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The interaction of flotation collectors with sulfide minerals takes place at the solid - solution interface. The electrochemistry of the processes which affect this interface are discussed. The interaction of xanthates with sulfides is an electrochemical process, xanthates being electro-oxidised to chemisorbed xanthate and dixanthogen. The role of oxygen is to provide a cathodic process to allow the anodic oxidation to occur. The hydrophobic condition of the mineral surface is brought about by the presence of the oxidised xanthate species. The action of reagents which can activate or depress the flotation of sulfides is discussed briefly.

Jan 1, 1971

By F. E. du Plessis

"The distinction between data suitable for process control and data subject to aliasing only becomes quantifiable with the availability of rapid real-time measurements. Expecting the dynamics of flotation to vary for different ore types, process flows and equipment types; a study was conducted to compare the dynamics of different flotation processes. The results shed light on the critical sampling intervals required for process control which in turn allows process stabilization and optimization. The technology used for the in-line measurements is based on diffuse reflective spectroscopy and has been introduced into the mineral processing industry over the past ten years. It has been widely implemented in the sulphide flotation industry in South Africa for the real-time measurement of grade.BACKGROUND AND OBJECTIVE A study was conducted by Du Plessis and Keet (2010) to quantify the minimum sample frequency required for grade and/or impurity control. The study was based on chromite data collected at 15 second intervals from the concentrate line of a flash float cell in the Platinum industry. The data captured the natural process variation of the entrained chromite through water recovery due to changes in feed parameters and flotation performance. It was found that the minimum rate of sampling required from the studied flash float concentrate was 2 minutes. This sampling interval time accounted for 90% of the variance in the process data. It was further found that a sampling interval time of longer than 4 minutes produced data with no significant correlation to reality. The dynamics of the flotation process has been misjudged in the past but can be quantified with the availability of real-time grade measurement based on diffuse reflective spectroscopy. The objective of the study was to compare the dynamics of different sulphide flotation processes through the comparison of maximum sampling interval times required to combat aliasing. All data were collected from single stream analyzers that are currently installed at mineral concentrators. The technology used is based on diffuse reflective spectroscopy."

Jan 1, 2012

Recent developments in diamond drilling practice have been chiefly 'concerned with modifications in drill design and 'operating technique whereby an increase in daily footage rates and reduced footage costs have been achieved without any marked improvements in the recovery of core. This trend is perhaps due to the general acceptance by the mining and drilling engineer alike of the belief that diamond drilling has definite limitations in exploratory work on mineral deposits characterized by irregularities in continuity and grade, such a belief arising from the fact that drilling technique has not yet evolved coring devices to ensure the full recovery of the rock and mineral formations penetrated.Current diamond drilling operations at Moonta and Wallaroo Mines, carried out by the South Australian Department of Mines, have attained remarkable results in completely eliminating core-loss by the use of a special double-tube core barreI.It is considered that assays of borehole samples taken with this special barrel have a reliability comparable, if not superior to that of similarly situated mine samples and, provided they are spaced satisfactorily, can be used as, a basis for calculating tonnage and grade. Formerly, with only partial core-recoveries, positive borehole results on narrow irregular lodes, such as those in the Moonta and Wallaroo Mines, could be accepted mainly as indications of the presence of mineralization, and could have only a limited bearing on estimates of ore reserves.The value of this special double-tube core-barrel lies In the fact that it guarantees good core recovery and, therefore, good samples, and eliminates the need for sludge-sampling, which is prone to give unreliable assay results from several causes, such as gravity concentration in the bottom of the hole and return water losses which cannot be overcome.In view of the increasing demand for minerals and the probability that the search for them will be carried on largely by boring, it is felt that it would be of interest and value to direct the attention of mining engineers to core-recovery results obtained by diamond drilling plants in South Australia and the features of the special core-barrel, designed by the writer, which has made this possible. Also, the writer is desirous of placing on record two other core-recovery devices designed to extract accurate samples in relatively soft or unconsolidated formations. The latter are used with percussion and calyx plants, respectively and their value has been proven on phosphate rock and coal deposits in South Australia.

Jan 1, 1943

By Verya Nasri, Scott Thorburn

The City of Toronto and the Toronto Transit Commission (TTC) have conducted an Individual Environmental Assessment (EA) for a 6.2 km, 4-station underground extension of the Spadina Subway from Downsview Station to Steeles Avenue. This Environmental Assessment Study was performed in three phases including routes and general station locations, alignments and station concepts and detailed assessment of the effects of the undertaking. URS Canada Inc. has led the consultant team for this Study. The anticipated total duration of the project is approximately 6 years and its estimated total cost is about $1.4 billion. This paper presents the planning process of the project, the environmental and engineering challenges, and the measures taken to address them.

Jan 1, 2007

By Thomas M. Gurtowski

The New Pacific Northwest Baseball Park, now known as Safeco Field, is located directly south of the Kingdome in Seattle, Washington, and will be the new home of the Seattle Mariners baseball team. The location of the ball field is shown on Figure 1, Vicinity Map. The seating capacity is 45,600, and outfield distances are 331 feet in left, 405 feet in center, and 326 feet in right field. The overall dimensions of the stadium are 680 by 800 feet. It is bordered on the east by the Burlington Northern Santa Fe Railroad main line. A unique aspect of this ballpark is the retractable roof with a north-south span length of 660 feet. The roof consists of three separate sections that roll on elevated rails running east-west on the north and south sides of the stadium. The soil conditions consisted of near-surface fill underlain with alluvial and Estuarine deposits to depths of 60 to 80 feet. The bearing soils consisted of very dense, glacially overridden deposits. Groundwater is 4 to 7 feet below the ground surface, and the alluvial deposits are subject to liquefaction during a strong motion earthquake.

Jan 1, 1998

By A. A. El-Midany

Traditionally, the choice amongst different upgrading techniques or in finding the optimum operating conditions for a given upgrading technology depends on whether one is looking at the grade or the recovery of the valuable mineral in the concentrate. In fact, the conclusions are not usually the same. This is because the best technique or optimum operating conditions for the highest grade are not the same as the conditions to achieve the maxi-mum recovery. Therefore, a unique measure that takes into consideration both grade and recovery is urgently needed. Finding such a measure is the objective of this paper. A proposed measure provides a selectivity index in the range of 0 to 1, where 0 is no selectivity and 1 is ideal selectivity. The index can be obtained by plotting the so-called Fuerstenau upgrading curve, which relates the recoveries of the components in products of separation and a running regression applying a one-parameter equation. The measure was applied to assess the selectivity of selective flocculation under different operating conditions when used as a sensitive upgrading technique for ultrafine ground ores. After applying the proposed selectivity measure in the case of the selective flocculation of ultrafine Egyptian iron ore without the addition of cations, it was found that the optimum conditions are pH 11, 1 kg/t sodium silicate and 0.4 kg/t potato starch with a selectivity index of 0.55. With the addition of cations, the optimum conditions were found to be pH 11, 1 kg/t sodium silicate and 2 kg/t potato starch with a selectivity index of 0.65. It should be noted that determining these optimum conditions using the traditional grade or recovery measures was highly ambiguous.

Jan 1, 2008

By B. Kahraman

About 70% of the world?s total boron reserves are located in Turkey. Boron minerals are typically concentrated by attrition scrubbing followed by screening and classification to remove clay minerals and other impurities. These wet concentration methods, however, result in a considerable amount of accumulated tailings in large tailings dams. The tailings are approximately 28% solids and contain 14% B2O3. Problems caused by these tailings can be minimized by employing dry beneficiation techniques involving heat treatment. This method has been successfully tested on laboratory and pilot scales. During heat treatment, borax undergoes expansion in volume. The amount of expansion is dependent on the particle size, temperature and duration of heat treatment. Because the optimum temperature and the duration of the heat treatment are not well defined, the boron ore acts as a calcined clay mineral and is discarded along with the gangue. It is important to predict such parameters using mathematical formulations. Thus, a mathematical model is used to predict the required temperature and duration period prior to heat treatment. In the experimental study presented here, a series of systematic thermal tests was carried out in a muffle furnace. Two variables, temperature and time, were studied in a response surface design. A quadratic regression model was chosen and regression coefficients were calculated. Using a regression equation, the volume expansion of the particles in various circumstances can be predicted. The mathematical test results are then correlated with the experimental results to relate the optimum expansion of borax with heating time and temperature and with borax grades and recoveries.

Jan 1, 2008

By K Pery, J Leahy

Established metallurgical plants operate in a complex environment of interdependent drivers including technology change, operating and maintenance practice, evolving markets, HSEC requirements, statutory and plant requirements, personnel turnover, ore supply, and financial conditions, to name a few. A successful optimisation program should comprehend these factors and drive towards not only lower operating costs, but also higher rates of return for a given level of investment. Optimisation programs have the potential for very high rates of return on capital that Greenfield projects rarely have. This paper presents a robust strategy and methodology for plant optimisation initiatives as well as a case study of how it was implemented at the QNI Yabulu refinery in Queensland, Australia by an integrated team of researchers, engineers and operators. The methodology is premised on the fact that nobody knows the production asset as well as the current operating team. It covers the optimisation process from ideas generation, various stages of selection against the agreed criteria, development, including testwork, funding approval and implementation. It highlights the benefits in the use of integrated teams, the establishment of a sound project basis, and a diligent, phased approach.

Jan 1, 2004

By Ian Orford, Peter Radziszewski, Lud Strah

"An autogenous grinding circuit was commissioned at the Brunswick concentrator in October 1998. The AG mill was subsequently converted to SAG operation in May 1999 for a number of reasons. The mill had 48 rows of the NORCAST top-hat integral lifter/liners configured in Hi-Lo mode. A charge motion simulation study, the results of which are the subject of this presentation, was initiated to develop a better understanding of SAG mill behaviour. Using a design of experiments approach, a lifter face angle was determined that would increase mill power draw. Once determined, lifter profiles were modified and installed in July 2001, and a second set installed in February 2002. Resulting changes in mill power consumption are presented.INTRODUCTIONThe Noranda Inc. Brunswick Mine, located near Bathurst, New Brunswick, is a large lead/zinc mine and began milling ore in 1964. The ore is massive sulphide with approximately 20% valuable minerals, 60% pyrite and 20% silicates. In October 1998, an autogenous grinding circuit was commissioned at the Brunswick concentrator (Cooper, Orford, Larsen, 2001).At the time, the autogenous grinding circuit replaced existing surface crushing plants, fine ore storage, rod mills and primary ball mills. The 8.54 m diameter x 4.27 m long (EGL) ANI mill was subsequently converted to SAG operation in May 1999.The mill had 48 rows of the NORCAST top-hat integral lifter/liners and was operated initially with all shell lifters at the same height. Following problems with packing and abnormal wear pattern, the profile was changed to a high-low configuration.Further, it was found that over the life of the lifters, mill power draw and throughput varied considerably. Although a change in mill power draw was expected following lifter replacement (predicted during mill design to be in the order of 300-400 kW), the replacement of the worn lifters with new high lifters resulted in mill power draw decreased by some 1000 kW."

Jan 1, 2003

By Howard Roscoe

Linking Ashford International Station to the new Channel Tunnel Rail Link required over 5000 rotary bored and CFA (continuous flight auger) piles to form tunnel walls and viaduct foundations and to support overbridges and trackside barriers.. Much of the work was carried out close to the existing railway infrastructure. Plunged columns were used to maintain traffic flows over the tunnel site during construction. The results of an extensive programme of vertical and lateral load tests on bored and CFA piles in heavily overconsolidated Weald Clay are compared to illustrate the relative importance of stress relief and of prolonged exposure to bentonite. The completion on schedule of this major piling and ground engineering contract (value £30 million) demonstrates that collaborative working in partnership produced cost effective solutions to a series of challenging technical and logistical problems.

Jan 1, 2002

In dealing with the pulverization and treatment of auriferous ores, it may be stated that there is not one system of treatment applicable to all classes. In the southern portion of New Zealand the ores generally contain free gold, with scarcely any impurity that is, it is found in an almost pure state, without any alloy, and its dissemination amongst the matrix is generally in tolerably coarse particles. The only difficulties the mill man has to contend with, are the economical concentration of pyrites, which in some of the lodes are rich in gold, and the extraction of the gold the pyrites contain. In some of the lodes there is what may be termed float gold, that is, the particles of the precious metal are so finely divided that it passes over the quicksilver tables, and, unless there are other appliances for saving it, this class of gold is entirely lost.Indeed it is only within the last five years that any attention has been given, in the southern portion of the colony, to saving the fine gold that has passed the amalgamating tables. In the North Island the ores are very complex there are scarcely two mines, although they may be adjoining each other, where the bullion is of the same character. On every field the gold is alloyed with silver', and in combination with other metals and mineral substances, such as copper, zinc, antimony, galenfl, iron, sulphur, arsenic, etc., and, in some instaaces, cinnabar, as in the case of the Champion lode at Tui Creek, Te Aroha. Ores of this class are extremly difficult to treat satisfactorily.

Jan 1, 1903

By Cristhian C. Mendoza, Renato da Cunha, Bernardo Caicedo, Max Barbosa

"Abstract This paper shows that a raft alone is not sufficiently appropriate to address the uncertainty of underlying soil variability; therefore, a piled raft system is a better option for mitigating such uncertainty. To study the variability of soil, the behavior of the Piled-Raft Foundation was analyzed with a type of self-drilling micropiles: the ""Alluvial Anker"" (common name for this pile type in Brasilia city). These micropiles have been used in the city and have the advantage that the drill pipe also serves as reinforcement. The studied parameters belong to an elastoplastic constitutive model for strain-stress analysis of soil; variability of these parameters can be intrinsic and/or epistemic. Simulations were performed for a hypothetical Piled-Raft Foundation subjected to vertical loading using the random finite element method. The average parameters of the constitutive model were obtained through laboratory tests. The simulations of the load test were compared with results of a real scale experimental test conducted exclusively for this work in the field. It is analyzed the relative importance of the variability of some geomechanical parameters and their variation with depth is considered. In addition, it is discussed a comparison between the uncertainty of the geomechanical parameters and the uncertainty of the results of the vertical loading test. Finally, this paper shows that a decrease of the safety factor may occur when taking into account the variability of the parameters.IntroductionBrasilia is located in a highly weathered residual tropical soil (lateritic & latossol on pedogenetic concepts). This soil presents high content of alumina and iron due to the lixiviation process of the upper layers. As a consequence, the cemented structure is highly unstable and it can generate strong changes of volume (i.e. collapse) due to changes in both moisture and state of stresses. Therefore, a greater understanding of the construction of Piled-Raft Foundation systems on this particular soil conditions is needed – especially because it covers more than 80% of the surface area of the Brazilian Federal District.Thereafter, this work investigates the influence of the variability of the soil parameters over the uncertainty of the Piled-Raft Foundation design. The studied parameters belong to an elastoplastic constitutive model for strain-stress analysis of soils. The simulations were performed for two hypothetical Piled-Raft Foundations subjected to vertical loading by using the stochastic finite element method. The results were compared to real load tests in Piled-Rafts with “Alluvial Anker” pile types."

Jan 1, 2014

Permian coal seams from the Tomago Coal Measures in the Northern Coalfield, New South Wales, were analysed petrographically and reflectance measurements made for each. Vitrite contents were moderate to high for most of the coals but for two they were very low.The mineral-matter contents were low to moderate by Australian standards. Different profiles of a particular seam could be correlated by petrographic methods.Standard seam profiles were drawn up and from these an idealized Tomago seam sequence was compiled. All the coals were of high-volatile bituminous rank. Their carbon contents, but not thcir reflectances, varied significantly with the quantity of vitrinite present.

Jan 1, 1968

By Bradshaw, Y. S. Cho

The size of bubbles plays an important role in flotation. Equations used to calculate the size of bubbles all show the effect of liquid/gas surface tension. However, the surface tension does not change much with frother concentration and experiments conducted using single capillaries (or single-hole spargers) do not reveal any clear effect of the frother concentration on bubble size. The size of bubbles does, however, strongly depend on frother concentration when multi-hole spargers are utilized (or when measured in a flotation cell); at low frother concentrations the bubble size is much larger indicating coalescence as a main mechanism determining the size. Coalescence can be prevented at frother concentrations exceeding the critical coalescence concentration (CCC), which in turn was found to be interrelated with the dynamic foamibility index (DFI).

Jan 1, 2001

Interest in those physical properties of minerals which might be used to good effect in prospecting is not new. Early in the nineteenth century attempts were made in th'e Cornish mines to measure the natural electric potentials set up by chemical changes proceeding in the lodes. The distortion of the earth's magnetic field by bodies of strongly magnetic iron ore received early recognition in Sweden. Treasure-finders, working on the principle of electrical induction, appear to have been invented about eighty years ago, though were probably not then applied to mineral exploration. By the end of the nineteenth century Eotvos, a Hungarian physicist, had constructed a highly sensitive type of torsion balance capable of measuring the minute distortions in the earth's field of gravitation resulting from variations in the density of the materials composing the crust. During the first decade of this century he demonstrated its value in tracing rock-salt deposits in virtue of their low density compared with the surrounding rocks. Geophysical prospecting began to be recognised as having a very definite value and its development gathered momentum. Its great expansion took place after the 1914-18 war, when its value in oil exploration was amply demonstrated, and this expansion has continued to the present time and shows no signs of abating.Divisions of Applied Geophysics.The four main divisions of applied geophysics are electrical, magnetic gravitational and seismic. With the importance of ores of radio-active metals, one might add to these a radio-active division. The first two are more important to the field of mining, but techniques based on gravitational attraction have their uses in particular cases. Seismic methods are not generally suited to the exploration of metallic ores, but have proved of enormous value in the search for petroleum. With vast quantities of oil as the prize, more money has been lavished on the deve10pment and practice of these methods than on all the others put together.Geophysical Prospecting Methods.Geophysical prospecting methods may be used to detect a mineral deposit directly in virtue of differences in the intensity of some physical attribute common to it and the enclosing country rock. Examples of this are the detection of rock-salt by gravity measurements, or of iron ore by magnetic methods. Of much wider application, however, is the indireot approach in which the aim is to determine, by geophysical means, the geological structures controlling the disposition of mineral deposits. These structures may be partly known from geological work, in which case geophysical methods are useful adjuncts. Where, because of an 'unbroken cover of overburden, no useful geological information presents itself, scout drilling or geophysical prospecting are the only alternatives. Overburden is here intended to mean any covering material not, involved in the structures controlling the mineral deposits. Prospecting for petroleum amounts to the detecting of favourable reservoir structures, and as the chief types of such are the same the world over...

Jan 1, 1950

By S. Prasad

The effectiveness of ultrasonic velocity measurements and attenuation of the propagating pulse was evaluated as a means of Non-Destructive characterization of cold worked and annealed copper. Commercial copper is subjected to mechanical working such as forging, rolling and thermal treatment to induce re-crystallization. The microstructural changes that occur in copper and a variation in its mechanical properties are subjected to analysis using the ultrasonic technique. The signal processing is carried out using the wavelet analysis technique. The features of wavelet analysis namely, localization in space and the presence of an infinite set of basis functions allows removing noise from the time series and components of a non-stationary signal to be analyzed. This is seen to improve the accuracy of the results obtained from the ultrasonic technique in the case of copper, which has distinct coarse grains that are difficult to inspect due to backscattering from the grain boundaries.

Jan 1, 2010

By Enrique Castells

La extracción del mineral es el método más habitual para la explotación minera y se realiza a través de rampas, galerías, y túneles que permitan el acceso hasta la zona de minado. Sin embargo, cuando se da una excesiva profundizaciión del terreno, se emplea el método de pique vertical ya que logra el acceso de los operarios a las zonas más profundas de un modo más rentable y rápido a través de la extracción del mineral por izado de vagones o skip hasta el de nivel de superficie o intermedio. Por ello, es común que las minas replanteen la sustitución de su sistema de extracción habitual por el de izado por piques. En este sentido, el presente trabajo desarrolla la aplicación de los piques verticales en los sondeos de exploracion de la mina Hullera Vasco Leonesa. La primera parte del proyecto describe la ejecución de dos piques verticales (Aurelio y Emilio del Valle), y la segunda, en la ejecución de más de 17.000 m de galerías y obras de infraestructura de diversa índole.

Sep 13, 2001

By Brendan Demich, Brendan Macdonald, Timothy J. Orr, Jason Navoyski, Jennica L. Bellanca, William J. Helfrich

Recent advances in computing, rendering, and display technologies have generated increased accessibility for virtual reality (VR). VR allows the creation of dynamic, high-fidelity environments to simulate dangerous situations, test conditions, and visualize concepts. Consequently, numerous products have been developed, but many of these are limited in scope. Therefore, the National Institute for Occupational Safety and Health researchers developed a VR framework, called VR Mine, to rapidly create an underground mine for human data collection, simulation, visualization, and training. This paper describes the features of VR Mine using self-escape and proximity detection as case studies. Features include mine generation, simulated networks, proximity detection systems, and the integration and visualization of real-time ventilation models.

By Mann V. I

The Mount Isa property has been in operation since June, 1931; during this period operations have changed from the production and treatment of carbonate ores to the mining, milling, and smelting of sulphide ores. This change involved revision of ore-extraction methods.Stoping methods have been designed to apply to parallel lodes ranging from 10 ft. to over 100 ft. in width and dipping at 50° to 60°. The hardness and strength of the ore and enclosing wall rocks, together with the strength and thickness of the country rock between lodes, have permitted the selection of a sub-level stoping method for mining the sulphide ores.

Jan 1, 1938

By H. Antrekowitsch

The decreasing quality of the input materials in copper recycling leads to a higher content of impurities in the anode copper. An improvement of the pyrometallurgical refining process is therefore necessary to produce high quality anodes for the copper refining electrolysis. The behaviour of the most important accompanying elements (e.g. nickel, tin, lead, zinc etc.) at different reaction conditions has to be investigated in order to improve the metal/slag reactions as well as the vaporisation by selective oxidation in the anode furnace. Therefore the thermodynamic conditions like reaction order and the activity coefficients at the copper refining process have to be known for the optimisation of this technique. Additionally the interaction between different elements has been investigated as a function of the temperature, the content of the elements and the slag composition especially for nickel. These investigations were done at the Christian Doppler Laboratory for Secondary Metallurgy of Nonferrous Metals.

Jan 1, 2005