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By R. L. Grayson

"Compliance standards for respirable dust, which are reduced because of high quart: concentrations, have become an industry-wide problem. Research on the physical and chemical character of quart-classified particles in respirable coal mine dusts indicates that they may exist in intermixed layers or may be coated by clay or coal material. The relative amount of intermixing varies with the coal seam being mined. If most of the quart: particles of a mine dust are ""pure,"" then the dust may have a high fibrogenic risk potential because of truly free silica and the compliance standard should be lowered. lf, however, quart: is locked inside another material matrix, or coated, a reduced compliance standard may not be appropriate.Although much research has been done on coal workers' pneumoconiosis (CWP) over the past decades, the etiologic agents of the disease still have not been pinpointed. The predominant methods of characterizing respirable coal mine dusts were bulk analysis techniques for determination of elemental and mineralogical concentrations, the results of which were used in statistical analyses to determine relationships between dust composition and the occurrence of CWP. These methods are incapable of finding the etiologic agents in the dust primarily because of complicated and confounding physiochemical factors, which may be discovered if the focus of characterization was done on a dust particle level.The SEM/EDXA-based research discussed here shows a significant difference in the number of ""pure"" quartz particles in respirable dusts collected from different mines. Some of the results have been reported previously (Grayson, Andre, and Simonyi, 1988). Concurrent research by other investigators (Wallace et al., 1989) demonstrates an SEM/EDXA-based methodology to pinpoint the location of the ""contaminating"" substance(s ) in a quartz-classified particle. The research of the European Economic Community has also begun analyses on the respirable-dust-particle level (Robock and Bauer, 1988).Since the compensatory and intangible costs of CWP are substantial in the United States, it is important that the etiologic agents be determined and then either controlled or neutralized in a cost-effective way. This line of research is especially important consid-ering the forecasted. near-term growth of coal production and the evolution of high productivity longwall panels (an immediate problem in compliance) and continuous mining sections ( a probable future problem).This need has been accentuated now that nearly all respirable dust samples submitted to MSHA are analyzed for free silica (Tomb, Parobeck, and Gem, 1986). Today a real problem exists in the coal industry, both underground and surface, because of high quartz levels in respirable dusts causing substantially reduced compliance standards (Murphy, 1989).The combined results of the respirable dust particle investigators indicate that conventional bulk sample analyses may not faithfully represent the amount of biologically available or active quartz in all mines with a high level (greater than 5% ) of quartz in the dust For example, some mine dusts might contain predominantly occluded (or coated) quartz particles where bulk analysis would result in anomalously high ""free silica"" measurements. The same result would occur when quartz particles are intermixed substantially with other minerals that can alter the surface of the composite particle away from a quartz-behaving character."

Mar 1, 1992

By Wilbur I. Duvall, S. L. Windes, Leonard Obert

"Previous investigations, too numerous to be listed in entirety, have been performed to determine the physical properties of rock. When considered according to their objectives, most of these investigations can be grouped as follows: First, the geologic group (1,2),4/ in which the purpose was to obtain information on the physical properties of the rocks that make up the earth's crust. Particular emphasis has been placed on the determination of the elastic constants--that is, Young's modulus, the modules of rigidity, and Poisson's ratio – as these quantities determine the propagation characteristics of seismic waves. Second, the structural properties group (3 - 11), in which the physical properties of architectural or monumental stone, concrete and aggregate rock, road blocks (cobblestone), and the like were desired. The tests have been quite general and include, besides the elastic properties; the compressive and tensile strength, and the toughness, hardness, and weathering properties of many types of rocks.To .a lesser degree, investigations have been carried out to determine the physical properties of mine rock. A few reports (12 - 14) present data on the crushability and grindability of mine rock, and a large number of papers discuss grinding and crushing procedures and methods of analyzing the data (for example, see references 15 - 17). Some of the latter group also have given the results of tests on mine rock; however, comparatively few include an adequate petrographic description or information on other physical properties of the rock. A few papers,(18 - 22) have reported studies of the strength of rock specimens in respect to the strength of parts of mine structures, such as pillars, roof, arches, etc. Other papers (23 - 26) have discussed investigations on such subjects as primary and secondary crushing, diamond and pneumatic rock drilling, explosive breaking and shattering of rock, rate of drifting and miring, and other allied problems. The majority of these reports have given no more than a cursory, description of the rocks and have included no statement regarding the physical properties. When statements have been given regarding the physical properties, they have usually referred only to isolated tests, making correlations between variations in the physical properties and variations in the .test under consideration difficult, if not impossible. Some reports have included handbook values on such characteristics as the crushing strength, hardness, and toughness. This practice is not satisfactory, because these values are usually given for col¬lective types of rocks, such as granites, limestones, and marbles, and it is known that the variations of the physical properties within these groups is often larger than the differences between the groups."

Aug 1, 1946

By Fraser M. Walsh

The objective of this program was to determine by laboratory experiments the kinetics and mechanics of the reactions that produce acid in coal mine drainage. The program was divided into three phases: In Phase I, five coil mines, representative of Appalachian coal mines, were chosen for sampling and an experimental design was identified suited to accomplish the program objectives. In Phase II, the five mines were sampled and test protocols applied. The results showed most pyrite weathering to be based on oxidation in the presence of water. Iron bacteria, especially Thiobacillus ferrooxidans, catalyzed the rate of pyrite weathering by a factor of three. An increase in initial iron concentration in a system that modeled the nine environment acted to inhibit bacterial catalysis of weathering. In Phase III, five tailings piles were sampled and the material obtained was used to evaluate this method of bacterial catalysis inhibition. The evaluation verified method effectiveness; inhibition of over 80% of the release of weathering products was observed.

Jan 1, 1982

By Hylton R. Brown

This publication, an abstract of a progress report covering an investigation of hazards in thermal coal-drying plants has been prepared according to the suggestions and recommendations of a committee6/ appointed by J. J. Forbes, Director of the Bureau of Mines, when the original report was reviewed at a meeting of representatives of the mining industry, operators of coal-drying plants, coal-mine workers, and the Bureau in Washington on May 6, 1955. The investigation on which the report is based was made in accordance with action taken at a previous conference in Washington on May 19, 1954, called by Director Forbes to consider what should be done to prevent explosions and fires in coal-drying plants. Scope of Investigation The investigation was planned to obtain information considered essential for properly appraising fire and explosion hazards in different types of coal driers. A questionnaire sent to Bureau personnel provided preliminary information on coal-drying facilities at more than 270 preparation plants. Information on methods used in operating different types of driers, with their furnaces, fans, cyclones, and other auxiliary equipment, was obtained by personal visits or conferences with the operators at 13 plants. Factual data on operating temperatures, composition of the drying gases, air flow, dust loading of the air or gas currents, use of water sprays, auxiliary air controls, and other factors were obtained by conducting full-scale tests at six different plants and making laboratory investigations with samples of dust and gas collected during the tests.

Jan 1, 1956

By Warren Hastings

This paper describes the methods and costs, in units of labor end materials, of sinking a 7 compartment vertical shaft 1,261 feet through a fractured, water-saturated formation. The shaft, designed for hoisting 2,500 tons a day, is at Friedensville, Lehigh County, Pa., approximately 6 miles south of Allentown and Bethlehem. It was sunk by the E. J. Longyear Co. under contract to the New Jersey Zinc Co. Preparation for shaft sinking W8A begun July 1, 1947, and sinking was completed August 18, 1952. A total of 604,858 man hours was required to sink the shaft.

Jan 1, 1954

By R. D. Brown

This Bureau of Mines report describes a new methodology for identifying and sorting scrap metals using two modern portable instruments: a thermoelectric sorter and a hand-held emission spectroscope. The method, tested on a 27-sample stainless steel and superalloy array, makes it possible to group and/or identify a typical mixture of high-value metal scrap in two or three steps, whereas as many as seven or eight steps are needed to perform the same separations using chemical spot tests. A portable fluorescent X-ray analyzer identified 19 of the 27 alloys in the sample array by name or type; these alloys are included in the microprocessor memory. The remaining alloys were identified by using the analyzer in its elemental analysis mode and comparing the results wit.h alloy specification chemistry.

Jan 1, 1984

By Robert R. Perron

The U. S. Bureau of Mines is engaged in many diverse programs for improving mine safety. Of particular interest to the Bureau are new and improved means for minimizing the hazard of fire which can be initiated by prolonged low energy electrical faults on trolley line systems. When a high energy fault occurs on a trolley line, wherein the current exceeds the magnitude normally drawn by legitimate loads, such as locomotives, then the circuit breakers at close-by power rectifier sets trip. Tripping of the breakers not only protects the equipment at the rectifier sets, but also disconnects the energy source from the fault and thereby minimizes the fire risk. However, the fault current is frequently of a level substantially below that required to trip the overload breakers. When the fault is a substantial percentage of the set level of the breakers, the energy dissipated by the fault is frequently sufficient to clear the system by rapidly burning itself clear. Such a fault is often short-lived and does not present as serious a fire risk hazard as a prolonged, much lower energy fault, wherein the energy level is too low to clear the system. The breakdown of a trolley line insulator, in which there was a 15 to 30 ampere fault to ground, would represent such a fault or illegitimate load and a substantial fire risk.

Jan 1, 1975

By C. R. Kuzell

This paper, describing the concentrator practice of the United Verde Copper Co., is one of a series being prepared by the Bureau of HISTORY The United Verde concentrator was constructed in accordance with recommendations based on certain novel reasons which were quite different from those usually justifying the expenditure of such an amount. Concentrator operations started in March, 1927, although the metallurgical staff had considered for several years the eventual addition of a concentrator department.

Jan 1, 1930

By Thomas M. Barczak

This U.S. Bureau of Mines report is intended to assist coal mine operators in the selection of longwall supports by providing advanced guidelines for performance testing and standardized test documentation to facilitate support comparisons. These advanced guidelines culminate in a series of proposed tests to evaluate (1) support resistance characteristics, (2) stiffness characteristics, (3) leg mechanics, (4) stability, (5) load transfer mechanics, and (6) structural integrity. The Bureau has conducted extensive studies on shield mechanics to identify boundary conditions that induce loading in support components, which is often not included in current testing techniques. This report discusses influential parameters that affect support behavior and provides insight into how components are loaded and what conditions produce the most severe loading. Testing philosophies and techniques in both active and static frames are discussed. Proper methods for determining support resistance are described and instrumentation requirements for advanced performance testing are provided.

Jan 1, 1989

By Michael J. Beus

This Bureau of Mines report describes a field experiment involving the sinking of two test shafts to directly compare the deformational behavior of circular and rectangular shapes. Results show that the circular shape is less sensitive to geologic discontinuities and applied stress field. Also, the rectangular shape is subject to a variety of behavioral modes, including beam bending and buckling. Geologic discontinuities around circular and rectangular shapes influence displacement significantly. Simple, two-dimensional elastic finite-element modeling, simulating circular and rectangular shapes in a biaxial stress field, shows that the structural response of a shaft is largely controlled by geologic structure. Consideration of anisotropy may be required for realistic analysis of a deep shaft.

Jan 1, 1985

By G. L. Humphrey

Although thermodynamic data for ferrous oxide are among the most important in extractive metallurgy, adequate values have not been available until quite recently. The older data suffered not only from the usual experimental difficulties but especially from lack of the knowledge that ferrous oxide of stoichiometrical composition does not exist as a single, thermodynamically stable crystalline phase under any circumstances. This paper reports new experimental data on the heat of formation of ferrous oxide by two methods (combustion calorimetry and solution calorimetry), employing material of unequivocal composition. The results are compared with values obtained from data for the hydrogen reduction, carbon monoxide reduction, and disproportionation reactions of ferrous oxide, and a best value is selected. A table of heat and free energy of formation values of ferrous oxide to 2,000°K is given. These values are combined with available data for water, carbon monoxide, and carbon dioxide to obtain theoretical heats and free energies of reduction corresponding to the selected heat of formation. Hydrogen and carbon monoxide reduction equilibria are compared, and the differences in trend with temperature and the percentage utilization of the reductants are considered.

Jan 1, 1952

By D. J. MacDonald

The Bureau of Mines has conducted bench-scale investigations leading to the design of an integrated process for producing reactor-grade zir-conium oxide (Zr02) from zircon sand, which avoids the air pollution, water pollution, fire hazard, and odor problems associated with the hexone-thiocyanate process. The integrated process consists of three steps: production of crude zirconyl sulfate solution, solvent extraction, and production of Zr02 from strip liquor. This report describes the solvent extraction step. Multistage, countercurrent liquid-liquid extraction with a tertiary amine in kerosine was used to separate zirconium from a dilute H2S04 solution containing hafnium and other impurities. Process steps de-scribed include extraction from an aqueous feed solution to form a hafnium-contaminated, zirconium-bearing organic-phase solution, scrubbing to separate zirconium from coextracted hafnium, stripping to transfer hafnium-free zirconium into an aqueous strip liquor, chloride-loading to produce a chloride-bearing organic solution, scrubbing with the chloride-loaded organic solution to remove traces of uranium impur-ity from the zirconium-bearing strip liquor, and regeneration to pre-pare the organic solution for reuse. These steps were performed simul-taneously in steady-state, bench-scale experiments. Zirconium recovery of up to 93 pct was achieved. Results of an economic evaluation are included.

Jan 1, 1984

By M. Kawahata

Methane sensors using principle of catalytic oxidation of methane are employed for determination of methane content in ambient air of coal mines. Certain foreign gases or vapors in the air poison the catalyst of the sensor effecting the sensor's response. After literature search of poison compounds of Pt and Pd oxidation catalyst, experimental studies of catalyst poison kinetics were made for three siloxane compounds, tributyl-phosphate, monobromotrifluoromethane, and hydrogen sulfide, selected as poison vapors. Concentration range of the poison vapors was varied in a range from 3000 to 0.1 ppb (v/v). Three siloxane vapors produced strong catalyst poison effect, followed by tributylphosphate, hydrogen sulfide and monobromotrifluoromethane for the high concentration level of the poison vapors. The poison effects are influenced significantly by concentration of the vapors. Threshold poison vapor concentrations where effect of the poison vapors on the sensor is minimal were determined experimentally. Experimental studies were made further for prevention method of catalyst poison by adsorption techniques. Use of activated carbon cloth inserted on the sensor's head prevented catalyst poisoning efficiently.

Jan 1, 1981

By W. R. K. Wu

Results of linear correlations of two to four variables by the least-squares method are presented. The variables include 63 parameters representing coal composition, coal plasticity, and coke strength. The composition parameters are on chemical analyses; the plasticity parameters, on three plastometer and dilatometer tests and four miscellaneous tests; and the coke-strength parameters, on three ASTM indices. Seventy-two to eighty-four plastic coals were used in the plasticity and carbonization tests, which together form the basis of this report; 43 nonplastic or weakly plastic coals were used in the coal-band studies. Plots of relations between volatile matter, carbon, and oxygen contents of 1,860 U.S. coals and the 84 coals used are shown. Similar plots between volatile matter and hydrogen or atomic H/C of the 84 coals are also included. Significances of regression coefficient signs for coal composition parameters in the significant correlations found are discussed. Based on these significances, the following relations are shown: (a) coke strength versus average aromaticity, or mineral matter content, of the parent coal; (b) characteristic temperatures of the plastometer and dilatometers, the free-swelling index, or the Gray-King type versus average hydroaromaticity of the coal; and (c) nontemperature parameters of the plastometer and dilatometers versus the physical properties of a certain group of compounds from thermal decomposition of coal. Similarly, significances between the positions of coals in the coal band and the aforementioned relations are also discussed. A structural theory of coal plasticity is proposed. Applications of the correlation results are discussed. Composition parameters, such as carbon, atomic H/C, and calorific value may be used as a basis for selecting coking coals for stronger coke. Plasticity parameters, such as the end temperatures of the plastometer and dilatometers and the free-swelling index, may be used for the same purpose. Based on the best correlations found, coke-strength indices may be estimated to within 4 to 8 units of the observed values; the end temperatures of the plastometer and dilatometer tests, 5° to 10° C.; and the free-swelling index, within 1 unit. Accuracies of all these estimated values are examined, based on the experimental errors of the data involved. Finally, estimations of plasticity parameters from one test with those from others are shown.

Jan 1, 1971

By C. H. Fisher

[Mxny methnhs of ,analyzing tpr oils fnr thoir tar acid ~nd base cnntent hava boon employL~d in connection mith both ac~d,.mic and. industrial investigs- tions. Mnst of thznu nnalyticel proc?durn~s aro bpsed nn th; diminution in volums caused by extract lon sit5 alkali 5 minL+ra,l acids (cantrsction rn,>thod) , although othrr mr~thrids havu &apos;sL<on ?q~lnglt 8 . In many instmccs th-: donti ti on of RT~ m~lytic~l m ithod was not ;r.:c ~d~d by ~d.jqunt9 study, and, ns 3 cone+ qucnce, tha lit .,ratur ? on thls sub,jr:.ct is consoScuous for its cnntr~dictnry . claims and rocnmmondatinna.. 1.t tiR.s b9~n shoyn in th;, cnsn of c.lrtn.in synth?tic solut innsfi/ thnt larg~ jr-orn sny rcsult if th2 ,mnlysis is c~rri~d out by sim~la extraction wi.th alidi r.nd min 3rd ncids.]

Jan 1, 1937

By C. H. Fisher

[Many methods of analyzing tar oils for their tar acid and base content have bun employed in connection with both academic and. industrial investigations. Most of these analytical procedures are based on the diminution in volume caused by extraction with alkali and mineral acids (contraction method), although other methods haves been employed.4/ In many instances the adoption of an analytical method was not preceded by adequate study, and, as a consequence, the literature, on this subject is conspicuous for its contradictory claims and recommendations. It has bin shown in the, case of certain synthetic solutions5/ that large errors may result if the analysis is carried out by simple extraction with alkali and mineral acids.]

Jan 1, 1936

By Alfred Bellows

The objective of this contract is to design, build and demonstrate a support system to improve roof control in the entries of longwall mines. The objective of this phase has been the detailed design of such a system and the selection of a test site in which to perform the pilot demonstration. The result is a complete set of detail drawings or specifications which define the three major components of the system. The Gate Support is a variation of a face chock which has an extended canopy and additional hydraulic legs to protect the region of the face-entry intersection. The Entry Support is a steel beam and hydraulic prop set which is reusable and serves to support the first 100 or more feet of entry inby the longwall face. The Transporter is a bolter-like vehicle with a crane used for installing and retreating the beam sets. The test site selected is CF&I&apos;s Allen Mine in Colorado. They presently use simi¬lar steel beams and expect the FMA support system to be more effective as well as recoverable. It is recommended that the completed drawings be used to build a prototype system and test it first in a remote section of the mine and then in the active longwall tail entry.

Jan 1, 1978

By Willard L. Hunter

The Bureau of Mines studied the effect of temperature upon the reduction of chromite by carbon and the relative reducibility of chromites as a function of their composition. Ferric oxide was also studied to provide comparative data. Pellets weighing approximately 1 gram and containing 70 percent ferric oxide, chromic oxide, or chromite and 30 percent graphite were subjected to closely controlled temperatures under a flow of argon for 15 minutes. The amount of CO and CO2 evolved was measured, and the reduced sample was analyzed by X-ray diffraction techniques. The reduction of Fe2O3 was studied over a temperature range of 600° to 1,400° C, while the reduction of Cr2O5 and chromite was conducted from 9000 to 1,621° C. The temperature above which appreciable reduction of Cr203 by graphite took place was 1,125° C. The temperature at which significant reduction started for three of the four chromite samples was approximately the same, indicating that there was concurrent reduction of iron and chromium oxides in the chromite mineral rather than selective reduction of iron oxides followed by reduction of chromic oxide. Rhodesian chromite appeared to dissociate at a lower temperature with concurrent reduction of iron. Based on the temperature at Which chromite was 50 percent reduced in 15 minutes, Transvaal chromite reduced most easily, followed by Mouat, then by Kampersian, and finally by Rhodesian DFC material. Statistical analysis of test results indicated that the ferric iron content of chromites affects their reduction behavior more than any other constituent.

Jan 1, 1966

By Robert F. Pettit

This paper on methods and costs of mining and milling iron ore at the Iron Mountain mine of Ozark Ore Co., St, Francois County, Mo., is one of a series of Bureau of Mines reports on methods, practices, and costs of mining and milling throughout the United States. The Iron Mountain operation is notable for its successful transition from open-pit to underground mining, for use underground of large earth-moving equipment, and for development of a multilevel room-and-pillar mining method. Milling methods also have undergone transitions - from hand sorting and log washing in the early days to gravity concentration. Milling ultimately may include flotation to recover additional iron from products now discarded as tailing,

Jan 1, 1957

By R. R. Sayers

That the maintenance of proper air conditions is a most important factor in the control of occupational hazards is shown by the large amount of material presented each year through the technical journal's on the effects on workers of injurious dusts, gases, and variations in temperature and humidity.. SUMMARY OF RECENT LITERATURE ON EFFECTS ON WORKERS OF EXPOSURE TO DUSTS The subject of the control of dust and dust diseases continues to be a matter of serious concern in most of the industrial countries of the world, as indicated by the following summary of reports published in a number of foreign countries as well as in the United States. Australia. The Workmen's Compensation Act of 1920 for New South Wales3 provided for the promulgation of schemes for the compensation of workers dis- abled by silica or other dust. In 1924 the prevalence of silicosis and tuberculosis among Sydney stonemasons, quarrymen, sewer miners and rockchoppers was investigated by a Technical Committee of Inquiry, appointed upon the recommendation of the New South Wales Board of Trade. The findings of this committee were published by the Government in 1925. No scheme was promulgated by the Government and in 1926 the Act was amended limiting its scope to workmen disabled by disease caused by silica-dust. This was promulgated and gazetted on September 16, 1927, and applies to men working in sandstone as stonemasons, quarrymen, rockchoppers, and sewer miners in the County of Cumberland.

Feb 1, 1931