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By T. P. Letsebe, L. Magwaza, T. A. Sethu, S. M. Rupprecht

"The authors were tasked with introducing safe and efficient drilling and blasting practices to a small artisanal mine located in the Eastern Province of Rwanda. The current mining methods employed at the mine are inefficient as rockbreaking is conducted utilizing hammer and chisel, or by drilling and blasting with no understanding of the rockbreaking process. The paper discusses the drill and blast cycle, as well as the associated activities necessary to support the mining cycle. The challenges and critical aspects in implementing drill and blast activities are discussed, as well as some of the technical aspects, i.e.drilling pattern, initiation and timing of the blast, and handling of misfires. Ancillary issues such as ventilation, training, communication, effective planning, logistics, and human relations are also examined. IntroductionRockbreaking accounts for 60% of the direct mining costs in small-scale mining. When drilling and blasting practices are poorly implemented the process becomes inefficient and dangerous. The introduction of a proven drill and blast system to artisanal mining offers a number of challenges, with safety being considered the backbone of any sustainable operation and a standard that cannot be compromised.The paper is based on a project at an artisanal cassiterite (tin) mining operation in a small village in the Kayonza District in the Eastern Province of Rwanda. A drill and blast programme utilizing industry best practice was introduced at an underground development end; a raise developed at an inclination of 23 degrees. The underground working is accessed via a 17 degree incline shaft with an operating length of 105 m and serviced by a single drum winder. The winder operates at a speed of about 3.5 m/min hoisting two 1 t wagons from the bottom of the incline to surface for tipping (Figure 1)."

Jan 1, 2017

By L. Aspola

The platinum group metals (PGMs), i.e. ruthenium, rhodium, palladium, osmium, iridium, and platinum, are typically found in association with each other, but also importantly, with nickel and copper. Typically Platinum and palladium have the greatest economic significance and other PGMs are typically produced as co-products of these. With recent increases in the value of nickel, cobalt, and the PGMs and an ever increasing focus on the sustainable use of metals, interest in the processing of secondary feed material sources and metal-bearing residues has also substantially increased. As an efficient, proven, and environmentally sound technology Outotec Ausmelt Top Submerged Lance (TSL) Technology has gained commercial acceptance in the nickel industry, including PGM recovery. For the processing of nickel- and PGM-bearing feed materials, five Outotec Ausmelt Furnaces at four sites are in operation. Two of these furnaces are located in Rustenburg, South Africa, which is by far the biggest mine-based producer of platinum. Outotec also has hydrometallurgical processes available for further treatment and extraction of PGMs, which are also briefly discussed.

Jan 1, 2012

By Jack Levin

Dr Laurence AlIison Bushel, a former President of the Chemical, Metallurgical and Mining Society of South Africa, now The South African Institute of Mining and Metallurgy, was born in Queenstown on 20th June, 1910, and died in Johannesburg on 4th November, 1991. There were three distinct periods in the career of Laurie Bushel, each enlivened by some special interests or achievements.

Jan 1, 1991

By E. Matinde

Human beings have been dependent on metals and alloys for livelihoods since time immemorial. In fact, there is irrefutable evidence that successful ancient civilizations achieved supremacy over their environments through the mastery of metals and alloys (Miller, 1995; Mtetwa, 2022). Over time, metals and alloys have evolved to become ubiquitous engineering materials indispensable to mankind, with applications in industrial and residential infrastructure, agriculture, energy generation and storage, transportation and communication systems, and manufacturing, among others (Elshkaki et al., 2018; Watari et al., 2021). Population growth, technological developments, and increase in urbanization and industrialization are all intricately linked to the intensity of use of metals and alloys. With up to 5 billion people estimated to live in urban areas by 2030 (Armstrong, 2009), the demand for metals and alloys will inevitably increase in order to satisfy the increased demand for infrastructure, machinery, and other human needs (Elshkaki et al., 2018; Watari et al., 2021). According to LePan (2022), urbanization and growth of mega-cities will increase the demand for metals and alloys, such as nickel, steel, aluminium, and copper by 116%, 50%, 57%, and 26%, respectively, between 2019 and 2035. Naturally, the production of metals and alloys from natural ores, secondary resources, and/or a combination of both, to meet this increased demand will invariably lead to the increase in generation of deleterious emissions in the form of wastes. In fact, mining and metallurgical wastes currently constitute the world’s largest anthropogenic streams by mass, often containing a high concentration of elements and compounds that can cause potential damage to natural ecosystems and humans (Hudson-Edwards et al., 2011; Lottermoser, 2011; Matinde et al., 2018; Seetharaman et al., 2022). Obviously, society’s heavy reliance on new mineral resources to drive the emerging energy transition entails that the legacy of these waste streams will continue unabated for the near-foreseeable future. The scarcity of high-grade mineral reserves, coupled with deliberate efforts to solve the anthropogenic circularity conundrum, therefore introduces a high level of urgency in the metal extraction industry to develop nascent and more eco-friendly processes and technologies. Integrating circular economy principles based on intentional configurations of circular industrial ecosystems in order to maintain the value of materials and resources in the economy for as long as possible is widely accepted as a practical approach to mitigating the negative externalities imposed by

Sep 1, 2024

By F. Habashi

The first documentary evidence for the use of fire to extract a metal was furnished by the wall paintings of the ancient Egyptians showing workers using the blowpipe and bellows to increase the temperature to melt gold in a crucible. Furnaces grew in size and complexity, coke replaced charcoal in the blast furnace, and the Industrial Revolution took place in England that gradually spread worldwide. More metals became known and new techniques were introduced for their extraction. Among these, metallothermic reactions became prominent in the nineteenth century immediately after the discovery of the electric current and its use to liberate the alkali metals from their salts. Once these metals became available, they were used to produce aluminium from alumina that resisted all other methods of attack. Aluminium, now available on a large scale, was used to decompose the most stable compounds and liberate more metals that became the basis of modern civilization.

Jan 1, 2004

By A. Mehmet

The feasibility of employing a multi-stage column for the recovery of gold from cyanided pulps using extruded carbon was investigated on a pilot-plant scale. It was anticipated that the column contactor would have certain advantages over conventional carbon-in-pulp plants. The feed pulp was screened to remove particles larger than 200 µm and was diluted to a solids concentration of about 23 per cent. The column was operated continuously for 24 days at a pulp flowrate of about 60 l/min and a carbon flowrate of 44 litres per day. The average gold concentrations in the barren pulp 12 hours and 24 hours after the carbon transfer were 0,012 and 0,031 mg/l respectively. The average gold concentration in the solution phase in the feed was about 2,0 mg/L. The average gold Loading on the carbon was 6290 g/t. Calcium carbonate was removed from the loaded carbon by treatment with 0,5 bed volumes of 2,8 per cent hydrochloric acid solution at ambient temperature. The calcium concentration was reduced from about 17 000 to about 500 g/t The carbon was eluted by the Zadra procedure at atmospheric pressure. The results of the elution were highly satisfactory, the gold concentration being reduced from about 6000 to about 20 g/t in 48 hours. The eluted carbon was regenerated in a Rintoul kiln at about 700°C. The activity of the regenerated carbon was found to be at least as high as that of fresh carbon.

Jan 1, 1992

By B. S. Xakalashe, I. J. Geldenhuys, B. Bowman, M. W. Erwee, G. A. Venter, J. Zietsman, C. Sandrock, Q. G. Reynolds

Understanding the behaviour of plasma arcs is an important part of the design and operation of direct current electric arc furnace smelting processes, which are used in the industrial production of many metallurgical commodities. In recent years numerical and computational modelling techniques have begun to illuminate the complexity of arc behaviour and how it is deeply connected to the thermodynamic and physical properties of the arc plasma. Plasma properties may be estimated from first principles using statistical mechanics methods, but this requires as input some knowledge of the composition of the gas phase that occurs over the process during smelting. In this paper the authors describe a workflow using thermochemistry software to predict the expected gas phase composition through a given process, followed by plasma property calculations using an open-source software tool that has been in development for several years. This tool, 'minplascalc' has been in development for several years and is also described in detail here. The workflow is then applied to the calculation of plasma properties of interest for a variety of historical and current pyrometallurgical processes, and the results are compared. The plasma property data are published in an open-access database for general use.

Mar 4, 2025

By N. B. Strydom

Die bedryfsfisioloog en lugbesoedeling N. B. STRYDOM, Ph.D. (Phys.) (Illinois) (Genoot) Although the industrial physiologist can still be regarded as a rarity in South African industry, it is obvious that he could make a positive contribution to the control of air pollution. For the past twenty-two years, the gold-mining industry has invoked the aid of industrial physiologists in solving various problems that continually crop up in the more effective and safer utilization of man-power. Air pollution is only one facet that has received attention. It can be stated emphatically that other industries could gain many advantages from the employment of this type of specialist. Because of inadequate opportunities for academic training, however, the industrial physiologists available might not be enough to fill all the possible posts in industry at present, but confidence is expressed that interested persons will soon be able to follow a full university course in this field of study.

By Y. F. Bulgakov, Y. V. Melnikova, V. S. Zakharov

A new technology of atmosphere in inertization of fire section with the help of gazeous nitrogen is presented in the report. This technology is based on membrane air subdivision into two streams, concentrated with nitrogen (up to 99%) and with oxygen correspondently with subsequent giving them into the place of fire. This technology belongs to environmentally friendly ones and it has a great number of technical, mobile and economic advantages comparing with the rest of well-known methods of fire extinguishing. This technology application in Ukrainian coal mines allowed to reduce the member of isolated places of fire at the expense of their extinguishing efficiency.

Jan 1, 2003

1. Book reviews Geostatistics for natural resources characterization, edited by G. Verly, M. David, A.G. Journel, and A. Marechal. Hingham (MA 02043, U.S.A.), D. Reidel Publishing Co., 1984. Pt I: 606 pp. Pt 11: 518 pp. U.S.$135,50 per set. Reviewer: D.G. Krige Magnesium, the international perspective, by Peter King. London, Financial Times Business Information Ltd, 1984. £120. 147 pp. Reviewer: D.G. Maxwell 2. Mintek reports Report M156 A kinetic study of the reactions of certain gaseous sulphur compounds with iron. Report MI57 Reaction mechanisms in the reduction of Winterveld chrome spinel with graphite and carbon. Report MI72 Computer programmes for the control and datamanipulation of a sequential X-rayfluorescence spectrometer. Report MI77 A proposed test for the determination of the grindabi/ity of fine materials. Report MI86 A survey of the erosion, corrosion, and abrasion of material-handling systems in the mining and mineralprocessing industry. 3. New journal Advanced materials & processes, issued monthly by American Society for Metals (Metals Park, Ohio 44073, U.S.A.). CIM conference The combined 24th Annual Conference of Metallurgists and the 15th Annual Hydrometallurgical Meeting will be held in Vancouver from 18th to 22nd August, 1985. Light metals The 8th International Light Metals Congress will take place from the 22nd to 26th June, 1987. These meetings, which take place traditionally every few years, are organized by the Austrian Metals Industry Association, the Austrian aluminium industry, and the University for Mining and Metallurgy in Leoben, in collaboration with the Aluminium-Zentrale Diisseldorf. President of AS&TS* Mr Arthur Woodington Reynolds (Sam) took office as President of The Associated Scientific and Technical Societies of South Africa on 28th November, 1984. Sam Reynolds was born in Boksburg on 27th December, 1930, and received his education at Christian Brothers College in Boksburg and at St John's College in Johannesburg. World mining Sweden, Finland, and Norway expect representatives of all mining countries in May-June 1987 to the 13th World Mining Congress in Stockholm. The Swedish Mining Association, the Finnish Association of Mining and Metallurgical Engineers, and The Association of Norwegian Mines will organize the Congress, together with the International Organizing Committee of the World Mining Congress. Sheet metal The German Group of the International Deep Drawing Research Group (IDDRG) will be organizing the 14th Biennial Congress of the IDDRG on 21st to 26th April, 1986, in Cologne and Munich. Safety in mines The 21st International Conference of Safety in Mines Research Institutes is to be held in Sydney from 20th to 25th October, 1985. ILAF A conferences The Instituto Latinoamericano del Fierro y el Acero (ILAFA) has scheduled the following congresses for 1985. Mechanical testing of materials The Deutsche Gesellschaft fiir Metallkunde, together with the Deutschen Verband fiir Materialpriifung and the Fachhochschule Osnabriick, is holding a course on the methods used for the mechanical testing of materials at Osnabriick from 9th to 11th September, 1985. Mine ventilation The Second U.S. Mine Ventilation Symposium will be presented from 23rd to 25th September, 1985, in Reno, Nevada, by the University of Nevada-Reno's Mackay School of Mines and Division of Continuing Education.

Jan 1, 1985

By F. S. A. de Frey, F. C. Kruger

Personnel management has undergone a remarkable change over the course of the past ten years. Personnel departments have played an increasingly important role, which today requires highly trained people and cannot be adequately served by the lesser qualified officials of yesteryear. Changes in the mining industry that stem from the demand for skilled labour to keep pace with technological developments and the mechanization of mines today demand that emphasis should be placed on the maximum utilization of manpower. Maximum utilization of manpower calls for more scientific and effective methods of recruiting, selecting, training, and placing workers so as to offer them the best opportunities for development and promotion, which naturally ensure a minimum labour turnover and eliminate labour unrest. This can be achieved only if well-qualified and properly trained personnel administrators are prepared to accept the challenge and apply themselves purposefully by assisting line mangement with the attainment of the company's corporate objectives.

Jan 1, 1982

By B. A. Obadele, R. Machaka, M. L. Raganya, M. E. Makhatha, N. A. Moshokoa

The influence of solution treatment on the phase evolution and tensile properties of Ti-Mo alloys was investigated to assess their potential use in biomedical applications. Phase formation and microstructural evolution were studied using X-ray diffraction (XRD), optical microscopy (OM), scanning electron microscopy (SEM), and electron backscatter diffraction (EBSD). The mechanical properties were characterized by means of tensile tests and bending strength. XRD analysis showed that solution treatment increased the volume fraction of β phase and supressed the α" phase. The microstructures of the as-cast alloys consisted of β equiaxed grains with sub-grain structures of different sizes, while the solution treated alloys comprised β equiaxed grains only except for Ti- 10.02Mo, which comprised needle-like α" structures. EBSD showed an increase in the volume fraction of the ω and α" phases in all the alloys after solution treatment. The elastic modulus and UTS of all the alloy significantly decreased after solution treatment, except for Ti-15.05Mo,whereas the elongation significantly increased. The fracture surfaces of all the alloys after solution treatment indicated more ductile behaviour than brittle

Jun 10, 2024

By G. Jandieri

An improved methodology is presented for assessing the economic feasibility and effectiveness of recycling industrial waste. The methodology is based on the break-even control mechanism, but at the same time provides for the introduction of new evaluation criteria such as the threshold of conditionality and the degree of ore substitution. Based on an improved analysis, it becomes possible to more precisely predict recycling efficiency. A more refined determination of the lower limit of concentration of recoverable metals, at which technogenic waste can be assigned the status of secondary raw materials and processed profitably, leads to a significant expansion of the secondary raw material base suitable for recycling. The potential for recycling manganese-containing dust from the production of ferrosilicomanganese, dehydrated sludge from the hydro separation of slags, and cake from the production of electrolytic manganese dioxide at the Chiatura mining enterprise is used as an example. It is shown that with a threshold of –24% Mn content, the highest recycling efficiency can be achieved by the production of low-phosphorus manganese slag and conversion to ferrosilicomanganese using the above waste to replace 40-60% grade III and IV manganese concentrates in the feed.

Jan 26, 2023

By M. J. A. Leal-Gomes

There is a set of settled ideas in the field of the mechanics of rock mass joints, that need a deep revision, after the last experimental works of several authors. In this paper, this theme is approached under several viewpoints, like the following ones: the essential influence of the mating or mismatching of rock joints on their strength (different strength models are applicable to these two situations, one leading preferably to normal scale effects, and the other to inverse scale effects); Patton's model is a bad formulation of the joint strength, whenever there is a dilation effect in the slidings (actually, the essential consideration of the amplitude of the roughess isn't made by any limit equilibrium model, like Patton's model); the joint strength increases as the width perpendicular to the sliding direction is reduced (previous works of other authors suggested the independence of the strength on that width); the reduction of the anisotropy of the roughness, as the sample symmetry and sample dimensions increase; there is no scale effect in the discontinuity mechanics, if there is no roughness heterogeneity; when only the same roughness and undulation orders are involved in the tests, shorter samples have larger peak displacements and lower shear stiffnesses than larger samples (usually, the contrary is admitted). For all these reasons, there isn't an easy correlation between the small scale tests and the natural large joint scale. Only "in situ" large scale tests have some representativeness. All the above mentioned questions are correlated to each other. Es gibt eine Menge eingewurzelter Ideen im Gebiet der Mechanik von Felsklüften, die, nach den letzten experimentellen Arbeiten von mehreren Verfassern, eine tiefe Überprüfung benötigen. In dieser Mitteilung, wird dieses Thema unter mehreren Blickpunkten angegangen, wie die folgenden: der wesentliche Einfluß des Zusammenpassens oder nicht Zusammenpassens von Gesteinsklüften auf ihre Festigkeit (verschiedene Festigkeitsmodelle sind auf diese zwei Situationen anwendbar, eins, das vorzugsweise zu normalen Maßstabseffekten führt, und das andere, das zu umgekehrten Maßstabseffekten führt); Pattons Modell ist eine schlechte Formulierung der Kluftfestigkeit, immer wenn es einen Dilatationseffekt in den Verschiebungen gibt (in Wahrheit, wird die wesentliche Berücksichtigung der Rauheitsamplitude von keinem Grenzgleichgewichtsmodell beachtet, wie Pattons Modell); die Kluftfestigkeit wächst wenn sich die Breite senkrecht zur Verschiebungsrichtung verringert (frühere Arbeiten anderer Verfasser suggerierten die Unabhängigkeit der Festigkeit von jener Breite); die Verringerung der Rauheitsanisotropìe, wenn die Probekörpersymmetrie und Probekörperabmessungen zunehmen; es gibt keinen Maßstabseffekt auf die Trennflächenmechanik, wenn es keine Rauhheitsheterogenität gibt; wenn nur die gleichen Rauheits- und Ondulationsgrößenordnungen in den Versuchen verwickelt sind, haben kürzere Probekörper größere Spitzenverschiebungen und geringere Schersteifigkeiten als größere Probekörper (gewöhnlich, wird das Gegenteil angenommen). Wegen aller dieser Gründe, gibt es keine einfache Korrelation zwischen den Versuchen im kleinen Maßstab und dem natürlichen großen Kluftmaßstab. Nur "in situ" Versuche im großen Maßstab sind einigermaßen repräsentativ. Alle die oben erwähnten Fragen hängen miteinander zusammen. Il y a un ensemble de des bien établies arrière-pensées idées dans le champ de la mécanique des discontinuités en massifs rocheux qui ont besoin d'une profonde revision, après les derniers travaux de divers auteurs. Dans cet article cette matière est abordée sous divers points de vue, comme les suivants: la signification essentiel de l'ajustement ou du désajustement des discontinuités dans leur résistance. Des différents modèles sont applicables à ces deux situations, une conduisant de préference à des effets d'échelle normaux et l'autre à des effets d'échelle inverses; le modèle de Patton est une mauvaise formulation de la résistance des joints quand il y a effet dilatant dans les glissement. En effet la contribuition essentielle de l'amplitude de la rugosité n'est pas consideré par aucun modèle d'équilibre limite comme le modèle de Patton; la résistance des joints croit au fur et à mesure que la largueur perpendiculaire à la direction de glissement est réduite. Des travaux antérieurs d'autres auteurs suggéraient que la résistance était indépendant de cette largueur; la réduction de l'anisotropie de rugosité au fur et à mesure que la symétrie et les

Jan 1, 2003

By B. M. Thethwayo

Graphite blocks are currently used in the concentrate - slag zone in primary PGM smelters, and can possibly be extended to the matte zone. This project evaluates the interaction between synthetic matte and graphite blocks on a laboratory scale. Static crucible tests were performed where graphite crucibles (prepared from standard and high-grade graphite) were filled with synthetic matte (27.7 per cent S ? 46.1 per cent Fe ? 17.0 per cent Ni ? 9.2 per cent Cu) and heated to 1550°C for different time periods (1?5 days). Matte penetration was evaluated using a SEM, while graphite dissolution was evaluated by measuring the carbon content of the matte with a LECO carbon analyser. Matte penetrated into standard grade graphite up to approximately 2 mm, while matte infiltration into the high grade graphite was limited to the immediate hot face. The saturation solubility of graphite in the synthetic matte at 1550°C was 0.43 per cent. Copper, iron, nickel, and sulphur were detected in an accretion that formed in the water-cooled part of the furnace. This accretion consists of mainly Cu-S and Cu-Fe-S based phases.

Jan 1, 2012

By E. Matinde

Poor phase separation and fine dissemination of the desired components within congruous slag phases are key challenges limiting the recoverability of values from slags by conventional beneficiation methods. Slag microstructure conditioning is a pragmatic approach to increasing themvalue-in-use of discard slags, especially when integrated with the broader smelter infrastructure. Although not yet tested on oxide slag systems, this paper explores the potential application of magnetohydrodynamic principles to the crystallization behaviour of bulk slags. Integrating the slag microstructure conditioning infrastructure to the existing smelter infrastructure is key to unlocking the economic value of slags because it is most economic to condition the properties of molten slag directly after tapping. A new business model that integrates smelting units to transversalmeconomic activities, such as cement production and suppliers of construction aggregates, canmsignificantly increase the circularity of metallurgical slags.

Oct 9, 2024

By X. W. Pan

It has been found that the MnO content of a slag decreases sharply when direct current is applied to a 1T1£tal-Slagsystem consisting of liquid Mn-Si-Ccsat metals and MnO-SiO2-CaO-AI203 slag in graphite crucibles. This paper reports a preliminary investigation into the electrochemical effects of direct current on the metal-slag system, the silicon content of the metals, and the MnO content of the slag. The results show that, when a direct current of 7 A is maintained, the MnO content of a metal containing 10 to 11 per cent silicon by weight is reduced rapidly from 26,5 to 17,2 per cent by weight. This reduction seems to proceed further when the process is continued. When the direct current and the voltage are kept constant at TA and 4 V respectively, the MnO content of a metal containing 1 to 2 per cent silicon by weight is reduced to 1 from 25 per cent by weight, which results in a manganese yield of 96 per cent.

Jan 1, 1995

By Mr P. W. J. van Rensburg

SOUTH AFRICAN NATIONAL COMMITTEE ON TUNNELLING In 1970, the South African Institution of Civil Engineers, the South African Institute of Mining and Metallurgy, the South African Institute of Mechanical Engineers, and the Geological Society of South Africa held an international conference on tunnelling, known as Tuncon 1970. SUID-AFRIKAANSE NASIONALE TONNELBOUKOMITEE In 1970 het die Suid-Afrikaanse Instituut van Siviele Ingenieurs, die Suid-Afrikaanse Instituut vir Mynbou en Metallurgie, die Suid-Afrikaanse Instituut van Meganiese Ingenieurs en Die Geologiese Vereniging van Suid-Afrika 'n internasionale konferensie in verband met tonnelbou gehou, wat bekend gestaan het as Tonkon 1970.

Jan 5, 1974

By C. V. O?Keefe

Volumetric flow and mass flow are two of the critical process parameters needed to understand and control flotation processes, with others being levels, densities, and metal analyses. Both volumetric flow and density measurements can be adversely influenced by entrained air, which will result in artificially high flow readings and artificially low mass flow calculations. Array-based instrumentation has been used successfully to accurately measure both volumetric flow of aerated slurry and the quantity of air entrained within the slurry. The latter measurement has been used to correct density measurements, thus providing an accurate mass flow calculation. A case study involving the use of this technology to measure both flow rates and air entrainment levels at Eland Platinum processing facility (concentrator) will be covered in detail. In addition, with certain traditional flow meters such as electromagnetic meters, erroneous volumetric flow rates can be recorded in the presence of paramagnetic or ferromagnetic material. The use of this array technology to avoid spikes in measurements due to steel fragments passing through the pipe will also be discussed.

Jan 1, 2012

By L. A. Jordan, D. van Vuuren

A two-dimensional finite difference model has been developed to describe the reduction of kilogram quantities of dehydrated phosphogypsum. The model’s scope has been limited to focus on the heat transfer and reactions that occur within a mass of material contained in a vessel inside a furnace rather than also including the effects of heat transfer to the vessel. Changes in the heat transfer properties (k, ρ, and Cp) are incorporated as the composition of the mass changes as the chemical reactions progress. The model is validated against experimental data, with samples heated to 1000°C at 3°C min−1 while purging with nitrogen gas. A sensitivity analysis of model predictions to the pre-exponential factor of the reaction rate constant of the main chemical reaction and the thermal conductivity of the powder bed indicated that, at the envisaged process conditions, the behaviour of the system depends much more on the rate of heat transfer than on the rate of the chemical reaction. The model demonstrated a significant increase in accuracy when the thermal conductivity was modelled to increase linearly with temperature compared to assuming a constant value.

Oct 1, 2022