Search Documents

By O. Herstad, J. M. Toguri, K. Grjotheim

DURING the last three years, investigations on the aluminum reduction of magnesium-bearing compounds have been initiated at the Institute of Inorganic Chemistry, The Technical University of Norway. The results of these investigations are reported in this paper. Very little information exists in the literature on the reaction between magnesium compounds and metallic aluminum. The available information itself is conflicting, and, to clarify the existing discrepancy, the reactions between aluminum and magnesium oxide (MgO), caJcined dolomite (CaO . MgO) and olivine (Mg2SiO.) were studied. The logical approach for the study of these reactions between condensed states with the formation of a gaseous phase is, ( 1) the measurement of the equilibrium vapour pressure of the gas, in this case magnesium, associated with the respective reactions and, (2) the identification of the end products of the reaction in order to establish the re-action scheme.

Jan 1, 1962

By W. G. Hubler

It has been within only the last two or three years that enough progress has been made in preferential flotation to warrant metallurgists in recommending the installation of commercial-sized plants for the treatment of copper-zinc-iron ores. Until the new processes had been worked out successfully, the treatment of this type of ore had proved a stumbling block in the path of metallurgical progress. Separation of lead-zinc ore is comparatively simple. A lead-zinc ore low in iron may be separated and concentrated by gravity con-centration, provided it is not necessary to grind too fine. Owing to the specific gravity of chalcopyrite and sphalerite being so nearly the same, however, their separation by gravity concentration is out of the question. Complex lead-zinc-iron ores in which the several minerals are intimately associated, requiring fine grinding to free them, have been successfully treated by flotation for the past fifteen years. Galena is easily floated, and its flotation, unlike that of chal¬copyrite, is not affected by the reagents used to inhibit the flotation of sphalerite and iron sulphides. When an attempt was made to use the methods of lead-zinc se-paration on copper-zinc ores, it was found that the depressant re-agents added to inhibit the flotation of the iron and zinc minerals would, under certain conditions, depress a large part of the copper. It was also recognized that, in the grinding of copper-zinc ore, soluble salts were generated which were detrimental to flotation unless properly controlled. The main part of this paper will be a discussion of solutions in the grinding circuit in relation to the pro¬duction of soluble salts and their effect on flotation.

Jan 1, 1931

By Seunghoon Lee

The increase in the number of higher and larger buildings is expected to require the buildings' outer wall maintenance process, which includes cleaning, painting and monitoring, still depends on manpower. In this study, we proposed the robotic building maintenance system and aimed to reduce the jerk effect through the motion control of the system, improve the performance of the maintenance task, and ensure longer life and safety by improving the stability of the building structure and robot system. Through the results of the motion control and field-test with the proposed system, in specific, horizontal sliding module (HSM) showed that the jerk oriented by impact force was significantly reduced, feasibility of the proposed method was verified, and the robotic challenges were explored.

Aug 1, 2013

By R. Al-Hent, M. Aissa, J. Asfahani

"This paper presents regional radiometric gamma-ray spectrometry maps of Syria for total radioactivity (Ur) and surficial concentrations of equivalent uranium (eU). The maps were created by merging airborne and ground-based gamma-ray spectrometric survey datasets. On the regional radiometric eU map, eU anomalies are closely related to either phosphate and/or glauconite deposits. The Ur and eU maps delineate the boundaries of three phosphate deposits, close to the Palmyrides ridge, in the northern part of the Coastal Range and Syrian Desert. Scattered occurrences of uranium mineralization in other phosphate formations are attributed to secondary chemical and physical processes, rather than primary accumulation.RÉSUMÉ Cet article presente des cartes regionales radiometriques de spectrometrie gamma de la Syrie pour la radioactivite totale (Ur) et les concentrations en surface de l’equivalent en uranium (eU). Les cartes ont ete creees en combinant des ensembles de donnees, aeroportees et au sol, de releves de spectrometrie gamma. Sur la carte regionale radiometrique eU, les anomalies eU sont etroitement reliees aux gisements de phosphate et(ou) de glauconite. Les cartes Ur et eU delimitent les limites de trois gisements de phosphate, a proximite de la crete des Palmyrides, dans la partie nord de la chaine cotiere et du desert de Syrie. Des dispersions de mineralisation d’uranium dans d’autres formations de phosphate sont attribuees a des procedes chimiques et physiques secondaires, plutot qu’a une accumulation primaire."

Jan 1, 2016

By Bill Dupley

We believe that the inability of employees to effectively manage information has reached an epidemic problem throughout the corporate world. ? All the available knowledge in the world is accelerating at a phenomenal rate. ? The whole world's codified knowledge base (all historical information in library books and electronic files) doubled every 30 years in the early 20th century. ? By the 1970s, the world's knowledge base doubled every seven years. ? Information researchers predict that by the year 2010, all the world's codified knowledge will double every 11 hours.

May 1, 2003

By Jianwen Yang, Yucai Zhou, Yanhong Dong, Daixiong Chen

"The study of combined depressants for flotation separation of lead from copper has been carried out to solve the copper-lead separation problem. Test results show that the depressant of CMC (Carboxyl Methyl Cellulose) or sodium sulfite plays an important role on the selective depression of galena flotation. When the two reagents above are combined, the selective depression effect on galena is further enhanced. When the mass ratio of CMC to sodium sulfite is 1:4, galena was best depressed, with the lowest lead content in the copper concentrateClosed-circuit tests indicate that under a certain pH value of the slurry, with the best ratio of CMC to sodium sulfite as depressants, the copper concentrate with the grade of 28.23% copper and 4.12% lead is obtained, and the copper recovery is 84.87%; the lead concentrate with 68.12% lead and 0.86% copper is obtained, and the lead recovery reaches to 92.20%. An efficient separation of copper and lead is achieved with the combined depressants. INTRODUCTIONComplex copper-lead-zinc sulfide ore is abundant in China. With the rapid increase of mineral consumption, it has become one of the important sources to produce copper-lead-zinc metals. However, it is difficult to achieve effective separation of copper and lead, due to the complicated ore properties, such as fine dissemination, low copper grade, complex symbiotic relationship and similar floatability of copper and lead.Poisonous reagents of bichromate and cyanide are often used as depressants for copper lead separation. They have good separation efficiency, but pose serious pollution issues. As the environmental protection is becoming more and more important, it is a trend to replace traditional toxic reagents with new nontoxic efficient chemicals. Organic depressant FCLS studied by Liu has strong selectivity against galena, and does not depress chalcopyrite. A new type of galena depressant of CLS-01 discovered by Jin-lin Yang shows good results in the separation a mixed copper and lead concentrate. In addition, dextrin, chitosan and some other natural organic compounds (Drzymala, 2003; Huang, 2012; Qin, 2013) have also been studied to separate copper and lead."

Jan 1, 2016

By D. Yu, T. A. Utigard, M. Barati

"Sulfation roasting of nickel concentrate to generate water-soluble metal sulfates was investigated as an alternative process to smelting for the recovery of valuable metals. The kinetics of dissolution of various species of the calcine in three leachants was studied; hot water, dilute HCl, and concentrated HCl. The results indicated that dissolution of sulfates by hot water at 90 ºC is achieved within 30 minutes. In order to increase the recovery of the valuable metals, acid leaching is necessary due to the existence of ferrite in the calcine.INTRODUCTIONInvestigations on the sulfation roasting of nickeliferous sulfide ores or concentrates were mainly carried out in 1950’s to 1990’s to generate water soluble non-ferrous metal sulfates followed by metal recovery by leaching (Stephens, 1953; Thornhill, 1954, 1961; Fletcher and Shelef, 1964a, 1964b; Fletcher and Hester, 1964; Frankiewicz, 1977; Norrgran, 1983). Commercialization of the sulfation roasting process was only performed by Falconbridge Ltd. (Thornhill, 1961; Boldt, 1967), which employed a sulfation roast process on nickeliferous pyrrhotite at 680 oC where Ni, Cu, and Co were leached and Fe2O3 was produced for the iron industry. In 1965, 118,342 tons of pyrrhotite was processed, however because of the huge SO2 emissions (no acid plant) relative to the nickel production and the poor economics, this plant was shut down.Nickel production from sulfide ores via pyrometallurgical means, especially the electric furnace smelting process, is a major emitter of SO2 to the environment and a big energy consumer (Warner, Diaz, Dalvi, Mackey, Tarasov and Jones, 2007). Nowadays, due to the more stringent environmental regulations as well as the need to reduce energy consumption, metal production by sulfation roasting is gaining more attention as an alternative process to smelting. The main focus of this paper is to investigate the extent and rate of leaching of valuable metals from the sulfation roasted nickel calcine, aiming to maximize the metal recovery and minimize the dissolution of iron species."

Jan 1, 2012

"The Waite-Amulet, an important copper-zinc mine, lies astride the Duprat-Dufresnoy township boundary about 8 miles northwest of Noranda, Quebec. It is an amalgamation of two properties, that of the former WaiteAckerman- Montgomery Mines to the north and that of Amulet Mines, Limited, to the south. This amalgamation took place in 1933. The description that follows is confined to the Amulet section.Ore was first discovered on the Amulet property in the autumn of 1924. The C Shaft and Upper A orebodies were found in 1925 and the F orebody in 1929, the latter by diamond drilling under a swamp. Under the present management, Lower A ore body was discovered by diamond drilling at a depth of 700 to 1,200 feet in 1938, and new ore was found from the old C Shaft workings between 1943 and 1945.From April 15th to October 20th, 1930, 60,291 tons of ore was produced from the Amulet. During the second half of this period, the ore averaged 4.2 per cent copper, 16.3 per cent zinc, and 0.02 oz. gold and 3.35 oz. silver per ton. Due to the prevailing low prices of metals, there was no further production until July, 1937. Output was greatly accelerated in 1940 when the newly found Lower A orebody assumed the main burden of production. Up to January 1st, 1946, mill reports indicate the treatment of the following ore: GENERAL GEOLOGYFig. 1 shows the geology of the entire property. To the east is the Lake Dufault granodiorite stock and to the west the Flavrian Lake granite mass. Around the granodiorite and separating the Waite from: the Amulet section is an older diorite intrusion. The ore occurs in a series of lavas that form a broad anticline pitching eastward at a relatively low angle into the Lake Dufault intrusives. There are several steep east-west faults. The late Powell diabase dyke is shown, also the general areas of strong dalmatianite alteration, a type closely associated with the sulphide mineralization."

Jan 1, 1954

At the end of a century of mining education in South Africa, it is appropriate to reflect on the past, take stock of the present and ponder the future of mining education. While it is likely that changes in the mining industry will generate an increased demand for mining graduates, the number of suitably qualified applicants to study mining is worryingly small. While good progress has been made in unifying the educational system that previously provided schooling on a racially separate basis, it appears that a decade or more will be required to raise competency levels in mathematics, science and English, and this paper describes the process as it affects mining engineering programs. It also describes the initiatives currently being undertaken by the University of the Witwatersrand and the mining industry to ensure that the South African industry receives an adequate flow of well-qualified mining graduates, despite more than 70% of the intake coming from severely disadvantaged educational backgrounds.

Jan 1, 1999

By David G. Meadows

During the last decade Antofagasta Minerals? Los Pelambres Mine has dramatically increased its ore throughput following the fast initial phase ramp up through a series of planned incremental expansions. The original 85,000 mtpd, two SAG line plant was commissioned in 1999 and rapidly exceeded nameplate tonnage in only a few months. Following this, the inclusion of a pebble crushing circuit resulted in throughputs in excess of 114,000 mtpd and a recent, final third line SAG and ball mill addition have taken the plant to over 175,000 mtpd even with increasing ore hardness and changing ore feed characteristics. The progressive changes are described in this paper together with how the technical challenges have been met.

Jan 1, 2012

By Sabine Noelte, Mikko Petteri Rantamäki, Christopher Robben, Anssi Takala, Karl-Erik Rånman

"Sensor-based ore sorting is on its way to establish as a standard option for physical separation. The increasing number of installations in coal, iron ore, industrial minerals and hard-rock metal mining segments underlines the technological and financial potential that is beginning to be untapped. The Ma’aden Phosphate installation with 1.650 t/h sensor-based ore sorter feed sets a new benchmark for the possible capacity of stationary installations. Besides stationary installations, including multiple sorters parallel in different size ranges and multiple stages, containerised semi-mobile plants are applied. These offer two advantages, first being the reduction of transport costs when applied close to the mining face. The second is that semi-mobile systems enable processing of tens of thousands of tonnes of ore in a piloting phase with an approximate duration of 0.5 to six months, verifying the results laboratory mini-bulk tests on 5–10 tonnes of sample. This is especially important for low-grade metal ores because of the inherent Fundamental Sampling Error, as well as the Grouping and Segregation Error. The paper elaborates the results achieved within the I2MINE project, treating polymetallic ore at the Boliden Concentrator in Sweden.INTRODUCTIONSensor-based ore sorting (SBS) is becoming a standard option for physical separation, applied in all segments of mineral production. The Umm Wu’al project sets the bar for stationary SBS installations with 1,650 t/h feed (TOMRA, 2015). TOMRA Sorting Solutions has finalised an agreement in cooperation with Outotec to supply Outotec-branded sorting solutions for the mining and metallurgical industry (TOMRA, 2014). Especially for low-grade hard rock metal ores, an interdisciplinary approach is necessary applying experts for all aspects of mineral production. Due to the impact on the whole process stream, it is important on the end user side to have high level managerial support and involve all disciplines to ensure that all stake holders are involved in the analysis."

Jan 1, 2016

By E. C. Keeley

Some Safety Measures at Ontario Mines The following safety precautions have of late been taken by several of the Ontario mines: installation of water crossovers; washing clown of faces to show-up missed holes; insistence on gloves being worn as a protection to men's hands; wearing of safety boots and hats by underground men; and wearing of goggles by all men using hammers, starting holes, etc. In the summer of 1924 the Mclntyre mine began experimenting with means of removing powder smoke from headings by installing fans and pipe-lines of various designs, also with different means of introducing water into the air-blast when blowing smoke. By October of that year they had devised a scheme of water connection between the water and the air line, at a distance of about one hundred and fifty feet back from the face, using two valves and a short hose. By this means a limited amount of water could be introduced into the air which blew into the face, resulting in a fine spray of air and water combined. This spray not only helped to eliminate fumes but also introduced fine particles of water into the air, raising it above the dew point, with the result that when these fine particles of water settled they had attached to them fine dust particles, thus eliminating, to a great extent, the injurious dust caused by blasting. The combined air and water is turned on immediately after blasting and allowed to blow continuously for from four to five hours, until the muckers come on shift.

Jan 1, 1931

By Ward E. Kilby, Bruce I. Mcclymont

"Data from the South Fork Pit Area of the Bullmoose deposit in northeastern British Columbia are used to demonstrate the usefulness of microcomputers to the on-site geologist. The technique utilizes a series of digital surf aces in the form of a network of points to define various geologic parameters such as seam positions, topography and coal quality characteristics. Manual digitizing, kriging and combinations of these techniques are used to calculate these digital surfaces, the best method depending upon the type and quality of the data in question. Digital surfaces, each modelling a specific feature when combined and manipulated with the computer form a powerful tool, the deposit model. The resultant model, containing all the surfaces, is used to examine seam and inter-seam thicknesses, deposit volumetrics, seam quality characteristics and the adequacy of sampling.IntroductionCoal deposit modelling using computer-based techniques has become routine. However, a geologist working in the field, without access to mainframe or minicomputer, ha s considerable difficulty implementing these procedures. However, microcomputers, which are portable and inexpensive can handle exploration data, perform various geological analyses, and produce deposit models virtually at the same time as the data is being collected. For the on-site geologist this means that quick access to the results of such modelling could point out inadequacies in deposit definition and trends in coal quality deserving investigation."

Jan 1, 1985

By A. Warczok

Chalcocite concentrate obtained by magnetic separation and flotation of Bessemer matte is processed in the Inca top blowing bottom stirring MK reactor into semi-blister copper. The semi-blister is then converted into blister copper in the multi-purpose vessels (MPV) by oxidation of iron, nickel and sulphur. High melting point NiO and Fe30 4 are formed inside the MPV s, which together with Cu20 and smaller amount of fayalite are the major constituents of the solid mush. The accumulation of solid mush and buildup requires periodic MPV cleaning by adding reductant and copper-nickel matte, a unique process called "washout". Various reductants and their combinations, such as pig-iron, 15%Si Ferro-silicon and 50%Si Ferro-silicon, have been used for the reduction of solid mush and buildup. The possibilities of using calcium carbide as a reductant and slagging flux were examined experimentally at the crucible scale. The rate of reduction of MPV buildup was determined by continuous measurement of CO and C02 contents in the offgas and the flowrate of argon carrier gas. The rate of the buildup reduction with calcium carbide was approximately five times faster than the rate of reduction with coke. Additionally, the formation of CaO results in the melting of reduced buildup and formation of a slag at 1300°C and higher temperatures. It was found that simultaneous silica addition enhanced the melting and slag formation. The results showed the strong dependence of the reduction rate on temperature. Activation energy is approximately 225 kJ/mol. Expected benefits of using calcium carbide are related to cost saving on reductant, significant acceleration of solid mush reduction, and reduced amount iron input from reductant.

Jan 1, 2007

By Jason Palmer

"Water in mining is the commodity that has driven the mining industry for decades. Often used frivolously, modern economic and social pressures are forcing change to use less water and to improve the quality of water and effluents. Used in many processes, water is ultimately consumed in tailings disposal and technologies which can increase the recovery of water are constantly being developed. Filtration and thickening are often seen as competing technologies for water recovery however new cases are developing that show significant advantages can be achieved by combining the two technologies to develop the most effective solution. Supported by case studies this paper investigates the merits of each of the technologies and which strategies of combining the two produce the best outcomes.INTRODUCTIONMineral processing applications generally require water for the processing of ores, whether utilising physical or chemical methods. Water is first added in the milling stage and additional water added as required throughout the circuit. Water losses from the circuit are principally associated with the tailings stream. Optimised water recovery is necessary both because it is a scarce commodity and to minimise the environmental impact.Water recovery is usually accomplished through a sedimentation or filtration processes. Water can be removed from the tailings impoundment by evaporation but this does not improve the mine’s water consumption. The water recovery methodology also determines the water quality; increasing water recovery concentrates solutes in the process water and may create recirculating loads of fine solids."

Jan 1, 2016

By P. Kordi, L. Egorova, R. J. Bowell, D. Gurevich, V. Sedov, A. Mikhailov, D. A. Holwell

ABSTRACT Reconnaissance exploration in the Kuene region Namibia has included geological mapping, soil and stream sediment geochemistry, and ground geophysical methods. Copper mineralization occurs within a well-defined belt with north-northwest to south-southeast trend, parallel to the regional strike of the sedimentary rocks. The occurrences vary in size but are generally stratabound. The mineralization is centred on the transition from calcareous shale and interbedded limestone, through carbonate rocks, to quartzite. Geochemical anomalies have been identified correlating to induced polarization (IP) and magnetic anomalies. The anomalies identify one potential metallogenic zone more than 17 km in strike length.

Jan 1, 2012

By P. G. Claridge, G. P. Holmes, M. A. Redfearn

"IntroductionThe purpose of this chapter is to describe current practices in operation and maintenance of flotation circuits in Canadian mineral processing plants. The chapter consists of five sections covering description of equipment, typical flow diagrams, operating practice, instrumentation and maintenance. The approach to this subject matter is intended to be practical in nature, hence no deeply technical treatment of flotation theory will be included.Flotation is an extremely common method of beneficiation of ores. Reasons are the relatively low cost of flotation compared to many other processes, the wide range of minerals to which flotation may be applied and the high efficiency of separation which can usually be achieved. The flotation process as we know it today has been developed within this century and it has had a major impact on the mining industry. While flotation is commonly considered to be important because it provides a relatively simple method of separating minerals in complex ores, the availability of flotation has also made a multitude of mineral deposits in Canada into economically viable mining operations because it allowed production of a concentrate of valuable minerals from the ore. These concentrates could then be transported from geographically remote locations to centraHzed plants for further processing, although the existence of the remote and perhaps small ore body alone would not have justified installation of metallurgical processing plants on site and the grade of ore would not have justified direct shipment of ore.Some of the more common minerals concentrated by flotation are sulphides of copper, nickel, cobalt, iron, zinc, molybdenum, lead and arsenic, as well as non-sulphides such as sodium chloride, potassium chloride, phosphates, silicates, chromite, fluorite, limestone and coal. Precious metals are also recovered by flotation, generally in association with another sulphide mineral."

Jan 1, 1989

By D. B. Smith

DURING the summer of 1953, test work commenced at the Sullivan Concentrator with a view to the modification of filtration practice by the inclusion of wet cyclone classification of the lead concentrates, with separate filtration of the underflow and overflow products. Formerly, practice was conventional and the equipment employed comprised one 50-foot diameter thickener ?with the underflow routed via a 20-foot stock tank to two 8-foot by 12-foot Oliver filters. Heating of the filter feeds to 40° C. and the use of mechanical slappers on the filter drums ?have both been standard features of Sullivan practice for years. Both of these have been retained. Currently (February, 1956), lead concentrates are being classified into sands and slimes by 12-inch cyclones with the underflow, at 75 per cent solids, being fed to No. 1 Oliver filter. The overflow is thickened to 75 per cent solids and filtered separately by a No. 2 Oliver filter . The tonnage split is approximately two of underflow to one of overflow. The overflow contains 75 to 80 per cent of the total minus I 500 mesh slimes in the feed.

Jan 1, 1956

By G Anders

The mucking out of sub-level headings by slusher and by Autoloader is described, and the performance and costs of both methods are compared. The introduction of the Autoloader is taken as an example to illustrate the meth-od used at the mine for evaluating the suitability of new equipment. The consecutive steps in the process are covered in detail -from the preliminary cost analysis and the preliminary estimate of savings and advantages, and the review of these data after a field investigation, through the elimination of dubious factors, and detailed time and performance studies at the property, to the final assessment of the new equipment and an evaluation of the initial forecast. The Autoloader in Operation. 1198 Introduction AT Mattagami Lake Mines Ltd., the mine workings are laid out basically on a pattern of 60-ft.-wide stapes alternating with 60-ft.-wide pillars, with stope lengths varying from 80 to 200 ft. and stope tonnages generally between 80,000 and 200,000 tons. Stapes are drilled off from sub-levels at 60-ft. intervals, with the

Jan 1, 1965

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003