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By O Ishiyama, L Lu

Sintering is the most economic and widely used agglomeration process to prepare iron ore fines for blast furnace use. Due to the depleting reserves of traditional high-grade iron ore, there have been considerable changes in iron ore resources available throughout the world, especially in steel mills in East Asia. Corresponding to the changes in the availability of iron ore resources, the amount of impurities in iron ore has been slowly increasing. Some of these impurities have been found to have deleterious impacts on sinter quality and sintering performance. In the meantime, an increasing number of large blast furnaces with inner volumes of more than 5000 m3 have been built that require more sinter and are often more demanding in terms of the quality requirements of the ferrous materials. Finally, sinter plants are facing increasing pressure due to more stringent regulations regarding their environmental impact. This paper gives an overall review of a variety of technologies developed worldwide to tackle the changing raw material characteristics and mitigate emissions from sintering operations.CITATION:Lu, L and Ishiyama, O, 2015. Recent advances in iron ore sintering, in Proceedings Iron Ore 2015, pp 61–68 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

With the iron ore industry in Australia producing hundreds of millions of tonnes of ore per annum, the associated costs of these operations extend into the billions. It is no surprise in the current economic climate that more and more companies are looking into different ways of optimizing their costs to keep their sites operational. One way of improving operations is the use of electronic initiating systems like i-kon and Uni tronic detonators. These systems have been used around the world to improve current practices and optimize drill and blast costs. However, these systems have yet to make an impact upon the iron ore sector in Australia. Some of the potential improvements include:pattern expansion and a subsequent reduction in drilling and explosive costs;improved fragmentation and hence increased dig rates, thereby driving $/tonne down;embracing the 'mine-to-mill' concept by reducing the downstream costs of crushing and milling;improving the overall condition of pit walls and floors, leading to a safer working environment in which optimal haulage performance can be achieved; and improvements in vibration management around heritage sites and critical infrastructure, thereby saving the cost of relocation works. This paper introduces some of these concepts and the process of making the changes leading to potential savings from the improvements, using various examples as proof of the concepts.

Jan 1, 2009

By C I. Edwards

Phosphorous is typically present in iron ore either in the mineral apatite, Ca5(PO4)3OH, or associated with the goethitic fraction of the ore. In this paper, we present results that show that phosphorous associated with the goethitic fraction can be removed with a heating pretreatment around 300 176;C for 1 h, followed by a caustic leach with 1 - 5 M NaOH, or a leach with sulfuric acid at pH 0.5. The heating pretreatment is considered to dehydroxylate the goethite to form a haematite intermediate phase, ‘protohaematite’, that reacts during the leach making the phosphorous accessible to the leachant. In the acid leach, ten to 15 per cent of the sample was dissolved to obtain a leach product with 0.08 per cent P. In the caustic leach, as no weight loss occurs, it is proposed that iron species associated with the protohaematite have either not dissolved or have reprecipitated at the high pH values of the leach.For an ore containing apatite as the source of phosphorous, a leach with sulfuric acid dissolved the apatite, lowering the phosphorous levels in the sample. The sample treated contained carbonate minerals (including siderite) that also reacted with the acid, and in practice a balance between the dissolution of the apatite and the carbonate minerals may be needed to minimise acid consumption.

Jul 11, 2011

Valuers of mineral properties should be aware that accountants are a major user of their opinions of value. Reliance by accountants can range from obtaining comfort that book values in balance sheets are not overstated to establishing values by which to assess the fairness of a takeover offer. Accountants using mineral property valuations clearly can't be expected to have the same level of expertise as the valuer and ""second guess"" the valuation. But they do have an obligation, under the ASC guidelines and their own professional standards, to'check the logic and reasonableness of the valuation before being able to rely on it. This means reviewing the valuation report for general sensibility, discussing the methodologies and assumptions with the valuer and being satisfied as to his competence and independence. This paper outlines how accountants use mineral property valuations, the level of scrutiny applied to such valuations and the problems commonly encountered in practice by accountants seeking to rely on them. The paper also explains how values of-mineral properties are established in company balance sheets and why these often differ, quite validly, from fair market values.

Jan 1, 1994

By H R. Phillips

Fresh air intake in an underground coal mine is of critical importance to the occupational health and safety of workers due to the dynamic, confined and dangerous nature of the mining environment. In most coal mines in South Africa, belt road is not separated from the fresh air intake to the sections. Intake air to coal production faces generally contains dust generated by conveyor belts, transfer points and travelling roads. Long roadways (up to a few kilometres in some of the existing mines) to the coal sections are involved in the ventilation circuits of individual sections. This leads to a progressive increase in the dust levels in the intake fresh air and thus high dust levels in the air delivered to the working sections downstream. In the process of reducing worker exposure to dust in the face area, attention to the monitoring of fresh intake air is generally given a low priority. This paper summarises the intake dust levels measured in selected South African underground coal mining sections over the past five years and its use as a parameter in assessing worker exposure to dust through a newly developed model called the Dust Exposure Level Index (DELI). Based on the measured data of the South African coal mines, the average section intake dust level was 0.78 mg/m3. Approximately 60 per cent of the samples collected for the study have exceeded the 0.5 mg/m3. The intake dust level measured at a longwall face was much higher than in the CM headings. The measured section intake dust levels furnish the South African coal mining industry with the latest depiction of the level of face area dust contamination due to the intake air. Further, this paper demonstrates the use of intake dust level as a parameter in estimating exposure levels of workers, as it clearly plays as a corner stone in effective control of exposure to face area respirable dust. It must be borne in mind that intake dust is a base level to the mine worker exposed to dust without carrying out any additional work in the section. If the intake air is seriously contaminated by airborne respirable dust; then the exposure of the workforce in the section will constantly be elevated by that background dust level.

Jan 1, 2005

By Rowe P, Rogers D, Warren M

Pressure cyanidation of the minus 10 micron slimes fraction of the Fimiston flotation concentrates for the recovery of gold values has been evaluated as an alternative processing route to the roasting and atmospheric cyanide leaching of the calcine. Laboratory and pilot trials have demonstrated that gold extractions of greater than 94 per cent can be achieved at cyanide consumptions of 12-24 kg/t and oxygen consumptions of 0.1-0.3 Nm3/t with total pressures of 1000-2000 kPa. Economic and operational assessment of several reactor configurations suggests autoclaves may be preferred over pipe reactors at treatment rates of 10 t concentrate/h.

Jan 1, 1996

The Key Issues - An Overview Minerals industry needs Mining companies want technologies which are ò cost-effective, ò high likelihood of delivery (ie transfer existing technologies from other industries), ò highly useable, ò an evolutionary rather than revolutionary approach, and ò to be developed in partnership with the mine, supply groups and researchers, For example, `soft' systems for information collection to better manage the mining process rather than mechanical systems.

Jan 1, 1997

By Standish N

The heterogeneous reactions of carbonaceous materials with oxidising gases are basic to all combustion phenomena and to many gasification processes. The carbon- carbon dioxide reaction at elevated temperatures (Reactivity) plays important roles in many metallurgical operations like iron blast furnace and ferro-alloys smeltings, zinc and lead smelting, alumina reduction, cupola operation and direct reduction processes. The stoichiometry but not the mechanism of the reaction between CO2 and carbon is represented by the equation (Boudouard reaction) CO2 + C 2CO (1) This reaction is more complex than that between carbon monoxide and metal oxides, which involves essentially a transfer of oxygen from the oxide to carbon monoxide to generate carbon dioxide without any change in gas volume, whereas the volume of the product gas of Equation (1) is twice that of the reactant gas. In the present paper an attempt has been made to review critically the reactivity measurements of various carbonaceous materials in carbon dioxide atmosphere. Steps in C-CO2 reactions, surface reaction mechanism, role of mass transfer on reaction kinetics, dynamic oxygen exchange reaction and rate equations and rate controlling steps are discussed. Various methods of reactivity measurements with their pros and cons are also presented. Effects of pertinent process variables on the reactivity of carbon are also described in detail.

Jan 1, 1986

By M Zhu, G Tranell, J You, K Tang, X Ma

The thermal conductivity of slag is critical for the efficiency of high temperature metallurgical processes such as the smelting reduction of ferroalloys, the ladle refining and the continuous casting mold flux in steelmaking. Experimental determination of slag’s thermal conductivity is fraught with challenges, as seen in yielding data for the SiO2-Al2O3-CaO system that are often inconsistent and widely dispersed. In molten slags of this system, thermal transport occurs via phonons within the network structure. To quantitatively describe thermal conductivity based on the microstructure, hightemperature Raman spectroscopy was employed to measure the silicate tetrahedra Qi (i = 0, 1, 2, 3), with Q4 species inferred from mass balance. This study also integrated molecular dynamics simulations to provide a fundamental understanding of the microstructure units distributions. Machine learning algorithms, especially deep neural networks, were applied to establish the relationship between slag composition and the configuration of tetrahedra. The thermal conductivities were then connected with silicate tetrahedra Qi using an Arrhenius-type formalism. This study sets the stage for extending our findings to more complex, multicomponent slags, enhancing their practical application in industrial processes.

Aug 21, 2024

In 1987 the control strategies at the then ZC Mines' New Broken Hill Consolidated concentrator were a miscellaneous mixture of computer hardware and technology for ISA, grinding and residue thickener control. Field instrumentation was based on current-to-air technology of approximately the 1960s. Decisions were made to rationalise computer and field instrumentation technologies; the object being to consolidate control loops into one system to enable expansion of the system to include all facets of plant operation. The first stage was to install a DEC Micro PDP 11/23 computer and serial line communication as recommended by AMDEL Ltd, for the ISA system, as discussed by Walsh and Freeman (1988). The second stage was to select and install a distributed control system for the centralisation of the control loops into one system, and to replace field instrumentation with state-of-the-art technology. This paper deals with the second stage of the rationalisation, in an attempt to give an insight into what is required when personnel are faced with such a decision, details of costs involved in keeping a system functioning and utilised; and the requirement to train personnel for acceptance of further control strategies.

Jan 1, 1991

By K A Plumb

New structural studies in the Walker Fault Zone of eastern Arnhem Land are integrated with basin-wide reconnaissance observations, made to refine models for the structural evolution of the McArthur Basin and provide new insights into the nature of metal logenetical ly important pre-inversion phases of the basin's evolution. At least five principal events may be identified during the Proterozoic: The Tawallah Group and equivalents were deposited throughout the McArthur Basin during an extensional event. Rifting of an incipient Batten Trough occurred at this time, in a terrain characterised by orthogonal, linked extensional faults. Uplift and erosion of the Tawallah Group accompanied continuing extension and was penecontemporaneous with continuing deposition of the overlying Parsons Range Group, within a precursor to the Walker Trough. Dt (of the Walker Fault Zone) relates to a new rifting event, penecontemporaneous with deposition of the McArthur Group and its equivalents in the Walker and Batten Troughs. This rifting accompanied dextral strike-slip faulting along northerly-trending bounding faults, as a result of northwesterly-directed oblique extension, leading to pull-apart basins. D2 inversion of the Batten and Walker Fault Zones pre-dates deposition of the Roper Group. In the proposed model WNW-ESE directed shortening (D2.), accompanied by folding and thrusting, and by local development of cleavage in the Walker Fault Zone, is seen to be followed by northerly-trending sinistral faulting (D2b), about a SE to ESE-directed compression. D3 is basin-wide and post-dates the Roper Group. It is characterised by conjugate faulting and folding about ENE to NE-directed compression. The latest Proterozoic event to be identified (D4) comprises widespread north-trending strike-slip dextral faulting of Roper Group, coupled with N-S directed thrusting across the Urapunga Fault Zone and Murphy Inlier This is accompanied by late dextral reactivation of NNW to NNE-trending faults in the Walker and Batten Fault Zones.

Jan 1, 1994

By S C. Dominy

Grade control programs aim to deliver economic tonnes to the mill via accurate definition of ore and waste. The foundation of a successful program is high quality sampling supported by geology and a suitable data management and modelling system. Underground sampling methods include chip, channel and panel samples; grab/muck pile samples; and drill-based samples. Grade control strategy is related to mining method and orebody type. Sampling protocols must be designed to suit the style of mineralisation in question. Holistic studies focussing on ore mineralogy and gold particle deportment, size and distribution are required for sample collection and preparation protocol optimisation through ‘Theory of Sampling’ application. Where possible, such programs should be undertaken early in the life of a project. Appropriate assaying procedures are also required. Program implementation will require suitably skilled individuals to train and mentor staff, with ongoing Quality Assurance/Quality Control (QA/QC) monitoring and review will allow protocols and staff to be updated as required.

Aug 22, 2011

By G Le Juge, K Waldock

The current suite of bulk mining explosives has been available to the industry for over 20 years. The flexibility and performance of ammonium nitrate based emulsion blend explosives were accepted by the mining industry in the early 1980s. These water resistant explosives rapidly displaced the water gels and slurries developed during the previous two decades. However, since the 1980s there has been no equivalent step change to the basic formulation or application of bulk explosives, although there has been a continuous process of refinement with respect to stability, handling characteristics and most significantly, cost. In the 1980s explosives supply contracts were awarded based on technical evaluations, usually accompanied by field trials. Technical personnel from both mining companies and explosives suppliers dominated the negotiations and there was a strong focus on explosive energy and blasting requirements. Today, explosives from alternative suppliers are difficult to differentiate on the basis of energy so the focus has shifted to aspects of service and price û bulk mining explosives are now largely treated as a commodity and the negotiations are dominated by commercial personnel. Commercial pressures from large mining companies have seen a substantial reduction in the real price of explosives. However, this has come at a cost. In order to reduce manufacturing costs, emulsion formulations have changed. In general they are not only cheaper, but also less energetic. Powder factors have had to increase to achieve the same blasting results, especially in hard ground. It is debatable whether the mining companies have achieved all of the economies they were seeking. This paper discusses these issues and argues that the mining industry would benefit from taking a more technically driven approach to meeting their blasting requirements. Recent trends towards more open contracts between the mining companies and their suppliers can be extended to explosives. To achieve this, mining companies will need to acquire sufficient technical knowledge to take a more pro-active approach to specify the characteristics of the explosives required to maximise the economic performance of their operations.

Jan 1, 2004

By S M. Denn

The Cawse nickel-cobalt operation is situated 50 km NW of Kalgoorlie in Western Australia, at latitude30o22'30'' south and longitude 121o08'30'' east on the Kalgoorlie 1:250 000 geological map sheet (SH 51-9) (see Figure 1). The project is owned and operated by Centaur Nickel Pty Ltd (CTR) and was the first in Australia to commercially produce nickel metal and cobalt sulphide through pressure acid leach (PAL) technology. Cawse has a total resource base (all categories of resources + reserves) of 213 million tonnes Mt at 0.7 per cent Ni and 0.04 per cent Co, comprising 127 Mt at Cawse Central which is 100 per cent owned by CTR and 86 Mt at Cawse Extended where CTR has a 80 per cent equity. Cawse Extended is located immediately to the northwest of the Cawse Central leases. All current reserves (proved and probable) of 30 Mt at 1.0 per cent nickel are contained within Cawse Central. In addition the Siberia project area 20 kilometres to the NW has a resource of 63 Mt at 0.7 per cent Ni. Cawse is a dry laterite deposit, with nickel and cobalt hosted by iron and manganese oxides. Cawse Central mineralisation extends over a ten kilometre strike length, with three pits currently being mined. The Bunyip pit has the premier nickel and cobalt grades within Cawse Central. There are seven dominant lithology types forming mappable units within current pit exposures. Four of these units are host to nickel and cobalt mineralisation. Ore types are defined as Upgrade, Grind and Non-upgrade, depending on their physical characteristics with respect to the treatment route. Mining commenced in February 1998. To the end of calender 1999 the operation has produced 2100 tonnes nickel plate and 470 tonnes of cobalt as a cobalt sulphide product. Future production will target 9000 tonnes per annum Ni metal and up to 2000 tonnes per annum Co, based on processing 500 000 tonnes of ore per annum.

Jan 1, 2000

By M S. Manono, K C. Corin

The optimisation and process developments surrounding the beneficiation of Cu-Ni-PGM ores is of fundamental importance when considering the continued rise in global demand for these precious metals. The selective sequential flotation of these ores is accompanied with various processing challenges such as the successful separation of the Cu-Ni-PGMs from non-sulfide naturally floatable gangue and pyrrhotite. Reagents such as sodium iso-butyl xanthate (SIBX) and sodium carboxymethyl cellulose (CMC) have proven to significantly improve the selectivity of the flotation process in their respective roles. The use of recycled water with abnormal inorganic electrolyte concentrations can modify the selectivity of these reagents, as ions may adsorb onto minerals such as pyrrhotite, thereby hindering or promoting the hydrophocity and floatability of pyrrhotite. Process water quality effects on the behaviour of pyrrhotite may have negative or positive influence on the recovery and grades of the wanted Cu-Ni-PGMs as valuable minerals associated with pyrrhotite such as pentlandite may be affected in like manner. Thus, the impact of concentrator process water quality on the behaviour of pyrrhotite needs to be determined. In this study synthetic process water at various ionic strengths was investigated against various CMC dosages to understand the behaviour of pyrrhotite during the flotation of a Cu-Ni-PGM Merensky ore in a batch flotation cell. This study showed that pyrrhotite grades increased with an increase in CMC dosage for fixed ionic strengths whereas the recoveries of pyrrhotite increased with an increase in ionic strength until 3SPW, then a trend of a decrease in recoveries was seen with 5SPW resulting in the lowest pyrrhotite recoveries. Furthermore, this study showed that moderate CMC dosages of 100 g/t resulted in the highest pyrrhotite recovery for all four ionic strengths of synthetic process water tested. It can be said that to maximise value recovery from Cu-Ni-PGM ores, understanding the behaviour of pyrrhotite against degrading water quality and reagent suites could be of paramount importance given the sensitivity of pyrrhotite to oxidising chemical conditions.

Aug 24, 2022

By Faidel VV, Yushina TI, Yagodkina NG, Yatsimirsky AK, Chanturiya VA

Among the problems of the flotation of sulphides by the thiol collectors is the dependence and varieties of the flotation starting with the time and oxygen contents in the slurry. For sulphides, the flotation stage follows after the electrocatalytic oxidation of the collector with oxygen on the surface of the conductor minerals. The necessity of the oxygen for sulphide flotation (Plaksin and Bessonov, 1957) is in accordance with a corrosion model of a collector surface sorption (Salamy and Nixon, 1954). As Golikov and Nagimyak (1961) showed, the sulphides possess catalytic activity which provides the autoxidation of the xanthates in the sluny to the dixanthogen. This stage can be rather protracted, which limits the speed of the total process. Disulphides constitute important collectors for the sulphide flotation and the optimal degree of the xanthate oxidation is about 20 per cent for different ores (Abramov, 1978) or, following Chanturiya and Nazarova (1977) the surface compositions for various sulphide ores are different and an optimal oxidation degree is variable from five to 25 per cent according to the ore nature. The optimisation of the surface composition is possible by application of the dixanthogens, or by a partial chemical, electrochemical, or catalytic oxidation of xanthates (Desains, 1847; Schall, 1896; Vigdergauz, 1989). According to Rand (1977) and Vigdergauz (1991) sulphides possess different catalytic activities for oxygen electroreduction. In neutral solutions, for example, the following decrease in the order: FeS2 (Fe,Ni)9S8 CuFeS2 FeS; Cu5FeS4 Cu2S; PbS (Vigdergauz, 1991). For the cases of low catalytic activities of the sulphides, the preflotation oxidation of xanthate could be useful to optimise the process kinetics.

Jan 1, 1993

By D Wei

Large tonnages of low-grade haematite ores need to be treated every day in China. One of the mineralogical characteristics of these haematite ores is that the grain size of haematite is smaller than that of quartz and is not uniform in the ores. Therefore, a flow sheet consisting of gravity concentration, low-intensity magnetic separation, high-intensity magnetic separation and reverse flotation is mainly used to separate haematite ores in China, to obtain acceptable beneficiation performance and reduce the operating costs. Nowadays, whether based on mineral processing practice or theoretical analysis, the results show that the application of the above-mentioned flow sheet is able to take full advantage of these mineral processing methods and achieves satisfactory benefi ciation of haematite ores. For example, when the iron grade of the haematite ore is about 29 per cent Fe, a concentrate assaying 68 per cent Fe can be obtained and the recovery of iron is over 80 per cent. In the future, research work on the beneficiation of haematite ores should focus on investigating the most feasible particle size for gravity concentration circuit feed so that the operating costs can be reduced and ultimately the separation performance can be improved.

Jul 11, 2011

By R R. Lovel, G J. Sparrow

Currently there are large reserves of good quality iron ore near to existing infrastructure that are not being developed because the phosphorous levels are above acceptable market specifications. Since the high phosphorous content is considered to be mainly associated with the goethite fractions of the ore, attempts were made to leach the phosphorous from the ore after a heat treatment to dehydroxylate the goethite. Heating the ore and leaching with 40 g/L NaOH lowered the phosphorous levels from 0.145 wt per cent P to 0.075 wt per cent P or lower, but a heating temperature over 800¦C was required to achieve this reduction in phosphorous levels. However, when sodium hydroxide was added to the iron ore before the heat treatment, similar phosphorous removal was achieved with a heating temperature of 300 - 350¦C. It was considered that dehydroxylation of the goethite in the presence of the hydroxide makes the phosphorous available for removal with a water leach. As well, 50 per cent of the silica and 60 per cent of the alumina in the ore were also removed in the leach, but some sodium remained in the leach product. Further work is required to remove the residual sodium to produce a marketable product.

Jan 1, 2009

By LefTvre Y

In May 1991, AZSA commissioned a new conventional Cell House. This paper focuses on the major improvements introduced in the design and the construction of the equipment, machinery and control. An effective control system together with good reporting and routine operation has resulted in quality control of the Cell House at the highest possible level. Consequently the monthly current efficiency consistently averages above 93 per cent with a total energy usage of 3000 AC kWh/t of cathode zinc. The new concept for the year 2000 and beyond is introduced.

Jan 1, 1993

By G E. Smith, G N. Lye

Wall control blasting practices are necessary to reduce the impact of blasting on mine faces but can also have a significant negative impact on mine productivity and operating costs. The conventional practice in deep open pit mines is to use so-called trim blasts adjacent to pit walls. To provide burden relief these trim blasts have fewer rows than full production blasts and are fired to a cleared free-face; hence they are termed æunchokedÆ. This practice leads to scheduling constraints on the pit operations and can cause ore dilution due to excessive muckpile movement. The use of such trim blasts stems from the perception that increased wall damage results from æchokedÆ blasts. These concerns are based on the unproven assumptions that blast vibration levels and explosive gas penetration increase with increased blast burden and face confinement. This paper describes work undertaken as part of a major investigation into wall control blasting at the KCGM Fimiston Mine, Kalgoorlie, Western Australia. It details a study to assess damage effects due to blast burden. Borehole air pressure measurements and borehole video camera inspections were done behind a series of single blastholes drilled with varying burden distances, as well as behind a dedicated trim blast and a full production blast. It was found that the measured damage effects, including visible rock cracking, dilation, and the limited extent of gas penetration behind the blastholes, did not vary significantly with burden or blast type for the cases tested. This result was in complete agreement with detailed vibration measurements conducted by Blair and Armstrong (2001) during the study, which found that vibration was independent of blast burden. As a result of these investigations, changes to the blasting practices at the mine were implemented. Dedicated trim blasts and free-face blasting have been replaced by modified production blasts and the practice of æchokingÆ blasts has been introduced. This has resulted in a significant improvement in productivity and cost savings without compromising pit wall integrity.

Jan 1, 2001