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By Jack Barrett

The oxidants which participate in the bacterially catalyzed oxidation of minerals are dissolved oxygen and some aqueous iron(III) complexes. Speciation studies indicate that these complexes consist of iron (III) -sulfate and iron (III) -arsenate ions. The complexes have different oxidizing powers as indicated by their calculated standard reduction potentials. The thermodynamics of the oxidations of pyrite and arsenopyrite are related to the mechanisms of the reactions. The mechanisms are discussed in terms of primary processes occurring on the mineral surfaces and the secondary reactions of the primary products. The importance of the conclusions to plant operation is discussed.

Jan 1, 1993

By Richard J. Ebens

The trace element geochemistry of the cherty, clay-rich carbonate residuum. Covering much of southern Missouri and adjacent parts of Arkansas was investigated during the early 1970's as part of a statewide geochemical survey of Missouri-1/2/3 The study was environmentally oriented and focused on the character of the "natural' geochemical environment of the state. A great deal of effort was made to collect samples that would represent the geochemical variability of the near-surface environment in an unbiased way. In general, this was accomplished by use of randomization procedures in both collection and analysis. Most of the sampling sites were selected randomly to prevent personal bias from entering into sample selection. In the laboratory, samples were analyzed in a randomized sequence to circumvent the effects of any systematic bias that may have entered into the laboratory procedures. Several residuum samples contained 1 000 parts per million (ppm) or more of Pb, Zn and Ba. All these samples were collected in Washington County in or near the barite district. The frequency distributions shown in figure 1 indicate just how unusual the residuum in Washington County is with regard to these three metals and copper. The shaded parts of the histograms represent the samples from Washington County. The histograms are based on analyses of 141 samples from 38 localities scattered over the subcrop of the Cambrian and Ordovician Formations of southern Missouri and northern Arkansas. Eight localities were selected randomly from over each of four bedrock units--Bonneterre Dolomite, Potosi and Eminence Dolomites, Roubidoux Formation, and the Jefferson City, Powell and Cotter Dolomites. Six localities were selected randomly from over the Gasconade Dolomite. The geochemical "background" for these elements in residuum is defined by samples from outside of Washington County (unshaded part of the histogram); lognormal distribution curves have been fitted to the corresponding parts of each histogram. Clearly, these lognormal models (curves) describe well the background

Jan 1, 1977

By Olice C. Carter, B. J. Scheiner

The Bureau of Mines investigated the removal of two toxic/heavy metals (cadmium (Cd) and lead (Pb)) from brass foundry wastewater. Polymers, copolymers, guars, and gums were used in conjunction with calcium hydroxide (Ca(OH)2) and magnesium oxide (MgO) to remove the metals from solution. Several polymers were successful in removing Cd and Pb from the wastewater. The concentrations of Cd and Pb were lowered from 19 to 0.01 ppm and from 20 to less than 0.01 ppm, respectively. The methods investigated could easily be adapted to many existing wastewater treatment facilities and/or be used independently.

Jan 1, 1991

The amount of hydrophobic materials constituting the mineral froth strongly influences the froth viscosity. Higher froth viscosity on the other hand can retard the drainage of physically carried over hydrophobic particles. In phosphate flotation tests a direct correlation was observed between froth viscosity and recovery and an inverse correlation between froth viscosity and grade. Phosphate flotation tests in the presence of a silica depressant indicated that higher froth viscosity is an effect rather than a cause of silica particles reporting in the froth.

Jan 1, 1992

By P. Bevilacqua, G. Ferrara

The paper discusses the problem of accuracy in the determination of the partition curve of gravity separation processes, which is strongly affected by both the sharpness of separation of the density analysis system used and the width of the density range selected. The problem is important when the density analysis of the separation products cannot be performed using heavy liquids, but has to be performed using heavy suspensions or using other systems such magnetogravimetric separation. The imperfect separation given by these systems and the use of large density ranges lead to the determination of apparent partition curves instead of actual partition curves for the process. In the paper the relation between apparent and actual partition curves is studied under different conditions through a simulation program. For different input data, special diagrams are given which, once the apparent partition curves and the sharpness of the density cuts are known, allow calculation of the actual partition curves and the related parameters.

Jan 1, 1995

By Paul M. Godlewski, Gerry Millar, Harvey W. Parker

Recently, over 70 railroad tunnels in the western USA have been enlarged and rehabilitated "live track," utilizing modern excavation and lining methods, in most cases to clear the larger double-stack container cars. This paper presents the general conditions of the tunnels and the technical aspects and costs of the rehabilitation of approximately 40 kilometers of tunnels, which range in length from a few hundred meters to 13 kilometers. Concrete-lined tunnels were rehabilitated by grouting and rock bolting, while unlined or timber-supported tunnels were relined with shotcrete and rock bolts. High output lining methods were required because of limited track time. Enlargement has been accomplished primarily by carving notches out of the concrete linings with a roadheader, or occasionally with saws. Unlined tunnels were enlarged by drill-and-blast or roadheader excavation.

Jan 1, 1991

By M. Karmis

Surface subsidence has been recognized as an inevitable consequence of underground coal mining for several centuries. The damage resulting from this phenomenon has been witnessed in rural as well as in urban areas and ranges from simple land settlement to severe structural damage to buildings. Subsidence prevention is not feasible, at least under the existing technological and economic constraints of underground coal mining. Using a rational method of subsidence prediction, it has been demonstrated in many coalfields that subsidence control can be successfully practiced in order to reduce and accommodate subsidence within environmentally acceptable levels. This paper presents the development and testing of a subsidence model, based on the zone area method. This technique is a refined development of the influence functions and it is capable of investigating a mining plan of any shape, thus facilitating both longwall and room-and-pillar mining systems. More specifically, this study can be divided into two major efforts: (a) The development of the zone area model. This formulation was designed to accommodate the analysis of an optimum number of zones, over the area of interest, both accurately and efficiently. (b) The testing of the computer techniques with appropriate field measurements. In order to accomplish this, published as well as unpublished information was collected and analyzed according to a regionalized scheme. This procedure minimized differences in subsidence characteristics between the various coalfields and allowed a regional validation of the predictive capabilities of the model.

Jan 1, 1982

By J. J. Daniels

Advances in borehole geophysical research for mineral assaying and remote detection of mineralization away from the borehole are cited. Nuclear activation measurement research has provided accurate in situ assays of economic metals with neutron-gamma activation, using a high resolution intrinsic-germanium detector. Although nuclear activation analysis is the present "best hope" for obtaining in situ assays for some elements, gamma-gamma and magnetic susceptibility measurements can provide accurate assays for lead-zinc and magnetite, respectively. Borehole optical spectroscopy and X-ray fluorescence are being investigated as possible in situ assaying techniques for some minerals. More laboratory and field calibration research is needed before non-linear complex resistivity (NLCR) can be routinely used as a quantitative assaying tool. Field tests have shown that variations in the local geologic environment can affect the quantitative accuracy of assay values from downhole NLCR measurements. Deeply penetrating borehole geophysical methods are increasingly being used for mineral exploration as drilling costs and exploration have increased. Borehole electrical measurements have been shown to be useful for detecting conductive ore bodies that are not intersected by a drill hole. Hole-to-surface resistivity and surface-to-hole time-domain electromagnetics are demonstrated to be particularly effective for defining mineralized zones in a massive sulfide environment. Borehole gravity meters and three-component magnetometers have been developed and should prove useful for defining geologic anomalies away from the drill hole.

Jan 1, 1987

By José Salim, T. V. Subrahmanyan

The occurence of primary stratiform and vein gold deposits in the Precambrian rocks of Northeastern Brazil is discussed. The stratiform deposits are related to clastic sediments (quartzites and conglomerates). The veins are associated with quartz and sulfides and are structurally controlled by shear zones. The gold was recovered for a long time by small miners. Developmental programmes for large scale mining are now envisaged. The recovery problems and gold economics are also discussed.

Jan 1, 1988

By J. Siege1, R. S. Popielak

A computer model was used to simulate the effect of leakage through confining beds on a hypothetical in situ leach operation in an aquifer with a thin mineralized section. The simulations were used to assess economic and potential environmental implications of leakage on an in situ leach operation. Four scenarios were modeled - three representing cases with different degrees of confinement, and the fourth representing a stratified ore zone under a low degree of confinement. The model simulated the travel path and travel time of lixiviant given the hydraulic conditions prescribed in each scenario. The results show that the travel path and travel times vary by about 10% for confinement ranging from nearly impermeable (essentially no leakage) to an extremely low level (thin confinement with a permeability about equal to that of the aquifer) for isotropic aquifer conditions. The aquifer thickness contacted by the lixiviant varied from 85% to 90%. Horizontally, 55% to 60% of the aquifer was contacted. The flow paths in the stratified aquifer were reduced in the vertical direction and expanded horizontally. Forty- five percent of the aquifer thickness was contacted vertically with 88% contacted horizontally. Break- through time for lixiviant traveling at mid-depth of the aquifer increased two times when the leakage was increased from nearly zero to a value representative of thin and highly permeable confinement. Leakage affects the economics of in situ mining by (1) increasing the time required to leach out the ore, and (2) increasing the thickness of the ore zone aquifer to be restored. The potential for environmental impacts appears to be minor. In all four simulations, the lixiviant did not contact the confining strata. Restoration would be limited to cleanup of the ore zone aquifer within the thickness contacted by lixiviant and within the radius of the lixiviant that traveled farthest away from the production cell.

Jan 1, 1988

By J. A. Hrabik

The feasibility of mining deep phosphate deposits by a borehole mining system was compared with mining by proven conventional techniques. An economic comparison of the borehole mining system with conventional dragline and bucket wheel excavator mining systems was completed at various mining depths and production rates. Hypothetical phosphate deposits, with various overburden thicknesses and reserve tonnages, were defined. Geologic conditions necessary for the application of the borehole system were identified. Discounted cash flow analyses based on derived capital and operating costs were used to generate rates of return and product prices. Borehole mining was found to be more economical where overburden thickness was 46 m (150 ft) or greater. However, at 15- and 30-m (50- and 100-ft) thicknesses, conventional surface mining was more economical. Overburden thickness has a great effect on the economic feasibility of the conventional mining systems but less effect on the economics of borehole mining. Economies of scale are only realized in conventional mining, since larger equipment is used to achieve greater production, whereas increased production from borehole mining is achieved using additional equipment units. A comparison of the environmental effects of borehole and conventional surface mining systems showed that borehole mining is environmentally more desirable.

Jan 1, 1987

By Edward L. Mooney

The past 15 years has .seen a dramatic increase in the use of computers in the mining industry. Sanford (1) has provided a comprehensive listing of available programs by application within the mining industry as a whole. Figure 1 below illustrates some of the primary uses and computer techniques currently in application in surface coal mines. As shown in Figure 1, computers have been applied to virtually every facet of surface mine development and operation. In particular, many programs presently exist to significantly reduce the time and effort required during the, planning and design phase of a surface mine. Close examination of the approach taken to utilize existing programs, however, reveals that in most instances applications have been implemented piecemeal with the result that users must be fairly sophisticated in their knowledge of computer applications.

Jan 1, 1979

By Regina N. Tempel, Laurie S. Balistrieri, Lisa L. Stillings, Maggy F. Lengke

The Dexter pit lake, within the Tuscarora volcanic field in Elko County, Nevada, formed after closure of the Dexter mine. Mineralogy at the Dexter mine is related to widespread feldspar, silica, and chlorite alteration. Major mineralogy includes quartz, alkali feldspar, albite, phlogopite-biotite, hornblende, iron-titanium oxide, chlorite, kaolinite, smectite, illite, and sericite, with lesser amounts of calcite, zircon, apatite, and rutile. Trace element geochemistry is characterized by high levels of As, Ba. Cr, Cu, V, Zn, B, Zr, Li, and U. Detailed mineralogy and geochemistry are required for geochemical models to accurately predict trace element concentrations in pit lake waters.

Jan 1, 2000

By Salt Lake City Research Center, D. G. Foot, J. D. McKay

As part of its research program on column flotation, the Bureau of Mines, Salt Lake City Research Center has performed studies on (1) column flotation amenability and comparison with conventional flotation results for over 15 mineral systems, (2) alternative methods for improving column bubble generation systems, (3) mineral behavior within a column, and (4) the effect of changes in column operating parameters on flotation grade and recovery. Based on results from these studies, flotation columns (1) are capable of producing higher grade concentrates in fewer stages than conventional flotation cells at equivalent or increased recoveries, (2) require less retention time than conventional flotation cells, and (3) can be divided into cleaning and collection zones that have characteristic mineral-upgrading-per-foot values. Attempts to improve the column air sparger have led to the development of a superior external bubble generation system, which can (1) achieve increased air holdups. (2) produce bubbles from 400 Um to 4,000 Um average bubble diameter with minimal frother addition, (3) provide superior bubble size control, and (4) be maintained without column shutdown. Efforts are continuing to improve column flotation and transfer successful technology to industry.

Jan 1, 1988

By M. Manrique, E. E. Vidal, I. Accorsi, P. R. Taylor

Various pyrometallurgical methods for treating ilmenite and zircon concentrates are reviewed. Laboratory experiments using a thermal plasma reactor were performed to evaluate the conversions of ilmenite to TiC or TiC-Fe and zircon to ZrC or ZrC-SiC. Results are examined and possible processing routes are identified.

Jan 1, 1999

By B. Tönjes

In the course of the last decade, the concept of sustainability has turned from a catchword into a vision - a vision to which politics and industry feel increasingly committed. In terms of the energy industry, the key criteria for sustainable development are supply security, economic efficiency and social responsibility. Coal is able to meet all these criteria if it is produced in conformity with high safety standards through the use of modern mining technology and converted into electricity with the aid of environmentally friendly methods. Among the fossil energy resources, coal will, according to the vast majority of global energy scenarios, continue to be the most important input energy in power generation for the foreseeable future. Coal is therefore today, and will in future continue to be, an important element in ensuring sustainable energy and raw material supply, worldwide, in Europe and also in Germany.

Jan 1, 2005

By J. A. Herbst, L. B. Hales, R. A. Ynchausti

Industrial application, theoretical discussion and technical research programs continue to stimulate acceptance of column flotation. Numerous authors have published model, parameter and application studies discussing advantages and problems which are associated with this minerals processing technique. This paper dispells the myth of the self-controlling column while focusing on the problems and opportunities which are inherent in the computer control of a column flotation cell.

Jan 1, 1988

By N. Harrigle, Tsutsumi

Very fine wet sizing of minerals such as kaolin, precipitated calcium carbonate, lime milk, and clay slip is a difficult process to achieve using standard vibrating screens. With particle sizes ranging in the sub-microns combined with the agglomerating tendencies of certain materials, screen blinding becomes a serious issue. Sizetec, Inc. has developed an innovative screening equipment to help solve this problem. The High Performer Screen uses powerful linear vibrations to help break apart agglomerated particles and prevent screen blinding. Optionally fitted with the Air Explosion Screen Cleaning System, compressed air can be periodically injected into the screen underflow chamber to clean the screen surface without the use of water sprays. This paper highlights some of the key features of the Sizetec High Performer Screen and describes typical performance that can be expected based on results from various trials conducted in the kaolin industries.

Jan 1, 2002

By Bilgehan Kekec, Sertac Dündar, Niyazi Bilim

"Knowledge of the abrasion resistance of aggregates is important when using them for asphalt and concrete mixes and highway construction materials. In this study, the usability of natural building stone waste as aggregates for different engineering applications was investigated. To this end, test samples were obtained from a number of natural stone quarries and stone cutting factories. The abrasion tests were carried out on the test samples and results were compared between samples. The abrasion strength values were determined with both the Micro-Deval (MDe) and the Los Angeles (LA) abrasion test methods. A correlation coefficient was also determined between the LA and MDe tests results using an appropriate statistical model.Introduction The rapid consumption of natural resources has led researchers to work on the efficient utilization of such resources. To this end one can convert waste into useful raw materials, or determine alternative uses of the industrial waste materials. This has become increasingly important as storing or dumping waste may result in environmental problems. In addition, the use of industrial waste in a different application of the construction industry prevents rapid consumption of limited natural resources and can mitigate environmental problems related to raw material production, Industrial waste such as blast furnace slag, fly ash, building demolition material, marble waste and dismantled asphalt have been used as highway and concrete materials (Ahmed 1993, Ramaswamy and Aziz 1992, Schroeder 1994, Ceylan and Manca 2013, Holtz and Eighmy 2000, Hebhoub et al 2011). It is very important to analyze whether these aggregates are of the required quality in terms of their application and their economic life. This analysis can be carried out using various tests such as the Micro-Deval and the Los Angeles abrasion tests, sieve analysis, durability chemical resistance, peeling and adhesion, and freezing-thawing tests (Erdem et al 1996). Specifications for aggregates also include terms that define the grain shape, cleanliness and surface textures."

Jan 1, 2017

By G. Olson, T. Mudder, T. Clark

An evaluation was made of an innovative chemical approach for controlling the biotic portion of sulfide oxidation of tailing and waste rock using thiocyanate. This lipophilic anion is selectively toxic toward acidophilic bacteria, including those that oxidize metal sulfides. Sulfidic materials from precious metal and base metal mining operations were treated with thiocyanate solutions and subjected to accelerated laboratory weathering at 1 to 50 kg scale in humidity cells, trays, and columns. Initial field trials were conducted at 13.6 t and 100 t scale. Thiocyanate at relatively low concentrations reduced ARD from 50% to over 99%, depending on the sample and specific ARD parameter measured. Test work also was done with phosphate as an agent to coat reactive sulfides, further reducing their oxidation by biological and chemical reactions. The combination of phosphate and thiocyanate treatment is the basis for a potentially comprehensive approach to ARD prevention and control. Additional research and pilot testing are underway.

Jan 1, 2004