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By G. C. Weatherly, D. S. Wilkinson, A. M. Limarga

Competition between stress generation and relaxation mechanisms during the oxidation process has been observed. However, the nature of the intrinsic growth stress in thermally grown scales is not well understood. In this talk, we will propose a conceptual model to calculate the intrinsic growth stress based on the analysis of stress-driven diffusional process of oxygen ions along the oxide grain boundary. The calculated stress, which is considered to originate from the constrained lateral expansion of the oxide, is in agreement with a range of experimental observations.

Jan 1, 2004

By Emile D. L. Rienks

We have studied the interaction of NO with the quasi-hexagonally reconstructed Au(100) surface. Using variable temperature scanning tunneling microscopy we have observed formation of the unreconstructed phase of Au(100) after NO exposure. This NO adsorption induced phase transition is observed in a window of temperatures around 170 K. Under the same conditions, CO and O2 cannot drive the phase transition, suggesting weaker interaction. Thermal desorption spectroscopy experiments provide an estimate for the strength of NO chemisorption on Au(100) of 57 ± 4 kJ mol-1.

Oct 1, 2003

By Lawrence Devon Smith

What is a Failed Project? For mining projects, some key indicators of a ?failed? project are: ? Cost is more than it should be (particularly capital) ? Schedule ? It takes longer to build than expected ? It takes longer to ramp-up than expected ? It does not do what it is supposed to do ? Poor performance; output, product specifications; ? Low revenue ? High costs ? No one is happy about it: Management, Shareholders, Bankers ? Does a project fail if it does not meet expectations that were unrealistic and unattainable? ? Caution: Failure may not become evident until years later

May 1, 2010

By W. Geslin

Backward extrusion process is a metal forming process, which limits the manufacturing?s extra thickness when compared with classical die forging technique. Because of a lack of alloy?s mechanical behavior knowledge, the basic strategy of design is as follow: ?Definition of a small scale blank ?Performing experiment in order to get useful process data ?Improvement finite element simulation conditions ?Development of the full scale blank forming process (design of tools,...) using the finite element simulation A comparison between the result of modeling and the experimental data has been done to validate the finite element simulation.

Aug 1, 2010

By M. Proulx

"RÉSUMÉ Le diagramme ternaire Al2O3-Sr-Y est un nouvel outil servant à l’exploration de gisements de sulfures massifs volcanogènes (SMV) archéens. Le diagramme permet de discriminer entre les roches volcaniques à minéralisations à zinc dominant (domaine Zn+) et celles à minéralisations à cuivre dominant (domaine Cu+), ainsi que les roches volcaniques ayant subi une chloritisation hydrothermale pouvant aboutir à la formation de chloritites associées aux cheminées d’altération (domaine Cl+). Ces trois domaines délimitent des zones d’influence géochimique ou d’empreintes hydrothermales résiduelles ou fossiles produites par les cellules de convection hydrothermales générées par des magmas. Le diagramme permet aux sociétés d’exploration de déterminer de façon peu coûteuse la fertilité potentielle des roches volcaniques archéennes en ayant recours à leurs bases de données et aux résultats de leurs analyses de terrain, sans aucune manipulation des données. Le diagramme ne s’applique pas aux SMV aurifères.ABSTRACT The tertiary diagram Al2O3-Sr-Y is a new tool to explore Archean volcanogenic massive sulphide (VMS) deposits. The diagram can be used to discriminate between the volcanic rocks where zinc is the dominant mineralization (Zn+ domain) and the rocks where copper is the dominant mineralization (Cu+ domain), as well as the volcanic rocks that were subjected to hydrothermal chloritization that could have led to the formation of chloritites associated with alteration chimneys (Cl+ domain). These three domains define the zones of geochemical influence, or residual or fossil hydrothermal footprints produced by hydrothermal convection cells generated by magmas. Exploration companies can apply the diagram to determine, at low cost, the potential fertility of the Archean volcanic rocks by using their databases and the results of their field analyses, without any data manipulation. The diagram does not apply to gold-bearing VMS deposits."

Jan 1, 2015

By Grazyna Zakrzewska-Trznadel

The paper outlines the main objectives of the project that concern the evaluation of the possibility of uranium production from indigenous resources since Poland enters the nuclear program. The best available technologies are considered for uranium extraction and obtaining the yellow cake - U3O8. Liquid-liquid extraction with novel extracting agents, as well as membrane processes for separation of by-products will be tested in course of the project. The technological part will be completed with techno-economical analysis. Acknowledgement The studies were supported by the POIG project, No 01.01.02-14-094-09-00 ?Analysis of the possibility of uranium supply from domestic resources?.

Aug 1, 2010

By Y. Dong, L. Li, L. Yu

Converter slag has become an important secondary raw material. Consequently, vanadium bearing converter slag is of great interest for the recovery of vanadium. Solidified converter slags are made up of three main mineral components: dicalcium silicate, calcium ferrite and wustite. Vanadium in modified slow cooling down converter slag of Magang is found mainly concentrated in a separate mineral phase. The mineral phase with high content of vanadium (24%, wt, V205), concentrating 83% of vanadium, can be separated from the slag for economical vanadium recovery. Some characters of the mineral phase were discussed comparing with dicalcium silicate, one of the typical mineral phases in converter slag studied well.

Jan 1, 2004

By M. Specht, D. Pörzgen, W. Lorenz, A. /. Buhr, R. P. Racher

The introduction of the near net-shape casting process at CORUS Staal IJmuiden in January 2000 required changes of secondary metallurgy processes including a development towards more aggressive slag compositions in the steel ladle. Therefore the steel ladle lining has been changed from fired andalusite bricks to magnesia-carbon bricks and, most recently, to fired spinel bricks to withstand the severe slag conditions. In comparison to the andalusite bricks the new steel ladle linings have a higher thermal conductivity. This requires the capability to keep the lining warm by ladle preheaters to sustain the overall thermal stability of the steel ladle in case of interruptions during hot cycling of the ladles.

Jan 1, 2004

By A. Cadieux, J. -B. Pineault, C. Allaire

The temperature measurement of the molten metal in the aluminum transformation process is of prime importance. This is particularly the case for aluminum treatment furnaces, such as holding and melting furnaces. Such reverberatory type of furnaces involve a thermal gradient across the metal line which limits the life of conventional thermocouple protective ceramic shields, due to the action of locally induced thermal stresses. This paper presents a novel thermocouple assembly using a composite refractory protective shield allowing long term resistance to such above conditions. Example of results obtained from various tests in aluminum holding furnaces are presented. The results confirm the superiority of the novel thermocouple assembly, as compared to conventional thermocouple units.

Jan 1, 2004

By M. Bavand-Vandchali, F. Golestani-Fard, S. Khalili, S. Rowshanfekr-Fallah

In the secondary metallurgy of steel, the availability of ladles plays an important role in decreasing the production cost. The refractory lining, therefore, should satisfy optimized quality to grant higher heats. This paper reports the results of an investigation carried out in Iranian Mobarakeh Steel Company in order to increase the lining life of ladles by employing different types of MgO C and Al203 - Mg° - C. The zoning concept was used in replacing the conventional refractories either in slag line or the lower parts of ladle. The number of heats could be improved to almost two times as before. The results are explained in terms of refractory quality as well as zoning approach. The economical impact of this improvement will also be analyzed.

Jan 1, 2004

By M. McKim

"Due to the fact that there were no formal papers submitted for this session we can only print the discussions of the papers. a) Maqnetic Mill Liners : M. MckimE. MarcotteFalconbridge LimitedReplyIn looking at the slides on magnetic mill liners a question comes to mind, particularly in the case of a large diameter mill using large grinding media, concerning the potential hazzards which may exist from large chuncks of steel hanging in the mill. Would you comment.The magnetism was sufficiently strong from liner to liner to hold ........................ .(We are sorry but we could not transcribe the full reply to this question as no microphone was used by the speaker and i't was impossible for us to complete the rest).·"

Jan 1, 1984

By E. Paransky, M. Rigaud, G. Paschek, S. Palco

Some of the negative impacts of carbon addition on the strength of castables are yet to be overcome in order to fulfill its potential benefits for oxidation resistance. This paper reports the results of recent studies conducted at CIREP on the effects of different types of carbon additives on the thermo-mechanical properties of magnesia-based castables. Experimental techniques included measurements of the hot modulus of rupture (HMOR), hot modulus of elasticity (HMOE), as well as the wedge-splitting test (WST). The comparison of evolving microstructures was carried out employing scanning electron microscopy with microanalysis attachment (SEM/EDS) and X-ray diffraction (XRD). HMOR values of 12 MPa at 1300°C have been reached in MgO-Si02-C castables containing up to 7% carbon.

Jan 1, 2004

By Chih-Huey Lin

The Au/?-Al2O3 catalyst prepared by AuCl3 impregnation is subjected to the influence of residual chlorine after an oven drying. A post-impregnation NH4OH treatment was able to eliminate chlorine, and to reduce the cluster size of Au moiety. However, the CO oxidation activity was not increased by this post-impregnation NH4OH treatment. This suggests that certain metal-support interaction (MSI) is the determining factor for the activity of Au catalysts. Thermal treatment under H2, O2 or He was attempted to increase MSI of the prepared catalyst with or without the post-impregnation NH4OH treatment. No significant activity enhancement was found but the TPD analysis suggests that a H2 treatment has a higher chance to induce MSI.

Oct 1, 2003

By G. Dörsam, M. Spreij, S. J. Van der Wal, A. P. Schmidt

The transfer of hot metal desulphurising from the torpedo cars to the hot metal ladles at the IJmuiden BOS plant no.2 caused a decrease in ladle lining life from 680 to 470 heats. Changing the desulphurising agent CaC2 for CaO during a trial period, for environmental reasons, led to a further decrease in refractory life. Availability of the ladles became critical and the major reasons for the low life were identified. Solving one of them, temperature, quickly resulted in restoration of the original lives. However, re- introduction of the new desulphurising agent on 50% of the heats again resulted in a decrease, this time from 700 to 550 heats. In order to be prepared for the full introduction of the new agent, thorough investigation of worn linings was conducted, revealing the major (chemical) wear mechanisms. With these findings, a new design for the hot metal ladle is proposed.

Jan 1, 2004

By Martin Irving

Adding Value to Canadian Diamonds - A Changing Diamond Industry - Diamond Mining - Diamond Manufacturing - Diamond Jewellery Markets - NWT Diamonds Changing Diamond Industry - De Beers ? privatization - Oppenheimers (45%), Anglo-American (45%), Botswana (10%) ? going retail - LVMH joint venture - New Players ? jurisdictions - Canada ? companies - BHP-Billiton - Aber Diamonds

May 1, 2002

By W. Melnyk, L Pokhilenko, J. A. McDonald, A. Hall

The Camsell Lake property comprises 270 000 acres located about 240 kilometres northeast of Yellowknife in the Northwest Territories. Kimberlite has been located in two areas of the property:

Jan 1, 2001

By Y. Qi

A cell-level nonlinear dynamic model of solid oxide fuel cell (SOFC) based on physical diffusion principles is built in this note. It demonstrates that reactant diffusion processes from gas flow bulks to triple phase boundaries (tpbs) play an important role in the dynamic behaviors of SOFC. The simulation shows that under certain condition, the effect of the double layer capacitance may be neglected. The phenomenon of slow rise of voltage in current interrupt experiment may be explained by the dynamic behaviors of partial pressures in the vicinity immediately above tpbs.

Jan 1, 2005

By D. Xia

Pt-Bi intermetallic Nanoparticles was prepared by the polymer-anchor method. The electron micrographs shows that the dimensions of particles sharply distribute in the range of about 3-6 nm. The elemental ratio of Pt/Bi in the bimetallic particles is estimated by the electron probe microanalysis method. Pt-Bi intermetallic Nanoparticles shows a higher activity for the ORR than pure Pt. No significant dependence of the oxidation currents on the rotating speed of the electrode could be observed in the presence of methanol. This clearly indicates that the Pt-Bi is inactive to methanol.

Jan 1, 2005