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Minerals similar to the indicator minerals used in kimberlite exploration are widespread in the Cainozoic alkali basalts of north Queensland. Magnesian ilmenite, pyrope garnet, chrome diopside, chrome spinel, phlogopite and zircon were recovered from most of the localities examined. The occurrence of these minerals creates significant problems when indicator minerals are used for diamond exploration. Basaltic ilmenite is visually similar to kimberlitic ilmenite. Untransported grains are rounded and have pitted surfaces. Basaltic ilmenite grains often have exsolution lamellae and reaction rims of titanomagnetite. Although kimberlitic and basaltic ilmenite are chemically similar, basaltic ilmenite grains are usually less magnesian than their kimberlitic counterparts. Basaltic ilmenite contains very little Cr203. Pyrope garnet occurs as megacrysts and in a variety of xenolith lithologies in north Queensland basalts. Most basaltic garnet is Cr-poor and comparable with kimberlitic garnet from Groups 3 and 5 of Dawson and Stephens (1975). Wine-purple, chrome-bearing garnet is common in kimberlite but rare in basalt.

Jan 1, 1984

The operation of quarries for the production of crushed stone and aggregates, depends heavily on rock blasting efficiency, which usually represents a major share of total production costs. After investigating the causes of this situation, a series of technical aspects have been detected, and they are described for the purpose of contributing to the minimization of costs, which also reduces the effects of blasting on the environment. Utilization of empirical design methods, of inadequate explosive types, and of erroneous drilling pauems with respect to rock properties, are the main factors to be corrected, as a consequence of poor engineering criteria, with scarce use of computational methods and field instrumentation. Several concepts of blasting optimization are pointed out, and their application to industrial operations in a Portuguese limestone quarry indicated clear trends for the reduction of production costs, as well as some of the deleterious consequences of blasting on the environment.

Jan 1, 1990

By Hayes J. A

The satisfactory ventilation of an extensive coal mine is a subject which requires continual attention from all concerned.It must be remembered that a colliery contains many miles of workings, extending in all directions and throughout which noxious gases may be given off either naturally or by oxidation of the coal; fumes from explosives will be produced, dust will be gathered and carried in suspension, and water will be evaporated, producing a high humidity. Hence a considerable quantity of air in movement must be available to provide sufficient oxygen for men and horses, as well as to dilute and sweep away impurities, and maintain a tolerable degree of coolness.To maintain these conditions a modern colliery is divided up from the main ventilation shafts or adits (as the case may be) into a system of main airways, and in the working districts is further subdivided into district splits. To initiate the air movement, large centrifugal fans with a displacement capacity of up to 400,000 cu. ft. of air per minute are installed, generally in drifts off the upcast shaft, or adit, and at the return end of the ventilating circuit. These fans are thus exhausting fans and by producing a region of low density bring the heavier air at the other extremity of the circuit into movement to correct the difference in density, so far as it is not prevented by the frictional resistance of the airways. A flow of air is thus established, and it is obvious that to enable this volume of air to be as great as possible, the frictional resistance of the mine airways should be maintained at the lowest practicable figure. To this end, main airways should be as large as possible, have sides as smooth as practicable, and be straight, any necessary bends being of large radius.REQUIREMENTS OF THE VENTILATION SYSTEMThe New South Wales Coal Mines Regulation Act contains stringent provisions on requirements of the ventilation system. The main points are expressed in the following extracts:"In every mine which is in operation, unless a certificate of exemption from compliance with this rule has been granted by the Minister, whether any person employed therein shall be...

Jan 1, 1947

By B Arthur, K Sexsmith, D Hockley, S D

At the proposed Crandon Project, mill tailings would be depyritised for upland disposal. The resulting pyrite concentrate would be disposed of in the underground workings as a cement-amended paste backfill. In the long term, the underground workings would be flooded and the potential for the paste backfill to generate acid would be limited. However, while the mine is operational, there is potential for oxygen ingress to the backfill that may lead to sulfide mineral oxidation and acid generation. A series of humidity cell tests were completed to assess the potential for groundwater contamination. To assess effects of surface area on oxidation, the humidity cell tests were conducted on moulded cubes of paste backfill. The tests were terminated at different intervals, and the cubes were dissected and examined mineralogically. Various leach extraction procedures were also used to assess the progress of oxidation and secondary mineralisation within the paste backfill. The test results showed that: the cement amendment significantly contributes to acid neutralisation and results in a lag in excess of one year before the onset of acidic conditions (in comparison to less than three weeks for the pyrite concentrate); the depth of oxidation in the paste backfill is restricted to about 1 mm after 107 weeks of testing; and secondary minerals form a distinct ærindÆ at the surface of the paste backfill. The results indicate that acid generation in the backfilled stopes would be minimal. The importance of including the surface area effect in the testing (ie using moulded cubes) is clearly demonstrated.

Jan 1, 2003

By Juniper LA

ERM Consultants Pty Ltd was established in 1980 for the purpose of introducing a disciplined coal technology and power station planning service, to support Australia's efforts in establishing a major export steaming coal industry. At that time, major coal exploration programs were mounted on more than 50 potential export coal deposits with proven open-cut reserves to export 200 Mt/a of coal. The fact that Australia achieved an export trade of only 30 Mt/a, equivalent to the energy requirements for a population of around 5 million people, illustrates the very small achievement to date. The main reasons for this small export steaming coal growth have been: 1. Failure to convince potential overseas coal buyers of the benefits of coal-fired power generation, and the ability of proper power station design to overcome environmental problems, and achieve reliable operation and long life when burning Australian coals. 2. Failure to promote Australian power engineers to advise on the use of Australian coals, resulting in Northern Hemisphere power station experience dominating in market countries. 3. Failure of governments to draw on privately practising Australian power engineers and coal technologists in technical workshops, presentations and assistance to overseas countries, to ensure that personnel whose business it was to serve the follow-on needs of countries were readily available. The result of these failures has been that: 1. Only a fraction of prospective overseas coal-fired power projects have proceeded. 2. Australia has had no influence in the design of overseas power stations to ensure that potential customers would be confident that Australian coals could be reliably burnt in their boilers.

Jan 1, 1987

By Baczynski NR, Fagan MJ

A 3050m long section of a 1.65m internal diameter tunnel is presently under construction in the Brisbane area by means of the pipe-jacking method. The soils along the alignment had been deposited in a deltaic/estaurine environment and rapid changes in soil type occur. The tunnel passes beneath several extensive bodies of surface water. Groundwater problems have been experienced with tunnelling through alluvial sands and gravels. Details of the ground conditions, the pipe-jacking method used and tunnelling experience are discussed in this Paper.

Jan 1, 1987

Don Hausen was a pioneer in the field of quantitative mineralogy. Methodology that he developed at Newmont almost 40 years ago is still employed today, only the technology has advanced. Petrographic methods were stressed with an emphasis on alteration, mineralisation and paragenesis. Methodologies employed by Don on the Carlin deposit were applied to developing the Carlin Trend by helping to work out lithology and structure, which ultimately led to the discovery of deep high-grade deposits. Quantitative methods used by Don on San Manuel, Copper Creek and Superior, Arizona were applied to the development of the Batu Hijau Deposit in Indonesia. Advancements in technology since DonÆs time have made the mineralogist much more efficient. Manual measurement of peak heights off of strip charts for semiquantitative XRD has been replaced by software that does Rietveld refinement and whole pattern fitting. Hand contouring of XRD data has been replaced by digitised data incorporated into geologic models. Optical point counting, which would take a dayÆs work to process 1000 points, has been replaced by automated SEM methods where 20 000 points are possible in an hour. The use of the optical microscope remains relatively unchanged, and still remains as Don emphasised the æeyesÆ of mineral exploration. However, the information can be relayed much more quickly with digital image capture and electronic data transfer. Don insisted on becoming involved in projects at the grassroots level and supporting the project through mine closure. This made the mineralogist a liaison between exploration geologists, mine geologists, metallurgists and mine engineers. The methodology that Don helped develop continues to provide invaluable support to Newmont geologists and metallurgists worldwide today.

Jan 1, 2008

The recovery of Copper by solvent extraction was arguably the most significant hydrometallurgical development of the 1960's. However, only dilute solutions at relatively high ph. could be treated effectively. ICVAcorga introduced in the 1970's the much stronger salicylaldoxime based reagents, which resulted in a dramatic change in plant configurations. So for example plants which normally use 3 extraction stages and 3 stripping stages could be reduced to 2 + 2 staging or 2 + 1 staging, even for high copper tenors at low ph. Leach liquors up to 40 g A copper are being treated at some locations so that almost any copper bearing liquor can now be purified by solvent extraction. Following a considerable amount of research and development effort ICI/Acorga have made further significant advances in the application of copper solvent extraction. The first of these is in computerised flowsheeting. In conjunction with ICI's Process Technology Department, Acorga have developed the Minchem Computer program, which uses laboratory generated equilibrium data to facilitate optimisation of metallurgical operating parameters. The program can operate in two modes, prediction and assessment so that given suitable extract and strip isotherms plant performance can be predicted for a given set of conditions. Alternatively existing plant performance can be assessed rapidly and accurately, thus providing a valuable quality control tool. Pilot plant work can now be restricted to evaluation of the physical aspects of the SX circuits, and to looking for the unexpected. Secondly using the patented 5-Nonyl Salicylaldoxime in precise admixture with a number of carefully selected strip modifiers, the Acorga M-range has resulted. Reagent selection from these new extractants can now be based on how the reagent can alleviate the remaining problems such as hydrolytic stability, transfer of iron, and organic losses by entrainment which may be related to particular features of the operating plant. Thus the Acorga M-range has enhanced and significantly extended the use of solvent extraction for copper, whilst refinements in the processing of metallurgical data has considerably simplified circuit design and analysis of results.

Jan 1, 1989

A standard practice of auditing mill designs has developed in the mining industry. The purported aim of this task is to ensure that the mill being offered conforms to the design specification, thus reducing the purchaserÆs risk. However, careful examination of the auditing methods used in the past shows that this is not the case. In some cases, what auditors have been providing is effectively a quality assurance check of the input data, not a full independent audit of the vendorÆs design. It will be shown that these past auditing methods have contributed to the stagnation of mill specification development. This lack of specification improvement combined with the current trend towards increased allowable fatigue stress ranges can result in an increase in risk for the purchaser.

Jan 1, 2002

By C van Wyk, I Reeves, J Webber, G B. Gnoinski

The minerals industry has been given an opportunity to grow and continue to advance again in an environment where there is the potential to reap big rewards for efficiency improvements due to buoyant metal prices and the growing demand of markets in Asia. Improving efficiency may also provide a better return compared to risks of expansions and bringing new projects online due to limited human and financial capital.An opportunity for improvement presents itself in the area of mine-mill reconciliation, which entails the quantification of the variance between measurement points along the mining value chain. Reconciliation factors are calculated from the variance between respective sections within the mining sequence. These factors are commonly used as key performance indicators to provide a check on the performance of the operations. Over parts of the mining value chain, there is a fair understanding of the reconciliation between the Resource and Reserve estimates and the measured metallurgical plant inputs and product outputs through understanding of the mine-mill interface. The quality of reconciliation data gathered across the mine and plant is generally not well established due to practices employed in generating the data. The reconciliation variances are often a function of data accuracy and quality used in the comparison. In general, the sources and magnitude of measurement and sampling errors and their impact on reconciliation are not that well understood. Examples of the current practices of mass measurement, sampling, sample preparation, chemical analysis and quality assurance for broken ore and across the metallurgical process stream are considered. Guidelines are given for those reconciliation elements that are identified as requiring a high degree of confidence for Mineral Resource/Reserve and metal accounting reporting. These guidelines are presented and practices are demonstrated to improve mine to mill reconciliation and support increased resource to product efficiency and value.CITATION:Gnoinski, G B, van Wyk, C, Webber, J and Reeves, I, 2012. Guidelines and practical applications for continuous improvement in mine to mill reconciliation, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 309-316 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By Lott JB, Scuffham JB

Until very recently the application of solvent extraction to. the recovery of metals has been considered only for ithose operations where no other process was available. In general, .these operations, have involved metals such as 'f uranium or the rare earths, where the value of metal recovered has been very high. As a result, the tendency has been to consider solvent extraction as a very specialised, high cost technique with minimal application in the base metal industry. Since the mid-1960's this attitude has had to be changed drastically with the development of solvents specifically designed for the selective extraction of individual metals such.ascopper. The result is that solvent extraction must now be regarded as a proven hydrometallurgical technique for the recovery of base metals, and in particular copper. The first significant event in the application of solvent extraction to base metals was the production by General M. Inc. of a compound, designated LIX-63 (R)(1), which was a specific extractant for copper from ammoniacal sns. This did not find a wide application, however, because copper solutions with a pH in the applicable range we more readily treated by conventional techniques.

Jan 1, 1970

Broken Hill South Limited's discovery of phosphate deposits in the northwest of Queensland in 1966 prompted intensive exploration which has proved phosphate rock in excess of 2,000 million tons at ten separate deposits.Systematic exploration for phosphate in Australia was initiated by the company in 1964. Early in 1966, an investigation of oil wells in the Georgina Basin in the Northern Territory and Queensland revealed widespread anomalous phosphate in early Middle Cambrian Beetle Creek Formation and Thorntonia Limestone. Phosphorites recognized in oil wells in the southeastern part of the Basin, Queensland, led to the discovery of the Duchess deposits. Exploration of the Beetle Creek Formation since 1966 has disclosed nine other sizeable deposits north of Duchess around the eastern margin of the Basin. The Lady Annie and the adjoining Lady Jane deposits, by reason of their location, 160 miles south of the Gulf of Carpentaria, are expected to be the first to be brought into production.Beneficiation testing and engineering investigations commenced in 1967. Transport between the deposits and various port sites in the Gulf of Carpentaria has been extensively studied and a slurry pipeline as a means of transport to a deep water island port, is now being investigated.

Jan 1, 1971

By D L. Decker, G C. Miller, C Papelis

Arsenic, often associated with precious metals ore deposits, is a major contaminant released during large-scale gold mining. Because of the complex oxidation/reduction and sorption behaviour of As, prediction of the long-term mobility of As in pit lakes is uncertain. The behaviour of As in pit lakes is investigated in this paper by conducting a series of laboratory experiments where As is allowed to adsorb onto pit lakes sediments. Experiments were conducted over a range of pH with both As(III) and As(V) allowed to adsorb onto sediments collected from existing pit lakes found in the three main orebody types in Nevada, USA; porphyry copper, quartz-adularia gold, and Carlin Trend type gold deposits. Results from adsorption experiments show that As(V) and As(III) adsorption is strongly pH dependent with higher uptake at pH 5 and lower uptake at pH 9 for As(V) and higher uptake at pH 9 and lower uptake at pH 5 for As(III). This behaviour, as expected for oxyanions, has been described previously for agricultural soils, iron oxides, and Carlin Trend heap materials. Maximum adsorption of As(V) for the Carlin Trend type gold sediment was 3.0 g/kg at pH 5, 2.0 g/kg for the quartz-adularia sediment, and 0.9 g/kg for the copper porphyry sediment. Maximum adsorption of As(III) for Carlin Trend type gold sediment was 2.5 g/kg at pH 9, 2.2 g/kg for the quartz-adularia sediment, and 2.1 for the copper porphyry sediment. Adsorption isotherms are non-linear and show Freundlich isotherm behaviour. Variations in sorption between the different pit lake sediments under similar conditions can be explained by differences in the elemental composition of the sediment. Most rock forming elements from XRF analysis are similar in quantity except for Fe. The Fe content is highest in the Carlin Trend type gold deposit sediments and lowest in porphyry copper deposit sediments and is the third most abundant element in all three sediments. The Fe content of the sediments correlates well with the amount of As sorption seen in the laboratory experiments.

Jan 1, 2003

By A Xenidis, N Papassiopi, I Paspaliari

Acid generating sulfidic tailings covering a surface area of approximately ten hectares have been deposited in the historic mining area of Lavrion in Greece. For the development of a remediation strategy, the performance of three alternative acid generation control techniques was assessed under actual field conditions. The techniques involved the application of dry covers, including a synthetic HDPE liner and a compacted clay layer with capillary barriers. Furthermore, the potential formation of a low permeability hardpan layer at the sulfidic tailings surface by limestone addition was investigated. The field tests covered an area of 2500 m2, which was divided in equal quadrants, corresponding to the control plot and the three alternative remedial options. To monitor the amount and quality of percolated water, lysimeters were installed beneath the four plot areas. Based on the monitoring results over a period of six years, due to the dry climate encountered in the Lavrion area, a low amount of water percolates through the pyrites if no action is taken (control area), corresponding to 20 - 25 mm per year. This water is highly acidic, pH = 1.2, and contains a heavy load of contaminants, eg Fe 40 g/L, Zn 15 g/L, and As 1.5 g/L. The HDPE cover eliminated the percolation of water into the material for a period of five years, whereas thereafter the volume of leachates increased to values similar to those recorded in the control plot. The water collected in the lysimeter of the clay cover has been minimal corresponding to approximately five per cent of the drainage volume produced in the control area. In the fourth plot, which involved limestone addition to sulfidic tailings, the volume of drainage initially collected was almost double compared to the control area. After three years of monitoring, significant reduction in the amount of percolated water was observed, attributed to the formation of a cemented layer (hardpan), at a depth of 40-80 cm from the testpad surface.

Jan 1, 2003

By Edwards A. B

Re-opening of the old Proprietary mine has provided new exposures of the system of uralite dolerite dykes observed in 19110 by the Geological Sub-Committee of the Scientific Society of Broken Hill. The newly exposed dykes have been invaded and replaced by the massive ore, with development of manganese garnet and biotite adjacent to the sulphides. A similarly altered dyke in massive ore has been encountered in the North Broken Hill mine.The textures of the unaltered portions of these dykes indicate that they have not been affected by the intense regional metamorphism that has recrystallized the other rocks of the area. Moreover, in mineral composition and textures, in chemical composition, and in cross-cutting relations, they are so similar to the uralite dolerites of the district which post-date the folding and metamorphism of the Broken Hill area, that they must be regarded as typical members of this suite of post-metamorphic dykes.The invasion and replacement of the dykes by the massive sulphide ore, and their metasomatic alteration adjacent to the invading sulphides, establishes that the lode was formed after the dykes were intruded, so that the high temperature features of the ore cannot be attributed to metamorphism and recrystallization, but are primary features of high temperature hydrothermal deposition.INTRODUCTIONTwo cross dykes are recorded on the plan of the 300-ft. level of the Broken Hill lode accompanying the report on the geology of the Broken Hill lode published by the Geological Sub-Committee of the former Scientific Society of Broken Hill (1910). One dyke occurs in Block 12, and the other in Block 13, and both were stated to consist of a dark basic amphibole rock, called diorite for convenience. The more southerly dyke was traced from some distance out in the footwall, and even through the lode, by means of occasionalpatches of it still existing in the ore, in a direction...

Jan 1, 1956

By M J. Nugus

A substantial cost is invested into the data collection phase of any exploration or development program; notwithstanding, it is impractical to expect a database of information can be collated to ensure a perfect geological interpretation. The question then becomes, is there a possible alternative interpretation and what is the likely impact of the variations? Modelling in 2005, of the Cosmo lode at Sunrise Dam Gold Mine, Western Australia led to consideration of the philosophical implications associated with resource management. It was concluded that several plausible geological models could be constructed from the known geological database. To varying degrees, this predicament is common to all geological reconstructions, as several alternative geological models can be generated at almost any stage that will impact on the resultant resource estimation and mine plan. The significance of that variation and the associated risk of multiple geological models (MGMs) requires due consideration. What is being suggested is that using plausible multiple geological models advances the holistic understanding of a mineral deposit within the bounds of the data collected, providing fluidity for updating geological knowledge and building inherent variability into the design and planning departments where variations of the geological models may materially impact on the resource performance.

Jan 1, 2006

By D Craw

Interactions between structure and lithology in the Hyde-Macraes Shear Zone controlled the style of gold mineralisation at the Macraes mine. Large volumes of rock in some mine pits have most gold disseminated in hydrothermally altered schist, rather than in quartz veins. Mineralisation was initiated in the latter stages of metamorphism. Pods of massive schist rich in quartz and feldspar are surrounded by more fissile schist consisting of interlayered micaceous and quartzofeldspathic schist. Later shears have been partly controlled by the micaceous schist, and anastomose around pods of more massive schist. Micaceous schist was replaced by pyrite and arsenopyrite, accompanied by recrystallisation of phengitic muscovite under lower greenschist facies conditions. Gold occurs in sulfides and with microcrystalline quartz formed during minor silicification. Massive schist is locally mineralised along sulfidic microshears which have phengitic muscovite largely illitised under sub-greenschist facies conditions. Mineralised massive and micaceous schists were overprinted by cataclastic shears, with addition of graphite and more sulfides. Mineralisation occurred during a transition from ductile to brittle deformation regimes as the schist was uplifted in the late Jurassic.

Jan 1, 2004

By Sandenbergh RF

The debate on the mechanism of adsorption of gold and silver di-cyanide onto activated carbon could be divided into two schools of thought. On the one hand, it has been proposed that the combined effects of electrostatic and chemical interaction between the activated carbon surface and adsorbing gold di-cyanide anion results in the adsorption of the latter. On the other hand the `ion-pair' adsorption reaction mechanism has been vigorously advocated as the dominant mechanism responsible for the adsorption of gold di-cyanide onto activated carbon. It is maintained that gold is adsorbed onto the carbon surface as the neutral ion-pair [M"+][Au(CN)z ]". Adsorption is viewed as the result of mainly the chemical interaction while electrostatic interactions are neglected. The validity of the `ion-pair' adsorption mechanism may be challenged on a number of counts. However, the alternative mechanism (based on aqueous surface chemistry principles) has not gained general acceptance yet, because it has not been applied widely enough to explain the different adsorption phenomena associated with gold di-cyanide on activated carbon. In the present study the case in favour of an adsorption mechanism based on general aqueous surface chemistry principles is presented. A model framework is developed for the adsorption reaction mechanism of gold di-cyanide onto activated carbon which incorporates the effects of chemical and electrostatic interactions between the dissolved species, the aqueous solution and the carbon surface. This model is then employed to explain a wide variety of reported adsorption phenomena for gold di-cyanide on activated carbon, such as the effects of pH, the adsorption of different metal cyano complexes, ionic strength, and type and concentration of cations in solution. In addition the effects of cyanide and dissolved oxygen concentration were investigated. No ready explanation, in terms of aqueous surface chemistry principles, is yet available for the switch in adsorption behaviour that agrees with ion exchange to ion-pair adsorption with increasing ionic strength.

Jan 1, 1997

By D Mukendi-Ngalula, G Hearn

Beach sand minerals from the volcanic rock structures of the Drakensberg, Kwazulu-Natal, (South Africa) have been processed. Screening, flotation, spiral concentration and magnetic separation methods were used either separately or successively in an attempt to concentrate monazite minerals. Products thereof and those from a long time (up to 72 hours) microwaves treatment of the finally produced ilmenite-bearing minerals have been studied using the M÷ssbauer effect spectroscopy. The 57Fe M÷ssbauer effect spectroscopy has demonstrated its versatility and power in monitoring the ilmenite internal reduction mechanism and products and, in characterising the iron-bearing phases contained in different products from the beach sand minerals processing. Microwaves heating of ilmenite for up to 38 hours reduced internally the Fe3+ from the ilmeniteÆs structure. A more prolonged microwaves heating (up to 72 hours) re-oxidised the mineral. 61 per cent natural ilmenite recovery was obtained in the floating products of a spiral concentrated -212+106 ¦m screened and beach sand minerals fraction. A preferential concentration of hematite with a 62 per cent recovery was found in the sinking products while the combination of screening-spiral separation-magnetic separation and flotation yielded a floating product with the highest ilmenite and the highest hematite abundanceÆs (71 per cent, 19 per cent respectively). A natural ilmenite containing 87 per cent ilmenite and 13 per cent hematite could be produced and extracted from the sinking products of the flotation process collected subsequently to the spiral concentration and the initial screening.

Jan 1, 2000

Despite the research interest on non-cyanide gold lixiviants over the past three decades all the non-cyanide gold processes are still at the developmental stages with limited understanding on solution and pulp chemistry in some cases. This is partly associated with:the difficulties in measuring reliable equilibrium data for various gold(I/III) complexes with non-cyanide ligands; the lack of knowledge on mixed-ligand complexes; and different kinetic stabilities of gold(I) complexes with respect to disproportionation. This paper presents reliable equilibrium data for complex formation, dissolution, precipitation, hydrolysis and disproportionation reactions of gold(I/III) compounds with a range of non-cyanide ligands: S2-, HS-, S2O32-, SO32-, SCN-, SC(NH2)2, OH-, NH3, Cl-. Solubility of gold(III) compounds with non-cyanide ligands follows the order: Cl- > NH3 > OH-. In the case of gold metal the solubility order at a given temperature is MgS > Fe(III) or Cu(II) / Cl- > Cu(II)/NH3 > NaOH, but the solubility increases with increasing temperature. Rate of gold oxidation with different non-cyanide lixiviants depends on the oxidant, ligand and temperature and follows the general order of oxidants: Fe(III) or Cu(II) > X2 or OX- > O2 (X = halogen). In the case of metal ion oxidants oxygen is required to reoxidise Cu(I) or Fe(II). Some of the reported data on chloride and thiosulfate leaching of gold are presented to highlight the effect of additives and the copper, silver and sulfur contents of the starting material on the success of non-cyanide leaching processes.

Jan 1, 2004