Search Documents

By S. Seetharaman, Du Siehen

"In the processing of molten metals, it is extremely important to monitor continuously the concentration levels of various minor elements. In the production of common metals like copper, iron and aluminium electrochemical sensors involving solid as well as liquid electrolytes are being increasingly used to measure the concentrations of minor elements. The present paper deals with the electrochemical principles underlying these measurements and the possible errors involved. One of the major difficulties in the case of the solid electrolytes is to correct for the consequences of the electronic contribution to the conduction of the electrolyte.The application of the electrochemical sensors for molten metals processing involves designing of these probes to withstand the industrial operating conditions. In this respect, significant achievements have been made with respect to the design of oxygen probes for liquid metals in general and liquid copper in particular. Some of the salient design features are discussed in the paper. The application of auxiliary electrodes for impurities in molten metals like phosphorus in copper and silicon in iron are taken up. The development of oxygen sensors for slags is given special attention. Recent developments in the field of sensor technology, as applied to metals processing are highlighted.1. IntroductionThe rapid technological advancement today require precise control of the process parameters and the impurity levels. Most of the molten metals processing in industrialized countries are often steered by suitable computer models, either phenomenological or simulations based on theoretical principles. These models often require that the process parameters are continuously monitored so that the progress is followed and modified suitably as and when required. It is common practice to measure temperatures by incorporating temperature sensors at the various strategic points of the reactor. In the case of monitoring the composition changes in the various phases, the method of sampling followed by routine chemical analysis involves a time lag as well as uncertainties in sampling and analysis. In this respect, electrochemical sensors have the advantage of generating accurate data when properly applied and increasing attention is being paid in the development of electrochemical sensors for various common species in molten metals processing. In the present paper, the developments in this area over the years are outlined and typical process applications are discussed. A greater emphasis will be laid on sensors based on oxygen conducting electrolytes and their application to the production of common metals like iron and copper."

Jan 1, 1996

By S. Kelebek, U. Demir, T. C. H. Richards, E. Koss

"Laboratory-scale tests were carried out to investigate the response of a high-grade (~143 g/tonne) well-liberated gold ore to flotation using two collector types. Octyl and amyl xanthates, representing conventional types of collectors, were tested against an n-octanoic and hexanoic acids under moderate and high redox potential conditions. The latter was based upon a suggestion in literature that monocarboxylic acids are able to adsorb onto the surface of gold at redox potentials near 600 mV (SCE). This investigation did not demonstrate that these carboxylic acids could function as collectors for gold in real ores. In fact, they appear to have slightly depressed gold. However, the results demonstrated that octyl and amyl xanthates acted as highly effective gold collectors for this ore and that an increase in the collector dosage led to an increase in recovery for all mean particle sizes. In some tests, gold recoveries of around 95% were attainable in concentrates with grades around 6 kg/tonne, indicating that xanthate flotation remains a viable means of concentrating gold even at coarse grain sizes. Various aspects of the process such as grade-recovery performance and recovery by size are discussed.INTRODUCTION Three methods are used for the recovery of gold in mineral processing, either alone or in combination: gravity concentration, cyanidation and flotation. Gold occurs as a by-product in some ores together with platinum group metals and as the primary metal in other ores in the form of native gold and electrum, which are alloys of gold, silver and minor amounts of copper. Flotation is a viable method for recovering liberated gold where the gold is visible under an optical microscope (greater than 1 µm in size) and where the attachment of gold grains is not prevented due to bubble loading by competing minerals. It is generally known that grains finer than 150 µm in size will float with most collectors."

Jan 1, 2017

By J. H. Zietsman, M. W. Erwee, Q. G. Reynolds

Pyrometallurgical furnaces, essential for metal extraction, operate at temperatures exceeding 1600°C and represent complex multiphase systems that challenge direct industrial research. Multiphysics models play a key role in shedding light on their intricate behaviours, supporting the refinement of design and operational strategies. Integral to the operation are the tap-holes, which facilitate the removal of molten products and are routinely opened by lancing, a process comparable to the use of a cutting torch, where high temperatures result from oxygen reacting with an iron lance. When the lance pierces the clay, oxygen gas enters the furnace, which could influence the behaviour of the molten material inside. In this work, a multiphase fluid flow model was used to investigate bulk flow dynamics, with a focus on the effects of the lancing process on the inside of the furnace, immediately behind the tap-hole. Incompressible and compressible multiphase fluid solvers were used and compared with respect their performance – the intention was to assess whether using a compressible solver would yield a different solution to the incompressible one. It was concluded that there are negligible disparities in bulk fluid flow behaviour between the solvers for the case studies examined, indicating that solver selection might be less consequential for certain aspects of oxygen lancing.

Apr 16, 2024

Safety is the No. 1 concern of any drill contractor or mine operator. Everyone in the industry knows a safe site helps stabilize operational costs and enables higher productivity. When it comes to exploration drilling, research has proven a majority of injuries are caused by the mishandling of coring rods. A driller helper will typically handle up to 50 rods per shift or up to 15,000 rods per year. With an annual 340 t (750,000 lb) in rods managed by hand, the risk of serious injury is extremely high. Because of this, the top request from the exploration industry is diamond rod handling. The Boart Longyear 4200 surface exploration drill, slated for release in 2009, will give the industry a hand-free, operationally safe rig.. Developed through the collaboration of its global drilling services and products divisions and targeted at the 1,200-m (3,900-ft) NQ market, the upcoming Boart Longyear 4200 surface exploration drill features the safest and most flexible rod management sys-tem in its class. The rig includes the industry?s first, truly hands-free rod handling system. This increases operator safety on the jobsite. In addition to the rod handler, the rig also features many new innovations that boost productivity and rig efficiency while minimizing the risk of downtime due to component failure or operator error. Boart Longyear has also included an intelligent PC-based operating system designed to allow complete drilling control as well as diagnostics reporting for the rig.

Jan 1, 2009

By C. A. Herbert

The mine of the Alpha Portland Cement ..Co., Iroaton, Ohio, ..working in. a. bed of limestone 96 feet thick at a depth of approximately 510 feet below the surface, has established a won¬ derful safety record, having operated 6 years—frcra September 21, 1926,. to September 21, 1932 - without a lost-time accident. This mine, with 61 to 86 employees (average 68) and daily output of 1,000 to 1,200 tons of limestone, operated 1,041 days during the 6-year period, or the equivalent of 578,894 man-hours of exposure. ...... ... . Immediately above the limestone is a 20-foot .bed of hard..sandstone.. At present about 10 feet of limestone is left up as. a roof and.about. 42 feet is being extracted. Of the lower portion of the bed it is believed that about. 25 feet. ..immediately below . the .present workings is suitable for cement and will be extracted later. The mine workings are reached by two rectangular concrete shafts, one a 2-compartment hoisting shaft and the other a 2-compartment air and escape shaft- In the latter shaft one compartment is used as an airway and the other, as a cage compartment fo.r a man and material cage. .. . - . The tipples at both the air shaft: and. hoisting shaft are-of steel. The.ground landings at both shafts are fenced in with hand-operated gates in front of the cage compartments.- The two shafts and the crushing plant, which .is.a part of the hoisting shaft-tipple structure, are adjacent to the mill buildings. The rock is hoisted on self-dumping cages in 4 ton capacity, end-gate, steel cars. An electric hoist with automatic overwind device is used at both the main shaft and air shaft. The controls for the main hoist are in the tipple where the engineman is stationed and from which point he has an unobstructed view of both the ground, landing and the cage coming into the dump.

Jan 1, 1933

By Erica McGlynn, Brian Negrea, Lance Jackson

There was no need for the people of Cleveland to ask “Where does the raw sewage go? We want to know!” because it was clear. The raw sewage was being discharged into Lake Erie during heavy rainfall events due to the outdated design of the combined sewer system. In efforts to resolve this ongoing issue for the City of Cleveland, the Northeast Ohio Regional Sewer District developed Project Clean Lake in collaboration with the US EPA. Project Clean Lake is a 25-year, $3 billion program consisting of seven large-diameter CSO storage tunnels to be constructed beneath the city’s existing infrastructure. The first four tunnels have been completed using traditional hard rock TBM excavation methods. The fifth tunnel, the Shoreline Storage Tunnel Project, presents unique challenges and complexities as it will be the first large-diameter EPB TBM to dig under the City of Cleveland. The project itself consists of one tunnel drive 14,100' (2.7 miles) in length, two pipe jacking tunnels, three large slurry wall shafts, two diversion structures, and three regulator reconstructions. Upon completion of the project, 12 permitted CSO locations along Lake Erie will be taken offline, reducing overflow volumes by approximately 350 million gallons per year. This paper will discuss the current status of construction and the chosen means and methods, including the myriad of nuanced differences between hard rock and EPB TBM tunneling methods. Particular attention will be given to the site preparation, setup, and organization; TBM assembly; and TBM launching practices.

Jun 13, 2023

By S. Paul Singh

"The long-term viability of seismically active and/or deep mining operations hinges upon the industry's ability to maintain profitability in a climate of increasingly difficult conditions, escalating operating costs and fluctuating metal prices. Within this context, it is prudent to explore mining techniques that could provide means for safer and more profitable extraction of seismically active and/or deep seated deposits that are vital to the long term survival of the industry.The first step was to examine Penetrating Cone Fracture (PCF) and other relevant concepts with the objective of semi-continuous mining in deep underground hard rock mines. This was followed by an assessment of the current conventional drilling and blasting practice. Thirteen blasts were monitored in five different seismically active workings of an operating deep mine. The main concerns during the current drill and blast practice were identified.On the basis of the literature review, three short round blasting techniques were short listed for further review. These techniques were evaluated based upon the available literature and discussions with the persons associated with their applications. Justification, requirements and major challenges for the application of short round blasting have been discussed in this paper. Suggestions for improving the current drilling and blasting practice have also been outlined.INTRODUCTIONRock fragmentation is the key to mineral excavation and production. Increasing working depths, environmental concerns and trends towards continuous mining necessitate the development of new and improved rock breakage methods.The excavation of hard rocks is still dominated by the sequential routine of face preparation, drilling, charging explosives, blasting, ventilating for fume and dust removal, mucking and roof support. Worse still, drilling and mucking require specialized equipment that fills the end of the heading so that no other operation can be performed and the equipment must be removed from the face to protect it from fly rock."

Jan 1, 2010

By E. L. Schrader

Statistical Process Control (SPC) is a cooperative arrangement between a component or raw materials supplier and a manufacturing customer. The supplier must analyze his own manufacturing process and determine, predict, and control those variable elements in the circuit which affect finished product characteristics according to the customer's specifications. The results include: control of fluctuations in product characteristics to a narrow range, close communication between supplier and customer, and an increased responsibility for quality control placed on the supplier. In the mining and. processing of airfloated kaolin some unique problems arise with the SPC concept: 1) The SPC system was designed for manufacturing facilities that did not have to deal with natural variations in their raw material; 2) The airfloat process is relatively simple and offers limited opportunity to change processing steps or "fine tune" a circuit for special product needs; 3) Determining adequate sampling frequency for a plant which processes hundreds to thousands of tons per day is statistically difficult; and, 4) Due to the variety of customer industries served, different SPC programs must be set up to deal with widely varying specifications. For airfloated kaolin, SPC is "in line" process control, not after the fact "quality" control. The emphasis must be on statistically valid sampling of the kaolin ore and complete monitoring of its path through the beneficiation circuit.

Jan 1, 1987

By T. Mulja, Michel Boily, Anthony E. Williams-Jones, Pierre Pilote

"The Preissac-Lacorne batholith is composed of suites of early metaluminous calc-alkalic gabbroic to granodioritic intrusives, three late peraluminous monzogranite plutons and numerous Li, Be and Ta-bearing granitic pegmatites. The Lacorne pluton is dominated by biotite and biotite + muscovite monzogranites containing abundant Be and Ta-bearing granitic pegmatites (40-80% volume). The pluton is surrounded by swarms of unzoned or poorly zoned spodumene-rich pegmatite dykes. The La Motte pluton is composed of biotite monzogranites, biotite+ muscovite monzogranites and rare muscovite + garnet monzogranites. Li, Be and Ta-bearing pegmatites are less abundant than in the Lacorne pluton and are commonly associated with molybdenite bearing quartz-muscovite-K-feldspar veins. In the Preissac pluton, muscovite + garnet monzogranites and muscovite + biotite + garnet monzogranites are the dominant rock types. The pluton rarely contains granitic pegmatites and these are generally barren. However, numerous molybdenite bearing quartz and quartz-feldspar-muscovite hydrothermal veins are observed.Li, Be andTa-bearing pegmatites display a crude spatial zonation around their parent monzogranites. Spodumene-rich pegmatites are generally unzoned or poorly zoned and are confined to the surrounding metasedimentary or metavolcanic rocks or crop out in the early gabbroic to granodioritic intrusives surrounding the monzogranites. Ta and Be-bearing pegmatites are usually concentrated towards the margins of their parent monzogranites. The highly fractionated nature ofmonzogranites (high Rb/Sr, low K?Rb, Ba?Sr, Zr/Nb ... ), their peraluminous composition (corundum normative and muscovite bearing) and the numerous occurrences of Ta and Be-bearing pegmatite dykes represent important criteria for the exploration of fertile granites."

Jan 1, 1990

By E C. Holloway

"The financial valuation of mining assets has a number of fundamental differences to the valuation of many other asset groupings. One such difference is that typically, the greater proportion of both the cost and revenue sides of the cash flow are inherently governed by systemic market forces.As a result, the range of outcomes for the valuation of each mining asset is more unpredictable, with higher levels of risk and uncertainty. In contrast, the management function of many other non-mining businesses or industry groups can control at least a portion of the cash flow by maintaining the margin or controlling the sales price. The management teams of mining businesses and operations typically have limited options, and are thus price-takers for both costs and revenues. As mining is an inherently cyclical industry, large, long-life operations can exist through several price cycles, making valuation both subjective and challenging.The outcomes of both static- and stochastic-based valuations, as well as the internal probabilities of the associated cash flow statements, are significantly impacted when the correlations between the appropriate parameters are quantified, modelled and incorporated into the valuation framework. The appropriate parameters for correlation modelling primarily include those that are governed by systemic market forces. Applying this process results in a different risk profile for the asset by allowing the risks resulting from systemic market movements to be more accurately quantified and then objectively minimised. This process also reduces the level of residual uncertainty in the valuation outcome.This paper presents a valuation methodology to pragmatically incorporate this level of valuation sophistication and statistically quantify the associated increase in the level of confidence of the valuation outcomes reported.CITATION:Holloway, E C, 2016. Correlated valuation methodology, in Proceedings Project Evaluation 2016, pp 181–200 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 8, 2016

By C. Roos, K. Jetmore

Developing a strategic underground mine plan is challenging and investigating multiple scenarios may take weeks. This process can be sped up using the Theory of Constraints to isolate the bottleneck mining activity and simplify the mine schedule process. This paper presents a technique to apply the Theory of Constraints to test multiple cutoff grade scenarios in Mineable Shape Optimiser and quickly produce many high-level production-based schedules that can be easily interpreted using stope-by-stope graphs, the Hill of Value, and through incremental return analysis.

Mar 2, 2022

By Jack C. Haptonstall

The Tayoltita Unit of Minas de San Luis, S. A. is situated in an isolated corner of the state of Durango, Mexico. The ore deposits in the region were first worked by Indians, but by 1757 the Spaniards had discovered them, and the first systematic exploitation of the mines commenced. By the early 1900's most of the mines had been acquired by American interests, and the San Luis Mining Company was organized. The modern period of exploitation, uninterrupted for the last 74 years, began. In 1962 the company was fully "Mexicenized" in compliance with the modification of the mining law, and the name was changed to Minas de San Luis, S. A. Tayoltita continues as one of Mexico's most important silver and gold mines. The ore is extracted in en extensive underground operation, mining epithermal fissure veins by selective methods. The ore is milled and treated in an efficient counter-current cyanide plant, where 95 % of the silver and 96 % of the gold is recovered. Current annual bullion output is 55,000 kg (1.7 million troy oz) of silver and 1000 kg (31,000 troy oz) of gold from milling 165,000 try (181,900 stpy). Rough, 33-kg (1000-troy oz) bullion bars are smelted at the mine, shipped by air to Mazatlan, Sinaloa, and are thence sold to the Met- Mex Peñoles smelter in Torreon, Coahuila. Ore reserves, blocked by very conservative methods, are currently at 540,000 tons (595,000 st). Ore reserve grade is 425 g of silver and 6 g of gold per ton (12.4 troy oz Ag and 0.18 troy oz Au per st).

Jan 1, 1976

By Neil D. Donnell, O&apos

Ore reserve estimation at the Syncrude Canada Ltd. open-pit oil sands mine in Northern Alberta has evolved since the project's inception. Early techniques followed a conventional petroleum reservoir analysis format, with relatively widely-spaced drill holes and semiquantitative grade data. Experience has developed a more standard mining approach, including classification of geological materials by both lithology and sedimentary origin, timely and multi-purpose drill holes, precise analytical data, empirical recovery factors, a computerized geological data base, and an ore body block model. Future efforts will involve enhancement of existing techniques, use of geostatistical algorithms, quantification of confidence limits, and improved control of the ore model by geological parameters.

Jan 1, 1985

By Jan C. Still

The Glacier Bay subarea is that part of the Juneau Mining District (JMD) within Glacier Bay National Park and Preserve (GBNP). It is the western portion of the JMD and consists of the land between the Fairweather Range crest and the Takhinsha and Chilkat Ranges crests (excluding that land east of Excursion Inlet.) Figure B-1 shows the area. It is bounded on the north by the Alaska-British Columbia International boundary, to the south by Cross Sound and Icy Strait, and contains Glacier Bay. During 1975 -1977 the Bureau conducted a detailed study of the occurrences, prospects, and deposits in GBNP (B_4).2 This work was in cooperation with the U.S. Geological Survey (USGS) under the provisions of the Wilderness Act (Public Law 88-577). As a follow up to this earlier Bureau work, limited studies were conducted, during 1985 and 1986, as part of the JMD study. This report covers the most important aspects of the earlier studies and the 1985 and 1986 studies. ACCESS The Glacier Bay area may be reached through Gustavus airport, a paved strip which is serviced by scheduled jet airliners in the summer and air taxi services year-round. The airport is connected to Bartlett Cove (GBNP headquarters) by an all-weather road. No other roads exist in the area except a skid road to the LeRoy Mine and mill in the Reid Inlet area. Much of the Glacier Bay area is accessible through the salt water inlets and fjords which are part of Glacier Bay. Cruise ships, charter boats, and fishing boats visit these inlets and fjords during the summer months. Elevations within the area range from sea level to over 15,000 feet in the rugged Fairweather Mountain Range. More remote areas are accessible by small boat, foot, or helicopter. Glacier ice is a year-round hazard to navigation in Glacier Bay, and during the winter months some of the more northerly inlets are frozen.

Jan 1, 2012

By ALBERT F. J. BOARDEAUX

(Canal Zone Meeting, November. 191(j.) I. GENERAL INTRODUCTION. 1. Historical. ALLUVIAL gold was first discovered in Guiana in 1852, in the sands of the Arataye river; by Paulino, a Brazilian convict. During the following years, gold was found also in the rivers Orapu, Cirubé, etc. In 1873 the famous placers of the Sinnamary system were opened: Saint-Elie, Dieu-Merci, Adieu-Tat, and Couriége. This group of mines has produced nearly $10,000,000, according to official records, not including the gold that escaped the taxes. The discoverer was a mulatto named Vitalo. Except in a few rich spots, the gold was rather evenly distributed along the creeks. In one instance, gold was found in the red dirt from the slope of a hill, which, after transport to the creek, gave an amount of 150 kilograms. The placers of the Mana system, Enfin, Elysée, Pas-Trop-Tot, date from 1878, and their production has been about $5,000,000. In 1888, the Awa placers, along the boundary between the French and Dutch Guianas, on the Maroni and its tributaries, were discovered. They have yielded $12,000,000. The only industrial company,, the Dutch Guiana French Mining Co., produced in 15 years about 2,500 kg. of gold, worth $1,500,000. From 1893 dates the famous Carsewene discovery, in territory then in dispute between France and Brazil. A settlement was made recently in favor of Brazil, by arbitration of the Switzerland State Council. Carsewene is said to have pro-duced about $18,000,000 in six years (1894-1900), but not even one-fourth of the production went through French Guiana and

Nov 1, 1910

By Halagowder Devaraj, Mostafa Sheykhnazari, Veer P. Bhavanandan

"A sensitive colorimetric assay for detecting mucins and glycoproteins rich in 0-glycosidically linked saccharides is reported. The method combines the susceptibility of N-acetylgalactosamine terminating 0-glyco idically linked saccharides to P-elimination with the Morgan-Elson reaction for N-acetylhexosamines with free reducing ends. All mucin and mucin-type glycoproteins but none of the serum-type glycoproteins tested resulted in characteristic color production. All mucins tested gave linear responses in the range 5 to 200 ""g and the assay was also adapted to the microscale involving the use of 96-well microtiter plates. The microassay in which the volumes of samples and reagents are scaled down 2.5-fold was particularly useful in monitoring of mucins, in the presence of other glycoconjugates, in large numbers of samples obtained during fractionation procedures. Cesium chloride, cesium bromide, potassium thiocyanate, and various detergents do not interfere with the colorimetric determination. Guanidine hydrochloride, cesium triftuoroacetate, and B-mercap- . toethanol decreased color by 30 to 45%; however, the interference was not serious to prevent the use of the method for detection of mucins in their presence. The use of the method for the specific detection of mucin during fractionation by gel filtration and density gradient centrifugation of cystic fibrosis sputum samples is demonstrated. Mucins are an important class of biomacromolecules whose structure-function relationship is poorly understood (1,2). The investigations of mucins are hampered by difficulties in purifying these very large size molecules which appear to avidly bind other components of the mucus (3,4). One of the problems during purification is the specific detection of mucins. For example, during the various purification steps, the fractions containing mucins are typically detected by assaying for neutral sugars (hexoses) (5,6), for sialic acids (7), or for periodate oxidizable saccharide units (8). However, these methods are not entirely satisfactory because neutral sugars, sialic acids, and periodate-oxidizable saccharides are also components of other glycoconjugates. In addition, the neutral sugar and sialic acid measurements are also subject to interference from high levels of proteins and nucleic acids."

Jan 1, 1990

By H. Dreissen

Upgrading of low-concentration ores is of growing importance today. The Heavy Medium Cyclone Process, thanks to strong centrifugal forces, effectively separates particles varying only slightly in specific gravity but widely in size. The paper discusses the separation efficiency, the method of assessing that efficiency, and the influence of such factors as medium solids. The operating results of nine heavy medium cyclone plants handling following minerals are reported: barite, wolfram, iron, magnesite, diamond, lead-zinc, fluorspar, rocksalt potash. Highlighted are an improved recovery system for heavy medium and some other developments, such as techniques for separation down to 0.1mm and the application in the field of recycling.

Jan 1, 1980

By Benjamin W. Haynes

As part of the first-order assessment of potential manganese nodule processing reject waste materials, the Bureau of Mines estimated the physical and chemical characteristics of reject waste materials that would be generated from each of five potential process flowsheets. These processes were chosen because of their economic and technical feasibility for first-generation nodule processing. A brief description of the five processes is given to show process inputs and outputs, The physical characteristics are predicted based on land-based laterite processing where applicable, and where no land-based analog exists, on the basis of process chemistry. The probable chemical characteristics such as element content and compound form are tabulated for each process for 16 elements: As, Ba, Be, Cd, Go, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se, TI, and Zn. These elements were chosen based on their presence on the toxic substance list of priority pollutants, EP toxicity criteria, and major and minor elements of economic importance (Co, Fe, Mn, and Mo). Physical and chemical analyses as well as results of the EP toxicity test of one industrially supplied pilot plant reject waste material are presented.

Jan 1, 1982

By G Haywood

This paper presents the evolution of the planning, scheduling and mining practices at the Yilgarn Star underground. The paper will concentrate on the principals of æjust in timeÆ and the impact of such practices on mine planning and scheduling and subsequent development and production. The principals of æjust in timeÆ were developed to minimise the impact of creep and time dependent failure of the ground in the ore and hangingwall zones. These zones are characterised by altered schistose material with inherent weak rock strengths compounded, at depth, by the maximum principal stress of the virgin stress field approaching the UCS of the rock mass. Yilgarn Star underground has and continues to develop the æjust in timeÆ methodology to ensure the continued viability of the mine. The mine continues to use longhole open stoping mining methods to ensure high levels of productivity with minimal dilution and at an acceptable cost of production.

Jan 1, 2002

By CHENCHEN SUN, GUOPING LUO, GUOCHENG ZHANG

Preparation of briquettes by adding CaF2 reagent into the Australian iron ore powder. The structure and morphology of iron ore briquettes during various reduction stages (i.e., Fe2O3→Fe3O4, Fe3O4→FeO, and FeO→Fe) were observed via an ore microscope and scanning electron microscopy. The results showed that CaF2 reacted with SiO2 to form CaO and SiF4 gas during the roasting process. The reduction swelling index decreased from 12.36 to 8.83% when the CaF2 content in the briquettes increased due to CaF2-mediated refinement of the hematite grains during the first stage of the reduction process. Lattice distortion resulting from the presence of Ca2+ in the FeO lattice during the second stage of the reduction process, coupled with an increase in the porosity of the iron ore briquettes and the formation of a low-melting-point slag phase, promoted the anisotropic growth of FeO lamellar crystals, which resulted in an increase in the reduction swelling index from 4.27 to 7.36%. During the third stage of the reduction process, the growth of iron whiskers was promoted by wüstite (FeO) lattice distortion caused by a solid solution of Ca2+ in the FeO lattice; the reduction swelling index increased from 15.61 to 24.72%, resulting in the catastrophic swelling of the iron ore briquettes.

May 27, 2021