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By A. G. Bulaev

Biohydrometallurgical technologies based on activity of acidophilic microorganisms oxidizing ferrous iron, sulfur, and sulfide minerals are widely used to extract base and noble metals from sulfide ores and concentrates. As sulfide minerals oxidation is exothermic, industrial processes are usually preformed at 40–50°C. Moderate thermophiles predominate under these conditions. Most of moderately thermophilic acidophilic microorganisms that oxidize metal sulfide are mixotrophic, i.e., they use both organic nutrients and CO2 as carbon sources. Carbon availability is crucial for microbial activity and affects efficiency of biohydrometallurgical processes. Aeration with CO2-enriched air is often used to increase microbial activity in biooxidation reactors. Organic nutrients can be used as alternative carbon source for moderately thermophiles performing biooxidation of sulfide concentrates. We performed several experiments with different sulfide concentrates to study effects of organic carbon sources on biooxidation efficiency and demonstrated that application of such organic nutrients as yeast extract (YE) and molasses made it possible to increase biooxidation efficiency. For example, addition of 0.02% YE in the nutrient medium increased biooxidation rate of pyrite–arsenopyrite gold bearing and chalcopyrite concentrates in batch mode at 45°C. YE addition increased oxidation rate of sulfide sulfur and gold recovery level from 65 to 87% and from 73 to 81%, respectively. Similarly, YE addition increased copper extraction from 47 to 54%. At the same time, YE addition increased efficiency of biooxidation of pyrite–arsenopyrite gold bearing concentrate in continuous mode. Without YE addition, oxidation rates of pyrite and arsenopyrite were 65.7% and 94%, while gold extraction was 71%. YE addition (0.02%) made it possible to oxidize 74% and 95 % of pyrite and arsenopyrite and extract 78% of gold. Addition of molasses (0.02%) similarly affected biooxidation efficiency. Thus, addition of organic nutrients in nutrient media is a promising strategy for improvement of biohydrometallurgical processes.

Jan 1, 2018

By Kozlov Andrey, Matveeva Tamara

"The results of mineralogical and technological studies of platiniferous dunites from Svetloborsky zonal massif (Urals platinum belt) are presented and the basic typomorphic signs of productive mineral assemblages are substantiated. The characteristic features of platinum ore mineralization are revealed: a wide range of iron-platinum alloys, enrichment of ore-formed system by the elements Os, Ir, Rh and activity of the S and As in it, intrusion of Fe-Ni sulfides in platinum and its fusion with magnetite. More than 80% of PGM mineral grains has size less than 100 microns, that determines the possibility of significant losses of platinum in the process of gravity separation and the need for additional recovery processes for small and fine fractions of platinum tailings and sludge products. Summarized results of laboratory tests of small-volume sample processing of platiniferous dunites are presented and the processing flow sheet is developed and tested. The flow sheet incorporates several stages, including stage-wise grinding and gravity separation of ore using the centrifugal concentrator Knelson KS-MD for differently sized material and flotation treatment of tailing products using new classes of reagents for additional recovery of PGM fines."

Jan 1, 2014

By Masanori Mori, Hajime Miki, Osamu Ichikawa, Tsuyoshi Hirajima, Mitsuru Sawada, Keiko Sasaki

For pretreatment of selective flotation, surface oxidation of chalcopyrite and molybdenite was applied by oxygen plasma then the minerals were washed by solution at pH 9 with oxygen bubbling. Surface characteristics of these minerals were investigated with AFM, XPS, zeta potential and contact angle measurements. Contact angle of chalcopyrite and molybdenite decreased a lot by plasma treatment. When they were washed with pH 9 solution with oxygen bubbling, contact angle of molybdenite increased whereas chalcopyrite one kept low. Adhesion force measurements indicated similar behavior. Result of flotation experiments indicated low recovery of both chalcopyrite and molybdenite after plasma treatment and only molybdenite recovery became higher after washing. Selective flotation of chalcopyrite and molybdenite could be achieved with this process. Possible mechanism of selective flotation was proposed from the results of XPS, AFM, etc.

Jan 1, 2014

By P. Braga, A. Chaves, S. França, A. Luz

"In Brazil, there are no official reserves of molybdenum, and the unofficial reserves are modest. Therefore, the molybdenum ore (molybdenite) produced as a co-product or by-product of emerald mining in the region of Campo Formoso, BA, has arisen as the only economic option. The flotation process is commonly used in Brazil for the recovery of molybdenite from emerald mining tailings, but it produces low-content molybdenite concentrates, thereby resulting in a product with low economic value. The molybdenite concentrate produced in Campo Formoso contains 83.5% MoS2 (50% Mo), which is less than the international standard product that contains > 90% MoS2 (54% Mo).This low value is due to the presence of talc, which is a naturally hydrophobic mineral that is also floated with the molybdenite during the flotation process. Separability studies were done in a Partridge-Smith cell using dextrin and quebracho as a molybdenite depressor in solution at different concentrations and pH values to produce a technical-grade concentrate (i.e., 90% MoS2). These basic studies were accompanied by measurements of the zeta potential and contact angle, which was determined by the capillary rise method. The results of these floatability studies were used in bench flotation tests, which were performed in a Denver laboratory flotation cell. A molybdenite concentrate of 93.4% MoS2 was obtained when dextrin was used at a concentration of 100 g/t."

Jan 1, 2014

By G. V. Sedelnikova

Biohydrometallurgical studies were performed on the sulfide gold-arsenic concentrate obtained in treatment of refractory ore from a deposit located in northern Russia. Gold is disseminated in sulfides-arsenopyrite, pyrite and antimonite (their content is 10.0%, 30.4% and 0.7%, respectively). Gold extraction is only 11.8% by cyanidation. Results are given for test bacterial oxidation of the concentrate in continuous mode at temp. = 28~32°C using mesophilic bacteria and at temp. = 32~38°C using the association including moderate thermophilic bacteria. The paper shows that the use of moderate thermophilic bacteria allows to speed up sulfide biooxidation and reduce its time to 96 hours compared to leaching at temp. = 28~32°C for 110~120 hours. The optimal range of pH = 1.5~2.0 of biooxidation process was determined where bacterial solutions are produced with the molar ratio Fe:As > 3 necessary for precipitation of hard-to-solve, environmentally safe arsenical precipitates. Electron microscopy showed that sulfide biooxidation results in liberation of disseminated gold with nanoparticle-level sizes. High sorptive activity of carbonaceous matter and other compounds of bacterial residues cause low gold extraction into cyanide solution ? 28.7%. 10% resin load makes it possible to extract 88.1% Au. Aeration of pulp in calcareous medium enhances extraction to 95.7% and decreases cyanide consumption from 17kg/t to 8 kg/t.

Jan 1, 2014

By A. Muhammad, A. Abdelaal, M. EL Salmawy

"Energy is vital for economic growth and sustainable development. Greater efforts are being devoted to developing unconventional energy resources such as oil shale as an alternative promising source of oil or solid fuel supplement. The main object of this contribution is to determine the upgrade potential of El-Nakheil oil shale using froth flotation. Samples were prepared by comminution followed by sieving into different size fractions. The flotation behavior of the material and extent of cleaning was studied with respect to nonionic and ionic collectors of anionic and cationic types. It was found that the organic rich portions could not be rendered sufficiently hydrophobic by the used collectors and selectivity towards surfactant was very low."

Jan 1, 2014

By G. S. Zeng

The mechanism of cobalt removal from zinc sulfate solution with zinc dust is still not understood well. The experiments in this paper were carried out by zinc dust from zinc sulfate solution with high cobalt to study the mechanism of cobalt removal. Residues after the cementation process from zinc sulfate solution were analyzed by SEM and Electron probe micro-analysis (EPMA) to investigate the morphology of products. Different temperature will cause different structure of particles. With the increasement of temperature, cobalt removal can be improved considerably. The mechanism of cobalt removal by zinc dust is thought as follows: firstly, the cobalt ion forms Co-Zn alloy with zinc particles, and the reaction reaches equilibrium quickly; secondly, the Co-Zn alloy continues reacting to Co with Co2+, which is the control procedure of the whole reaction.

Jan 1, 2014

By P. Romm

The German Kupferschiefer (copper shale) mining history reaches back over 800 years with its last active mines being shut down in 1990. Increasing metal demands and potential thread of future supply shortages led to the initiation of new exploration programs including feasibility studies for the Spremberg deposit as well as Federal Ministry of Education and Research (BMBF) funded research investigations of Kupferschiefer Waste Dump treatment in the Mansfelder region. This article describes the sensor based sorting results of coarse Kupferschiefer via Near Infrared (NIR) Sorting, being conducted by the department of mineral processing (AMR) in Aachen, Germany. It provides information about the necessity of presorting of the different ore types prior to flotation and puts the NIR Sorting results into context with conventional Kupferschiefer processing. Keywords: NIR sorting, kupferschiefer, sensor based sorting, preconcentration

Sep 1, 2012

By A. K. Mukherjee

In this apparatus closed sized particles are placed in a container and then fluidized by passing water through the load of particles. Water flow is adjusted to deposit particles in one or more layers depending on the specific gravity of each of the particles, after which the deposited particles are separated in portions of different specific gravity. The obtained portions represent different ore content of the closed sized fraction. The process is repeated for all other size fractions to generate washability curve of the feed. Three different types of iron ores and one coal sample are tested in this equipment. The theoretical yield-grade curve generated for iron ore feed is unique in absence of any such practice for ore minerals. Similar curve is generated for coal and it is compared with washability curve, an existing practice followed worldwide. This comparison validates the performance of the process and the equipment.

Sep 1, 2012

By S. A. Kubyshkin, A. A. Agafonov, A. L. Shakhnin, S. M. Sukharzhevsky, A. A. Komlev, N. V. Vorob’ev-Desyatovskii, A. Pichugina

Cyanidation of gold ore results in formation not only of Na[Au(CN)2], but also cyanometallate complexes of some transition metals. During subsequent gold extraction from such solutions and pulps, using activated carbons (??), a number of problems arise. An effective solution of the problem is not possible without detailed knowledge of the interaction mechanism of transition metals cyanide complexes with AC particles. The chemical properties of AC particles and graphene, saturated with [?u(CN)n](n-1)- (n=2, 3), were studied by XPS, ESR, SQUID, and DFT. The obtained results were compared with the data on AC adsorption of anionic form of Ag(I), Au(I), Cd(II), Hg(II), Cr(III), Fe(II), Fe(III), Co(III), Rh(III), Ni(II), Pd(II), Pt(II) and Pt(IV) cyanide complexes. The adsorption of [?u(CN)n](n-1)- (n=2, 3) on AC from aqueous solutions in air is accompanied with oxidation of ?u(I) atoms. Besides, Cu(II) and Cu(III) compounds were found on AC surface. Quantum-chemical calculations confirmed the possibility of formation of Cu(I) complex with carbene-like sites of AC. The reactions of [?u(CN)n](n-1)- (n=2, 3) complexes and aromatic carbenes and their cation-radical were theoretically studied at DFT PBE level to obtain the information on adsorption of cyanometallate complexes on AC. Carbenes with different fragments were regarded as a model of activated carbons, which have free edge sites with paired o and n electrons. It was shown that [Cu(CN)2]- bounds firmly with triplet carbene, if one Cu-CN bond breaks. The dissociation process occurs through a multi-step spin-crossing mechanism to reduce total spin multiplicity of the metal-carbene complex. The behavior of transition element complexes in contact with AC in aqueous solutions is determined by the following characteristics: geometrical structure of ionic complexes; nature of ligands bonded to the central atom; concentration of reactive oxygen species in solution and its pH; nature of binding sites of AC.

Jan 1, 2018

High flotation of iron sulfide minerals at high pH values in copper ores is mainly due to the activation of these minerals by copper species dissolved from copper sulfide minerals during grinding. Several methods have been tested to reduce this copper activation during grinding and therefore to depress iron sulfide flotation. They include grinding the minerals at high pH values or with a less reactive medium such as high chrome, and addition of a thiol collector or copper complexant during grinding. The efficacy of these methods in the flotation of a copper ore was tested against more common methods of depression of iron sulfide flotation. The mechanism of iron sulfide depression in these methods was also investigated.

Jan 1, 2014

By R. Singh

The paper presents the results of characterization and beneficiation studies carried out on a lean grade tungsten ore sample from Degana, India. Basically, three different routes, involving gravity separation, magnetic separation, and froth flotation were studied for concentration of the sample by physical and physico-chemical methods. Considering the low recovery by physical methods, efforts were put in to produce a tungsten concentrate by physical methods suitable for subsequent hydrometallurgical recovery of tungsten as ammonium para-tungstate. This strategy proved quite helpful in minimizing the losses of tungsten in tailings. Based upon these studies a novel integrated technological process flow-sheet was developed for the exploitation of lean grade tungsten ore deposit of Degana, India. Keywords: lean tungsten ore, characterization, beneficiation, gravity and magnetic separation, hydrometallurgical extraction, integrated process route

Sep 1, 2012

By Neill Bartie, Jacques Eksteen, Sharif Jahanshahi, Shouyi Sun

The gradual increase in Cr2O3 levels of UG-2 ores has become a matter of concern for platinum producers in South Africa due to the formation of chromite spinels in melters. The effect of bulk FeOx/MgO ratio, Cr2O3, temperature and oxygen partial pressure on phase stability and composition in the system FeOx-MgOSiO2- Cr2O3-Al2O3-CaO has been studied between 1400°C and 1600°C using the drop-quench technique. An increase in temperature was found to result in a decrease in [Fe/Cr]spinel. An increase in bulk FeOx/MgO caused Mg, Al and Cr in spinel to decrease, forming more magnetite relative to other spinels. [Fe]spinel decreased and [Cr]glass increased with a decrease in oxygen partial pressure.

Jan 1, 2003

By A. Vidyadhar

Using pure quartz and hematite minerals, the adsorption mechanism of mixed cationic/anionic reagent schemes was investigated through Hallimond flotation studies. The flotation response of quartz and hematite independently with cationic and anionic collectors as well as with mixed cationic/anionic collector systems is assessed. The flotation response as a function of pH and collector concentration was investigated. The single mineral flotation tests in the presence of anionic collectors, quartz does not respond to flotation, but the C12 amine flotation of quartz was observed to be pH and concentration dependent. It was observed that hematite flotation recovery is maximum at acidic pH with sodium dodecyl sulphate (SDS), neutral pH with oleate, and at basic pH about 9.5 with C12 amine. Flotation results with both quartz and hematite indicate an increased adsorption of cationic collector in the presence of anionic collector apart from its own co-adsorption. The incorporation of oleate in between C12 amine molecules decreases the electrostatic head-head repulsion and thereby increasing the adsorption of C12 amine due to attractive tail-tail hydrophobic bonds, besides forming a closely packed adsorbed layer enhancing the hydrophobicity. The increase in oleate concentration beyond C12 amine concentration leads to the formation of soluble C12 amine-oleate complex / precipitate and the adsorption of these species decreased the flotation since the alkyl chains are in chaotical orientation with a conceivable number of head groups directing towards the solution phase. Keywords: quartz, hematite, adsorption, mixed collector system, flotation, zeta-potential

Sep 1, 2012

By Y. H. Zhang

Mechanism of BK501 in desiliconization from bauxite was studied by use of flotation test, EDS, ?-potential, FTIR. Results of flotation show that almost all of diaspore can be depressed when BK501 is put into pulp ranging from pH 4~12, in the meanwhile kaolinite is slightly activated. In the light of surface analyses, it is concluded that the adsorption of reagent on the diaspore is dominant by chemical interaction. Moreover, kaolinite may float more by addition of BK501 because of flocculation.

Jan 1, 2014

By F. H. Wang

The Yinmao Lead-Zinc Mine Co. Ltd. has got 50 years of mining history. In recent years, the manganese grade in the flotation tailings has been continuously increasing. In order to make fuller use of the existing resources, as well as to increase the company?s economic efficiency, our company adopted the technique ?magnetic separation? and ?iron removal? to effectively recycle the manganese concentrate resources.

Jan 1, 2014

By Y. S. Sun, P. Gao

"In this investigation, a pilot-scale suspension magnetization roasting reactor was introduced and used to enhance magnetic properties of an iron ore. Consequently, the effects of roasting temperature, reducing gas CO flow rate and fluidizing gas N2 flow rate on the magnetization roasting performance were investigated. The results indicate that the hematite and siderite are almost completely converted into magnetite by a gas mixture of 3.5 Nm3/h CO and 2 Nm3/h N2 at roasting temperature of 520 °C. Under the optimized conditions, the magnetic iron concentrate with an iron grade of 60.18% and iron recovery of 90.17% was achieved. The XRD and Fe mineral phase analyses revealed that most of the hematite and siderite were converted to magnetite, and the magnetic properties were greatly enhanced. INTRODUCTION The steel and iron industry in China has rapidly developed in recent years requiring a large quantity of iron ores. Low-grade and complex iron ores are currently the overwhelmingly dominant mineral resource for iron in China. Therefore, China depends on imported iron ore resources heavily, resulting in an increase in the production costs of iron-making and steel-making[1-3]. Using domestic resources to produce a steady supply of high-quality iron ores is an important step toward the sustainable development of the steel and iron industry[4-5]. The iron ore from Jiuquan iron and steel company is abundant and recognized as typically complex iron ore resources in China. Magnetization roasting followed by low-intensity magnetic separation has been proven as the most feasible methods to upgrade refractory iron ore[6-10]. In present research, an innovative roasting technology, namely suspension magnetization roasting, was developed and applied to recover iron from a typical refractory iron ore. Suspension magnetization roasting technique and equipment developed by Prof. Yuexin Han’s Group at Northeastern University (NEU) is an effective way for the utilization of refractory iron ore. The advent of suspension magnetization roasting will, in China and even globally, produce a significant technological revolution in the field of iron ore beneficiation. Based on the previous works, this paper mainly described experiments on the separation and recovery of iron from a complex refractory iron ore by means of suspension magnetizing roasting and low-intensity magnetic separation processes. The purpose of the research is providing a new technology for effective utilization of refractory iron ore. Process parameters that affected the separation and recovery rate of iron were conducted and optimized, and the reaction process was analyzed by XRD and Fe mineral phase analysis."

Jan 1, 2018

By Sergey S. Gudkov

In the current climate of changing the approach to mining and treatment of mineral resources, processing technologies are being developed that require little maintenance and are economically as well as ecologically sustainable. This may also involve the development of entirely new ways of ore processing. One promising approach is to use bioleaching for the pretreatment of gold refractory ores to cyanidation. Capital costs for vat bioleaching of concentrates and ores are very high and cannot be applied for small or medium-size deposits. IRGIREDMET JSC carried out bio heap leaching test work on refractory ore samples from three Russian deposits. Following this biological treatment a combination of flotation, vat bioleaching, and cyanidation are used to recover gold. After heap bioleaching, gold recovery was 75-80 per cent. It was found that efficiency of heap bioleaching process depends on ore feed size. High duration of this process is another feature and it lasts for about a year. This process can be also used for carbonates in the combination with other process during which acid generation occurs. The results of our studies have shown that this technology is amenable for refractory gold ores. Its introduction allows an increase gold recovery and to solve a number of environmental problems. Keywords: heap biooxidaton, the refractory of the ores, the degree of oxidation, arsenopyrite, pyrite, CIL

Sep 1, 2012

By V. Tsyplakov

This article reviews factors of preg-robbing effect, occurring in the course of pressure oxidation of ore and concentrates, containing chloride compounds and so-called 'organic carbon'. The article also summarizes the main results of the studies and testwork conducted to overcome this effect. The following efficient preg-robbing mitigation methods have been noted: higher temperature of pressure oxidation process, preliminary removal of natural carbonaceous material from concentrate, chloride removal prior to concentrate pressure oxidation, and addition of water-soluble organic blanking agents, which suppress the adsorption activity of the native ore adsorbents. Keywords: preg-robbing, double-refractory gold concentrates, pyrite, arsenopyrite, blanking agents, pressure oxidation, autoclave leaching

Sep 1, 2012

By H. Tiefel, M. Schneider, T. Neesse, J. Regler, J. Dueck, F. Donhauser

In practice the advantages of high-quality hydrocyclone separation are often reduced due to varying feed suspension properties, solids concentrations and particle size distributions. Control systems of large hydrocyclones are usually fitted with controllable underflow nozzles, which is not practical for small hydrocyclone batteries. Therefore, a new control system for a battery of hydrocyclones with a nominal diameter of 150 mm was invented at the LUR in cooperation with AKW Apparate und Verfahren GmbH & Co. KG. This process was developed for bentonite slurry regeneration associated with tunnel excavation using bentonite slurry as a transport aid and lubricant.

Jan 1, 2003