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By Quan P. M

The great advances made in the application of solvent extraction to the recovery of copper from low grade ore sources over the past 15 to 20 years are well known. Solvent extraction is an essential step in the recovery and purification of copper from dilute sulphate leach solutions by which some one million tonnes of copper are now electrowon annually. A reagent is also available for the selective recovery of copper from chloride leach solutions and this may hold the key to the processing of complex sulphide ore concentrates. By comparison, the use of solvent extraction in the recovery and processing of zinc has as yet found little favour and is confined to only a few specific and comparatively small applications. This is despite the ready availability of a large number of low grade zinc sources and zinc-bearing wastes and residues. It is suggested that this difference is due in large part to the absence of suitable reagents having the particular features required to enable them to fit into a solvent extraction - electrowinning based process for zinc. Ideally, for the recovery of zinc from dilute sulphate solution, an extractant should operate on a proton exchange principle and be strong for zinc in the same way that o-hydroxyaryloxime reagents are strong towards copper. It should load efficiently with zinc at the pH of typical sulphate feed streams without the need for neutralisation and yet be stripped efficiently by spent zinc electrolyte. Another factor of major importance for many applications, however, is that it should be highly selective for zinc over ferric iron. These features have now been realised in a development extractant DS5846, which is a formulation of a novel class of reagent currently under investigation by Zeneca Specialties. The properties of this reagent are described with respect to selectivity, isotherms and how they compare with phosphoric and thiophosphoric acids that have been previously proposed for the extraction of zinc. For the recovery of zinc from concentrated chloride solutions a solvating or neutral donor type of extractant is required which again should ideally have high selectivity for zinc over a number of other metals, particularly iron. The new reagent Acorga ZNX50 is based on a formulation of a novel class of compound developed specifically for this purpose. It gives efficient extraction of zinc from feed solutions that are four to six molar in chloride ion but is readily stripped at 60 - 65¦C using either water, dilute brine, or spent zinc chloride electrolyte. The reagent is highly selective for zinc over iron and a range of other metals including cadmium, arsenic, lead and magnesium.

Jan 1, 1993

By V N. Rudashevsky, N S. Rudashevsky

Characterisation of platinum-group element (PGE) deposits and their process products has many challenges for the process or applied mineralogist. It is now well established that the PGE distribution for such samples is variably divided between submicroscopic concentrations of PGE in sulfides, tellurides and related minerals occurring as discrete platinum-group minerals (PGM), of which there are a large number of species, many with partial replacement between the PGE and between anions. Each PGE deposit type requires a targeted approach but fundamentally, there are two general methodologies in vogue. One way is to make a large number of polished or polished thin sections for detailed scanning electron microscopy (SEM)/optical examination to determine the PGM distribution and their associations and grain sizes. The other is to make concentrates of representative crushed or processed samples, thus having fewer subsamples to examine. Our method of choice is to use hydroseparation (HS) for concentration. HS provides representative concentrates of sizes down to ~10 ¦m, not possible by other techniques. Various microbeam methods have been used for analysis of trace quantities of PGE (EPMA, micro-PIXE, SIMS and LAM-ICPMS). We prefer LAM-ICPMS (laser ablation microprobe û inductively coupled mass spectrometry) because of the relatively large analytical volume sampled, the ability to measure all the PGE, monitor up to 20 elements, together with detection levels in the tens to a few hundreds of ppb. We provide typical results derived in studies of stratiform PGE ores and tailings, and a massive Ni-Cu sulfide ore.

Jan 1, 2008

The mIning operations of Bougainville Copper Pty. Limited are located at Panguna on the Island of Bougainville which is part of the Territory of Papua and New Guinea.C.R.A. Exploration Pty. Limited first established mineralization in the Panguna area in 1964. Exploration work since then has established ore reserves estimated to be 900,000,000 long tons of ore assaying 0·48 per cent copper and 0·36 dwt/ton gold. An economic feasibility study completed in July, 1969 enabled a decision to be made to proceed with a major mining operation. The ore will be mined by open cut methods and will be treated in a conventional concentrator with a nominal capacity of 90,000 short tons/day. The concentrate will be pnmped as a slurry through a 16 mile long pipeline to a port established on the east coast where it will be filtered and dried ready for export. Other supporting facilities for the mine include two towns, a 135 MW steam power station, and access roads.

Jan 1, 1971

The aquifer at Phosphate Hill, north-west Queensland, presents special management challenges. The site contains a phosphate rock mine, fertilizer plant and camp. All of the site water is provided by the Duchess Embayment Aquifer, located within the Burke River Outlier of the Georgina Basin. The Duchess Embayment is a triangular shaped, Cambrian marine sedimentary basin consisting of siliceous and calcareous phosphorites, shales, siltstones and sandstones. It is fault-bounded on all sides and has a regional dip of 5¦E. The aquifer is largely confined to the siliceous facies of the Beetle Creek Formation. It has a very flat potentiometric surface and an average thickness of 45 m with confining beds above and below. The siliceous facies derives from weathering of the calcareous phase and is highly transmissive while the calcareous zone itself contains less water and is dependent upon interconnecting fractures for its permeability. Recharge appears to occur where the siliceous facies crops out around the edges of, and within, the Embayment. Aquifer management issues revolve around two points: successful dewatering of the orebody for mining; and efficient management to maintain water quality and ensure supply over the predicted 30-year life of the project. Current operations are extracting water at levels much below that originally estimated. This is having a detrimental effect on mine dewatering with the SWL lowering at a rate slower than anticipated. As a result, ore parcels are now beginning to intersect the water table, providing a major constraint to the mining plan. The aquifer drawdown cone is extensive and very flat so to keep the water table at an appropriate level for mining the management plan will include more aggressive dewatering to lower the level of the entire aquifer. The additional water will either be disposed of downstream or stored in a holding dam or via the use of artificial storage and recharge. Water resource management will also need to maintain the current quality. About 37 per cent of the water currently extracted forms the low chloride supply required by the ammonia plant and the power station. This ratio is expected to remain applicable under any future operating conditions but the low chloride resource is restricted so will require prudent management to enable the supply to continue. At current usage rates aquifer recharge versus use will need careful monitoring to ensure that the resource remains viable in the long-term.

Jan 1, 2003

By C L Humphrey

Biological monitoring programs for environmental protection require techniques that will provide both early detection of possible adverse effects, and assessment of the ecological significance of these effects. Monitoring techniques must include responses sensitive to the impact, that can be subjected to rigorous statistical analysis and for which statistical power is high. Such issues in baseline research of 'what and how to measure?' and 'for how long?' have been the focus of a program being developed to monitor and assess effects of mining operations on the effectively pristine, freshwater ecosystems of the Alligator Rivers Region (ARR) in tropical northern Australia. Application of the BACIP design, utilising a form of temporal replication, to univariate data (single species) and multivariate (community) data is described. For new ventures in Australia (such as mining), monitoring programs should be designed to establish with high probability that an impact on the ecosystem no greater than a prescribed amount has gone undetected - as opposed to simply allowing development to continue as long as 'proof' of impact is not available. Such a precautionary approach represents a shifting of the 'burden of proof' and would require with the BACIP design, a minimum number of baseline years in order to achieve some desired level of statistical power in a test for impact. Power analyses conducted on two to five years (depending upon the technique) of baseline data from streams of the ARR indicate that the BACIP design would not impose developmental constraints on mining and that a policy of reversal of the burden of proof would provide the cornerstone required for managing such development in an ecologically sustainable manner.

Jan 1, 1994

By A F. Cooper

The northeast-southwest trending ~25 km2 area incorporating Bald Hill is located 18 km northeast of Haast, and 5 - 7 km west of the Alpine Fault in South Westland, New Zealand. The geology consists of Greenland Group greywacke overlain by a Cretaceous-Tertiary sedimentary sequence and fluvio-glacial/marine terrace deposits of Quaternary age. Alluvial gold in Cole Creek, draining west from the summit of Bald Hill, may be derived either from vein mineralisation in basement rocks or from fluvial or marine terraces.   This paper focuses on the potential for in situ gold and base-metal mineralisation in sporadic, siderite-rich quartz veins that cut basement greenschist facies metasediments that have been overprinted by contact metamorphism.   Throughout the area, vein compositions are dominated by quartz and commonly feature zoned plagioclase. Alteration adjacent to veining within the contact aureole is dominated by 1 - 2 mm, coarse grained biotite, with small amounts of sulphide, and is pervaded by abundant siderite veinlets. Outside the aureole, wall rock alteration to veins consists of fine grained chlorite. Trace element XRF analysis has been used to ascertain base metal concentrations within samples of vein and alteration zones collected from throughout the area. Vein and alteration zone mineral assemblages containing <5 per cent sulphide, with low concentrations of As, Cu, Pb and Zn indicate low potential for gold and base-metal mineralisation in the Bald Hill region. Contact metamorphism of Greenland Group basement in the northeast of the region, is likely due to emplacement of a poorly exposed Cr- and Ni- enriched gabbro. The presence of biotite and andalusite in hornfelses indicate contact metamorphism occurred at temperatures >350¦C and at depths <10 km. Widespread vein distribution does not appear to be related to contact metamorphism or gabbro emplacement. Further research is required in order to establish the fluid source from which the veins were precipitated.

Jan 1, 2007

By J Manuel, N Ware

Ideal iron ore sinter is produced by optimising the balance between coarse (+2 mm), stable ore nuclei and a reactive matrix consisting largely of fluxed -1 mm fines. The authors have previously published work evaluating the matrix melting behaviour of a number of fine ores, using techniques developed by CSIRO. The focus of that work was to demonstrate the contribution of the matrix to overall sinter quality, with the results showing a direct correlation between melting point, matrix porosity and strength. CSIRO has also developed a complementary test to study the behaviour of coarse ore nucleus particles in contact with the sinter matrix and provide an evaluation of their reaction and assimilation properties. This test provides valuable fundamental information that can be used to better understand the role of specific ore types and optimise blend composition.The CSIRO laboratory-scale assimilation test is carried out by embedding particles of ores of specific sizes into a fluxed matrix of known sinter blend composition, using real ores and fluxes, in a laboratory test that directly relates to pot-grate and plant sintering conditions. Samples are fired under controlled conditions in a tube furnace using a standard heating profile and a constant, low-oxygen potential atmosphere. These conditions simulate the actual sintering process while removing the effects of the many locally-variable parameters (eg temperature, oxidation potential and localised chemistry) that exist in the actual process, meaning that trends in behaviour can be more clearly seen. Designed as a compromise between the industry-standard pot-grate sintering test and a more fundamental test using chemical reagents, the aim is to isolate and evaluate the nucleus behaviour of an individual blend component to allow an improved understanding of the role that an individual ore plays in a specific blend. Measured cross-sections of the resulting fired samples provide a semi-quantitative measure of reactivity, while accompanying photomicrographs allow a qualitative assessment of assimilation properties (eg volume and distribution of secondary porosity generated during reaction).In this paper, to complement the previous work published on melting behaviour, nucleus particles were selected from hematite, hematite-goethite and goethite ores and embedded in a simulated plant sinter matrix. Drilled core particles of two sizes were tested at fixed temperatures simulating low- (<1300°C) and high-temperature (>1300°C) sintering conditions. The resulting assimilation properties are compared and discussed as a function of particle size, temperature and ore/sinter mineralogy. The implications for the contribution of each component to the prediction of blend sinter quality are also discussed.CITATION:Ware, N and Manuel, J, 2015. Fundamental nucleus assimilation behaviour of hematite- and goethite-containing ores in iron ore sintering, in Proceedings Iron Ore 2015, pp 77–82 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By Katsuyama K, Nag DK

Three aspects of rock mechanics, namely, in-situ stress estimation by acoustic emission (AE) method, strength of rock mass and role of chemicals to reduce the strength are covered. It is possible to detect the previously applied maximum stress by stressing a rock specimen to the point where there is a substantial increase in AE activity. This is known as Kaiser effect. From the AE signatures in the second and subsequent loadings, AE take-off point was identified more easily than in the first loading. In determining the compressive strength of rock mass, two factors have to be considered, namely, the size effect on the compressive strength of intact rock and the effect of discontinuities on the compressive strength of rock mass. Although a modified Bieniawski criterion gives best agreement with the triaxial test data, modifications have been suggested to Hoek-Brown criterion due to its popularity. It is possible to reduce the tensile strength of sandstone by saturating it with weak chemical solutions made with dodecyltrimethyl ammonium bromide, polyethylene oxide and aluminium chloride by up to 30%. In the case of compressive strength, there is no appreciable effect. The possible explanation is that the chemical solutions produce an effect on the strength of sandstone only when the failure mechanism is dominated by tensile mode.

Jan 1, 1998

By Parker C. J, Mikula P. A

The excavation for the Sydney Opera House Parking Station comprises a large donut shaped underground cavern with a central sandstone pillar. The maximum effective roof span is about 19 m and the rock cover is between 7 m and 8 m. Permanent support for the roof and the various services tunnels consists of a combination of tensioned anchors, and untensioned dowels, and mesh with shortcrete and fibrecrete as the final lining. Steel sets were installed at main intersections.Fundamental to the design philosophy for excavation of these spans at such shallow rock cover was the use of monitoring to check on the adequacy of the installed support. Prior to excavation, extensometers, inclinometers, piezometers and surface settlement survey stations were installed. Underground survey stations, anchor load cells and shotcrete pressure cells were installed as excavation proceeded. Excavation commenced at the crown using an initial heading and three widening stages. Geological mapping during excavation confirmed borehole expectations, namely sandstone beds 1 to 4 m thick interbedded with thin shale units. Bedding plane contacts varied over short distances from tight partings to thick brecciated seams. Jointing was subvertical and joints tended to be bed-limited.

Jan 1, 1993

By Zamel G. I, Zenari L. P

Technological developments in modem Tunnel Boring Machines (TBMs) and associated back-up equipment are offering significant alternatives for mining operators to consider, in the selection of equipment for coal mine development drifts, roadways, longwall gate roads as well as metalliferous mining declines and development drives.Greater flexibility in handling variable ground conditions, muck disposal and radius of turn as well as advance rates, are just some of the areas where modem TBMs can accomplish the flexibility that mine operators require to achieve cost-effective developments.Compact TBMs are achieving this acceptance because of the fundamental design of a shielded machine containing electrics and hydraulics within the forward shell, ability to achieve tight radius of curvature and grades, and ability to provide highly flexible support systems to meet all possible ground conditions.However, a single TBM design will not suit all mine developments, as each development method - while having common goals with all mine developments - will also require certain unique criteria to be fulfilled.

Jan 1, 1993

By Sennitt C. M, Hartley J. S

The Twin Hills Gold Deposit is an example of a preserved, high level, epithermal system, with mineralisation introduced contemporaneous with deposition. The deposit is hosted within sediments of the Late Devonian to Early Carboniferous Saint Anns Formation, of Cycle 1 Drummond Basin stratigraphy, situated in central Queensland. Prior to epithermal activity in the Twin Hills region, a lacustrine fan delta depositional environment existed, together with minor tuffaceous activity. An and palaeo climate, with occasional periods of torrential rainfall, together with a basin with faulted margins, allowed alluvial fan prograda- tion. Cyclical repetitions of the fan indicate repeated faulting and seismic activity took place during deposition. Significant gold mineralisation was first intersected at Twin Hills by Metana Minerals NL in 1988, after drill testing a "blind" target outlined by geological mapping and bedrock geochemistry.

Jan 1, 1991

The first stage in process design for coal preparation is a study of the coal seam and its associated features followed by an examination of the mining method to.be employed and the coal market requirements. Normally benefication is based upon the differences in relative densities of the coal constituents and asso- ciated ash forming components. Since initial liberation is obtained at a relatively large particle size, the size to which coal is crushed is more subject to the market requirements than to liberation studies. It is possible to estimate energy requirements for comminution and recoveries and product grades can be cal- culated following the interpretation of standard laboratory tests. Numerous units are available for the separation and concentration of the components of run of mine coal in- cluding jigging, dense media separators, and for the finer particle size fractions, flowing film separators, dense media cyclones and froth flotation.

Jan 1, 1975

By Ranklin W. J, Swinbourne D. R

Lead blast furnace slags contain typically 10 - 20 mass per cent Zn. The zinc can be recovered by slag fuming, in which a powdered coal/air mixture is injected into a molten slag bath. Volatilised zinc is recovered as zinc oxide from the gas and processed hydrometallurgically to produce zinc metal. The ISASMELT continuous lead smelting process in operation at Mt Isa produces a slag containing about 12 per cent Zn which is currently granulated and stockpiled. This slag could flow to a further bath-smelting reactor for continuous zinc fuming. Rather than collecting the zinc as fume from such a process, one option would be to recover it using a lead splash condenser. The success of this operation would depend on the composition of the gas produced, in particular the concentrations of gases capable of reoxidising zinc vapour, viz, carbon dioxide and water vapour. The aim of this investigation was to determine the smelting conditions for a bath-smelting process such as ISASMELT or SIROSMELT which would produce a gas similar in composition to that from an Imperial Smelting Furnace by thermodynamic modelling of the process using the CSIRO Thermochemistry System. It was found that such a gas could be produced if coal injection and oxygen enrichment of the combustion air to at least 40 per cent 02 were used. However, the off-take gases must be conditioned by addition of methane to reduce the water vapour content to acceptable levels. An addition rate of ten per cent of the off-gas flowrate was found to be adequate. Addition of methane to the off-gas had the added advantage of cooling the gas from the bath temperature to a temperature suitable for normal lead splash condenser operation.

Jan 1, 1993

The results of a systematic geochemical survey of rare elements are applied to elucidate genetic relations in a suite of rocks and to predict the probability of mineralization. The geology, radioactivity, major element geochemistry and classification of the main intrusives are described. The distribution of a group of rare elements, their concentration trends and the bearing these have on the emplacement sequence of the rocks are considered in some detail. The guides for exploration in the Pilanesberg that emerge are listed and some areas which substantiate predictions are described briefly. It is concluded that a study of rare element trends can make a considerable contribution as an exploration tool and for clarifying relations between the members of rock suites.

Jan 1, 1986

By Van Weert G

Ferrous chloride solution pyrohydrolysis is a successful IICI regeneration process which is carried out in either a spray roaster or a fluid bed. Pyrohydrolysis is not restricted to ferrous chloride only, every metal chloride can theoretically be hydrolysed. In practice, however, the conditions for ferrous chloride pyrohydrolysis differ from those of many non-ferrous metal chlorides eg zinc, lead and cadmium. Hence, a pyrohydrolyser could function as a ferrous/non-ferrous separator, eg an iron oxide and zinc chloride separator. Most pyrohydrolysers operate on solutions, in which case more than 50 per cent of the process energy is needed for heating and evaporating water. However, this disadvantage would be diminished by feeding a slurry to the reactor. Against this background it was decided to investigate the chloridisation of zinc ferrite which is an iron bearing solid with a non-ferrous impurity, and subject to processing and disposal problems. Synthetic zinc ferrite was chloridised in a tube furnace. The gas atmosphere in the tube furnace resembled that of a fluid bed pyrohydrolyser and consisted of HCI, 1120 and nitrogen. Gas composition, temperature, residence time and sample mass were varied. The experiments showed that complete (99.6 per cent) zinc extraction from synthetic zinc ferrite was possible in a simplified pyrohydrolyser atmosphere at 1100 K in four hours. The zinc ferrite was converted into gaseous zinc chloride, and hematite and magnetite solids. It was also found that zinc removal from the zinc ferrite lattice caused not only rccrystallisation of the zinc ferrite into hematite, but also hematite crystal

Jan 1, 1993

Most orebodies have one or more boundaries which are gradational, where the decision to stop mining is based on an economic cut-off. To maximise profit, this cut-off grade must be chosen correctly. It is necessary to review cut-off grades regularly, as the optimum cut-off grade changes with time, and major changes are hard to implement in a working mine without disruption to production schedules.Whenever a cut-off grade is used, there will be errors in its application caused by errors in the estimation of block grade. These can be minimised by stringent quality control in sampling and by the use of kriging, which attempts to minimise the absolute errors in grade estimation. The kriging method used should produce the most accurate estimates of marginal grade blocks - this will not necessarily be the technique that gives the best overall prediction of head grades.

Jan 1, 1993

The author describes 1. The classification and characteristics of various thick seam mining techniques in various Japanese coal mines. 2. Practices of thick seam mining methods experienced in Taiheiyo Coal Mine. Currently, thick single lift, simultaneous multi lift and non simul- taneous multi lift mining methods are adopted as underground flat thick seam excavations in Japan. These are now reliable and effective in increasing the extraction ratio. At Kushiro Colliery of Taiheiyo Coal Mining Co., these three thick seam mining methods have been used. According to the results, if solidification of the top lift goaf is essential, the non simul- taneous multi lift mining method is the most effective in increasing the extraction ratio without minimising productivity of each lift and it points out that further development of this method is necessary.

Jan 1, 1976

Railway cuttings require the highest care in design and construction, as the pro- bability of failure concept does not allow any risks to be taken with hundreds of lives being dependent on continued stability. The usual geological influences on stability such as bedding dip and faulting are often discus- sed, but other major problems may come from the presence of sheet joints, cross joints differential weathering and seasonal or daily changes of ground water level. The design of rail cuttings has taken little note of the problems imposed by cons- truction methods, and low cost quarrying methods may seriously weaken a designed shape. The presence of berms and drainage ditches is often difficult to achieve as blasting imposes cumulative stresses and jointing on rocks. Contractors face difficulties in bidding extensive rock cuttings as variations in rock properties are often concealed and overshoot- ing the toe of a batter can easily occur. Modern blasting methods offer some solutions, but the best guide to safe successful cuttings is extensive investigation and the continued involvement of engineering geology at the stages of feasibility, design, construction and maintenance. Two case histories show the influence of folding, faulting and construction methods in the case of slope failure and slope stability.

Jan 1, 1979

Extensive infrastructure construction works were required for the development of the underground and open-cut coal mine at Ulan to a production capacity of 5 million tonnes of steaming coal per annum. The Ulan Mine development project was constructed in a two year period at a cost of $240 million. The infrastructure component included the construction of the mine site building works, civil works and 150km of railway, valued at $105 million. These works were successfully completed under a construction management agreement within two years. The separate elements of the project are described in detail in the paper.

Jan 1, 1983

Over the 20 years to 1990 the Australian mining industry, presently worth some $A60 billion, generated a negative real rate of return (McDonald, 1992); not surprisingly under-performing the returns from bonds and industrial equities. Over this same period more than $A70 billion was invested in expanding the Australian mineral industry.

Jan 1, 1993