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By Wenhua Wan, Jan M. Mutmansky

Many concerns have been expressed worldwide regarding the use of diesel equipment in underground mines due to the potential health risks associated with diesel particulate matter (DPM). In assessing the risk to the health of miners and designing control strategies for DPM, it is important to know the concentration of DPM in the working areas of a mine. In some mines, significant stratification occurs due to the characteristics of the diesel exhaust, affecting exposure and the ability to measure DPM concentrations accurately. This study outlines some of the concentration profile data obtained during sampling at three mines where diesels were employed. Mine #1 (a gold mine) employed large openings in which a diesel-powered roof bolter was used. Mines #2 and #3 are both room-and-pillar operations with varying conditions. Mine #2 is an experimental mine where two stationary diesels were utilized for sampling purposes, while Mine #3 is a traditional evaporite operation using two mobile diesel vehicles for section haulage. These field studies indicated that some level of stratification occurred in all the mines, but the stratification was not as pronounced in the case of Mine #2 due to the complex pattern of exhaust emissions generated by the vehicles. The stratification seemed to depend on the distance from the vehicle, the mine air velocity, whether the vehicles were moving or stationary, and whether the exhaust was diluted by equipment design features. The concentration of DPM was generally higher at samplers located near the roof and lower at samplers located near the floor. However, this was not found in all cases. This paper provides conclusions on how knowledge of stratification patterns can be utilized in sampling and control of DPM in mine atmospheres.

Jan 1, 1997

By K. Wangerud, B. S. Caruso

A water-balance model with deterministic and stochastic components was developed and used for the Gilt Edge Mine Superfund Site in South Dakota. The model was developed to evaluate the risks of contaminated runoff discharging to surface waters based on assumed water treatment plant (WTP) rates, for different remedial alternatives. The objectives of the modeling were to use a stochastic approach for the analysis of precipitation based on historic records and to make a probabilistic estimation of annual and monthly runoff from disturbed/mining activity areas that now require, or will need, treatment at the WTP, water storage and changes in a major pit, and risk of contaminated water bypass of the WTP to a downstream drainage. Subareas/source areas generating contaminated runoff requiring treatment were delineated. A simple water-balance model was used based on precipitation inputs and evapotranspiration and groundwater losses. Annual and monthly precipitation records for Lead, South Dakota, were used to estimate precipitation at the mine site. A lognormal distribution was estimated for monthly precipitation. The stochastic software package/ Excel add-in "@Risk" was used to generate random monthly precipitation values using a Monte Carlo method based on the distributions. The average annual and monthly distribution of pan and lake evaporation and of groundwater losses were also estimated for the site. Stochastic outputs from the model for the end of each month and year included contaminated runoff requiring treatment, water storage in mine pits and the risk of WTP bypass given different assumed WTP rates. The probability of the time required to dewater the pits was also modeled.

Jan 1, 2003

By N. Ohmura, H. Saiki, T. Nagaoka

A microbiological flotation system that facilitates the removal of pyritic sulfurfrom coal is reported. The chemoautotrophic bacterium Thiobacillus ferrooxidans is utilized as a pyrite-selective biological surfactant that augments the flotation-mediated rejection of pyritic sulfur. The bacteria were produced by continuous cultivation in 50-L tanks, where it was possible to produce 3.8 x 1012 cells/day when the dilution rate was optimal and the pH was 1.6, a condition that prevented ferric precipitation. Prior to flotation, the bacteria were mixed with coal, which allowed cells to selectively adhere to the pyrite. The adherence of bacteria made the pyrite surfaces more hydrophilic, which facilitated separation by increasing the tendency of pyrite to sink, while the hydrophobic coal floated. When a synthetic coal/pyrite mixture (10.1 % sulfur) was subjected to microbial flotation, the level of sulfur rejection was stable during the entire period of operation (i.e., one hour). In the absence of bacteria, flotation reduced the sulfur content of a coal/pyrite mixture to within the range of 6.7% to 7.4%, with the combustible recoveries ranging from 93.9% to 99.0%. In the presence of bacteria, the sulfur content of cleaned coal was in the range of 1.3% to 1.4%, with the combustible recoveries ranging from 80.8% to 86.3%. Bacterial activity accounted for 57% of the total sulfur rejected through flotation. The desulfurization capacity of the system was further confirmed by testing it with run-of-mine coal. The pyritic sulfur content was reduced from 2.9% in the feed coal to around 1.2% in the froth product, while 80% of the combustible recovery was retained. Microbial flotation removed 60% of the pyritic sulfur from the feed. These findings demonstrated that micro¬bial flotation could be utilized for the removal of pyritic sulfur from coal in a semicontinuous system.

Jan 1, 2000

By Christopher J. Hall

It has been known for a long time that summing pressure drops and rises due to friction, shock, fans and natural ventilation is incorrect. In fact, lost works and works should be summed. In spite of this, the traditional method of finding a fan/system operating position has been the H/Q Curve. This paper presents (lost) work/m curves, progressing from a single fan moved around the system to include natural ventilation work, and fans in a series, parallel and series/parallel. The solutions obtained graphically are substantiated by dry air thermodynamic solutions, and the traditional solutions are shown to be in error. This method of solving problems is particularly useful when moving fans around the system, and essential in series/parallel and series situations with substantially different fan densities. The dry air analysis is employed because of its simplicity. Real air, with evaporation and condensation, will react somewhat differently, and one should use real densities (i.e.[l + w +w]/va ) when using this method. One source of error when applying this method to real air, although probably not major, will be investigated in a subsequent paper. Friction and shock losses are proportional to the square of the mass rate of flow, leading to the typical parabolic system curve. However, the unbalanced water stuff potential energy term, on a unit mass basis, is substantially independent of the mass rate of flow. It is possible that this could be handled as a negative natural ventilation work.

Jan 1, 1987

By Rossen Halatchev

The production sequence optimization of open pit mine is a procedure that reflects the exploitation conditions over life of mine. These conditions are determined by the geological characteristics of the deposit, requirements of the mining and processing technologies and economic parameters of the exploitation. From a technological point of view the production sequence optimization deals with two aspects - spatial and time. Each of them plays a tremendously important role in searching for the optimum solution of the problem. This paper treats the time aspect of the production sequence optimization. This aspect is revealed in the context of the problem of the working zone formation of the open pit mine in time. The problem formulation places an accent on the determination of the theoretically possible time distribution of the waste and ore quantities of each bench of the open pit mine. A mathematical solution to the problem has been developed based on combinatorial analysis. The solution provides a multi-variant investigation of the production sequencing with the use of an optimization model developed as a linear programming formulation. The model objective function uses the Net Present Value as a criterion for assessing the effectiveness of production sequencing. A case study is provided for the conditions of Assarel copper open pit mine (Bulgaria) to illustrate the applicability of the approach. The results obtained reveal the complex nature of the variation of the Net Present Value as a function of the mining factor.

Jan 1, 2002

By G. Vik, P. Chryssanthakis, S. C. Bandis, L. Haruik, N. Barton, M. Christianson, A. Makurat

The large jointed chalk reservoir situated at 3 km depth in the North sea's Ekofisk field is undergoing major compaction after nearly 15 year of oil and gas production. Approximately 150 km 3 of the overlying sediments, mostly shales, are involved in the subsidence. A maximum central subsidence of nearly 3 meters, and a maximum present rate of 45 cm per year has set in motion numerous studies of the phenomenon. Non-linear finite element (FEM) and non- linear distict element (DEM) analyses of the compaction and large scale subsidence were performed. Consistent differences between the continuum and discontinuum analyses were noted. In the latter, slip on hypothetical bedding planes and sub- vertical or vertical faults was allowed, which possibly gives a more realistic simulation of the real processes of subsidence in such a large body of rock. Laboratory studies of the reservoir joints included roughness measurement, JRC and JCS characterization, direct shear tests while saturated in heated Ekofisk oil, and coupled closure-shear-flow tests with heated oil followed by heated sea water. Discontinuum modelling using Cundall's UDEC was performed on representative jointed assemblies (two sets of steeply dipping conjugate joints) to investigate the effect of a major reduction of pore pressure within the deformable matrix and along each joint. It was found that the large shrinkage deformation of the matrix allowed joint shearing to occur despite the constraint of uniaxial strain. Relative mass bulking due to small but widely distributed joint shear possibly explains the observed maintenance of excellent productivity despite large vertical strains in the reservoir.

Jan 1, 1986

By Susan T. Bagley, Linda D. Gratz, Kirby J. Baumgard

The extensive use of heavy-duty diesel engines in underground mines has raised concerns about the potential adverse health effects to miners exposed to diesel particulate matter (DPM) which contains mutagenic and carcinogenic organic compounds. The purpose of this study was to compare the levels of DPM, biological activity, and polynuclear aromatic hydrocarbons (PAH) attributable to diesel engines in underground coal mines and similar data collected in engine laboratory facilities to assess whether laboratory data could be used to predict in-mine levels of diesel emissions. Mean in-mine DPM and SOF concentrations varied from 0.90 to 1.9 mg/m3 and 0.08 to 0.40 mg/m3, respectively. DPM-associated mutagenicity (mean) levels at two of the mines varied from 400 to 970 revertants/m3. Concentations of three PAH differed by up to four-fold between two of the mines, largely reflecting differences in DPM and SOF levels. The laboratory raw exhaust data were divided by 100 to obtain expected or predicted values for in-mine concentrations. The predicted DPM, SOF, mutagenicity, and PAH values based on laboratory samples were not significantly different from many of the in-mine values. Using a potential in-mine dilution ratio range of 20 to 200:1, virtually all in-mine data fell within the predicted range. Therefore, an estimate of in-mine concentrations can be determined by evaluating laboratory data. This will allow for extrapolations from laboratory tests with particulate emission control devices to assess potential health-related benefits due to their in-mine use.

Jan 1, 1991

By R. F. Hüttl

The restoration of surface mining landscapes requires the (re)creation of ecosystems. In Lusatia (eastern Germany), large-scale open-cast lignite mining operations generated spoil dumps widely consisting of acidified, phytotoxic substrates. Amelioration and rehabilitation measures have been developed and applied to these substrates since the 1950s. However, it is still not clear whether these approaches are sustainable. This paper reports on collaborative research work into the ecological potential of forest ecosystem development on typical minesites in the Lusatian lignite district. At first sight, pine stands on minesites along a chronosequence comprising about 35 years did not show differences when compared with stands on non-mined sites of the general region. Furthermore, with some modification, conceptual models for flora and fauna succession in forest stands on non-mined sites seem to be applicable, at least for the early stages of forest ecosystem development. For example, soil organism abundance and activity at minesites had already reached levels typical of non-mined sites after about 20-30 years. In contrast, mine soils are very different from non-mined soils of the test region. Chemically, mine soil development is dominated by processes originating from pyrite oxidation. Geogenic, i.e. lignitic, soil organic carbon was shown to substitute for some functions of pedogenic soil organic matter. Rooting was hampered but not completely impeded in strongly acidified soil compartments. Roots and mycorrhizae are apparently able to make use of the characteristic heterogeneity of young mine soils. Considering these recent results and the knowledge accumulated during more than 30 years of research on minesite rehabilitation internationally, it can be stated that minesite restoration might be used as an ideal case study for forest ecosystem development starting at "point zero" on "terra nova".

Jan 1, 2002

By Robert Seal, James J. Rytuba, Michael P. Hunerlach, Roger Ashley, Dean Enderlin

Cessation of open pit mining in 1996 at the McLaughlin hot-spring type gold deposit has resulted in the development of two pit lakes that will be managed as permanent lakes with a total storage capacity of 10,000 acre-feet. The south pit lake developed from alkaline ground water infiltration and had an initial pH of 7.2. It contained high concentrations of boron and chloride, indicating that it consisted of a mix of meteoric and evolved connate waters. Numerous carbon dioxide gas vents were present initially in the shallow south pit lake, but as the pit lake increased in depth, gas venting ceased and carbon dioxide is retained in the lower layer of the chemically stratified lake. Continued increase of dissolved carbon dioxide in the lower layer increases the potential for a limnic eruption. A chemocliie occurs at a depth of 47 m. The upper layer of the lake has lower pH, temperature, and conductivity than the lower layer. Effluent from ore and waste rock piles directed into the south pit lake has contributed to high levels of antimony, arsenic, cobalt, copper, mercury, nickel, and zinc. Iron oxyhydroxide is abundant in mine effluent that enters the pit lake and adsorption onto this phase has lowered the arsenic and antimony concentrations. The north pit lake formed primarily from winter surface runoff. The acidic water, pH 4.56, initially had high concentrations of cobalt, mercury, and nickel derived from weathering products of pyritized serpentinite and shales. Buffering by wall rocks has established a slightly alkaline pH of 7.62. The concentrations of trace metals in the north pit lake have substantially decreased due to continued dilution of the lake by surface runoff and remediation of parts of the pit walls that have been covered by backfill.

Jan 1, 2000

By Wayne Charlie, Joseph P. Martin

INTRODUCTION Typically, uranium mills produce slurred tailings which are transported by pipeline to a tailings impoundment. The slurried tailings contain about 250 solids (75% liquids) by volume and, depending on the milling process, have a high or low ph. Despite decanting water from the tailings pond and losses by evaporation and seepage, Staub (1978) estimates that for lined impoundments over half of the input water is stored in the tailings. As long as the impounded tailings remain in a loose and saturated state, potential hazards exist and include potential for short and long-term seepage from the impoundments and the potential for large scale release and movement of liquified tailings should an embankment fail. The breach of an earthen dam on July 16, 1979 at Church Rock, New Mexico, and the subsequent release of 100 million gallons of water and liquified uranium tailings, underlines the potential hazard. Loose saturated tailings also have a high potential of liquefaction during earthquakes (Charlie and Wardwell, 1979; Martin, Finn and Seed, 1978; and Mittal and Morgenstern, 1976). If the tailings could be dewatered, the liner's integrity would become less critical, longterm seepage and settlements would be greatly reduced. In addition, the potential for tailings liquefaction from an embankment failure or earthquake would be greatly reduced. This paper reviews the concept, criteria, and design of various proposed interior drainage systems to dewater the tailings after deposition. ADVANTAGES OF INTERIOR DRAINAGE The primary purpose of interior drainage systems for uranium mill tailings impoundments is dewatering the tailings as rapidly and as thoroughly as possible. The expected benefits of this new technology are: • Reduction of potential seepage losses by decreasing the hydraulic head. • Reduce earthquake liquefaction potential of the tailings by inducing non-saturated conditions and/or lowering the water pressure. • Reduce the potential for large-scale release and movement of tailings should an embankment fail. • Stabilize the tailings to permit early reclamation. • Recovery and potential recycling of tailings liquid. • Inhibiting long-term seepage out of the impoundment by inducing nonsaturated conditions to provide capillary suction in the tailings.

Jan 1, 1980

By J. Siege1, R. S. Popielak

A computer model was used to simulate the effect of leakage through confining beds on a hypothetical in situ leach operation in an aquifer with a thin mineralized section. The simulations were used to assess economic and potential environmental implications of leakage on an in situ leach operation. Four scenarios were modeled - three representing cases with different degrees of confinement, and the fourth representing a stratified ore zone under a low degree of confinement. The model simulated the travel path and travel time of lixiviant given the hydraulic conditions prescribed in each scenario. The results show that the travel path and travel times vary by about 10% for confinement ranging from nearly impermeable (essentially no leakage) to an extremely low level (thin confinement with a permeability about equal to that of the aquifer) for isotropic aquifer conditions. The aquifer thickness contacted by the lixiviant varied from 85% to 90%. Horizontally, 55% to 60% of the aquifer was contacted. The flow paths in the stratified aquifer were reduced in the vertical direction and expanded horizontally. Forty- five percent of the aquifer thickness was contacted vertically with 88% contacted horizontally. Break- through time for lixiviant traveling at mid-depth of the aquifer increased two times when the leakage was increased from nearly zero to a value representative of thin and highly permeable confinement. Leakage affects the economics of in situ mining by (1) increasing the time required to leach out the ore, and (2) increasing the thickness of the ore zone aquifer to be restored. The potential for environmental impacts appears to be minor. In all four simulations, the lixiviant did not contact the confining strata. Restoration would be limited to cleanup of the ore zone aquifer within the thickness contacted by lixiviant and within the radius of the lixiviant that traveled farthest away from the production cell.

Jan 1, 1988

By Scott G. Britton

In the real world of coal mining, the bottom line for almost every support project decision is economic (i.e., what is it going to cost?). Up to this point, I have discussed the methods to improve the performance of typical support projects by better installation, materials, and techniques, thus lowering the impact of the bottom line cost. In this chapter, 1 shall explore what costs are relevant in mining construction, and how these costs are developed. The chapter centers around two major discussions: (I) developing cost accounting techniques, and (2) cost-estimating procedures for support construction. Each focuses on the fundamentals of practical cost considerations necessary for decisions on construction projects underground. Since cost accounting, economics, and investment planning are all subjects which warrant complete discussions on their own, this chapter will focus on distilling the important concepts required by a planning engineer into an easily understandable presentation.

Jan 1, 1983

By Sriram Padmanabhan, Jan M. Mutmansky

The subject of quartz occurrences in respirable coal mine dusts has been of increasing concern in recent years. The primary impetus for this concern has been provided by better measurement technology that has detected an increased number of mines with high quartz content in their respirable dusts. This paper presents the results of statistical analyses of quartz levels in multi-stage impactor samples from eighteen different coal mining sections located in Pennsylvania, West Virginia, Ohio, Illinois, Kentucky, Colorado and Utah. The quartz and kaolinite determinations were then determined by combining impactor stage loadings to provide larger dust masses and applying the infrared spectrometry procedure outlined in Bureau of Mines/MSHA Method P7. The results will be presented using two categories of data collected during two separate phases of the research: (1) quartz concentration data from mines where quartz was known to be present in relatively high concentrations, and (2) quartz concentration data from mines chosen at random. The aspects of the occurrence of quartz in coal mine airborne dusts that will be reported include the size dependence of the quartz content, quartz variations with location in the mining section, and variations due to mining region. The results of the study show a strong pattern of size dependence of the quartz content in mines for which high quartz concentrations exist. A similar, though less pronounced, pattern exists in mines chosen at random. Quartz levels appear to have a varying relationship to section location and strong geographical patterns do not appear to exist in the data collected. Kaolinite content was found to be similar to that of quartz with patterns that are somewhat more consistent.

Jan 1, 1989

By Jamal Rostami, Wei Hu

Efficient performance of EPB TBMs in clayey ground is primarily dominated by the flow capability of the excavated muck in the cutterhead and screw conveyor. Currently, Consistency Index approach is used to evaluate clay clogging potential, but it does not include the effects of surcharge pressure on clay behavior. In this paper, a macro-scale soil rheometer is introduced to assess the clogging potential under various water content and surcharge loading conditions. The results show that, in addition to water content, surcharge pressure has clear impact on clay clogging too. In practice, Consistency Index chart can be refined to incorporate the impact of face pressure to better simulate the EPB tunneling conditions.

Jun 13, 2021

By Jon P. Stone

The Automated Minerals Information System (AMIS) is an integrated data base system being developed to support the Bureau of Mines minerals information collection and analysis activities. The system facilitates cross-referencing and integration of domestic and foreign information from a variety of sources. The AMIS provides a central source of minerals information that is versatile and responsive to the needs of problem and policy analysts as well as supporting the needs of those involved in data collection and interpretation. As the AMIS becomes fully implemented, it will become an important tool in forecasting and assessing the impact of policy decisions that affect the supply and demand for minerals. The Bureau of Mines has long been the Federal Government's principal source of worldwide information on non-fuel minerals. Emphasis is placed on the analysis of mineral problems and policies as they affect the world's nonfuel mineral resources. To facilitate timely and accurate analysis, comprehensive data on 87 commodities are collected by various Bureau programs. Minerals information is made available through a number of periodic publications including the annual Minerals Yearbook and monthly Mineral Industry Surveys. These data collection and analysis activities have traditionally been supported by over 200 separate information processing systems. The Bureau of Mines has begun to implement a broad information strategy to provide a better response to the mineral problems and issues of the 1980's. The cornerstone of the Bureau of Mines information strategy is the development of the Automated Minerals Information System. When fully operational, we believe that the AMIS will provide the Bureau of Mines with the most comprehensive source of minerals information available anywhere in the world.

Jan 1, 1982

By Leo Misagi

THE ROLE OF MANAGEMENT IN PLANT SAFETY Safe Production In plant management, safe production is an ideal. It becomes reality when: 1. Plant employees work in healthful and safe conditions. 2. Plant safety is in harmony with productivity. 3. Worker absenteeism and turnover are low-the work force is stable. Plant management must apply its talents, skills, and resources to build and maintain the foundations of safe production on a system of policies, procedures, and attitudes. It must do so by marshaling all managerial functions - staffing, direction, control, innovation, and representation-toward that goal. Ideally, a plant safety program is proactive. Management should plan and implement safety activities that are aimed at prevention. Past accidents-accomplished facts-should not be the sole guide of future actions. In other words, positive preventive measures, not the fewness of accidents are the criteria for safety production. An ideal safety program is one which is cost effective. Management should view plant safety as part of a broader program-loss control. Loss control includes prevention of fires and other accidents, unhealthful conditions, and occurrences that cause bodily injury, illness, property loss, or damage. Management evaluates the employees' productivity and safety. An effective training program aimed at loss control is the hallmark of safe production. Ideally, both labor and management should be well versed in safety. They believe in the premise that work-related injury and illness, as well as property loss and damage from fire and other accidents, are manageable and preventable. Such belief prompts them to learn more about the work process and potential hazards associated with each job. They also learn how to expect and prevent fues and other accidents, and respond to emergencies at the plant. Plant management determines which individuals or groups of employees are accountable for the following functions:

Jan 1, 1991

By Charles U. Keranen

The Tilden Mine is an iron ore mining, processing and pelletizing facility located on the Marquette Iron Range in Michigan's Upper Peninsula. It has a designed capacity to produce 8 million long tons of pellets annually from 21 million long tons of crude. It is a partnership owned by The Cleveland-Cliffs Iron Company, Algoma Steel Corporation, LTV Steel Corporation, the Steel Company of Canada, Wheeling Pitts- burgh Steel Corporation and the Sharon Steel Corporation. Cleveland- Cliffs manages and operates the Tilden. The crude ore averages 35% iron and is primarily non-magnetic iron oxide and silica. The major ore mineral is martite. Hematite, earthy hematite, goethite and magnetite are also present. The principal gangue mineral is chert. The ore grains are mostly in the 10 to 25 micron size range which necessitates very fine grinding for liberation. The concentrating process is the most complex one used in the iron ore industry. The unique technology for Tilden was developed in the mid and late 60's. The design and construction occurred in the early 70's and operation of the first phase which was of 4 MLTPY capacity began in October. 1974. Expansion of the facility to the current 8 MLTPY capacity was completed in 1979. Chemicals are the key to the beneficiation process at the Tilden Mine. The flowsheet utilizes selective flocculation - desliming, cationic silica flotation and concentrate dewatering by thickening and filtering. Nine different process chemcals are used. The control of the reagent feed systems is highly auto- mated. The entire concentrator is operated from a central control room. The concentrator flow diagram is presented in figure 1. The plant consists of 12 primary autogenous grinding lines, a common crushing circuit to handle an intermediate product within the primary grinding section, 24 pebble mill lines with cyclones and deslime thickeners, 12 flotation lines, 4 concentrate thickeners and slurry tanks, 8 lines of filters with six machines per line, and 2 tailings thickeners. A pumping system was installed in 1980 to permit the direct return of tailings thickener overflow water back to the reuse water pumphouse.

Jan 1, 1986

By M. J. Friedel

The scale-dependent hydraulic properties in a fractured porphyry copper oxide deposit are investigated for relevance to In Situ Leach Mining (ISLM) design. In most well field designs, mine operators assume that hydraulic properties represent a continuous spatial function, or continuum. The problem, however, is that the representative elemental volume, the volume over which hydraulic properties are described as a continuum, is a domain (if it exists) that occurs between end members representing varying degrees of heterogeneity. At the Cyprus Casa Grande mine, transmissivity fluctuations are spatially correlated. This suggests that, at the scale of ISLM, the hydraulic process is heterogeneous, and a typical continuum representation is inappropriate for design. Alternatively, a conditional stochastic approach using the Simulated Annealing (SA) technique is deemed useful for the imaging of heterogeneous hydraulic properties. Specifically, SA preserves transmissivity extremes and spatial complexity, both necessary for accurate conditioning of a flow simulator. Also, the stochastic continuum approach provides an avenue whereby uncertainty (or risk) may be addressed. Currently, the SA weaknesses are that it is computationally time consuming and that uncertainty may increase when simulating under conditions of statistical isotropy. Recognizing that ISLM exerts a dynamic influence on hydraulic properties with time, the mine design should be re-evaluated at intervals throughout the evolution of the leaching process.

Jan 1, 1994

By James Watson Baxter

Fluxes are used to promote pyrometallurgical processes that rely on adhesion (soldering or brazing) or fusion (gas and arc welding) to join metallic surfaces. In the adhesive processes, the metal surfaces to be joined are not melted; the join is formed using a filler metal with lower melting point than the base metal. Fusion welding involves use of heat in excess of the melting point of the base metal. The fused joint may be achieved either by simply fusing together metal surfaces brought in contact with each other or by introducing additional molten metal of similar composition to form a fused joint. ADHESIVE PROCESSES--SOLDERING AND BRAZING In order for molten filler metal, solder or braze, to spread in a manner that creates a successful join; the work surfaces on the base metal must be thoroughly cleansed. Fluxes remove stubborn oxide films and other surface contaminants, promote wetting of the work surfaces, add fluidity to the solder or braze, and enhance workability and ease of spreading. Brazing processes involve higher temperatures than those reached in soldering. Brazing fluxes, which must remain active and effective at the higher temperatures, differ from those employed in soldering. Some common fluxes used in adhesive processes are rosin for soldering tin and electrical connections, hydrochloric acid for use in soldering galvanized iron and other zinc surfaces, and borax for brazing. Soldering and brazing are similar processes, the primary difference being the temperature at which the joining operation is carried out. Soldered joints, produced with low-melting-point fillers (solders) that melt and flow at temperature less that 450°C (Althouse et al., 1988) can sustain loads of 1 to 1.7 MPa for extended periods of time (Anon., 1966). Brazing involves the use of filler materials with melting points commonly above 500°C and generally provides stronger joints than those obtained with solder. Both processes require local application of heat to melt and spread the filler so that the molten filler can wet (adhere to) the base metals by alloying and diffusion. Soldering Soldering is a means of joining metals by adhesion using a metallic bonding alloy as the filler, commonly a mixture of lead and tin. However, the adhesion of solder depends more on its ability to be keyed into minute surface irregularities than on alloying. The most familiar application is to provide and secure electrical connections. Soft solders can range from 1 to 70% tin with the remainder mostly lead. However, for general-purpose, soft-solder work, the alloy is commonly 50% lead-50% tin. Higher lead contents provide a wider range in the melting temperature and, for this reason, a 60% lead-40% tin alloy, which yields a mushy mixture, is used for wiped joints in lead sheet and pipe work. Conversely, 40% lead-60% tin alloys are used in soldering tin and other low- melting-point materials for which a narrower range of melting temperature is required. There are numerous other solder compositions such as tin-silver, 95% tin-5% silver and antimony-tin, 95% tin and 5% antimony (Carlin, Jr., 1992). Heat needed to melt and spread the solders is commonly provided by electrically heated, copper-tipped soldering irons or by means of torches; the solder is applied by hand, usually face-fed by means of wire. For wiped joints in plumbing and lead-cable splicing, the solder is manipulated with cloth pads. The molten solder wets the joint surfaces and is drawn, by surface tension, into minute fissures and capillary openings. Other applications involve use of induction heaters and furnaces with pre-shaped solder appropriately placed prior to fluxing and heating. In some processes, the joints are immersed in molten solder. Constituents and Role of Soldering Fluxes: Soldering fluxes generally fall into one of three categories: highly corrosive fluxes, intermediate fluxes, and noncorrosive fluxes. These same categories are sometimes designated inorganic, organic and rosin-based respectively (Althouse et al., 1988). Common constituents of each group are discussed briefly below. Corrosive Fluxes (Inorganic). Work with aluminum, magnesium, stainless steel, high alloy steel, aluminum bronzes, and silicon bronzes is carried out at temperatures in the upper portion of the range for solder operations. Soldering these materials requires use of highly active, corrosive fluxes to remove and prevent the formation of the especially stubborn, hard, oxide films that form on these materials upon exposure to the atmosphere. The corrosive fluxes consist of inorganic acids and salts that are applied either as pastes or dry. They are active at elevated temperatures and, since they remain active after the soldering is completed, must be completely removed. The main constituent of most corrosive fluxes is zinc chloride with a melting temperature well above the solidus temperature of most commercial tin-lead solders. It is made by the action of hydrochloric acid on zinc. When zinc chloride is used alone, un- melted particles of this corrosive salt get caught up in the joint and weaken it. For this reason, other inorganic salts such as ammonium chloride (NH4Cl) or sodium chloride (NaCl) may be added to lower the melting temperature. A mixture of zinc chloride and ammonium chloride is very effective because the excellent oxide reducing properties of ammonium chloride and the protective action of the molten zinc chloride combine to produce a fluxing action superior to that achieved when either is used alone. In addition to zinc chloride, ammonium chloride, and sodium chloride; common con-

Jan 1, 1994

By Richard P. Killmeyer

In 1985 the Pittsburgh Energy Technology Center (PETC) of the U.S. Department of Energy (DOE) conducted a study to evaluate the emerging selective agglomeration processes (Killmeyer, 1985). This paper covers a recent similar study evaluating an associated technology, the emerging advanced froth flotation processes. This study has goals similar to those of the 1985 study: to evaluate the emerging froth flotation technologies collectively and determine how far they have progressed in their ability to clean ultrafine coal, and to assess the differences among the participants. The major concern again in this study was not the level of development, nor the economics of each individual process but only the current technical performance.

Jan 1, 1989