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By T. Bezuidenhout, J. D. Visagie

In recent years the requirements for a barrier system between the waste body of tailings storage facilities (TSFs) and the natural ground (NG) has necessitated the use of HDPE-lined TSFs in South Africa and other countries. The addition of an HDPE liner creates an interface between, inter alia, the tailings and surrounding soils on the footprint of the TSF. It is known that low-strength materials beneath slopes can cause slope instability. One method which can theoretically mitigate this instability of a lined TSF is the addition of stability bunds along the footprint of the TSF. Altering the profile of the footprint to include slope changes which oppose the direction of the failure creates passive slices in a limit equilibrium analysis. The passive slices actively oppose the movement of active slices, resisting the mobilization of tailings, thus greater active slice forces are required to develop a failure surface running along the liner interface. Two scenarios are presented and compared. The first scenario retains the ground profile unaltered and the second scenario includes stability bunds along the ground profile. An in-depth assessment is made of the interslice forces and the interface shear stresses for each scenario. The theoretical background is discussed in greater detail to determine the mechanisms of reinforcement provided by the bunds.

Jun 2, 2022

By C. O. Aksoy, G. G. U. Aksoy, A. Fisne, I. Alagoz, E. Kaya

Coal produced in underground mines is transported to the surface by means of conveyor belts throughout long roadways. The combustion of belts puts a large number of employees at great risk. Underground collieries differ from other underground mines -due to the combustible nature of the product. The most prevalent cause of belt fires in underground coal mine is spontaneous combustion due to oxidation of the coal, which also enables the conveyor belt to burn over time. In 2014, a belt fire in an underground coal mine in Manisa-Soma, Turkey caused 301 fatalities. A study has been conducted on this accident for approximately 3 years, consisting of combustion tests in a purpose-built research gallery, comparison of the test results with mine records of the accident, and CFD modelling of the mine environment. The intensity of the fire was sufficient to redirect the air flow underground, causin large amounts of toxic gases to fill almost the entire mine in approximately 15 minutes. It is recommended that CFD analysis be used in planning emergency action strategies in underground mines.

Dec 13, 2023

By J. A. L. Napier

It has been established that significant time-dependent stope convergence may occur over time periods of hours and days in certain hard-rock gold and platinum mines. The source of this time-dependent behaviour appears to be associated with both pre-existing discontinuities and with mining-induced fractures that form near the stope face. These induced fractures may be associated with blasting processes and may also be formed in response to high stress concentrations in the unmined regions immediately ahead of the stope face. In shallower platinum mining operations, time-dependent behaviour is, however, observed to be much less marked unless some form of specific mining-induced fracturing occurs. One particular case of considerable interest is the time-dependent behaviour that is found to be associated with the formation and deployment of crush pillars. The purpose of the paper is to present a simple limit-equilibrium computational model of this behaviour that is sensitive to both the formation sequence and the size of planned crush pillars in a mine layout. This model provides a useful means to optimize the sizing of crush pillars, and at the same time may be used to identify potentially hazardous circumstances in which pillars may not crush in a stable manner.

Jan 1, 2012

By M. de Beer

The conversion of carbon-containing feedstock into liquid fuels can proceed via the Fischer-Tropsch synthesis, which is catalysed using supported cobalt catalysts. These catalysts contain noble metals to facilitate the reduction of oxidic cobalt species in the catalyst precursor to metallic cobalt, which is the catalytically active species for the Fischer-Tropsch synthesis. This is thought to occur via hydrogen spillover, i.e. the diffusion of atomic hydrogen over the support from the noble metal to the oxidic cobalt moieties. Noble metals may also affectthe dispersion of cobalt in the active Fischer-Tropsch catalyst. The economic aspect of the addition of noble metals to the Fischer-Tropsch catalyst is discussed.

Jan 1, 2014

By X. Zhang, Z. T. Yuan, C. Zhang, H. M. Zheng, X. M. Wang, L. X. Li, N. Li

In metal mines, comminution is commonly used to liberate minerals for subsequent mineral concentration processes, such as flotation, magnetic separation and gravity separation. However, ores are aggregates of valuable minerals and their disseminated gangue minerals, and these minerals exhibit diverse comminution behaviours. In carbonate-bearing iron ores, hematite, siderite, and quartz are the predominant minerals, of which hematite is the objective recoverable mineral. In this regard, the present study aimed to identify the imperfections in siderite minerals by X-ray computed tomography (XCT), and thus quantitatively characterise their size and shape in terms of Feret diameter and aspect ratio, as well as other parameters. XCT images indicated the protogenetic ubiquity of pores <5 μm in diameter and cracks of 7-8 μm inside siderite particles. In the ground product of artificially mixed siderite and hematite, siderite particles were smaller than hematite particles. Siderite particles had a larger surface area and greater surface roughness than hematite particles of the same volume, which was attributable to the intrinsic holes and cracks in siderite particles. This study provides an insight into the relationship between the inherent imperfections of minerals and their comminution properties. Keywords: Siderite; X-ray computed tomography; particle imperfections; grinding behaviour; sliming

Jan 1, 2020

By H. Zhong, S. Wang, Q. Sun

The flotation performance of 2-(benzylthio)-acetohydroxamic acid (BTHA) to diaspore was first evaluated by micro-flotation tests. The adsorption mechanism was further investigated through adsorption experiments, molecular dynamics simulation, zeta potential and X-ray photoelectron spectroscopy (XPS). The results demonstrated that BTHA had a stronger ability to collect diaspore in comparison with another diaspore collector, benzohydroxamic acid (BHA), especially under the condition of weak alkalinity, the flotation recovery can reach 90%. The more negative interaction energy (ΔE) between BTHA and diaspore from molecular dynamics simulation results revealed that BTHA had an easier adsorption ablity onto diaspore than BHA, which matched with adsorption results. The zeta potential and XPS revealed that Al atoms might bond with -C(=O)NHOH by formation of Al-O bonds. Keywords: Diaspore, flotation; adsorption; 2-(benzylthio)-acetohydroxamic acid

Jan 1, 2020

By DeVerle P. Harris, David E. Euresty

"Potential metal supply refers to metals to be produced from as yet unknown deposits. Naturally, to measure potential supply requires, among other things, inference to the number of deposits, their tonnage, and their grade Thus, probability distributions were constructed for each 400-square mile cell in Northern Sonora, Mexico. A computer system was developed that simulated the occurrence of deposits for each cell, exploration for the deposits, and their exploitation. Evaluation was performed for each deposit by discounted cash flow analysis.An objective of this study was to explore the effect of the transportation network and required road or railroad construction upon potential supply. Consequently, the evaluation system was designed to consider the spatial location of a simulated deposit to the existing transportation network and the market destination. The construction of linkages to connect the deposit to existing transportation arteries as well as the carrying of the concentrates to the intended market were simulated. in terms of cost. The selection of the path took into account the existing terrain. This was done by digitizing topographical maps and representing the topography of the area by an orthogonal grid of elevations. The optimum route was selected by dynamic programming, meeting a prescribed gradient constraint. The potential supply of each cell was determined, allowing for the infrastructure effect."

Jan 1, 2014

By S. A. Hosseini, O. Asghari

"Recoverable mineral resources assessment has become a standard geostatistical application in the mining industry, with various geostatistical techniques currently available. This investigation aimed to improve the prediction at the Sungun deposit and to obtain mineral resource models capable of handling (i) the change of support from drill-hole composites to selective mining units (SMUs), (ii) the multivariate nature of the ore control selection criteria that involves both copper and molybdenum grades; and (iii) the local uncertainty on the true (unknown) grades. The solution presented in this paper is to use direct block-support sequential cosimulation in order to construct a set of alternative outcomes of the copper and molybdenum grades on block support over the deposit, with no need for storing point-support values, hence with a considerable gain in memory management and CPU time. The grade realizations so obtained are then processed to calculate the uncertainty in the mineral resources that can be recovered above given cut-off grades, both globally and on a blockby- block basis. IntroductionGeostatistical methods are widely used by mining companies to determine a resource model of the tonnage and head grade of a potential orebody, which is one of the first and most critical inputs underpinning any mining project. The prediction of the grade, tonnage, and recoverable metal for a particular mining plan and the corresponding financial forecast constitute the main technical risks in mineral resource evaluation. The conventional approach to this problem is to predict the mineral grade for constant volumes relevant to the mining plan and to base the recoverable mineral resource calculations on those predictions. Alternatively, one can directly predict the local variability in the mining block grades based on a spatial distribution model (David 1988; Rossi and Deutsch 2014). Multiple realizations can also be constructed by conditional simulation, providing a more complete representation of block grade uncertainty, as well as the uncertainty over multiple blocks. Simulation methods allow quantification of the uncertainty of the mineral resource prediction risks in downstream studies such as mine design, mine planning, or operational optimization studies; the risk assessment is achieved after applying transfer functions to the conditional simulation models (Dimitrakopoulos 2012; Rossi and Deutsch 2014)."

Jan 1, 2017

By T.R. Stacey

Physical testing of rock support for rockbursting conditions has been carried out for over 40 years. A review of this testing shows that it has been mostly component based, rather than actually testing support systems. Further, it is concluded that none of the testing is truly representative of rockburst loading in a similitude sense. Similitude conditions are not achievable, mainly because the real conditions in a rockburst event, such as seismic source location and magnitude, wave frequencies, amplitudes, and interactions, are not all known. Because such information is not available, and because the results of all testing carried out to date have not been able to define, for support design purposes, the capacity of support systems, ongoing physical testing of rockburst support systems is essential. It is essential that the test should simulate, or actually take place in, a supported rock excavation. A rock support system is a combination of individual support components that work together to retain and contain the rock. In doing this, the components are subjected to loading by the rock and to interactive loading between one component and another. It is necessary to prove the capacity of such rockburst support systems by subjecting them to severe loading, as in direct blasting. The direct blasting approach, pioneered more than 40 years ago, probably still provides the greatest validity as a significant test of rockburst support capabilities, even though it does not simulate a rockburst. Direct blast testing of rockburst support systems in a surface environment, such as in a quarry or on exposed rock cutting surfaces, could represent a practical development of the approach, facilitating the execution and monitoring of tests.

Jan 1, 2012

By J. Pelders, G. Nelson

"Fatigue is a significant concern in the mining industry as it is a causal or contributing factor in many incidents and accidents. Fatigue can be caused by work- and non-work-related factors. There is a lack of information about associations between demographic and other non-work factors, and fatigue. This study aimed to assess associations between demographic, work, living, and socioeconomic conditions, and lifestyle characteristics, and fatigue at a platinum smelter in South Africa. Eight interviews with management and two focus groups with production workers were conducted, and 75 questionnaires were completed by production and other workers. Both work- and non-work-related factors were considered to be causes of fatigue. These factors included overtime, shift work, high workloads, activities performed outside of work, age, race, housing tenure, diet, sleep disorders, stress, and job satisfaction. In general, higher levels of fatigue were reported by younger participants, those who rented accommodation, ate less healthily, had a sleep disorder, and those with high levels of stress and low job satisfaction. As various demographic, lifestyle, and wellness-related factors were associated with fatigue, both work and non-work contributors should be addressed in fatigue management plans. BackgroundFatigue may be defined as ‘a state of impaired mental and/or physical performance and lowered alertness arising as a result of, or a combination of, hard physical and mental work, health and psychosocial factors or inadequate restorative sleep’ (BHP Billiton, 2005). Williamson et al. (2011) define fatigue as a biological drive for recuperative rest. Sleepiness and fatigue are related, and the terms are often used interchangeably. However, sleepiness, more specifically, can be defined as sleep propensity, or a person’s tendency to fall asleep (Hossain et al., 2003; Shen, Barbera, and Shapiro, 2006).Increasing levels of fatigue and sleepiness are associated with lapses in attention, errors, response slowing, fluctuations in alertness and effort, and impaired attention, working memory, long-term memory, decision-making, and creativity (Alhola and Polo-Kantola, 2007; van Dongen and Dinges, 2000). Fatigue is also associated with adverse effects on mood and impulsive behaviours (Alhola and Polo- Kantola, 2007; Minkel et al., 2011; Schwarz et al., 2013). It is a significant concern in the mining industry as it is commonly identified as a causal or contributing factor in many accidents and injuries (Schutte, 2009). Fatigue can also lead to long-term health problems, including digestive problems, heart disease, stress, and mental illness (Shaw, 2003)."

Mar 1, 2019

By Y. Jeong, K. Kim

Excess water can lead to instability and even failure in tailings storage facilities (TSFs). Simply reducing the amount of water in TSFs could be the best way to ensure the safety of nearby communities. In this case study we investigated the effects of reducing the water content in tailings slurry at a copper-cobalt-zinc mine in Mexico. An environmentally friendly polymer was used as a drag reduction agent (DRA) to offset the increase in solids percentage. The potential effects of the increased solids concentration on the tailings transportation system were also assessed. A series of ‘what if’ studies was conducted to assess whether adding the polymer would allow the solids concentration to be increased without changing the pressure loss in the tailings pipeline. The studies entailed conducting pipe loop tests to investigate these changes under various solids/ polymer concentrations and then constructing a computational fluid dynamics (CFD) simulation model using the test results. The validated model was used to determine the optimal polymer percentages needed to maintain the same pressure loss under baseline (30% solids) conditions, and to assess the potential risks (clogging, increased erosion rates) to the pipelines. The potential water savings were found to be significant, varying from about 1.852 Mm3/a at 35% solids to 3.915 Mm3/a at 45% solids.

Dec 13, 2023

Sedimentary Ores-Ancient and Modern (Revised), edited by C. H. James. Proceedings of the 15th Inter-University Geological Congress. University of Leicester, December, 1967. Special Publication No.1, Department of Geology, University of Leicester, February, 1969. Obtainable from: Leicester University Bookshop, May&apos;s Walk, Leicester LE 17 RD. Price: 42s. Postage and packing, 3s. 6d. This volume should be of interest to economic geologists and students in this field. A number of illustrated papers on the genesis of ores in sediments are presented; the authors include experts such as Prof G. C. Amstutz, Dr K. C. Dunham, Prof D. Williams and W. G. GarIick. The papers deal mainly with sulphide deposits, but the late Prof J. H. Taylor&apos;s contribution concerns ores of iron and manganese. Brief references to the Witwatersrand ores represent the only discussion of South African deposits. With the notable exception of W. G. Garlick&apos;s paper on Zambian copper deposits, the Abstracts given are inadequate, necessitating thorough reading of the papers to extract the important matter.

GENERAL Invitation to attend O.F.S. Branch Meeting: Members of the Witbank/Middelburg Branch were invited to attend a branch meeting of the O.F.S. Branch on the 15th November. The subject of the meeting would be a talk on the Hendrik Verwoerd Dam Project and up to 25 members could be accommodated on the nights of the 14th and 15th November by kind invitation of members of the O.F.S. Branch. A questionnaire would be issued at a later date, to obtain the names of those interested in attending the meeting. PAPER FOR PRESENTATION The Chairman called upon Mr G. H. J. Kitson to present his joint paper, entitled: &apos;Photoelectric readings; their significance for dust control on collieries.&apos; G. H. J. Kitson (Member) and Y. J. F. Haven (Visitor). After Mr Kitson had presented his paper, both he and Mr Haven answered questions from the floor. The Chairman then thanked Mr G. H. J. Kitson for presenting the paper, and the meeting closed at 6.15 p.m.

By S. A. Ghoreishi-Madiseh, F. P. Hassani, H. Rafezi, H. R. Manouchehri, A. Shadic, A. P. Sasmito

Weakening rocks by taking advantage of microwave-induced microcracks is a promising solution for comminution processes. This paper investigates the effects of microwave treatment of the rock/or samples in single and multi-mode cavities. Based on the experimental results of using a 2.45 GHz microwave generator, the performance of different cavity setups and their impact on the energy effectiveness of the microwave irradiation was examined. Physical interpretations were drawn from multiple experiments with a relatively wide range of power rates and exposure times. Both basalt and kimberlite samples were used in experiments, and their results were systematically compared. For single-mode cavity tests, a microwave applicator waveguide antenna was placed at different distances from the samples to evaluate the effects of sample positioning on microwave heating, both numerically and experimentally. Eventually, cavity performance was assessed by using calorimetric test results, and strength decay was documented based on the spallation of the samples. It was found that the singlemode cavity setup has unique properties that can significantly improve the electromagnetic heating and therefore, strength degradation process. Keywords: Microwave, fragmentation, energy effectiveness, calorimetry, mine-to-mill

Jan 1, 2020

By J. Baklík, V. Rak, W. Kolarcík, Z. Franc

The paper deals with hydraulic transport of thin and dense slurries. Based on mathematical modelling of three-phase flow, dynamic properties of the systems for pumping of thin slurry are solved. Theoretical calculations were experimentally verified both at the testing hall and in real operation. For thin slurry (e.g. bauxite slurry), a three-chamber hydrohoist with float is used. Dense slurry (e.g. ash and water) is transported from the power plant to a deposit site by means of a three-chamber hydrohoist with sealed separator (piston).

Jan 1, 2007

By M. C. Bekker, T. Govindasamy

The potential benefits of implementing the Last Planner System (LPS) on mining infrastructure projects were explored through two case studies in the South African mining industry. The first part of the study involved measurement of the impact of LPS through earned value techniques on secondary project data. The second part sought to establish the lean construction success factors leading to improvements in construction performance. This was done by means of a research questionnaire distributed to the project owner’s teams, contracted parties, and the LPS facilitators. The results revealed a positive correlation between LPS application and planned percentage complete. However, the performance achieved during the LPS pilot was not sustained. The success factors and benefits considered most evident in the case study pilot differed among the three stakeholder groups. The findings are expected to guide construction stakeholders to better define performance measures and focus on factors required to make LPS implementation more effective in the South African mining sector.

Feb 12, 2024

By M. Khodadazadeh, K. G. van den Boogaart, T. Leißner, L. Tusa, J. Gutzmer, R. Gloaguen, M. Kern

Ore sorting is a technology that is increasingly used to process primary raw materials. Timeconsuming and expensive empirical state-of-the-art test work is carried out to assess whether the use of ore sorting for the enrichment of a particular ore makes technical and economic sense. With the innovative simulation-based approach presented here, it is possible to direct the selection of a suitable sensor based on quantitative mineralogical and textural data, thus avoiding much of the empirical studies. Required data can be collected quickly and cost-effectively using available methods of automated mineralogy. The obtained parameters such as mineral grain size distribution, modal mineralogy, mineral area and mineral density distribution have been utilised in this study to simulate the prospects of success of ore sorting, applying different types of sensors. Empirical tests with commercially available sensor systems have been conducted to experimentally validate the predictions of the simulations. The estimation of the target mineral grade can be further optimised by the use of machine learning algorithms for the integration of automated mineralogy data and sensor data. The approach can easily be adapted to other types of raw materials and thus has great potential to become a key technology for the optimisation of processing experiments. Keywords: Automated mineralogy, hyperspectral imaging, machine learning, ore sorting

Jan 1, 2020

By C. van der Merwe, R. Lumbule, J. Kgomo

"The mining industry in the Democratic Republic of Congo has seen a significant expansion in copper and cobalt production in recent years. The greater proportion of this expansion has arisen through processing of oxide ores. The design of metallurgical processes for these oxide ores is based on the conventional equipment and layout for processing of sulphide ores, and comprises milling followed by leaching, solvent extraction, and electrowinning. The physical characteristics of the oxide ores, however, provide the process design engineer with an opportunity to examine critically the principles on which equipment selection is based and to design processes better suited to these ores. In 2015, ERG Africa began a project to expand the leaching capacity of the Luita hydrometallurgical facility. A number of innovative changes to the conventional process design were included in the modified flow sheet, which were validated when the project reached design throughput in November 2017. Of these changes, the most novel presented an alternative approach to mitigate the impact of colloidal silica on the operation of the solvent extraction plant. Introduction ERG Africa operates the Luita hydrometallurgical facility located at Kakanda in the Democratic Republic of Congo (DRC), treating malachite and heterogenite minerals to recover copper as electrowon cathode and cobalt as a hydroxide precipitate. The process was originally conceived as a heap leach operation followed by direct electrowinning of copper, with solvent extraction (SX) and electrowinning (EW) of cobalt. In preparing the sized ore for the heap leach operations, the undersized ore fraction at a P80 of 625 µm was discharged to a fines storage facility for later processing. This fraction carried with it approximately 30% of the copper contained in the run-of-mine (ROM) ore feed, and an equivalent proportion of cobalt.In a subsequent development, the cobalt SX section was converted to a copper SX facility, the leached cobalt being recovered from a bleed stream from the copper heap leach circuit. The operating cost for the process as then installed placed this facility well in the fourth quartile of the industry cost curve. The initial Luita operation was established in 2010 at a time when metal prices were above long-term averages (copper above US$3.00 per pound; cobalt above US$20.00 per pound), and the drop in prices in 2015/2016 presented a major challenge. The London Metal Exchange (LME) copper price dropped below US$2.00 per pound, with cobalt dropping below US$10.00 per pound in Q1 2016. This set in motion a range of improvement initiatives for the Luita operation. Central to this was the installation of a tank leach circuit to process the discarded fines and a modified SX circuit to manage colloidal silica. The revised Luita circuit reached design capacity in November 2017 and has proven to be well suited to processing of the oxide ore feed. This process design challenges the boundaries of conventional thinking in the areas of leaching, solid/liquid separation, solution management, impurity management, and metal recovery, and is the subject of this paper."

Nov 1, 2018

The February General Meeting of the Branch was held in the St. Helena Club at 8.00 p.m. on the 10th February, 1971. Mr G. Y. Nisbet (Chairman, O.F.S. Branch) was in the chair. There were also present: Seven Fellows: Messrs. N. A. Honnet, C. J. Isaac, J. M&apos; Meyer, I. Thomas (Committee Members), J. Lorenzen, S. L. S. Swart and D. Waterman. Six Members: Messrs. R. Campbell, D. J. Couperthwaite, R. Cross, A. H. Edwards, C. G. J. Vermeulen and G. J. C. Young. Two Graduates: Messrs. J. McLuskie and M. H. Smith. Six Associates: Messrs. J. Dean, W. F. de Lange, J. S. Freer, A. Hooper, A. Paschalides and L. Vorster. One Student: Mr D. J. Hammond and nine visitors, a total attendance of thirty-two. Minutes As the minutes of the General Meeting held on the 17th November, 1970 had not yet been published in the Journal, the Chairman moved that the adoption and discussion thereof be deferred to the next General Meeting. This motion was adopted unanimously. Office-bearers The Chairman informed the meeting that this branch had received the resignation of Mr J. N. Saunders. Following his resignation the Committee elected the following office-bearers: Chairman - Mr G. Y. Nisbet Vice Chairman - Mr J. M. Meyer The Chairman also announced that Messrs. J. M. Meyer and G. J. C. Young had been co-opted onto the Committee. General Members were advised that arrangements had been made for the Cookhouse Tunnel visit towards the end of March. Talk by J. Freer The Chairman called on Mr J. Freer to deliver his talk on "Uranium Extraction, Processing and Conversion for Fuel Element Manufacture". The presentation of this talk, illustrated by sketches, proved very interesting and entertaining and was received with applause from all present. Mr I. Thomas proposed a vote of thanks to Mr Freer on behalf of all members of the O.F.S. Branch. After thanking Mr Freer for his talk and all present for their attendance, the Chairman declared the meeting closed at 9.30 p.m.

By R. Koen, H. Visser, A. Roodt

"SynopsisThe tetraethylammonium salt of the mono-anionic coordination compound mer-oxidotrichlorido(thenoyltrifluoroacetylacetonato- K2O,O’)niobate(V) (NEt4)[NbOCl3](ttfa)], has been prepared under aerobic conditions and characterized by single-crystal X-ray diffraction. (NEt4)[NbOCl3](ttfa)] crystallized in the monoclinic P21/c space group, with a = 11.483 (5), b = 12.563 (5), c = 17.110(5) Å, and ß = 100.838 (5)o. The complex structure exists in a 50.0% (NbA) : 50.0% (NbB) positional disorder ratio.IntroductionComplexes containing organometallic type ß- diketone ligands with O,O and O,N donor atoms are used widely in coordination chemistry and have applications in catalysis, radiopharmaceuticals, etc. (Schutte et al., 2011; Roodt, Visser and Brink, 2011; Brink et al., 2010; Otto et al., 1998). These ligand systems are very useful because of their highly coordinative nature, high solubility, and also due to their ability to be functionalized with various substituents on the carbonyl carbon atoms (Schutte et al., 2011).Only a small number of ß-diketonate ligands have successfully been coordinated to a Nb(V) metal centre, with only a select few being characterized by X-ray crystallography (Viljoen, 2009; Bullen, Mason and Pauling, 1965; Preuss, Lamding and Mueller-Becker, 1994; Funk, 1934; Davies, Leedlam and Jones, 1999; Allen, 2002. The synthesis and crystal structure determination at room temperature of mer-oxidotrichlorido (thenoyltrifluoroacetylacetonato- k2O,O’)niobate(V) {(NEt4)[NbOCl3(ttfa)]} was first reported by Daran et al. in 1979. Accordingly, for this current investigation, (NEt4)[NbOCl3(ttfa)] was re-evaluated at 100 K to determine if the structural features might change with temperature."

Jan 1, 2015