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By N. T. Avard

THE Joggins coal field, Cumberland county, Nova Scotia, is on the easterly side of Chignecto bay, at the head of the bay of Fundy. In area, so far as proven, the field extends easterly from the town of Joggins about fifteen miles to Chignecto. The distance across the outcrops of the several seams exposed is approximately one mile. HISTORY Early records of coal mining in this locality are somewhat obscure, but it is known that prior to 1750 the French settlers were mining coal for their own use from the seams which outcrop in the floor of the bay adjacent to the shore, where, at low tide, the reefs are bared for a mile or more. Coal was also mined from the seams outcropping in the cliffs. It is known, too, that at Joggins coal has been mined commercially for over one hundred years. At first, all shipments were made by water, but in 1882 a railway connecting with the Intercolonial railway at Maccan was built to serve this field. GEOLOGY Due to the abundance of fossils in the strata forming the Joggins cliffs, this area was for many years a mecca for geological students from all over this continent. A 'sunken fcrest' in the shoreline was of particular interest but, due to constant erosion by the sea, this has apparently been all washed away. On the Joggins shore, the cliffs stand sixty to one hundred feet high, and six workable coal seams, with numerous smaller ones, are there exposed. Others outcrop in the reefs extending from the shore toward the bed of the bay. In working underground, fossilized trees are often found immediately overlying a coal seam, and standing at right angles to the pitch of the seam. This is said to be an unusual condition. In most cases, the bark of the tree is a fine-quality coal, with high carbon content, whereas the pulp has turned to 'stone'. There is a definite tendency for the coal to run out, or turn to shale. One seam, workable two miles from the shore, has almost completely disappeared in the outcrop at the shoreline. ? It was thought that a large area could be mined under the bay from an opening near the shore, but the first submarine level had to be abandoned at a distance of 4,000 feet, where the coal became very dirty and shaly, and the mine able area to the westward became more restricted as the mine was developed to the deep. This tendency is common to all seams.

Jan 1, 1944

By Nordau R. Goodman

"IntroductionTHE HISTORY of Nova Scotia's gypsum industry goes back about two hundred years. The extensive deposits found in the Windsor formation, which is Lower Carboniferous, were the first discovered in North America and were known to the earliest .settlers. There has been a steady increase in production from these beds, except for minor setbacks in years of wars and depressions, but at the same time there has been a decrease in the number of operating quarries. This decrease reflects the change from the days of horse-and-cart recovery to the modern, large-scale, highly mechanized operations. In the beginning, almost any outcrop could •supply the tonnage requirements and the most •convenient were selected, but the millions of tons needed to meet present-day needs are not easily found.Despite the size and importance of the Nova Scotian deposits there has been little detailed geological work. Sir Charles Lyell, in 1843 ( 10), established that the beds are Lower Carboniferous and this was confirmed by Sir William Dawson (3) a .few years later. Both Lyell and Dawson agreed the calcium sulphate beds were an original part of a bedded series .but did not consider they resulted from a concentration of sea water. Lyell reached the conclusion that the gypsum was related to volcanic action in the form of heated vapours or hot springs. Dawson believed it was formed by the action •of sulphuric acid on calcium carbonate. The acid, derived from the oxidation •of iron pyrites which was abundant in the older formations, was carried by rivers into basins which were rich in shells."

Jan 1, 1954

By L. Cifuentes

The temperature dependence of: a) electrolyte density, viscosity and electrical conductivity and b) the equilibrium constants of formation for all relevant species have been determined as part of an effort to model the operation of a copper electrowinning cell based on reactive electrodialysis. The studied ranges were: 1.01 to 1.25 g/cm3 for density, 4.9x10-4 to 16.4x10-4 kg m-1 s-1 for viscosity and 0.02 to 86.0 Sri m-1 for electrical conductivity. Density and the electrical conductivity of the catholyte increased linearly with temperature whereas the viscosity increase was exponential. The main effect of ionic speciation was to decrease the electrical conductivity with increasing metal concentration due to ion association (mainly the formation of bisulphate ion) which lowered the concentration of protons (the most mobile species) in solution. This effect was specially noticeable in the anolyte. Mathematical relationships with correlation coefficients between 0.959 and 1.000 have been found for all the studied variables.

Jan 1, 2007

By Y. Masuda, Y. Nakamura, K. Haraguchi, A. Taniguchi, K. Arita

Availability of the elements originating from steelmaking slag for various marine phytoplankters including purely cultured strains and natural populations was tested in land and shipboard laboratories. The results obtained demonstrate that, although their solubility was not uniform among different slags, dissolved iron, silicate and phosphate from the slag stimulate phytoplankton growth. No negative effect of the slag addition on their growth was observed at lower dose, e.g. less than 200 mg/l. Since most coastal waters are the hypernitrogenous environment due to anthropogenic load of ammonium, the slag can be an ideal source of silicate and phosphate, which restore the hyper-nitrogenous condition into truly eutrophic condition with balanced Redfield ratio. In so-called HNLC (high-nitrate low-chlorophyll) oceanic areas such as the Southern Ocean and the subarctic North Pacific, where iron is almost only limiting factor of the phytoplankton growth, the slag could also be a source of iron and enhance CO2 fixation by phytoplankton photosynthesis. (Key words: carbon deposition in deep-sea, marine environmental remediation, phytoplankton, slag as a source of iron, phosphate and silicate.)

Jan 1, 2004

By Alan Bauer, Melvin A. Cook

Measured detonation pressures of "prills and oil" (94/6 ammonium nitrate/fuel oil) and three of the new "slurry" blasting agents are presented and compared with computed, ideal detonation pressures and with detonation pressures expected from the measured detonation velocities. Results seem to show that the peak pressure in the detonation wave in these cases is the Chapman-Jouguet pressure and that no "spike" exists in these detonation waves. The absence of the Zeldovich-von Neumann "spike" is noteworthy in view of the very long reaction zone lengths of these mixtures. The measured detonation pressure of one of the slurry blasting agents (DBA-3") under steel confinement ( 172 kilobars) is shown to be considerably greater than the ideal detonation pressure of 75 per cent gelatin dynamite (p. = 135 kilobars) despite the fact that the detonation was still somewhat non-ideal in "DBA-3," its computed ideal detonation pressure being 180 kb. The popular 94/b AN /FO blasting agent exhibited a detonation pressure of only 13.5 kb in 5" paper tubes, but 37.5 kb in 5"• steel pipe compared with a computed ideal pressure of 40 kb.

Jan 1, 1961

By S. Banisi, J. A. Finch, A. R. Laplante

"A technique for on-line simultaneous estimation of gas and solids holdup (volume fraction), based on a combination of conductivity and pressure difference measurements, is proposed and tested in a laboratory flotation column (10cm in diameter and 447cm in height). Fundamental concepts underlying this technique and the effect of relevant parameters are discussed. In the studied range, 3-30 %v/v gas holdup and 2-18 % v/v solids holdup, experimental results showed good agreement between the estimated and actual holdup values (as determined by an isolating technique). The relative accuracy of the solids holdup estimation increased when solids density or solids concentration increased. Frequent re-calibration of pressure transducers was found necessary for accurate phase holdup estimation.IntroductionGas holdup is a key parameter in controlling the performance of flotation columns. For example, flotation rate is affected by bubble size and gas rate both of which, in turn, affect gas holdup. Moreover, gas holdup also determines the slurry residence time which indicates a direct influence of gas holdup on recovery.Gas holdup determination has been the focus of many studies (e.g., Castillejos, 1986; Marchese et al., 1992). Some of the techniques which have been used are given in Table 1."

Jan 1, 1994

By A. Brown

"The mining industry is no exception to the general rule that continuing research is essential to good management; in fact, because of the imperfect state of knowledge in regard to many important factors associated with a mineral extraction, mining research assumes a position of unusual importance. On the basis of a recent visit to mining research centres in a number of European countries, the author describes their organization and their role in the mining industries of these countries. Some observations are made on Canadian mining research efforts, with a view to indicating a more systematic basis of procedure."

Jan 1, 1960

By E. Faria

"The Santa Rita mine is located in north eastern part of Bahia in Brazil and is owned and operated by Mirabela Mineração do Brasil Ltda. Typical SABC circuit was designed as the preferred option for the 4.0 mtpa (500tph) to produce a P80 of 125um for flotation. Although the SAG was originally designed to operate with conventional radial pulp lifters, later it was fitted with Outotec’s Turbo Pulp Lifters – TPL (Latchireddi, 2005). The milling circuit commenced commissioning on the 24th of October 2009 and the milling circuit achieved the nameplate capacity within days. with small and relatively simple measures to rectify. Since commissioning, the SAG mill has been working in fully autogenous grinding (FAG) mode with no balls (in contrast to the estimated 10% ball charge) and has been consistently treated up to 650tph.This paper examines the comminution design process, the operating philosophies, start-up experiences, post commissioning optimization and future development works. An evaluation of mill performance relative to the design criteria for the project life to date is also included."

Jan 1, 2012

By P. A. Distin, Jr. da Silva

The history of commercial processes for zirconium/hafnium production and separation is reviewed. A new technology is then proposed as a potential alternative for zirconium/ hafnium separation in a simpler, cleaner way than achieved with current processes. Primary sources of zirconium always contain small amounts of hafnium that must be removed during production of zirconium metal for nuclear applications. This separation is usually carried out by a solvent extraction process, developed in the 1950s, that selectively extracts hafnium, as a thiocyanate complex, using methyl isobutyl ketone (MIBK). Environmental problems inherent to this process are the high aqueous solubility and low flash point of MIBK, and possible gaseous contaminants formation generated by the decomposition of the thiocyanic complexes in hydrochloric acid medium (H2S, HCN, mercaptan’s formation). The present work shows how these problems could be avoided by using organophosphorous extractants that were unavailable when the MIBK process was developed.

Jan 1, 1998

By James J. Holmes

ACCIDENT prevention as we know and understand it today is of comparatively recent origin. As a matter of fact, the Industrial Accident Prevention Association of Ontario, which is the oldest organization of its kind in the Dominion, celebrated its thirtieth anniversary only this year. On the other hand, one could say that the history of accident prevention is almost the history of mankind itself. In a general sense, every forward step that man has made throughout the centuries has been largely due to two things: (1) a desire for increased comfort, and (2) the need for safety; and, always, the need for safety has taken precedence over the desire for comfort. While it is true that hundreds of volumes have been published, dealing with the many aspects of accident prevention work, you cannot go to a library and pick out a book that has all the answers in it. Such a book has never been published-we are still looking for some of the answers. However, a good deal of real progress has been made.

Jan 1, 1945

By G. G. Bowser

PERUSAL of a list of present-day commercial explosives perhaps does not convey a full realization that there has been a great deal of improvement since the original dynamite was discovered nor that, in recent years, great developments have taken place in specialized explosives. This is true particularly of high-explosives for use in metalliferous mining or what is more commonly termed 'hard-rock' mining. Not many decades ago, only two or three types of explosive were avail-'able for commercial use. One was black blasting powder. Another was ordinary nitro-glycerin dynamite in various strengths. Black blasting powder remains with but very little change. Despite its ancient lineage, it is still with us as perhaps the sole explosive in use today which is almost identical in appearance, physical properties, and working ability or execution co the original. Which dynamite the story is different. Its evolution may be likened to that of the dog, nitro-glycerin as first discovered being the counterpart of the wild dog and, like it, dangerous and hard to control. The original dynamite as made by Nobel might then be considered as representing the first domesticaced species. This original dynamite, however, has been 'crossed with other bloods' until one sees now many distinct 'breeds' in the list. Present-day explosives still have the 'bark' and the 'bite', but with control and research have come many improvements; and types have been created which are specially adapted for particular kinds of work. We still have the direct descendant of Nobel's dynamite in the form of an improved nitro-glycerin dynamite. This C-I-L explosive, Polar Dynamite, is no longer the best type to use in the hunt for gold, silver, iron, and other metals. There have been developed other explosives more suitable for chat work. In Canada, such explosives are accomplishing this work effectively, not only where climatic conditions are moderate but through the rigours of our northern winters, with their sub-zero temperatures.

Jan 1, 1938

By X. J. Guo, Q. K. Wang, S. P. Zhong

With depletion of traditional clean copper reserves and fast expansion of the global copper demand and smelting capacity in the past decade, more and more copper smelters have to treat copper concentrate with increasing content of complex arsenic-bearing minerals. Developing economically viable and environmentally reliable methods and approaches for arsenic control in copper smelting has become more critical for sustainable growth of the copper industry. This paper will report the recent effort of Zijin Mining Group Ltd. in developing processes for improving arsenic control and management in the Zijin Copper Smelter. The arsenic distribution and balance data for matte smelting, converting and refining operations in Zijin Copper Smelter is reviewed for understanding of the current challenges in arsenic control. The processes developed for treating the arsenic bearing waste acid bleed stream from the smelting-converting off-gases wet cleaning circuit and the arsenic sludge produced in the refining electrolyte purification circuit for arsenic disposal are discussed. INTRODUCTION With fast expansion of the global copper smelting capacity to meet the world copper demand and depletion of traditional clean copper reserves, more and more copper smelters have to treat copper concentrate with an increasing content of complex arsenic-bearing minerals. China is the world largest copper consumer and also has the largest copper smelting and refining capacity, but majority of its smelting capacity relies on supply of imported copper concentrate. In order to meet the increasing copper demand and ease the tight supply of clean copper concentrate, the Chinese copper industry has to look at the domestic opportunity of developing non-traditional copper resources, specifically those of lower grades, more complex mineralogy, and increasing level of deleterious elements especially arsenic and also process imported copper concentrate with increased arsenic content. Due to a significant and growing environmental issue associated with arsenic contamination, developing economically viable and environmentally reliable methods and approaches for arsenic management and control in unlocking the maximum value of such arsenic bearing copper resources has become more critical for sustainable growth of the industry.

Jan 1, 2019

By Tedd E. Lister, Andre Anderko, Peiming Wang

Mobile electronic devices such as smart phones and tablets are a significant source of valuable metals that should be recycled. Value metals in phones are gold, palladium, silver, copper, cobalt and nickel. Devices now contain increasing amounts of rare earth elements (REE). Effective recycling schemes should include the recovery of these critical materials. Targeted recycling of items containing more of the less available critical materials could address their future criticality. This presentation will describe an electro-hydrometallurgy approach to efficient recycling of metals from scrap mobile electronics. The electrorecycling (ER) process generates oxidizing agents at an anode while reducing dissolved metals at the cathode. Development of the process involved generation of E vs pH diagrams, complemented with metals dissolution experiments used to assess the effectiveness of various solution chemistries. Although several schemes were envisioned, a two stage process has been the focus of work: 1) initial dissolution of Cu, Sn, Ag and magnet materials using Fe+3 generated in acidic sulfate and 2) final dissolution of Pd and Au using Cl2 generated in an HCl solution. Results from laboratory work will be discussed.

Jan 1, 2014

By G. Favini

A Bayesian decision model of minimun risk, based on the probability and costs of mine discoveries and non-economic projects, is presented for massive sulphide exploration in the Canadian Shield. The sample used for the model is composed of data relating to forty mines, sixty non-economic sulphide occurrences, and sixty occurrences of graphitic and pyritic material. These economic and barren samples consist of drill-tested occurrences which were, in varying degree, characterized by conductivity anomalies. Given the large size, the reliability and the homogeneity of the data base available for massive sulphide exploration, it is shown that certain statistical models can and should be utilized as a tool for decision-making by explorationists. Given this data base, information theory tells us that only those signals that are independent of one another will transmit information with minimum error. An ensemble of six significant multilevel signals, markedly independent of one another and consisting of numeric and geometric form descriptions derived from Bouguer anomaly, aeromagnetic and physiographic maps, were identified and evaluated by case studies. The use of these signals as input in a simple statistical procedure, or in a carefully planned and experienced visual appreciation scheme, can be of significant aid in decisions concerning the choice of favourable areas or sectors to explore in detail. The method of discriminant analysis is theoretically and practically suited for the statistical modelling involved. By way of a simulation on our statistical model, the efficiency of the model and of the underlying criteria is determined for historic cases and, by inference, for its validity in future exploration. An approximate optimized solution is derived from the model which suggests that over 90% of the known ore could be found by screening, according to a model such as that herein described, and drilling only 30% of the targets (mostly barren) normally identified and tested in current and past exploration.

Jan 1, 1979

By Robert A. Macinnes, Peter Moon, John P. Pappone

"This paper, in presenting the results of the application of the assessment centre method at Texasgulf Canada Ltd., illustrates a novel "" in-use"" technique for manpower training in the mining industry.IntroductionMining history is full of examples of what goes wrong when human judgment fails-disasters, floodings, loss of life and property. We must, therefore, assume the importance of selecting competent people for supervisory responsibility. This article de scribes a method for assessing supervisory ability, its first application in Canadian mining and the result s obtained over the past six years. It is known as the assessment centre method."

Jan 1, 1981

Adaptive processing is often related to the mineral composition of the mining block currently processed. The portions of waste, ore and secondary product minerals considered are always positive and typically sum to 100% (i.e. a composition). A typical solution to predict block averages of spatially dependent quantities would be block kriging. However, kriging is based on spatial correlations and it has been repeatedly shown that correlations of compositional data are spurious and blurred by the constant sum constraint. Aitchison (1982) proposed a general solution for compositional problems, based on transforming the compositional data to a set of logarithms of ratios of components, and analysing the transformed scores. The transform is chosen to be invertible to ensure that no information is lost in the process. This methodology avoids spurious correlation problems and ensures coherence between results obtained with different subcompositions. Pawlowsky-Glahn and Olea (2004) adapted the approach for point-support geostatistics, allowing the prediction of point compositions from spatially neighbouring data, without the artefacts induced by standard multivariate cokriging. Unfortunately upscaling the results of this approach with block cokriging is not straightforward, because of the nonlinearity of logratio transforms. Furthermore, we have to consider those nonlinearities created by the dependence on the block composition of extraction efficiency and processing costs of the possible processing choices. This paper proposes a solution for predicting the conditional expectations of the benefit of processing the block with each processing choice using geostatistical simulations of the local values of the composition and the resulting block integrals. The computation for a large number of blocks can be done efficiently using Cholesky decomposition. The approach also allows the calculation of prediction errors for expected compositions and expected benefit at almost no additional computational cost. Such compositional approach is necessary, for example when processing choices depend on proportions of certain minerals after other components have been removed; or if processing alters the composition in a multiplicative way, by partially removing a portion of some components.

Aug 1, 2013

By A. Singh

Two alloys Mg96.9Zn2.7Ho0.4 and Mg93Zn6Ho have been processed by direct extrusion at 300°C and 200/230°C to produce various microstructures containing icosahedral quasicrystalline phase with different grain sizes. The alloys were mechanically tested in tension and compression. The mechanical properties were related to the grain size and microstructures studied by transmission electron microscopy. The extruded alloys showed a mixture of nano-sized icosahedral and monoclinic Mg4Zn7 phase, as well as icosahedral phase particles a few hundred nanometers in size distributed in the matrix. Coarse icosahedral phase particles several micron in size also remained after extrusion. The alloys Mg96.9Zn2.7Ho0.4 and Mg93Zn6Ho extruded at the same temperature of 300°C produced very different grain sizes of 15 and 3 µm, respectively. The alloy Mg96.9Zn2.7Ho0.4 extruded at 200°C and Mg93Zn6Ho extruded at 230°C produced grain sizes of 0.7 µm and 1.5 µm, respectively. Both the alloys showed yield stresses of about 300 MPa in both tension and compression with elongations of about 18%. Hall-Petch parameters are calculated for the alloys.

Jan 1, 2006

By J. B. Rubenstein

This work demonstrates the feasibility of using confocal surface profilometry to measure and characterize wear of graphite anode surfaces. This method was tested using anode samples that were electrolyzed for 24 hours in a laboratory-scale magnesium cell with a high oxide molten salt electrolyte. The oxide produced accelerated wear on anodes designed for low oxide electrolytes. Contour maps, which are effective at displaying non-uniform wear, and total graphite consumption values were generated from the collected surface coordinates. Along with both qualitative and quantitative analysis capabilities, this measurement system was shown to have a fine resolution and a low detection limit.

Jan 1, 2004

By C. Jay Hodgson, Adrienne C. L. Larocque

Abstract -The Mobrun VMS deposit in northwestern Quebec does not fit the classic Noranda­ type model, but exhibits characteristics more consistent with a Mattabi-type deposit. The orebodies are underlain by fragmental volcanic rocks indicative of explosive volcanism in shallow water. Felsic volcanic rocks are more abundant than mafic rocks. Alteration assemblages comprise chlorite, carbonate, sericite, and quartz. Broad semi-conformable alteration occurs high in the footwall to the 1100 lens. Mobrun occurs higher in the stratigraphic sequence than most of the other deposits in the Noranda camp. In this part of the stratigraphy, zones of pervasive carbonatization may be more useful guides for exploration than zones of silicification.

Jan 1, 1993

By Jean A. Bastien

Cette présentation décrit les étapes de développement et l?exploitation souterraine au puits Penna chez Agnico-Eagle division Laronde. Les sujets suivants sont touchés : le fonçage du puits, le développement des niveaux, la méthode d?exploitation, la manutention de la roche brisée, le méthode de remblayage et la ventilation. En résumé : le fonçage du puits s?est fait sur 2,240 mètres de novembre 1995 à mars 2000. Le développement des niveaux a débuté en octobre 1998. Les opérations de minage ont débutés en août 99 dans le premier horizon situé au dessus du niveau 122. Les chantiers sont exploités par longs-trous d?environ 25 mètres de long avec un diamètre de 10 cm. Les accès à la zone minéralisée sont transverses. Le minerai est soutiré des chantiers et acheminé au passe-minerai a l?aide de chargeuses navettes. Par la suite, le minerai passe sur un marteau, est concassé et transporté sur un convoyeur, jusqu?au silo de 4,500 tonnes au-dessus de la station de chargement automatisée du niveau 152 d?ou les skips sont alimentés. Le remblai en pâte est envoyé de la surface par des trous ayant un revêtement d?acier. Le diamètre intérieur est de 15 cm. Le réseau de ventilation est principalement alimentée par des ventilateurs de surface (système aspirant et souflant) conçus pour acheminer sous-terre un maximum de 640 mètres cubes par minutes (1,350,000 pcm).

May 1, 2001