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By R. L. Crosby

From studies of wrought magnesium alloys containing rare-earth elements, data are presented on the mechanical properties of the alloys at room temperature and at temperatures of 100°, 200°, and 300° C. Results of studies of the solid-solubility of cerium and zirconium in magnesium as determined by electrical resistance measurements are also discussed and are compared with those of other investigators. The strength of magnesium-cerium alloys did not increase with the addition of vanadium and titanium dioxide. The addition of zirconium increased the tensile strength of the alloys as much as 10,000 p.s.i. at room temperature, but this increase diminished above 100° C.

Jan 1, 1962

By G. G. Campbell

Bureau of Mines research to develop an in situ retorting recovery method for oil shale has involved field testing of fracturing techniques for creating fluid-flow paths in impermeable oil shale. Electrolinking, hydraulic fracturing without and with sand propping, and explosive fracturing with a liquid explosive were tested in a 25-ft-square, five-spot pattern. These wells were drilled into oil shale at 50-to 88-ft depths near Rock Springs, Wyo. Results of the fracturing tests were evaluated by injecting air into a test well and measuring flow rates and flow profiles in adjacent test wells before and after each test. To identify points of air entry (location of fractures) in wells, flow profiles were determined by use of inflatable packers and by continuous logging with an airflow probe developed during the fracturing program. Electrolinking and hydraulic fracturing without sand propping were relatively ineffective; hydraulic fracturing with sand propping created horizontal fractures with desirable flow capacity; and fracture flow capacity was significantly increased by detonation of nitro-glycerin displaced in the natural and hydraulically induced fracture systems.

Jan 1, 1970

By D. A. Reynolds

Yields of ammonium sulfate obtained in the carbonization of coal frequently vary from plant to plant, because ammonia is an unstable compound at high temperatures and therefore sensitive, to changes in carbonizing conditions. Differences in byproduct yields of ammonium sulfate obtained at different plants generally are accounted for by variations in plant procedure, either in preparing the coal or in its carbonization. However, technicians of one large corporation,- which frequently obtained higher yields of ammonium sulfate in its Alabama plants than ever were attained in its Ohio plants, "could not reconcile the differences in yields with their plant operations. These investigators suspected that the Alabama, coal used in their southern plant yielded more ammonia because its composition differed inherently from that of the Pennsylvania and West Virginia coals fused in their Ohio plants, although this concept could not be proved readily in their large-scale operations. Their view is supported by experimental data obtained A Beau of Mines-American Gas Association (BM-AGA) carbonization tests) -21 of a large number of coals including those carbonized commercially in Alabama and Ohio.

Jan 1, 1949

By Wallace W. Roepke

The Bureau of Mines determined coal-cutting forces and primary dust generation of four styles of radial gage bits as used on end rings of continuous mining machines. Direct comparisons for reference were made with two widely used conical plumb-bob types having 60' and 90' (nominal) included tip angles. The cutting forces for all of the gage bits were similar to those of the 60°-tip plumb-bob bit. All bits except the RAD-3 gage bit generated similar amounts of primary total dust at shallow cutting, but during deeper cutting, the amounts varied and the gage bits produced as much as 2-1/2 times the dust produced by the 60° bit. This seems atypical since past experience has always shown differences in dust generation at shallow cutting. The specific energy was more like that found previously with other bits, since the values were spread at shallow cutting but became nearly similar at deeper cuts. The 90° bit and the RAD-3 gage bit are not recommended for use except in extremely difficult cutting conditions where dust and forces are of secondary importance. The choice among the remaining four bits can be made on the basis of dust, energy, forces, or cost, as circumstances dictate.

Jan 1, 1983

By N. S. Dalal, X. Shi

"Electron spin resonance (ESR) measurements on solutions and isolated powders provide direct evidence for the involvement of Cr(V) species in the reduction of Cr(VI) by NAD(P)H. ESR analysis of an isolated Cr(V)NAD( P)H solid yields 6 11 = 1.9831 and 6.i. = 1.9772, indicating that the unpaired electron occupies the d22 orbital of the Cr(V) ion, with square-pyramidal geometry. Addition of hydrogen peroxide (H2 0 2 ) to the N AD(P)HCr( VI) reaction mixtures suppresses the Cr(V) species and generates hydroxyl (""OH) radicals. The ""OH radicals were detected via ESR spin trapping, employing 5,5-dimethyl-1-pyrroline-N-oxide and a-(4-pyridyl-1- oxide)-N-tert-butylnitrone as spin traps. The dependence of Cr(V) and ""OH radical formation on the H20 2 and Cr(VI) concentrations indicates that the Cr(V) species react with H20 2 to generate the ""OH radicals. Similar results were obtained by using various diols (arabinose, cellobiose, FAD, fructose, glyceraldehyde, ribose, and tartaric acid), a-hydroxycarboxylic acids, and glutathione. Investigations with superoxide dismutase showed no significant participation of 02 in the generation of OH radicals. These results thus indicate that the Cr(V) complexes, produced in the reduction of Cr(VI) by cellular reductants, react with H20 2 to generate ""OH radicals, which might be the initiators of the primary events in the Cr(VI) cytotoxicity.In this paper we report an electron spin resonance (ESR)3 spectroscopic detection of Cr(V) species in the reduction of potassium dichromate, henceforth called Cr(VI), by NAD(P)H and other diols. Also reported here is the detection of the hydroxyl (""OH) radical in the reaction between hydrogen peroxide (H2O 2) and a variety of Cr(V) complexes. This work was undertaken because while the reduction of Cr(VI) to lower oxidation states has been suggested as a key step m the mechanism of Cr(VI) toxicity, mutagenicity, and DNA alteration, the details are not yet clear (1-5).Earlier studies on the mechanism of Cr(VI) reduction in cellular systems include those on the reduction of chromate by microsomes (6-8), rat liver DT-diaphorase (9), and aldehyde oxidase (10). All these studies imply that Cr(VI) can be reduced to Cr(Ill) by cellular constituents. Regarding the mechanism of Cr(Vl) carcinogenicity, Jennette postulated that Cr(V) is the ultimate carcinogenic form of chromium compounds (8). This conclusion has led to many further investigations of the formation of Cr(V) in the reduction of Cr(VI) under biologically relevant conditions (11-33). More recently, however, Kawanishi and co-workers (34) have investigated the mechanism of DNA cleavage induced by Cr(VI) in the presence of H20 2 and have argued that it is not Cr(V) itself that is carcinogenic, but it is the reactive oxygenated species (02, 10 2 , ""OH) (produced by the decomposition of the Crv(02) ¾ - ion) that cause the DNA alteration."

Jan 1, 1990

By R. F. Abernethy

Recent investigations in the United States and in other countries have produced considerable information on the nature and occurrence of minor elements in coal. The possibility of recovering certain elements, particularly germanium and uranium, from coal ash and other coal products has received considerable attention. Some flue dusts are potential sources of germanium, and certain lignite deposits are potential sources of uranium, but industrial recovery of these elements has been limited to small quantities for technical and economic reasons. Considering the large amount of coal mined annually, a small percentage of a rare element may have industrial significance if an economical method of recovery can be developed. In 1944 information on the occurrence of rare elements in coal was reviewed in Bureau of Mines Technical Paper 669 (46).3 This report is a revision of that paper with the view of summarizing published information available for United States coals, and pertinent information concerning coals of other countries. Selected references from the original paper are retained. New references do not include all preliminary reports when more permanent literature describing complete projects is available. Consequently, the list of references should not be considered complete.

Jan 1, 1963

By George H. Holmes

This paper is one of a series on mining methods and practices being prepared by the Mining Division of the Bureau of Mines . It describes briefly operations and mining methods at the Basic Refractories , Inc. , brucite deposit , the only commercial deposit of brucite in production in the United States . The mine and crushing plant are in secs . 26 and 35 , T. 12 N. , R. 36 E. , M. D. B. & M. , northwestern Nye County , Nev . , 1 mile east of Gabbs and about 33 miles northeast of Luning , a town on the Mina branch of the Southern Pacific Railroad and U. S. Highway 95. ( Figs . 1 and 2 ) .

Dec 1, 1949

By Richard A. Allwes

The Bureau of Mines conducted an in-mine case study on two consecutive three-entry gate road systems designed in accordance with the stiff-yield pillar design concept. This Bureau study was conducted in order to further develop technology that will improve the health and safety aspects of longwall mining. Support loading and strata activity were monitored to determine the effects of retreat longwall mining on the gate road ground control system. Analyses of pillar stress and roof bolt loading histories revealed that headgate roof support elements ex-perienced cumulative loading throughout the life of the longwall panel. Tailgate pillar loadings had significantly different histories from the loading histories of the headgate pillars. Stress relief occurred in the tailgate pillars following the passage of the longwall face. More-over, the stiff-yield pillar design, with the abutment pillar placed adjacent to the working panel when part of the headgate system, provided effective ground control in that no major roof falls or roof problems were experienced in the headgate or tailgate systems during longwall mining.

Jan 1, 1985

By Donna lynne Anderson

This report documents the status of a laser-based underground guidance system for tracking and controlling the movements of underground mobile mining equipment. This research is part of a multiple project effort at the U.S. Bureau of Mines to increase mine safety and efficiency by developing technology for computer-assisted mining. Guidance systems, which can track and control the movements of underground mining equipment, are essential during computer-assisted mining operations. A continuous mining machine at the Bureau's surface test facility served as the test-bed for initial development and experimentation of this guidance system. Subsequently, a continuous mining machine in an underground mine served as the platform for in-mine experimentation The first section of this report includes details of the laser sensors, communication network, and computer hardware. The next section includes experimental results, which show the system capable of accurately tracking and controlling the tram maneuvers of a continuous miner underground. The final section discusses conclusions and recommendations.

Jan 1, 1992

By R. Havens

During the course of the investigation of possible domestic sources of manganese, engineers of the Bureau of Mines examined and sampled two manganese mineral deposits in northeastern Utah. The Daggett Chief claims are situated in the northern part of Daggett County,5 miles southwest of Manila, Utah, and approximately 57 miles from Green-River, Wyo. Owners of the property are J.E. Harris Of Salt Lake City, Utah, Nels Palleson of Manila, Utah, and J. P. Larson. The manganese occurs in a vein 6 to 8 feet wide in a shale and sandstone formation. Two distinct occurrences Of manganese are present Within the vein, and samples of each were subjected to testing. Lot A, representing .probably the major portion of the Manganese; was composed of nodules and veinlets of manganese oxides in a semicompact; gray, shaly formation. Lot B represented a 15-inch vein of dense iron-manganese ore. .Most of the laboratory work at Salt Lake City, Utah, was done on these two samples; but preliminary testing also was carried out on a small sample, physically similar to lot A, submitted by the owners.

Jan 1, 1949

By Hillary W. St. Clair

Reaction rate coefficients were determined from analyses of the effluent gas for the reduction of granular ferrous oxide to metallic iron by passing carbon monoxide through a packed bed of oxide at a controlled rate in the temperature range 1,000° to 1,300° C. Coefficients were determined by the comparison of observed analyses and calculated analyses using a mathematical model that takes into account the nonuniform composition of both the solid oxide and the gas. A method is also given for finding the value of the rate coefficient that best fits the observed data.

Jan 1, 1968

By G. M. Potter, S. J. Hussey, R. Havens

The Artillery Peak manganese ores , from one of the largest known manganese deposits in the United States , present a difficult problem in concentration because they are low-grade and the association of manganese and gangue minerals is intimate and complex. The known size of this deposit has justified investigation of processes such as leaching, wherein preliminary enrichment of the original feed might be advantageous .. Therefore , the ore-dressing studies on Artillery Peak ores were carried on with the object not only of making directly marketable manganese products but also of removing acid-consuming calcite and raising the grade of ore for leachingplant feed . Owing to the extent of the deposits , test work was carried on at the Salt Lake laboratories in considerable detail on several lots of ore of varying composition . This paper summarizes the results obtained from laboratory testing of four samples obtained by engineers of the Mining Branch from the Maggie Canyon area of the Artillery Peak deposit . Also included are results obtained from testing one sample of Chapin Group ore , which was considered representative of numerous very low-grade ores submitted from the Artillery Peak district . During the course of the investigations , many data were obtained and compiled , but for the sake of brevity , data of secondary importance have been omitted or condensed and only those tests giving the more pertinent results are discussed in detail ...

Nov 1, 1947

Provide blasting-resistant, quickly reusable stoppings for large mine openings. Approach Stoppings are assembled using roof-to-bottom panels of brattice held together by Velcro seams that peel open when struck by a strong air blast. How It Works The Velcro seam is designed to open when exposed to forces lower than would normally damage the brattice. When the seams partially open, they relieve the blast air overpressure to prevent damage to the brattice panels and their anchoring devices. A stopping is returned to service by reclosing the Velcro seams. To hang a brattice panel, its top is stapled to a board, and wrapped once or twice around it. That assembly is then attached to the roof with bolts. The length of the board should be a foot less than the width of the panel to allow for the sealing seam on each side of the panel. The boards are installed end-to-end in an approximately straight line across the roof of the mine opening.

Jan 1, 1979

By W. A. Calhoun

The purpose of this investigation was to develop economical mineral dressing processes for removing objectionable quantities of impurities, such as quartz and pyrite, from refractory clay deposits in east central Missouri. The presence of excessive quartz in these clays causes crazing. Pyrite causes bloating and unsightly dark blobs on the surface of fired refractory brick. The iron concentration in the proper state of oxidation may also act as nucleation centers for carbon crystal growth which can result in bursting of the refractory. Numerous deposits, representing a very large tonnage, have been examined and prospected by various refractories companies and found to contain impurities in objectionable quantities. Upgrading these clays would greatly extend our reserves of high-quality refractory clays. Wet-tabling and wet-cyclone concentration were found to be effective for removal of impurities from clays. Of the two methods, wet-cyclone concentra¬tion would be cheaper and more effective. Although wet-tabling improved the refractory properties of each clay, beneficiation by wet-cyclone produced clays of superior quality. Clay recoveries by wet-cycloning ranged from 56.1 to 81.8 percent of the weight of the crude samples, and the beneficiated clays contained from 71.9 to 94.4 percent of the total alumina. The pyrometric cone equivalent (PCE) was increased from 1 to 3 cones by wet-cycloning. The beneficiated clays also met the reheat shrinkage requirements on refiring to 1,400° C. Missouri is one of the major domestic sources of fare clay. In addition to deposits of high-grade refractory clays, there arc many deposits that contain small percentages of impurities, which render the clays unfit for the production of high-heat-duty firebrick. Development of methods to beneficiate these submarginal clays to usable materials would greatly increase commercial fire clay resources.

Jan 1, 1961

By F. B. Petermann

Two-stage electric smelting tests, using small submerged arc furnaces, were made on high-iron manganiferous materials from the Pioche District, Nev., and the Cuyuna Range, Minn. The object was to reduce sufficient iron in the first stage to give a slag with a favorable Mn to Fe ratio for smelting to ferromanganese in the second stage. The nodulized flotation concentrate from the Pioche District contained 29.2 percent Mn and had a Mn to Fe ratio of 2.3:l. When smelted with coke and silica or alumina as flux, more than 90 percent of the manganese was recovered in slags with Mn to Fe ratios of 10: :24:1. The Pioche slag was smelted to ferromanganese using coke and lime- stone or dolomite as flux. The ferromanganese was high in silicon but other- wise met specifications. Recovery of manganese to ferromanganese in this step was 73 to 78 percent. Overall recovery of manganese was about 70 percent. The sintered flotation concentrate from the Cuyuna Range material contained 12.9 percent Mn and had a Mn to Fe ratio of 0.3:1. When smelted with limestone as flux, about 83 percent of the manganese was recovered in a slag with a Mn to Fe ratio of about 6:1. The Cuyuna slag was smelted to ferromanganese with coke and limestone for flux. Recovery in this step was 61 percent of the manganese in a high silicon ferromanganese. Overall recovery of manganese was about 50 percent.

Jan 1, 1963

By Michael Hamilton

Mineral resources have been identified at two properties in the Ten takes RARE II area (table 1). Commodities consist of copper and silver. The deposits, in the northwest part of the study area, are hydrothermal and associated with fissure veins that developed along northwest-striking faults within the Precambrian Purcell Lava. In addition to the identified resources, there is high potential for additional copper-silver resources at these properties and moderate potential for copper-silver-lead-zinc-bariun resources at five others (table 2) in the portion of the study area that is underlain by the Purcell. There is no evidence that significant mineralization occurred in strata above or below the Purcell.

Jan 1, 1983

By D. S. Burgess

A commercially available Halon 1301 extinguisher has been evaluated as part of an explosion-suppression system for use in coal mines. Studies were made both of the dispersion pattern of the Halon 1301 at an initial pressure of 280 psig, and of the efficacy of this suppressant against 9.5 percent methane-air flames. These flames were quenched successfully only when the suppressant was applied before the fireball diameter exceeded 18 inches.

Jan 1, 1971

By Merle L. Bowser

The Bureau of Mines has developed a portable recording methanometer that utilizes the Bureau's methane sensor. The methanometer can operate continuously for at least 30 hours on small, sealed, rechargeable lead-acid batteries.

Jan 1, 1969

By Irving Hartmann, John Nagy

"The pressures produced by dust explosions are frequently so great and are developed so rapidly that widespread destruction of manufacturing equipment and buildings results. Experimental data on maximum pressures and rates of pressure rise produced in a closed vessel by numerous metal powders and by dusts used in the plastics industry were published in two previous Bureau of Mines papers.4/5/One means for reducing structural damage is provision in the enclosing walls and/or roof of rapidly opening explosion-relieving devices or relief vents through which the pressure of an incipient dust explosion can be quickly dissipated. The vents can be simply unrestricted or free openings: hinged or pivoted sash which swing outward at a predetermined internal pressure; fixed sash, with light wall anchorages; scored glass panes; light wall panels; monitors or skylights; poppet-type vent closures; paper, metal foil, or other diaphragms that burst at low pressures; pull-out diaphragms, or other similar arrangements.The use of pressure-relief vents is recommended in the dust-explosion codes of the rational Fire Protection Association,6/ and recently a special committee on explosion venting has been organized. However, technical data on which the design and distribution of relief vents can be based are meager. An experimental study on venting grain-dust and cornstarch explosions was made by the Bureau of Chemistry and Soils, United States Department of Agriculture.7/ Tests on cork fines, cinnamon, starch, barley dust, and a phenolic plastic were made in a laboratory-scale (0.1-cubic-foot) apparatus by the engineering department of the Factory Insurance Association.8/ A study on the venting of explosions of acetone-air mixtures was made by the Bureau of Mines.9/The object of the present investigation is to extend the limited knowledge on the effectiveness of pressure-relief vents of different types, shapes, and sizes. The aim is to determine the venting requirements in equipment and structures of various dimensions and shapes for dusts of widely different explosive properties. On the basis of such accumulated information, together with theoretical considerations, it is hoped that ultimately it will be possible to recommend correct venting for most operations in which a dust-explosion hazard exists."

May 1, 1946

By R. W. Dalzell

The performance characteristics, efficiency, and operating pressure of jute line-brattice systems were studied under varying underground conditions; various fabric grades and installation methods were used. The test results indicate that line-brattice system efficiency is dependent upon the method of ventilation the method of installation, porosity of fabric, and size of tight rib area.

Jan 1, 1966