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By B. Courtaud, L. Donati, V. Weigel

As a growing mining company, ERAMET is looking for new positions in the strategic metals market. In this context, the Gabonese Maboumine pyrochlore deposit is currently being studied for the recovery of niobium, tantalum, rare earths and uranium. This ore shows mineralogical and chemical characteristics that make it challenging to process by existing practices, from both technical and economic points of view. ERAMET has developed since 2008 an innovative hydrometallurgical process, which has been successfully operated at a pilot plant scale (more than 35 weeks in continuous). The upstream part of the process aims to dissolve valuable elements in sulphuric acid. The first step is dedicated to dissolve the ore matrix, leaving the pyrochlore unleached. The second step consists in chemically breaking down pyrochlores in order to form soluble species of the valuable elements. After dissolution, the valuable elements are separated into different flows: niobium and tantalum are recovered and transformed as commercial ferroniobium on one side, and rare earths and uranium remain in the solution to be recovered in the downstream part of the process. The main goal of this paper is to discuss the upstream part of the process, which has given successful results.

Jan 1, 2014

By R. Carter, C. S. Samis

"SummaryThe results of this investigation indicate that the gold in the cyanide tailing of refractory gold cyanides is occluded in fused •particles formed during roasting. This conclusion was reached following microscopic examination of calcines produced at various furnace temperatures with different atmospheres, and a •comparison with calcines produced by decomposing samples of completely sulphated concentrate under conditions such that the maximum particle temperature varied between 6•50°C. and 1,100°C. This comparison showed that the particle temperature during a normal roast may be several hundred degrees higher than the furnace atmosphere, or that the fusion is associated with a low melting (950°C.) eutectic mixture of FeO and FeS.Because of the unavoidable particle fusion during a furnace roast, and because low particle temperatures are essential for gold extraction by cyanidation, aqueous medium oxidation under high oxygen pressures was studied. Gold recovery from calcines produced by this means was over 98 •per cent •compared with a maximum of 80 per cent from furnace calcines.IntroductionMANY arsenical gold ores are called 'refractory' because much ' of the gold cannot be satisfactorily extracted by cyaniding the raw ore or concentrate. Even when such ores are roasted to oxidize .the iron and arsenic and 'release' the gold, often 10 to 25 per cent of the gold present is lost in the cyanide residues."

Jan 1, 1952

By B. K. Mishra, Subrat Kumar Padhy, B. C. Tripathy, I. N. Bhattacharya

Manganese is a difficult metal to electrodeposit due to its high electronegativity and continues to possess unique process challenges. Manganese deposits of high quality are electrodeposited on 316 grade stainless steel from sulphate solutions in the presence of organic additives such as tetra ethyl ammonium bromide (TEABr), tetra propyl ammonium bromide (TPABr), and tetra butyl ammonium bromide (TBABr). The concentrations of these additives were examined over a relatively broad range to evaluate their effect on current efficiency, specific energy consumption and deposit morphology of the electrodeposited manganese metal. A maximum current efficiency of 68% was achieved in the presence of TEABr in the bath. X- ray diffraction studies revealed that (330) (411) planes were the most preferred planes of crystal growth during manganese electrowinning at a current density of 500 A/m2 resembling alpha-manganese irrespective of the nature of additive. Scanning electron micrographs showed smooth and uniform deposit morphologies when manganese was electrodeposited in the presence of TEABr.

Jan 1, 2014

By M. G. Mena, M. S. Mena-Junio

Silver (Ag) filler is the most attractive choice among all the conductive fillers of die attach materials for the attachment of silicon devices because of its balanced properties and relatively low cost. However, a major problem of silver is that it electrochemically migrates in the presence of moisture and applied bias. In microelectronic devices, silver migration can occur between adjacent conductors/electrodes, which leads to the formation of dendrites and eventually results in short-circuit failure. In order to assess the reliability of these conductive fillers, an investigation for two types of Agfilled die attach materials was done using the water drop test at room temperature and using a 1000 hour temperature-humidity-bias (THB) test under 85 ºC and 85% RH conditions. Four different bias/voltages and six different electrode distance spacing were used. Both dendrite and cloud/lace-like growths were observed as a result of the electrochemical migration of silver, Water drop test results revealed that increasing the applied bias/voltage and decreasing electrode spacing causes migration to occur faster, thus resulting into shorter time to fail (TTF). It was also observed that the growth rate of the dendrites from the cathode increased linearly as the dendrite approached the anode, probably due to a combination of increased ion availability and electric field. A minimum applied bias of 3 volts was required for migration to occur in Epoxy A as compared to 2 volts for Epoxy C. The higher migration voltage requirement for Epoxy A was attributed to the higher volume resistivity of the said epoxy. In addition to the minimum voltage requirement, it was observed that a minimum electric field of about 1 volt/mm is required for migration to occur. The 1000 hour THB testing did not result into any failures. It is surmised that the presence of condensed moisture is another requirement for migration. Such condition is not present during the THB testing.

Jan 1, 2012

By James F. Allan

"Abstract -The Kipawa yttrium-zirconium prospect is located about 150 km south of Noranda, Quebec . Yttrium-zirconium mineralization occurs in an elongate, regionally metamorphosed and deformed peralkaline complex in the Grenville terrain. The mineralized zone, as defined by ? 0.10% Y203, is 1300 m long and 10 m to 30 m wide. Zirconium content typically ranges from 0.50 to 1.20% Zr02. The mineralized zone strikes northwest and dips 20 degrees to 35 degrees to the southwest. It occurs at the structural base of the peralkaline complex in syenite gneiss and cale-silicate rocks and is conformable with both the footwall contact of the complex, and the layering and gneissosity in the enclosing rocks. Minerals of economic interest are eudialyte (sodium-zirconium silicate), mosandrite (sodium-titanium silicate), britholite (calcium-silica phosphate), and a few other uncommon zirconium and titanium silicate minerals.The highest and most continuous yttrium grades occur in the upper part of the syenite gneiss unit in areas containing eudialyte, mosandrite and rninor britholite. Yttrium also occurs in britholite in cale-silicate rocks and in mosandrite in syenitic rocks in the lower part of the syenite gneiss unit. Both the yttrium-bearing minerals and yttrium grades are erratic in the lower part of the unit. Zirconium is generally more uniformly distributed than yttrium. A peralkaline granite gneiss phase of the complex intrudes the syenite gneiss and possibly truncates it, and the mineralization, near the southern boundary of the mineralized zone.The mineralized zone is coincident with a radiometric anomaly and discontinuous yttrium and zirconium soil anomalies.More drilling and metallurgical studies will be required to determine the economic viability of the yttrium and zirconium mineralization at Kipawa."

Jan 1, 1992

By M. L. Haider

Introduction I Appreciate very much the opportunity of discussing with you tonight oil developments in western Canada. These developments are of importance to all of us, first because of their great economic significance to all of Canada, and second because of the location of the new oilfields. Situated as they are in the west and northwest, they are of considerable strategic value from the standpoint of continental defence. The story of oil development in Canada covers a span of almost a century, during which time success in finding reserves of petroleum was barely sufficient to maintain interest in continuing the search. Finally, in 1947, a well of the first importance was completed in Alberta and, judging by discoveries made since then, it appears that Canada, at long last, is to become an important producer of petroleum.

Jan 1, 1950

By E. W. Lucht

THE term "high pressure", as used in industry today, is applied rather loosely. Generally, it refers to pressures that are higher than those encountered in most industrial processes although no definite limits are normally stated. For the purpose of this talk I should like to set rather arbitrary limits to the term "high pressure", and in ab-solute figures this would be the range from 1000 psi to perhaps 40,000 or 50,000 p.s.i. The scope of high pressure technology is very broad, and it would take more time than we have avail-able here today to cover fully even one aspect of the field. Therefore, I should like to discuss just some of the techniques used and problems en-countered in high pressure operations. Research work into the high pressure region dates back about 150 years, but it was not until 1910 that the first commercial application of high pressure technology was made in the production of ammonia.

Jan 1, 1962

By A. Warczok

Smelting slags contain payable metals in a dissolved form and as mechanically entrained matte or metallic inclusions in the size range from 2 to 1000 µm. Slag cleaning requires reduction of magnetite and metal oxides and sedimentation of inclusions. Slag cleaning in an electric furnace is carried out in batch or semi-continuous mode. The strong trend for continuous slag cleaning generates the basic question about the optimal geometry of the electric furnace. Results of combined CFD, potential distribution and heat transfer modeling allowed for the determination of the fluid flow pattern and the temperature distribution in a classical, circular electric furnace as well as in a rectangular furnace. For the rectangular furnace, various length/width ratios and position of electrodes have been simulated. Analysis of key phenomena pointed out the advantages of the rectangular electric furnace over the circular furnace, particularly for continuous slag cleaning. Phenomena that have been analyzed were mass transfer, the rate of slag reduction, coalescence and settling of inclusions, all on the basis of the calculated slag flow pattern and the temperature distribution.

Jan 1, 2007

By A F. Kravic

Carbonyl nickel powders of irregular particle shape and low a11parent density are used extensively in the production of porous nickel electrodes for nickel-cadmium storage batteries and hydrogen-oxygen fuel cells employing alkaline electrolytes. Such porous nickel matrices are at-tractive for these intended applications as they are relatively inexpensive, are corrosion resistant, have good electrical conductivity, can be welded to form electrical contacts, have a long life (as demonstrated in alkaline storage batteries), and are rugged and vibration and shock resistant. This paper describes a feasibility study concerning the production of porous multi-layer nickel electrodes by the pressing and sintering of stacked layers of green-powder rolled nickel sheet. Background H AUSNER (1) conveniently listed nine different powder compaction processes used for forming metal powders into useful shapes. These are shown in Table I. There are additional powder metallurgy processes; however, most of these are combinations of two or more processes listed in the Table. A study of the literature revealed that every powder compacting process, with the exception of isostatic pressing and explosive forming, has been evaluated or is being used for the manufacture of porous metal electrodes.

Jan 1, 1965

By F. J. Gauthier, R. G. Gray

"The possibilities of expanding the production rate from the Copper Mountain Mine have been examined using computer programs for analysing a complete range of data, beginning with the diamond drill assays and embracing all steps up to the final rates of return.Programs have been developed to calculate the mineralization inventory file, a matrix of blocks containing the grade and the type of mineralization estimated for each block. Given the topography, prices of metals and costs, the pit limits are optimized using a three-dimensional technique. Within the pit, ore reserves at any cutoff can be calculated. Mining of the pit is then simulated using an interactive production scheduling program on a timesharing computer. The annual tonnage and grade figures from the production schedule are input to a financial analysis program, where the present value and the rate of return are calculated at various metal prices. The expansion possibilities can be run through the programs with their respective costs, and evaluated using the rate of return on the marginal cash flow compared to the additional capital expenditure."

Jan 1, 1971

By J. D. Campbell

"Coal is one of Alberta's major fuel resources, but its distribution, especially in the flat plains region, has been somewhat obscured by surficial deposits. After a period of neglect, easily strippable plains coal is presently approaching a position of dominance in electrical power production, a position it is likely to retain for a number of decades in the face of strong competition from hydro and nuclear power. Accordingly, the Research Council of Alberta has undertaken an inventory survey of the province's supplies of this resource.In the southern part of the province and in the north-central forest-fringe area, some strippable coal is found in the Belly River Formation and its equivalents, but major strippable coal reserves in large areas of central Alberta occur within the Edmonton Formation. The survey is planned on a reconnaissance scale, drilling test holes at 2-mile intervals in selected large areas. It appears to show that, in well-settled regions, large reserves of strippable coal are only to be expected where they have long been known; major presently unknown bodies of coal must be sought in unsettled regions or at depths too great for strip mining. However, such bodies might still be economically competitive with hydro and nuclear power in the production of electric power for some time to come."

Jan 1, 1967

By D H. Sharp

The Quebec Cartier Mining Company produces iron concentrate for twelve months of the year from Port Cartier. This J>Ort is designed to handle ship varying in size from 3,000 to 100,000 d.w.t., requiring 50 feet of water at low tide. The harbour was built on shore for reasons of economy and layout, after considering many more conventional offshore designs. It provides for heavy oil bunkering, tanker off-loading, a heavy lift derrick and freight handling, besides ship loading and mooring. The weather for the previous fifty years was studied to enable wind and wave conditions to be accurately assessed for design purposes, and to determine probable lost time due to adverse weather conditions through-out the year. The first ship to be loaded was 60,000 d.w.t.; the second, 20,000 d.w.t. The latter entered the harbour after dark, under its own power, following a tug through the partly dredged narrow entrance. Large ships use tug assistance. Ships may leave the loading berth with the other berths occupied.

Jan 1, 1963

By J. G. Thomson

Development of the Canadian North, a subject of growing national interest, must in part await the development of better forms of trans-port. The estimated 500,000 square miles of muskeg terrain in the north combined with the" scarcity of roads make essential the early development of special purpose muskeg vehicles. Good progress has been made in the last eleven years in classifying muskeg and some progress has been made in determining its mechanical properties. Limited travel is now possible through the use of special purpose tracked vehicles which have been built without adequate design data. A program to provide data which can be used to optimize muskeg vehicle designs began in 1957. The results of the second phase of this pro-gram are presented in this report. It is shown that vehicle performance in muskeg is directly related to the mechanical properties of the muskeg. Further, it is shown that good de-sign practice for tracked vehicles expected to operate in snow, sand, soft clays and loams is also good practice for muskeg vehicles. All indications are that muskeg mechanics is properly a part of conventional soil mechanics.

Jan 1, 1961

By G. O. Prickett, P. Somasundaran

An application of the statistical and computer techniques in basic mineral processing research is illustrated by means of a case history involving the study of starch adsorption on calcite. Multi-factorial experimental designs and computer techniques were used for determining the effect of different system variables, such as solution pH, sodium oleate concentration and starch concentration, and to obtain a mathematical model of the response. Response maps enabled the investigators to see the effects clearly and to predict the results of changes in factor levels within the design region. Use of time-shared computers and plotters made data processing and analysis efficient and relatively inexpensive.

Jan 1, 1973

By W. B. Dingle

"IntroductionMANY PAPERS presented on developments in the Canadian Petroleum Industry •during the past few years have commenced with this general sentence: ""The past year has been a record •one for the oil industry in Canada, with new records being set in nearly all phases •of exploration and development ,activity"". This sentence applies equally well to 1951. It is not possible to outline all the details of the broken records in exploration, development, and production but general comparisons can be made. There are several significant developments that have stolen the spotlight during 1951, some of which were foreseen in 1950 and some which were not. Among the high-lights were the following:(1) The greatly •expanded activity in the search for gas, which was touched off by the new Alberta regulations covering gas leases and reservations.(2) The discovery of commercial oil production in the Williston basin of North Dakota and Manitoba, which will have far reaching effects on Canadian oil.(3) The greatly increased activity in northern Alberta, northwestern British Columbia, the southern Northwest Territories, Saskatchewan, and Manitoba.(4) The new discoveries in the general central Alberta area.(5) The granting •of a permit for an oil pipeline to the Pacific coast.(6) The arrival of Western Canadian crude in central Ontario.(7) The number of new refineries completed, commenced, or proposed.(8) The present •and proposed expansion in the petrochemical industry.Most of the remarks made on various exploration and development •activities will refer to Western Canada operations, primarily because the greatest •activity and the most significant developments have been there. Eastern Canada exploration and development operations were at a slightly higher level than in 1950."

Jan 1, 1952

By J. G. Patterson

"The depressive action of sodium cyanide on chalcocite has been investigated and found to be unstable. Flotation results show that with the addition of sodium cyanide to the system chalcocite is initially depressed but rapidly recovers with time, provided there is sufficient oxygen present.lt is proposed that the unstable depression is due to the reaction of cyanide with adsorbed xanthate and copper ions at the chalcocite surface to form soluble copper complexes. When all the free cyanide has so reacted, xanthate anions can then re-adsorb on the chalcocite surface and the flotation will recover. Results are presented to verify the the above mechanism."

Jan 1, 1968

By E. Y. Carlson

"IN A SHORT PAPER it is impossible to do much more than to list the industrial minerals found in Saskatchewan and to give a brief description of the activity associated with each. I will not attempt to discuss the geology. It is sufficient to say that the settled part of the Province is covered by glacial drift which varies in thickness from a few feet to several hundreds of feet, and that this has hindered the search over much of the Province.CLAYA notable exception to this is the Cypress Hills area in the southwest corner which did not suffer any glacial action and where we find some of the large exposures of Cretaceous clays. In this area, the majority of the deposits are of stone-ware clays which are •an excellent raw material for such products as face brick and sewer pipe. Although the clay cannot be transported over any great distance it is used extensively in Alberta and Saskatchewan in the production of these products."

Jan 1, 1959

By Marc-André Villiard, C. St-Onge, V. Silla, J-C Milot

Rio Tinto Fer et Titane (RTFT) operates a metallurgical complex in Sorel-Tracey, Canada. In the Ore Preparation Plant (OPP), ilmenite ore is roasted through four parallel rotary kilns generating 95% of the plant wide sulphur dioxide (SO2) emissions. RTFT proactively set an annual emission cap for SO2 to be achieved by 2015. To achieve this targeted SO2 reductions, a technology evaluation and selection exercise was carried out, followed by detailed engineering and implementation. After a detailed evaluation of SO2 scrubbing technologies, the Circulating Dry Scrubber (CDS) system was selected as the most appropriate desulphurization system for this application. The system was implemented and commissioned from 2013 to 2015. General performance testing conducted in May 2015 demonstrated that the system achieved and surpassed the anticipated design values in terms of SO2 removal efficiency and hydrated lime utilisation. This paper summarizes the SO2 technology selection process, design features of the selected technology, project implementation and final performance testing of the SO2 abatement system.

Jan 1, 2015

By E. Barsky

"Theoretical notions of mass transfer processes in cascade separation of bulk materials have not been adequately developed as yet (Barsky M.D. 1980). In this paper we have derived linear difference equation of the second order for a cascade with initial feeding top any stage proceeding from mass exchange regularities. The solution of these equations has allowed us to determine quantitative dependences of the material distribution over the cascade stages, which serve the basis of the method of predictive estimate of the process results. We have also examined the model of the material distribution coefficient formation at individual cascade stages.We have checked the adequacy of this model to experimental data. It is noteworthy that the obtained theoretical results are phenomenological, i.e. they can be applied to the processes of separation of different physical nature, e.g. of isotopes, liquid media, gases, etc.INTRODUCTIONRecently, the processes of cascade separation of bulk materials have found broad application in various industries. They ensure a high separation efficiency and high-quality composition of final products. Although specialized literature gives serious attention to cascade processes [1], their theory is not sufficiently developed yet. To achieve optimal organization of this process, we examine mass transfer in a cascade gravitational classifier with stages of identical design."

Jan 1, 2016

By M. Piche

The western part of the Hauy Formation of the Opemisca Group, occurring near the town of Chapais, is described in this paper. As it has been defined previously, the Formation is composed of a succession of subaerial andesi tic lava flows with some interbedded proximal volcaniclastic sediments. Towards the East, these volcanics yield to coarse grained fluviatile sediments having similar composition to the interbedded lavas. Further east, the composition of these sediments is more arkosic with dioritic and tonalitic fragments. It is proposed that these arkosic sediments are a part of the Stella Formation which has been described by Dimroth et al. (1982).

Jan 1, 1984