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By B. J. Arnold, F. F. Aplan

Prior laboratory work has demonstrated that much of the fine ash forming minerals entering a flotation froth are there as a result of water carryover- from the bulk contents of the flotation cell (Arnold and Aplan, 1986a). Using a bank of four 8.5 m3 (300 cu ft) Wemco flotation cells cleaning a well-liberated Lower Kittanning seam coal, test results show that the sulfur and ash content of the froth is directly related to the water content of the froth (or inversely related to the percent solids in the froth). Reagent changes that result in a watery froth produce a higher ash content in the froth. A direct comparison of laboratory and plant results show that the standard laboratory flotation test produces a product higher in sulfur and ash than that produced in the plant. Caution should be exercised when extrapolating laboratory test results to the plant situation. A method of estimating coal flotation product quality in the plant based on laboratory tests is given.

Jan 1, 1991

By I. Iwasaki, X. Cheng

A series of batch flotation tests was performed on chalcopyrite-quartzite, on pyrrhotite-quartzite and on chalcopyrite-pyrrhotite-quartzite mixtures. Pulp potential measurements in the flotation tests with single sulfide minerals indicated that each sulfide mineral had its own optimal potential range for flotation. When these results were used to select the potential ranges for the separation of the two minerals from their mixture, their flotation responses changed, and the selectivity of separation was adversely affected. A possible mechanism involving surface alteration through galvanic interaction is discussed, and a method to improve the selectivity of flotation separation is proposed.

Jan 1, 1993

By J. D. Miller, P. L. Sibrell

The nature of surface sites for the adsorption of gold from alkaline cyanide solutions has been investigated using samples of synthetic, highly-oriented pyrolytic graphite (HOPG). This HOPG material offers an idealized graphite structure enabling the independent study of the graphitic basal-plane sites and the edges, or defect sites, of the graphitic planes. Radiochemical and X-ray photoelectron spectroscopic experiments independently demonstrated that gold adsorption was much higher on the edges (defects) of the graphite planes than on the planes themselves. These results suggest that site-specific adsorption is prevalent in the adsorption of gold by graphitic carbons (including activated carbon, carbon black and graphite) and that most of the favored sites are at edge defects in the graphite crystal structure.

Jan 1, 1993

By C. D. Harrison, G. S. Stallard

The 199O Clean Air Act Amendments specify national objectives for reducing sulfur dioxide emissions from coal fired power plants. System-wide reductions can be achieved by combining various emissions control technologies and allowances, or compliance credits, that can be purchased, sold or traded. As part of the Coal Quality Expert development project funded by the US Department of Energy and the Electric Power Research Institute (EPRI), Black & Veatch has developed an interactive computer tool, the Acid Rain Advisor (ARA). Through this program, integrated, system-wide compliance plans are generated by comparing the costs and emissions reduction benefits of emissions allowances and various SO2-control technologies (coal cleaning, fuel switching, scrubber retrofits, etc.)

Jan 1, 1993

By R. W. Seedsman

Mandalong Mine was originally planned to operate with panel widths of 250 m and a predicted surface subsidence in excess of 3 m. The consent conditions applied by the NSW government on this mine plan were very tight and, following a change in ownership, were considered by the new operator to present a number of unacceptable business risks An acceptable risk profile for the mine layout restricted surface deformations to less than 500 mm vertical subsidence, less than 7 mm/m tilt, and less than 5 mm/m strain. Empirical subsidence prediction methods indicated that it would be necessary to reduce extraction panel widths of 80 m - an uneconomic option. The application of a number of rock mechanics concepts identified that the local overburden geology could be exploited such that panel widths of up to 175 m could be possible. The 125 m width was selected as a low-risk introduction of this new subsidence prediction method. The extraction of the first 2 longwall panels has demonstrated the validity of the prediction subsidence method and has provided the opportunity to refine the selection of key input parameters. The impact of mining through a zone of thrust faults was successfully predicted. The mine is now planning the introduction of 160 m wide panels, and will review the associated subsidence impacts prior to any further increases in width.

Jan 1, 2006

By R. W. Barbaro, R. V. Ramani

Generally, production planning is concerned with the best use of fixed resources to determine a production schedule for one or more production units supplying one or more markets. Production scheduling determines when each production unit will be used and its production level. However, the production scheduling problems are intimately associated with the location of existing or new production units and processing facilities. Normally, mine location allows only a limited choice; processing plant types and locations are considerably more flexible. This paper presents a generalized multiperiod MIP model as an aid in determining the mine production schedule and the processing plant types and location to satisfy multiple markets. A brief description of MIP and how it has been applied in the mineral and other industries is discussed. A complete description of the model with an application to a coal preparation plant system is presented.

Jan 1, 1987

By Terry L. Logan, Arfon H. Jones, James C. Seccombe

Deeply buried coal seams [greater than 3000 ft (914 m)] are difficult and sometimes hazardous to test and complete due to coal sloughing, formation pressure anomalies and coal fine generation. Data collected while stimulating two deep coalbed methane wells located at the Gas Research Institute/Resource Enter¬prises, Inc. "Deep Coal Sean Project" test site in the Piceance Basin, Colorado, is presented in this paper. A single thick coal seam was completed openhole in each well. Core data, reservoir data, in-situ stress measurements, and pre-stimulation calibration test data were collected at the site to use in the design of the fracture stimulation treatments for both wells. A nitrogen foam fracture fluid treatment was selected for the first well and a linear gelled water for the second well. Treatment pressures were monitored with a downhole quartz pressure transducer. Atypically high treating pressures were observed, possibly indicating coal fines plugging at the fracture tip or increase in fluid viscosity caused by interaction of the generated coal fines with the fracturefl uid. In addition, a comprehensive fracture diagnostic effort was employed during the fracturing of the second well; namely, triaxial borehole seismic, seismic televiewer, hydraulic impedance monitoring, gamma ray log (in conjunction with radioactive additives in the sand), and temperature log. The results indicate a vertical fracture was created parallel to the face cleat as expected.

Jan 1, 1986

By Jerry M. Whiting, Samuel Frimpong

Superior ventures selection and the subsequent management of their development and production are crucial in the competitive environment of the upstream minerals and energy industry. An important element of this chain is the management of uncertainty and risk dynamics. In the world of faster and more complicated technological and environmental changes, international competition and commodity market dynamics, thorough and sophisticated valuation must be carried out to establish a venture's value and return on investment. Thus, managers and investors must use methods that respond to market dynamics, investment and feasibility study options and provide relevant information for strategic investment decisions. Conventional methods have no built-in procedures to help investors analyse these options. Modern financial methods based on the dynamic arbitrage theory overcome these and other limitations of conventional methods. In this study, dynamic arbitrage theory has been used to formulate 3D parabolic differential equations that govern the stochastic processes of a copper mining venture with ongoing feasibility studies. The alternate direction implicit algorithm is used to solve the numerical approximations of the differential equations and their boundary conditions. Phase dynamics of the venture have been analysed to provide investors the appropriate timing for strategic investment decisions. The study also shows the amount and value of appropriate feasibility studies required to maximize the value of the mining venture.

Jan 1, 1996

By John F. Spisak

Versatile living organisms, historically exploited as functionaries in the food processing, pharmaceutical and chemical industries, have not been successful in achieving similar or significant acceptance within the minerals industry. The current biotechnical revolution coupled with its expanded understanding, dictate that a flagging minerals industry reconsider the use of biotechnology in metallurgical applications. Living resources, either singly, in commensal association or in complex communities, are capable of duplicating fully integrated and complex processing functions. Organisms can mine and extract metals, detoxify chemical effluents and synthetically produce compounds. They have been criticized as exhibiting poor kinetics, excessive energy consumption and environmental sensitivity. However, expanding knowledge reveals that these organisms are surprisingly adaptable, variable and extremely durable. Applied biotechnology in specific cases offers favorable economic returns, environmental benefits and aesthetic value. Selective implementation of living systems can offer opportunities for reduced labor, increased productivity and technological advance. Success will not come easily. Capital must be risked, controversial decisions made and new ground plowed. Traditional, specialist thinkers will of necessity give way to interdisciplinary expertise and unorthodox methodology if success is to be achieved. Those who vigorously persevere, however, are likely to be rewarded with a dynamic and profitable new role in a restructured minerals industry.

Jan 1, 1985

By J. E. Gebhardt, J. A. Herbst, K. Y. Lee

Benefits of proper control of reagent usage in flotation circuits are typically improved metallurgy and savings in reagent costs. Improved metallurgy can mean more consistent product quality, i.e., final concentrate grade, better recovery of product values from the feed, or higher plant throughput at existing target recovery, and grade values. Flotation performance is sensitive to a variety of process disturbances which occur in operating plants, such as changes in flow rate, percent solids, size distribution. flotability of mineral species, etc. A way to handle these variations is to fully understand the dynamic flotation responses to disturbances and to implement a suitable control strategy to compensate for these disturbances. Depending on the objectives of the control system, various types of control strategies are available which employ different levels of refinement to achieve the desired performance. Typically, variables such as collector and frother dosages and reagent addition points can be manipulated to affect the performance of the circuit. In the case of sulflde mineral flotation, manipulation of the process electrochemical potential, in flotation and in grinding, offers another degree of process control. Because of the complex and interactive nature of flotation process variables, optimized reagent control requires consideration of all, or at least the most important, interactive variables of the flotation circuit. Model- based optimizing control provides a framework to handle the complex and dynamic nature of flotation reagent process control.

Jan 1, 1994

By G. Bhaskar Raju, S. Prabhakar

The amenability of column flotation for the beneficiation of fluorspar was investigated, and the overall performance of the column, flotation was compared to the performance of the existing conventional flotation cells at the plant. It was estab¬lished that improved grades and recoveries could be obtained by adopting column technology. Acidspar concentrates as¬saying 97% CaF2, suitable for HF manufacturing, can be produced by adopting two-stage column cleaning in place of multistage cleaning by conventional cells. Similarly, metspar concentrates assaying 90% CaF2, suitable for metallurgical applications, can be achieved in a single-stage cleaning by column flotation. This is an improvement over what is now being achieved using the existing conventional rougher and three-stage cleaning cells in the plant. The number of stages, i.e.,four in the acidspar circuit and four in the metspar circuit, including rougher stages, can be eliminated by adopting a three-column configuration. Thus, the cost of production, the complexity of the circuit and the power consumption can be effectively reduced with other attendant benefits.

Jan 1, 2000

By F. D. Mendes, A. H. Martins

The high copper grade in the Igarapé Bahia (Brazil) gold-copper ore restricts the direct application of the classical cyanidation process. Copper oxide and sulfide minerals react with cyanides in solution, causing high leach-reagent consumption, raising processing costs and decreasing gold recovery. According to studies, a feasible solution would be to pretreat the ore to remove copper minerals prior to cyanidation. The goal of this experimental work was to study the conditions for the removal of copper from the Igarapé Bahia gold-copper ore by sulfuric acid leaching, applying a statistical approach to the experimental design. By using the Plackett Burman method, it was possible to select the variables that exhibited the largest influence on copper extraction at the sulfuric acid leaching stage. These variables were leach solution temperature, stirring speed, sulfuric acid concentration in the leach solution and ore particle size. The individual effect of these variables and their interaction influences on the experimental response were analyzed by applying the replicated full-factorial design method. Finally, the selected variables were optimized by the ascending-path statistical method, which determined the best leach experimental conditions for maximum copper extraction. The optimized leaching conditions resulted in a copper extraction of 75.5%. Keywords: Copper, Gold, Extraction, Sulfuric leaching, Optimization

Jan 1, 2003

By John A. Herbst, Kuang Y. Lee

Coarse particle size measurement is essential for the automatic control of a size reduction process like crushing or SAG milling in order to achieve optimal process performance. However, the on-line size measurement of coarse material is not easily obtained due to the problems of material handling and sample statistics. A technique based on advanced image analysis and quantitative stereology has been successfully developed and tested in a pilot scale setting. The chord length distribution of coarse particles on a moving conveyor was measured with an image analyzer and then transformed to the mesh size distribution with a stereological model and a special numerical method. Some test results as well as the technique's industrial suitability and limitations of this method are also discussed.

Jan 1, 1992

By J. A. Organiscak

Data on dust-control practices, mining conditions and occupational exposures were gathered for approximately 80 underground continuous mining units. Despite silica contents on dust samples in excess of 5%, nearly forty units successfully maintained silica concentrations at or below 100 µg/m3 on a majority of occupational dust samples, while the remainder had difficulty maintaining this level. These two sample sets were termed Group A operations and Group B operations, respectively. This data was compared to identify causes of high occupational silica dust exposures. Analyses of dust-control parameters and geologies revealed only minor differences between these two groups. However, subsequent comparisons of face ventilation design showed considerable differences in silica exposure and silica content between Group A and Group B at the continuous mining machine and roof bolter operator occupations. These differences were minimal when using exhaust curtain ventilation with a dust scrubber. This face ventilation system can benefit operations having difficulty controlling silica dust exposure and silica dust content. The collected data also showed that occupational samples from Group B operations possessed generally higher silica exposures and silica content than similar samples from Group A. The single head roof bolter (helper) possessed among the highest silica exposures and silica contents in both groups.

Jan 1, 2002

By E. J. Beckman, R. M. Enick, C. Powell

Liquid carbon dioxide can be used as a replacement for organic solvents in the extraction of anionic platinum group metal complexes from an aqueous phase. However, because conventional extractant-metal complexes are not soluble in liquid carbon dioxide, this can be achieved only if highly carbon dioxide-soluble extractants are developed. For example, trioctylamine-gold chloride is not soluble in liquid carbon dioxide, although trioctylamine is CO2 soluble. The novel CO2-soluble extractants presented in this paper have a CO2-philic fluorinated tail to enhance solubility and a conventional amine head group for extraction of metals. Both the extractant and the extractant-metal complex are soluble at ambient temperature at pressures from 7 to 35 MPa. Efficiency factors as high as 2.23 have been measured using 1,1,2-trichlorotrifluoroethane (TCTFE), a low pressure screening liquid for carbon dioxide, indicating that these compounds will strongly bind the metal chloride. For example, 84% of Pt-chloride was extracted into TCTFE using a 3.5:1 ratio of a double¬tailed fluoroalkyl amine extractant: metal chloride. An 88% recovery of Pt-chloride into high-pressure liquid carbon dioxide was achieved using the same extractant at a 3.5:1 ratio. Therefore, it appears possible to replace organic solvents with liquid carbon dioxide during the extraction of platinum chlorides if highly carbon dioxide-soluble extractants agents are employed.

Jan 1, 2002

By Robert A. Jankowski, J. Drew Potts

By implementing various mining practices, mine operators can reduce the respirable dust exposure levels of the roof bolter and the continuous miner operators. The Bureau of Mines has developed a computer program, entitled AMP (Alternative Mining Practices), that gives a quantitative comparison of these reductions. The alternative mining practices and their corresponding reductions in dust exposure levels that are evaluated by the program include a remote control continuous miner, a half-curtain ventilation system, two auxiliary fan-tubing bypass ventilation systems, a modified cutting sequence, a comparison between single-split and double-split ventilation networks, and a comparison between exhausting brattice and exhausting tubing. Descriptions of each of these mining practices are included in the report. The report also includes a hypothetical case study to show how AMP enables mine operators to select the technique(s) that is best suited to their particular needs. AMP is a compiled basic program that has been designed to run on computers with a DOS version 2.0 or later operating system. It includes high resolution graphics (640 X 200 dot positions) designed to run with video boards that are functionally compatible with the IBM Monochrome/ Printer Adapter. Graphic screens are selected from menus, and can be bypassed if the computer is not equipped to handle high resolution mode. Their primary function is to show proper implementation of the mining practices evaluated by the program. This package requires a minimum of 256K bytes of RAM. (Reference to specific products does not imply endorsement by the Bureau of Mines.)

Jan 1, 1987

By G. G. O. O. Uwadiale, M. A. U. Nwoke

The recovery of iron from low-grade (31.6% Fe) Muro iron ore was investigated using reverse anionic flotation of quartz. Tests were performed to investigate the effect of pH, the effects of using distilled vs. tap water as the flotation medium and the effects of using cassava starch vs. dextrin for the depression of iron minerals. The optimum results were obtained around pH 10 and 11, and cassava starch was superior to dextrin in depressing iron oxides. Investigations at pH 11 using cassava starch and distilled water resulted in a concentrate grade of 69.4% Fe with a recovery of 84.4% Fe. Under the same conditions, the use o f dextrin produced a concentrate grade q f 65.9% Fe with a recovery of 78.6% Fe. Investigations at pH 10 using cassava starch and distilled water resulted in a concentrate grade of 60.2% Fe with a recovery of 83.9% Fe, and under these conditions the use of dextrin produced a concentrate grade of 56.1 % Fe with a recovery of 81.5% Fe. Flotation studies conducted at pH 11 using tap water and cassava starch resulted in a concentrate grade of 70.4% Fe with a recovery of 92.7% Fe. This demonstrated the superiority of tap water over distilled water in the reverse anionic flotation process. Investigating the effect of calcium ions on the activation and flotation of quartz with oleic acid revealed that a calcium ion concentration of 50 to 100 ppm was optimum.

Jan 1, 1996

By J. F. Stenebråten, W. P. Johnson, D. R. Brosnahan

Carbonaceous materials (CM) from ores of varying preg¬robbing activity from Barrick Goldstrike Mines Inc. (BGMI), Nevada, were characterized in terms of their functional group contents, hydrocarbon contents, elemental composi¬tions and humic acid contents. Fourier transform infrared (FT-IR) analyses did not show the presence of hydrocarbons or carboxylic, phenolic or sulfhydrolfunctionalities. The FT¬IR bands present included C=C stretching in aromatic rings and C-O-C stretching, indicating the presence of oxygen as ether linkages or thiocarbonyl functionality in the carbon matrix. Calculated atomic oxygen to carbon (O/C) ratios did not reveal a trend between the maturity of the CM and the preg-robbing behavior, possibly due to the low resolution inherent in electron microprobe analyses. However, the atomic O/C ratios agree with other chemical analyses, indi¬cating that the organic carbon is very mature, similar to or higher than anthracite grade coal. Gas chromatography¬mass spectrometry and nuclear magnetic resonance analy¬ses corroborated the relatively featureless character of the carbon, indicating that the carbon structure is virtually completely aromatic (graphitic).

Jan 1, 2000

By John A. Herbst, K. Rajamani

Process improvement is probably the most widespread objective of mineral process plant operators in the late 1980's. An important part of such improvements is dynamic optimization which involves reacting to inevitable plant disturbances in such a way that productivity is maximized at every instant of time. This paper describes the way in which mathematical models can be and have been used in dynamic optimization. Both off-line and on-line model applications are described.

Jan 1, 1989

By R. Hiebert, M. Canty, S. Beckman

An innovative biological process is described for the treatment of cyanide-, metals- and nitrate-contaminated mine process water. The technology was tested for its ability to detoxify cyanide and nitrate and to immobilize metals in wastewater from agitation cyanide leaching. A pilot-scale demonstration is described in which a pilot plant was constructed to demonstrate the technology on a mine process-waste stream at a mine in Nevada. The demonstration was performed jointly under the Mine Waste Technology Program (MWTP), funded by the US Environmental Protection Agency (EPA) and jointly administered by the US De¬partment of Energy's (DOE) Western Environmental Technology Office (WETO) under Interagency Agree¬ment Number DW89938513-01-0. The Superfund Innovative Technology Evaluation (SITE) demonstration program was also involved in the project. MSE Technology Applications Inc. (MSE), Butte, MT, was the contractor responsible for conducting the project, and Pintail Systems Inc., Aurora, CO, was the technology provider. The pilot-scale unit was field-tested at Echo Bay's McCoy/Cove Mine southwest of Battle Mountain, NV. The biotreatment process was considered successful in destroying cyanide in the mine process water. The process was also determined to be effective in removing metals. The pH was consistently neutralized and nitrates were successfully removed from the mine process water. From the results of these pilot-scale tests, it was concluded that the biotreatment process potentially of¬fers an innovative, cost-effective alternative for the treatment of mining wastewaters.

Jan 1, 2000