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By J. M. Kuchta

Concentrated hydrogen peroxide (H202) is a highly reactive oxidizing agent that liberates heat when it decomposes. The heat liberated may be sufficient to ignite combustibles with which the peroxide comes in contact. For this reason, concentrated hydrogen peroxide should be handled only by personnel familiar with its many unique properties.6 Hydrogen peroxide is used as a bleaching agent in the manufacture of textiles; this is its major single use in the United States. It is also employed as a reagent in chemical synthesis, as a source of free radicals to start polymerization, as a foaming agent in the manufacture of porous substances, and for its effect on biological processes. Moreover, highly concentrated hydrogen peroxide is a compact source of energy that can be utilized both as a monopropellant and as the oxidizer in a bipropellant system, During World War II, large quantities of highly concentrated hydro- gen peroxide were used as propellants, particularly in Germany. Since then, production of the peroxide has increased rapidly; in the United States alone it has more than doubled since 1950.7 Because of its widespread use, increasing interest has been shown in the hazards of handling the high- strength peroxide.

Jan 1, 1961

By R. R. Lowery

The Bureau of Mines developed hypereutectic aluminum-silicon alloys which 11.7.d better mechanical properties than the unmodified hypereutectic alloy. A commercial aluminum-20 weight-percent silicon LIr alloy was selected as a ary base for improvement. The primary silicon. grains were reduced from ASTM 4-5 to ASTM 8.5 by the use of phosphorus and phosphorus compounds. The remaining eutectic matrix was refined by sodium metal additions of 0.2 weight-percent. Solid solution strengthening of the alpha aluminum was obtained by adding 2 percent copper and 0.5 percent magnesium. Also, 1 percent nickel was added to harden the alloy. Optimum thermal treatment consisted of a solution treatment for 10 hour:, at 480° C with hot water quench, followed by aging for 6 hours at 175° C. The final alloy exhibited a Rockwell B hardness of 75 ±2 in the heat-treated condition. The ultimate tensile strength was 39,5O0 psi with no recordable elongation. The coefficient of linear thermal expansion was 20.4 x 10-6 per °C in the temperature range 20° to 300° C. No wear resistance data were collected.

Jan 1, 1966

By Michael E. Henderson

The U.S. Bureau of Mines (BOM) constructed the Hydraulic Transport Research Facility (HTRF) to investigate the hydraulic parameters relating to the transport of coarse coal. To achieve these goals in a timely and efficient manner, the Bureau contracted to Boeing Services International, Inc. (BSI) the responsibility of operating the HTRF and providing technical support. This data report is a summary of the testing and data results for the period from 6 September to 9 September 1983. The testing covered herein is for coarse 2-in by 0 (minus 50 mm) Pittsburgh Seam run-of-mine (ROM) coal in a 12-in (300 mm) pipeline, at velocities ranging from 8 to 16 ft/s (2.4 to 4.9 m/s) and at concentrations ranging from 15 to 50 pct.

Jan 1, 1985

By R. J. Kuczynski

The U.S. Bureau of Mines operated a 2,000-g (4.4-lb) batch process development unit for recovering platinum-group metals (PGM) from automobile catalysts. Virgin monolith, used pellet, and used monolith catalyst samples were tested. Leaching twice with 1-pct sodium cyanide (NaCN) solution at 1600 C for 1 h dissolved more than 95 pct of the PGM from virgin catalysts and more than 90 pct from used pellet catalysts. More than 85 pct of the PGM was dissolved from used monolith catalysts when a third autoclave step was added. Solid PGM concentrates containing more than 99.8 pct of the dissolved PGM and analyzing greater than 70 pct PGM were recovered by heating the pregnant leach solutions from virgin catalysts to 2500 C and used catalyst to 2750 C for 1 h. The solution after heating contained less than 0.2 ppm. total cyanide. The virgin residues passed the EPA Extraction Procedure Toxicity Test (EP Tox Test), the EPA Toxicity Characteristic Leaching Procedure (TCLP), and the California Waste Extraction Test (WET) for all elements except Ba. Adding sodium sulfate (Na2S04) to the virgin leach residues reduced the amount of Ba dissolved to an acceptable level. The used leach residues passed the EP Tox Test for all elements but failed the WET and TCLP for Pb.

Jan 1, 2010

By R. V. Ramani, P. M. T. White, D. Sutton

Appendix I. Part 1: Description Of Geology & Reserves System Introduction The Ore Evaluation and Reserve programs have been developed to aid in the evaluation of coal deposits, both qualitatively and quantitatively. The "Weighted Moving Average" technique used provides considerable flexibility in dealing with diverse parameters with differing distribution characteristics. Determination of Model Constants "a" and "k" - Unit 1 The flexibility of the method in dealing with diverse value parameter distributions lies in its ability to cater to the individual characteristics of each. These characteristics are embodied in the values determined for constants "a" and "k", namely, local and regional variations in value distributions, respectively. The empirical method used attempts to optimize the "a" - "k" combination. Realistic values for "a" and "k" are entered into the program together with sample values for the required parameters and their respective coordinate location values. All the values within a specified radius from the point being evaluated are used to interpolate a value at that point. (Note, the interpolated point is the location of one of the boreholes, values of which are not used in the calcula¬tion.) 3n a similar manner, interpolated values are calculated for each borehole location and for each parameter. This is done for each possible combination of "a" and "k".

Jan 1, 1974

By B. H. Eccleston, R. F. Kendall, D. E. Hirsch, Norman G. Foster

The mass spectra of 23 alkylthiophenes are presented , including 21 that have not been previously reported . Correlations between mass spectra and the structure of the thiophene homologs are discussed . Comparisons with , and corroboration of , earlier workers ' correlations and predictions are made . Several additional correlations are reported to enable the spectroscopist to identify the substituents on alkyl - substituted thiophenes , and the relationship of the mono - substituted and 2,5 - disubstituted alkylthiophenes is discussed in detail .

Jan 1, 1964

By Heine Kenworthy

In 1930 the Shenandoah-Dives Mining Co. near Silverton, Colo., put into operation a newly erected, 300-ton selective flotation plant to mill complex ores from its nearby mine. The operation was a steady producer and was enlarged to treat 600 to 800 tons a day. In 1942 the company opened and started milling an area in the mine containing semioxidized ore. The valuable mineral. Content of this ore was considerably higher than in the straight sulfide ore previously handled alone. The mixture of clean sulfide and semi-oxidized ore was difficult to treat; consequently tailing losses, especially with respect to lead, were high. A. few years later, in order to study the possibilities, of obtaining higher recoveries by a modification of the mill flow sheet, a 1,200-pound sample of mill feed, taken over a period of several days by the company, was submitted to the Mississippi Valley Experiment Station for testing. Although this sample proved to contain more than twice as much lead as the average yearly mill feed, the same problem of recovering the oxidized values were present.

Jan 1, 1948

By Jarrell C. Grout

The Bureau of Mines has developed a computer program for use in solving nonlinear regression problems. The program is written in a general form so that, regardless of the functional relationship, the unknown parameters may be evaluated by either the Gauss-Newton or the Newton-Raphson methods of iteration. Variances and covariances of the parameters, as derived from the law for the propagation of errors, are also determined.

Jan 1, 1969

By M. M. Fine

A laboratory mineral-dressing investigation of manganese ore from the Martin mine, Independence County, Ark., succeeded in recovering ferrograde manganese products. Sintered flotation concentrates analyzing 40.7 and 41.4 percent manganese at overall recoveries of 54.6 and 47.7 percent, respectively, were produced from preconcentrated feed, Preconcentration of the ore for flotation included treatment by magnetic separation and by a combination of magnetic separation and heavy-medium processing. The mineral-dressing study of the Martin mine rhodochrosite ore was part of a general program of the Bureau of Mines to develop domestic sources of strategic minerals, including manganese. Several such potential sources of manganese exist in the Batesville, Ark., district, one of which is represented by the Martin mine. Although the Martin mine area has not been delimited with respect to total reserve tonnage, it is considered to be one of the more important occurrences of manganese in the district. It is estimated that several 100,000 tons of manganese carbonate ore are present in this and similar properties.

Jan 1, 1954

By Michael J. Friedel

The integrity of mine structures, such as the roofs, ribs, face and supporting pillars, is difficult to assess beyond the exposed surface. To mitigate potential rockfall hazards, the U.S. Bureau of Mines is assessing the usefulness of Rayleigh wave dispersion analysis to detect damage and stress-relieved zones in mine structures. Classical surface wave dispersion modeling is utilized at both laboratory and field scales in damaged and undamaged material to assess the integrity of a mine pillar and roof. To more fully exploit Rayleigh wave propagation characteristics, derivation of a novel dispersion parameter was conducted using a convolutional model. The development of a suitable Rayleigh wave dispersion system based on insight derived from forward modeling is presented. The application of inverse modeling for damage and stress assessment in the mine environment is also discussed.

Jan 1, 2010

By R. V. Ramani, W. Miola, R. Srikanth, S. C. Soboleski

"Dust control in high-production longwalls requires attention to operating practices and ventilation schemes. Several studies have shown that the shearer is the major source of dust on a longwall face. Support movement has not been regarded as a major source of dust in US longwalls. Yet, under certain conditions, 31% of the shearer operator's dust exposure can be due to support movement.Several methods have been developed for the control of shield-generated dust. But the need for better methods is apparent. In this paper, the amount of airborne, respirable dust generated per shield move is estimated from specially designed experiments on longwall faces. Ten experiments were conducted on five longwall faces in four mines. Each experiment involved one face visit and lasted three to six hours. The contribution of shield movement to the airborne, respirable dust concentration immediately downwind of the shield move varied between 0.12 and 1.75 mg/m3 in the five longwall faces. The mass of airborne, respirable dust gener-ated by shield movement was found to vary between 39 and 386 mg per shield move. The results from this study reveal that control of dust from longwall shields requires a combi-nation of approaches involving alternative operating prac-tices, reducing shield dust generation rate, increasing face air flow and decreasing personnel exposure.IntroductionIn 1992, longwall mining accounted for about 36% of US underground coal production, a 240% increase from a decade ago. The absolute longwall tonnages were 46 and 133 Mt (51 and 146 million st), respectively. Compared with room-and¬pillar mining systems, the longwall mining system is charac¬terized by higher recovery, enhanced safety and higher pro¬ductivity.However, personnel dust exposure on a longwall face is higher than in other types of mining. According to Mine Safety and Health Administration (MSHA) data, fewer longwalls were in continuous compliance with the applicable dust standard in 1992 than in 1989.Controlling shearer-generated dust and reduction of per-sonnel exposure to airborne dust have commanded attention in the design of longwall faces, operational practices and ventilation schemes. Studies in the United States and abroad have revealed that support-generated dust can be a major obstacle to compliance under certain conditions (Becker et al., 1989; Bradley et al., 1983; Jankowski and Organiscak, 1983; Jankowski et al., 1990; Organiscak et al., 1985)."

Dec 1, 1996

By D. Harrington

The record of fatalities from mine explosions in the United States during the fiscal years 1934 to 1937 wars the best in the history of the mining industry; that for the fiscal year 1939, however, is not so favorable, since nearly as many men (170) were killed by explosions in 1938 as were killed during all of the previous 4 years (182). In spite of the large increase in fatalities from explosions during 1938, the average for the past 5 year period (70.4) is less than one-half the average (13) of the preceding 5 year period. The reasons for the large increase in the number of explosion fatalities during the 7 past year as compared with the previous 4 year are not entirely clear; it is: evident, however, that in some instances there has been laxity in the enforcement of State minim laws, and also that come of our coal-mining people, including workers and operating officials, have failed to carry out tine known precautionary measures to prevent explosions.

Jan 1, 1939

By W. A. Calhoun

This investigation of low-grade bauxites as potential sources of aluminum by caustic desilication and alumina extraction was undertaken by the Bureau of Mines to develop extractive methods for winning alumina from domestic deposits of low-grade bauxites. This report is the second of a series covering the work by the Bureau of Mines' Rolla, Mo., and Bauxite, Ark., laboratories. The first report published in the Journal of Metals, December 1951,3/ and dealt with kaolin and halloysite. The present investigation is concerned with low-grade bauxites only. The purpose of these investigations is to increase the domestic supply of aluminum ores. With eventual depletion of high-grade deposits, aluminous materials, such as low-grade bauxite, clays, shales, and high-iron laterites, will become our principal domestic sources of aluminum. The development of extractive processes for winning alumina from these low-grade materials is one of the many national security measures undertaken by the Bureau of Mines. A method has-been developed in the laboratory for successfully treating high-silica bauxites from domestic deposits. In this process the bauxite was calcined at 980° C. to form amorphous silica and alumina. The calcine was then leached by percolation with 15-percent sodium hydroxide solution at 940 to 96° C., removing 67 to 77 percent of the silica with a loss of 4.1 to 5.0 percent of the alumina. The sodium hydroxide in the spent liquor used in desilication was 95 percent recoverable, and comparable desilication results were obtained with 100-percent reclaimed liquor, The indicated cost of reagents, for sodium hydroxide and lime used in the desilication and regenera¬tion of spent liquor, was about $4.00 per ton of calcine treated.

Jan 1, 1954

By Frank E. Cash

The information in this report covers the accident experience of the pebble-phosphate industry of Florida for 1935 and 1936, as well as the 5 years 1930-34, inclusive, statistics of which were published in Information Circular 69174/. The compilation and publication of such accident experience statistics enable the pebble-phosphate industry, as well as other industries, to consider relative hazards and to compare experience and thereby promote accident prevention.

Jan 1, 1937

By Frederick C. Trutt

A guide to the development and utilization of an interactive mine-power-system fault program (Z-bus by algorithm) is presented. Theoretical foundations, as well as implementation considerations are discussed with respect to the mine-power system. Alternative Kron reduction techniques are presented along with a triangular-storage method for storage conservation. Program capabilities include the analysis of balanced and unbalanced (line-to-line, line-to-ground, and line-to-line-to-ground) fault situations using symmetrical component theory. To account for phase shifting in delta-wye transformers and zero-sequence network constructions, transformer and load configurations are specified by the user. The positive-and zero-sequence connections needed for network conformity are automatically constructed with the required impedances.

Jan 1, 1979

By Phillip N. Yasnowsky

"In this Bureau of Mines report, the Federal income tax treatment of mineral exploration and development expenditures is summarized, and changes in the tax treatment of these expenditures since 1951 are detailed and analyzed. Although no attempt is made to establish causal relationships, major tax changes favorable to exploration and development activities did occur in 1951 and 1966 when the Nation was engaged in military actions and the economy was expanding. More recent changes have been unfavorable to exploration and development and were parts of major tax reform efforts. INTRODUCTIONThis Bureau of Mines report discusses the Federal tax law provisions relating to mineral exploration and development expenditures. These provisions, contained mainly in sections 616 and 617 of the Internal Revenue Code of 1954 (Title 26 of the U.S. Code), apply specifically to minerals (other than oil and gas), and thus are of interest to the Bureau of Mines.Bureau of Mines involvement in this subject stems from the legislative mandate in the 1913 amendments to the Organic Act of 1910 (the Act creating the Bureau) to conduct economic investigations of the mineral industries. Congressional concern with the financial conditions in the economic and mineral industries was expressed more recently in the Mining and Minerals Policy Act of 1970 and in the National Materials and Minerals Policy, Research, and Development Act of 1980. The General Accounting Office recommended in 1976 that the Department of the Interior ""identify and evaluate laws and agency programs that affect maintaining and developing a sound and stable domestic mining and minerals industry"" (17, p. iii). 2Taxes, a source of revenue to governments, are a cost to private firms. Thus, taxes directly affect private sector profits, and unique tax provisions are designed to encourage (or discourage) activities such as agriculture, construction, or mining. Even the international competitiveness of the domestic mineral industries may be affected by taxes because many minerals are traded in world markets."

Jan 1, 1985

By H. Kato, G. Asai, R. Blickensderfer, R. Siemens

Some relationships were established among crystallographic orientation , rollability , deformation texture , annealing behavior , slip planes , and ductile- brittle bend transition temperature of molybdenum single crystals . Six large molybdenum single crystals obtained from an ingot melted by electron beam were oriented by X - ray diffraction and rolled on crystallographic planes of low indices in a known direction . During room temperature rolling , cleavage occurred on 100 type planes . At 300 ° C the crystals were rolled to 95- percent reduction in thickness . The crystals ( 001 ) [ 110 ] and ( 011 ) [ 100 ] were most easily rolled . Pole figures were used to correlate the deformation textures of the rolled crystals with the initial crystallographic orientation . Several of the textures which developed could be explained as a rotation about a < 110 > axis of symmetry . The cube crystal ( 001 ) [ 100 ] retained much of its " cubic " orientation . The (001 ) [ 110 ] crystal developed the simplest texture , whereas the ( 211 ) [ 113 ] and ( 211 ) [ 120 ] crystals developed the most complex textures . The 1 - hour recrystallization temperature of the crystal ( 211 ) [ 113 ] was 700 ° C , which is about 300 ° C lower than that of commercial polycrystalline molybdenum . The poles of the slip planes ( as determined from gross slip lines at relatively low magnification ) tended to lie within 20 to 60 degrees of the pole of the rolling plane . The Knoop hardness was slightly dependent upon crystallographic orientation but more dependent upon rolling direction . The ductile- brittle bend transition temperature was dependent upon the rolling orientation and the dislocation density .

Jan 1, 1964

By C. A. Herbert

Coal-mine explosions in the United States during the past 10 years ranked third among the causes of coal-mine fatalities and constituted 16.1 percent of the total fatalities. In Indiana, however, during this same period the percentage of fatalities from this cause was much higher than the average percentage for the entire country. It is only through knowledge of the factors that have led to these past explosions that intelligent steps may be taken to prevent similar occurrences in the future. Although information concerning many of the earlier explosions is lacking, an attempt has been made to tabulate the information available in the hope that it may be of assistance in calling attention to some of the principal causes of explosions in Indiana.

Jan 1, 1934

By Scott W. Hazen

This report describes exploration for lead-zinc ores at the Madonna mine between 1945 and 1953 by the Utze Lode Co., the Bureau of Mines, and the company with Government financial aid under the Defense Production Act of 1950. The Madonna mine yielded silver, lead, and zinc with a net smelter value of over $5,000.000. from 1882 to 1924. The mine was inactive from 1924 to 1942 when the Utze Lode Co. acquired the property. Possibilities for finding ore in the mine, especially at depth, were considered favorable. The Utze Lode Co. began rehabilitating the Madonna mine in 1945. An exploration program, which consisted of winze sinking and drifting, failed to produce commercial are.

Jan 1, 1956

By William E. Young

There are many large rhodunite-bearing veins containing manganese in the Eureka-Animas Forks area of the San Juan Mountains in Colorado. The Sunnyside vein is the largest known vein in the area. As observed on the surface, the vein is mineralized over 8,000 feet and attains a maximum width of 200 feet. The average width of the vein and its branches and ramifications is 58 feet in the area that was mapped in detail. The weighted-average analysis of surface and underground samples from the northeastern extension of the Sunnyside vein is 8 percent manganese. Most other known veins in the area have a similar manganese content. The Hidden Treasure vein lies southeast of the Sunnyside-No Name-Mastadon vein. The weighted average of the analyses of surface and underground samples from this vein is 13 percent manganese. Exposures of the Scotia-Silver Chord vein are visible over a strike length of 4,000 feet on Treasure Mountain. Diamond-drill holes show that the vein contains 10 percent or more manganese to a depth of 400 feet. The vein has an average width of 28 feet. The Independence vein is exposed on the surface for a distance of 600 feet and has an average width of 6 feet. Three cut samples taken across the vein had an average content of 20.7 percent manganese. Sampling of the outcrops of eight veins in the Placer Gulch area also indicates manganese. Numerous other veins cropping out in the surrounding area are similar to the outcrop of the. Sunnyside vein system mineralogically and are worth investigating.

Jan 1, 1966