. Just recently, this price has been raised to 96 cents. The value of the Canadian production amounts to about half a million dollars annually and the whole of this is obtained as a by-product of the lead-zinc-silver ores of the Sullivan mine in British Columbia. In 1947 Canada's imports of tin were 3,961 long tons valued at over $6,000,000. In addition, tin plate to a value of $8,000,000 was imported from the United States; the tin content of this is estimated to be from 650 to 700 long tons. An increase in domestic production would, therefore, be of great national importance, and the present high price may make the search for and development of tin deposits more attractive than it has been in the past. Although no one can foretell what future prices will be, there is reason to believe that, unless there is a drastic downward revision of production costs, the price will be maintained at present levels for some years. A number of tin occurrences are known in Canada, but none of these have been developed for their tin content alone.

Jan 1, 1948

By J. A. Bos, Z. Dai, P. Quinn, A. Lee

A flowsheet is being developed for processing Thompson ultramafic low-grade nickel ores. This type of ore is characterized by high content of serpentinized magnesium silicates which generate slimes during comminution. Flotation of this type of ore proves difficult due to problems associated with the slimes. The flowsheet, based on extensive laboratory and miniplant flotation tests, consists of two key components: desliming by hydrocyclones prior to flotation and using soda ash for pH control in flotation. Satisfactory metallurgical results have consistently been achieved in laboratory full circuit simulation and miniplant tests.

Jan 1, 2009

By Olav Mejia

The rising energy costs and environmental considerations in mining necessitate the development of energy-efficient copper and gold processing plants. This paper presents an analysis of technical strategies aimed at reducing energy consumption in these plants. Key approaches include the integration of advanced ore sorting technologies, High Pressure Grinding Rolls (HPGR), Coarse Particle Flotation (CPF), and high-intensity flotation. Ore sorting enables early-stage waste removal, reducing the downstream processing load and associated energy use. HPGR technology, recognized for its energy efficiency, contributes to significant energy savings in comminution circuits by reducing reliance on traditional grinding methods. CPF technology further optimizes flotation performance by enabling the recovery of larger particles, thereby decreasing the need for fine grinding and reducing overall power demand. High-intensity flotation units enhance separation efficiency and mineral recovery in a compact footprint, offering further reductions in energy consumption. Together, these technologies provide energy saving opportunities to achieve a more sustainable and economically viable processing operation. This paper evaluates the effectiveness of each method, highlighting their potential impacts on energy consumption, operational efficiency, and cost-effectiveness in copper and gold processing

May 4, 2025

By C. R. Julian

THE large pyrites ore-bodies, the underground mining of which is to be described, are situated at Rio Tinto in the Province of Huelva in Southern Spain. The situation of the different ore-bodies with relation to one another is shown in Figure 1. It will be seen on the plan that the strike of the ore-bodies is approximately east and west. The geology of the district has been very fully described by Dr. D. Williams (1), so that for the purposes of this paper it will be sufficient to give briefly the salient features o each of the two larger ore-bodies which are being mined by underground methods at the present time. (a) San Dionisio.-This ore-body is the largest single deposit in Rio Tinto, having on its upper levels a length of 3,500 ft. On the upper levels the average width is approximately 200ft. but in places on the lower levels there is a width of 900ft. of un broken pyrites. Diamond-drill holes, without running out of ore, show the ore-body to persist to a depth of at least 1,600 ft. The ore-body in the upper part lies between slate and porphyry walls, but in depth is enclosed in porphyry walls. (b) South Lode.-Faulting is considered to be responsible for the break in the solid ore between South Lode and San Dionisio. On the upper levels, the South Lode ore-body has an unbroken length of 4,000 ft. The massive pyrites has a maximum width of 300ft. and an average of about 100 ft. Ore has been proved to a depth of 1,000 ft., at which depth the ore-body is much reduced both in length and breadth. This ore-body, to the depth at which it has been proved, lies entirely between slate and porphyry walls. The South Lode and the San Dionisio ore-bodies are mined both by open-cast and by underground methods. There is evidence that these mines have been exploited intermittently during the last 3,000 years; but, as is to be expected, no records are available of the tonnage mined prior to the time of purchase by the present company.

Jan 1, 1940

By P. Latostenmaa, O. Forsén, M. Lundström, J. Aromaa

The history of electrolytic copper production in Finland is closely connected with the industrialization of Finland and events of the Second World War. Production of cathode copper by electrowinning from the processing of Outokumpu ore started in 1913 based on the Hybinette nickel process, however due to the poor performance of this process, the plant was closed in 1929. Outokumpu commenced copper smelting at Imatra in eastern Finland in 1936 producing blister copper for refining outside the country. Due to the threating military situation, a new electrolytic copper refinery was built in 1941 at Pori in western Finland to refine the anodes. This was the first electrolytic copper refinery in Finland. It was built with 108 cells having a capacity of 12,000 tonnes/y. In addition, the smelter was relocated to nearby Harjavalta in 1944–1945. To fulfill the war reparations included in the peace treaty with the Soviet Union, a doubling of the smelter capacity was realised, with the Pori refinery capacity increasing to 20,000 tonnes/y in 1946 by adding additional cells. The cornerstone of Finnish metallurgical technology — Outokumpu flash smelting — was invented with the new technology commissioned at Harjavalta in 1949 replacing the electric furnace and providing a further increase in copper output with subsequent enlargement of the refinery. By 1963, the plant consisted of 380 cells with a capacity of 48,000 tonnes/y of cathode copper. The Pori electrolytic copper refinery has operated continuously since 1941. Commencing in 2004 the Pori refinery has been part of the Boliden group of Sweden. The most recent plant upgrade was in 2007 with the installation of permanent cathode technology. In 2017, the production of the Pori refinery was 133,000 tonnes of copper cathode, 2,300 tonnes of nickel sulphate, along with 66 tonnes of silver and 4.6 tonnes of gold. This paper describes these outstanding achievements. INTRODUCTION In 1809 the Kingdom of Sweden was defeated by the Russian Empire in the Finnish War, and Finland was annexed by the Russian Empire as the autonomous Grand Duchy of Finland. Finland’s commercial and industrial interests were developed to serve the Empire’s needs. Finland had raw materials, but at the start of the 20th century Finnish industry was based on the use of wood as raw material and agricultural products. The mining industry was only a few percent of the country’s industrial production.

Jan 1, 2019

By J. Visman

"Cyclone separators of different design are being used in increasing numbers in the coal industry of today. One recent addition, the Compound Water Cyclone, is finding application in the North American and Australian coal fields for the beneficiation of coking coals and for the reduction of sulphur and ash in steam coals. In this paper, the combination of specific-gravity separation, thickening, classification and water recovery are discussed. All of these operations can now be accomplished by means of cyclones that are effectively combined in circuits of compact design. In the layout of such integrated plants, three main sections are distinguished, namely: a Main Section for cleaning the plus-28-mesh fractions; an Effluent-Beneficiation Section for treating the minus-28-mesh fractions; and a Water-Recovery Section, where the wash water is reconditioned, and the fine solids are removed in a semi-solid state as slugs or pellets. Depending on the nature of the coal and the specifications of the purchaser, water-cyclone circuits can be flexibly combined with HM Cyclones and froth flotation, as well as with ancillary equipment for dewatering and drying."

Jan 1, 1968

By C Carbonneau

In order to successfully produce columbium pyrochlore concentrates, St. Lawrence Columbium and Metals Corporation had to face two principal problems met in several new operations but possibly made more acute than usual owing to the newness of the project. 1.-The ore is particularly complex, as it is made up of an elaborate intermingling of carbonates and discontinuous ultra-alkaline rock bodies of various ages and types in which no less than seventy mineral have been re-ported. Obvious petrographic or structural controls are lacking. Ore boundaries have to be defined on the basis of assay results and the determination of several minerals which occur in trace amounts. 2.-The pyrochlore concentrates produced had to com-ply with a set of stringent specifications. This fact, combined with the low Cb205 content of the ore, necessitated the use of a beneficiation process that would have to operate at a concentration ratio greater than 100:1. A brief description of the mill circuit is given. Mill stability was obtained through extensive mineralogical study of the mill feed coupled with close geological and engineering control of the mining operations.

Jan 1, 1965

By M. Stogran-Baker, E. Legault-Seguin

"Fluorspar mining in the St. Lawrence area of Newfoundland and Labrador began in the 1930s and ended in the mid-1980s. In 2013, Canada Fluorspar (NL) Inc (CFI) discovered a new ore body, the AGS vein, which proved amenable to more economic open pit mining methods and began developing this resource. This paper discusses the flowsheet development of the AGS vein deposit. Testing at SGS began in 2009 with samples from other deposits in the area. The testwork included pilot-scale dense medium separation (DMS), laboratory-scale flotation tests to develop the flowsheet and a flotation pilot plant. The more recent work that is presented here has been devoted to the AGS vein, and included a variability testing program that gave tremendous insight into the metallurgical drivers of processing the deposit. The ore was found to be fairly variable in terms of fluorite grade, but also gangue mineralogy, which had greater implications on the DMS performance. The gangue mineralogy was also found to significantly impact the grindability characteristics of the DMS product. This paper will detail the testing conducted and the mitigating steps which were identified for the operation.INTRODUCTION Fluorspar is the industrial trade name for the mineral fluorite (CaF2), which is the primary industrial source of fluoride. There are a number of categories of fluorspar, most notably acid-grade fluorspar and metallurgical fluorspar (metspar). Acid-grade fluorspar has stringent specifications and is suitable for the production of hydrofluoric acid that is used for many applications. The typical specifications of acid-grade fluorspar are >97% CaF2 and less than 1% each of SiO2 and CaCO3, with a particle size distribution in the order of 80% passing 100 µm. Metspar is typically used for metallurgical purposes, typically as a flux in smelting, and has significantly more relaxed specifications (< 15% SiO2). The principle source of fluorspar in Canada has been from the Burin Peninsula in Newfoundland and Labrador. More than 3 million tonnes of fluorspar were produced there between 1940 and 1978 and from 1987 to 1990, when production ceased (Fulton & Montgomery, 1994)."

Jan 1, 2018

By R. B. Throndycraft

"1. Belt-Drop Agglomeration Preferred at Heap Leach Operations. The agglomeration method now preferred at heap leach operations utilizes belt-drops along conveyors. Belt-drop agglomeration is being designed into numerous upcoming heap leach operations. It offers substantial capital cost savings over previously favored drum agglomerators. It has such significant operating and maintenance advantages that some drum agglomerators have been retired in favor of belt-drops.The majority of heap leach operations are now built with crushing included in the flowsheet. If crushing is included, belt-drop agglomeration can be added for almost no cost. The agglomeration equipment is simply a few conveyor transfers, designed to provide the tumbling and rolling action which forms the agglomerates. Controlled water sprays are needed at each of these agglomeration transfers. Cement or lime is added as a binder, to stabilize the agglomerates. This reagent is also needed to raise pH to safe operating levels.Addition of the pH control reagent before stacking the ore offers a reagent cost benefit. In the belt-drop mixing technique, the ore is intimately mixed with the lime (or cement). After stacking on the heaps, when the cyanide solution is sprayed onto the high-ph ore, very little cyanide is consumed. Without the pre-addition of lime or cement, the leach solution is sprayed onto neutral ore. The mixture of high-pH leach solution and neutral pH ore causes the solution pH to drop, releasing cyanide gas. This release is minor from a safety viewpoint, much less than dangerous, but the gas release is a costly waste of the cyanide reagent. Pilot-scale comparison tests were made at Pinson. Ore pre-treated with lime or cement showed 30% less cyanide consumption than untreated ore."

Jan 1, 1989

By W. F. Scott, K. L. Somerville

"This paper outlines the development and inplementation of functional training at the Thompson Mine of Inco Metals Company, Manitoba Division. This training is an extension of similar methods implemented throughout the company to meet safety and health and productivity objectives. It consists of the orientation to the mine, induction in the basic mining skills, and specific training in drilling and other skills in the mine. Initial results indicated a positive effect on the safety performance and proficiency of the mine workforce.IntroductionThe primary mining method at the Thompson Mine is mechanized cut and fill, with secondary recovery of pillars by undercut and fill . These methods require a workforce of about 900 hourly operating employees to obtain capacity production of 6500 tons of ore per day.Historically, turnover of mine employees has been high and large numbers of new recruits are introduced to the mine every year. These men are recruited primarily in Manitoba, but also from distant areas of Canada; most of the se people have no previous mining experience.Training has always been an important component of mine operations. Mine supervisors and experienced miners have committed an appreciable amount of time and effort to training these new recruits. As well, training efforts have been directed toward upgrading the skills of experienced workers.Recently, a growing awareness of the significance of this training effort and its impact on accident frequency, productivity, turnover and other important parameters of the mine operation has led to a review of training methods. The training program described in this paper has resulted from this review."

Jan 1, 1981

By H. A. Halupka, I. A. Mozer

"At its plant in San Juan, Peru, Marcona Mining Company operates two grate pelletizing furnaces for the agglomeration of 3.5 million long tons of magnetic concentrates annually. Line One, installed in 1963, was built by Lurgi as a downdraft process furnace utilizing a furnace fan for the recuperation of hot gases from the cooling zone. This line was modified in 1966 to include both updraft drying and downdraft drying, and the original roof burners were converted to side-wall burners. Line Two, a Dravo-Lurgi furnace with an annual capacity of 2.4 million long tons, was built in 1966. This line, in contrast to the modified Lurgi furnace, employs direct recuperation of hot gases from the cooling zone and utilization of process gases from the firing zone for updraft drying.At its plant in San Juan, Peru, Marcona Mining Compa-ny operates two grate pelletizing furnaces for the agglo-meration of 3.5 million long tons of magnetic concentrates annually. Line One, installed in 1963, was built by Lurgi as a downdraft process furnace utilizing a furnace fan for the recuperation of hot gases from the cooling zone. This line was modified in 1966 to include both updraft drying and downdraft drying, and the original roof burners were converted to side-wall burners. Line Two, a Dravo-Lurgi furnace with an annual capacity of 2.4 million long tons, was built in 1966. This line, in contrast to the modified Lurgi furnace, employs direct recuperation of hot gases from the cooling zone and utilization of process gases from the firing zone for updraft drying. 5 per cent increased capacity, 30 per cent lower fuel oil consumption, and approximately 400 per cent reduction in grate bar and pallet corrosion. Firing of the pellet bed was improved by conversion from roof to side-wall burners. This modification also permitted utilization of monolithic refractory in place of pre-fired shapes, thereby improving over-all furnace availability and reducing refractory stock requirements from 154 different shapes to 18.Data are presented to compare operating performance of the Dravo-Lurgi furnace and the modified Lurgi furnace. These data show 30 per cent lower fuel oil consumption and 10 per cent higher capacity per unit grate area for the Dravo-Lurgi furnace, which also averages higher availability due to greater operating flexibility."

Jan 1, 1970

By G. V. Sirianni, G. E. Viens, R. A. Campbell, G. N. Banks, R. L. Sachdeva

"A combined shaft-electric furnace for the smelting of ores and the melting of metallized iron pellets is being developed. The materials are preheated, and in some cases pre-reduced, in the shaft before being transferred to the electric furnace, where melting or smelting is completed. It has been demonstrated that this combination of equipment will enable much of the relatively expensive electrical energy to be replaced by cheaper energy in the form of oil or natural gas, and preliminary experiments indicate that the total energy requirements for a melting or smelting operation are significantly reduced. Projections based on results obtained from the preliminary experiments indicate that further improvements will be possible when certain modifications to the equipment are completed."

Jan 1, 1968

By Franz Xaver Spachtholz

K+S Potash Canada GP (KSPC) is part of the K+S Group, one of the world&apos;s leading suppliers of standard and speciality fertilizers and the world?s leading salt producer. Globally, the K+S Group employs more than 14,000 people. The K+S share ? the only commodities stock on the German DAX index ? is listed on all German stock exchanges. Legacy, K+S Group?s most recent project, is a greenfield solution potash mine and production plant in the south of the Canadian province of Saskatchewan. Therefore K+S will invest 4.1 billion CAD. With the expected commissioning in summer 2016 the company projects to reach the two-million-tonnesmark of production capacity at the new location at the end of 2017. The gradual extension of the annual capacity to 2.86 million tonnes of potash products will occur afterwards. The Legacy Project will be Saskatchewan?s first new potash mine in nearly 40 years. It is one of the world?s most economically attractive potash projects. The project will contribute to Saskatchewan?s growth through employment, tax revenues, utilities, and local partnerships. Located in the southern part of Saskatchewan?s potash belt, the deposit is too deep to be mined conventionally due to rock mechanics and high temperatures. Legacy will therefore be a solution mine. Proximity to the urban centers of Regina and Moose Jaw is imperative, with their workforces and economy, as well as access to highways, railway carriers and, most importantly in the prairies, water. With this unique project setting and mining technique, we are convinced that Legacy will be one of the most efficient, economic, sustainable and safe potash facilities in the world.

Aug 1, 2013

By H. Ranjbar

The Darrehzar porphyry Cu deposit is situated in the Urumieh-Dokhtar magmatic suite of Central Iran. The REE and trace element data suggest that the deposit lies within a continental margin setting. Phyllic and propylitic alteration are pervasive in the area but potassic and argillicalteration are not readily recognized on the surface. This is possibly the result of super gene weathering of the surface rocks or because of an intense phyllic overprint. Poor soil development and abundant outcrop make the area suitable for a case study of lithogeochemical exploration technique for Cu deposits. A total of 262 rock samples was collected over the area and analyzed for 15 elements. The geochemical data cor-relate with the mineralogical composition of the rocks with the phyllic zone being marked by high-er concentrations of Si, Al, K, and by a high sericitization index while Ca, Mg, Sr, total Fe and Mn are more abundant in the propylitic zone. The lithogeochemical study indicates a metal zonation from a Cu + Mo-rich core to a Zn + Pb ± Ag-rich outer zone. Principal component analysis is useful for separating element associations, which in turn reflect the alteration halos. Principal components 1 and 2 depict alteration zoning, where-as 3 shows an association of Cu and Mo, that roughly defines the mineralized area.

Jan 1, 1997

By J. J. Baz-Dresch

"The Cannon Mine, a joint venture between Asamera Minerals (the operator) and Breakwater Resources, is located in the centre of Washington state at the eastern base of the Cascade Mountains. The mine complex is located three blocks south of the city limits of Wenatchee, part of an urban area with a total population of 47 000. The closest residence is 350 feet from the mine portal.The B-Neath zone is a narrow, high-grade, downward extension of the southern tail of the mine&apos;s main ore body, the B-North zone. It also underlies the northernmost portion of the B-West zone (Fig . I) . The ore is usually reasonably competent but completely surrounded by very weak rock consisting of shear zone and unsilicified sandstones and siltstones.The zone has maximum dimensions of 420 ft in thickness, 500 ft in length , and 200 ft in width . The economic reserves extend from the 70-ft elevation (elevation above sea level) to the 630-ft elevation and consist of about 1.3 million tons of geologic reserves (proven and probable) at an average grade of 0.33 ounces per ton.Acquisition and ExplorationInitial DiscoveryThe initial discovery of the B-Neath zone was made by Tenneco Minerals during July through September, 1984. Their 22-hole surface drilling program consisted of 18 200 ft of drilling. Tenneco Minerals had acquired the 91/2 acre lease from United Mining Corporation.Asamera Minerals subsequently purchased Tenneco&apos;s lease in July, 1985; Tenneco retained a royalty position which was later purchased by Echo Bay Mining.Follow-up drilling by Asamera Minerals consisted of both surface and underground drilling. Eight surface holes (7200 ft) were drilled commencing in December, 1985. Following evaluation of the geologic data, an access drift was driven on strike along the top of the ore zone on the 500 level. Diamond drilling from this platform consisted of 17 200 ft in 79 holes."

Jan 1, 1990

By Peter R. Drummond

THE paper consists of four sections: (1) a discussion of early work; (2) presentation of the results of a chemical investigation of Falcon-bridge nickel-copper blast-furnace matte; (3) application of the results of this investigation to mattes in general; and ( 4) a summary of conclusions. All general discussion will be confined to the fundamental system of ferrous-cuprous sulphides (FeS-Cu2S). Nickel-, lead-, and zinc-bearing mattes will be treated as minor varieties of the parent system. DISCUSSION OF EARLY INVESTIGATIONS Matte investigations may be divided into three classes: first, those treating the sulphides as alloys-theoretical studies of the system FeS-Cu2S, such as those of Hofman (ll)t or Carpenter and Hayward (2); second, chemical research on mattes made under smelter conditions, such as that carried out by Hawley (3) or Avetision ( 4); third, combinations of the . above, such as the investigations of Gibb and Philp (5) or Fulton and Goodner (6). Much research in the first of these classes, including determinations of . freezing points and of data for structure-composition diagrams of the system FeS-Cu2S, was carried out in the period 1890-1910. LeChatelier and Ziegler (1, 13) proved that FeS, when heated alone above its melting point, dissociated in part, and Friedrich ( quoted by Fulton, 6) showed the same for Cu2S. The reactions may be expressed by the following equations: [xFeS yFe + yS (volatilized)+ (x -y)FeS xCu2S )&apos;Cu+ yS ( vohtilized) + (x -)&apos;)Cu,S ] Sulphur is lost by volatilization, leaving a melt of metallic iron plus ferrous sulphide in the one case, and of metallic copper plus cuprous sulphide in the other. If the mixed sulphides are heated far above their melting points, there results either an iron-rich matte containing Fe-FeS-Cu2S or a copper-rich matte containing FeS-Cu2S3-Cu, depending on the relative amounts of each sulphide in the mixture.

Jan 1, 1940