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By W. Griffith

"While oxalic acid precipitation practices are commonly applied on purified rare earth elements (REEs) pregnant leaching solutions (PLS), few efforts have been reported using oxalic acid (OXA) to recover REEs directly from untreated PLS. High oxalic acid demand is the most significant issue in all these direct oxalic precipitation (DOP) practices. Preliminary research on DOP of REE from a dilute PLS originating from an acid bake followed by water leaching was conducted. At 75°C, the oxalic acid demand was between 12 and 18 times the stoichiometric requirement for complete REE precipitation. Conducting DOP at 25°C had superior REE recovery but the product purity and filterability declined. Between 75°C and 100°C, REE recovery increased with increasing temperature. When sodium hydroxide was used to adjust the pH during DOP, in the range of 0.5 to 1.5, higher pH benefited REE recovery. Using ammonium hydroxide in place of sodium hydroxide, the REE recovery was reduced by close to 5%. Sodium chloride addition to the PLS was also investigated and the results showed that at both 75°C and 25°C, the REE recovery was enhanced substantially. At 25°C, when the oxalic acid addition was controlled at 4.7 times the stoichiometric requirement, the overall REE recovery reached 95% with the addition of 240 g/L NaCl. Other reagents such as KCl, NH4Cl also showed significant enhanced REE recovery at the same oxalic acid addition. The addition of sodium sulphate appeared to largely enhance the precipitation of LREE but inhibited the formation of HREE oxalate. All results indicate the formation of rare earth double salts may play an important role in REE DOP sulphate media.INTRODUCTIONThe conventional routes for recovering rare earth elements (REEs) from a sulphuric acid pregnant leaching solution (PLS) involves an initial purification step for removal of iron, aluminium for example by precipitation through neutralization, followed by precipitation of REEs as hydroxide, oxalate or carbonate salts, or by bulk solvent extraction for REE recovery (Xia, 2013). Another route was used by Bayan Obo in their historical flowsheet, where the PLS was first subjected to double sulphate precipitation, then the remaining REEs, mostly heavy rare earth elements (HREE), were recovered by oxalate precipitation (Li, 2011)."

Jan 1, 2016

Research, whether applied or fundamental, is a human endeavour which increases our understanding of nature. It is insufficient to simply observe, explore, record and classify. It i necessary, as well, to fit the observations into a satisfying theoretical scheme; that is, to synthesize. Two examples of successful research programs in physical metallurgy are di cussed from this point of view. A pessimistic view is taken of the prospects for rapid growth of research activities in the Canadian metallurgical industry. THE term "research" is used indiscriminately to describe any intellectual or experimental activity which leads to a change in society. Proponents of various activities, ex-tending all the way from alloy development to subliminal advertising, use the status of the term for special advantage. With the Canadian Government entering upon a project of support to industrial research, it might be well to determine what definition is most in the public interest. As an academic, I have a rather jealous attachment to the definition that research, whether applied or fundamental, is a human endeavour which increases our understanding of nature.

Jan 1, 1963

By C R. Crook

A brief outline of production methods and processes is given to show how maintenance fits into the picture at this plant. The work force, and the tools needed to carry out this function, are then described. Preventive maintenance practices, scheduled annual shutdowns and routine check-downs are explained, especially as related to planning and to the materials and labour involved for a mini-mum downtime. A brief explanation of the materials, sup-plies and spare parts program, as well as the part played by the Stores Department in conjunction with the Maintenance Department, is given. Cost control and equipment expenditure indicators are explained. Some specific examples of maintenance jobs are described in order to show the flexibility of the program. S HERRITT GORDON Mines Limited has been in continuous production, except for the planned downtimes needed for expansion tie-ins, or the annual shutdown check-over periods, since the first shipment of nickel on a commercial basis in July of 1954.

Jan 1, 1964

By F. H. Edmunds

Introduction This paper, it is hoped, will serve as an introduction to further work upon the origin of the soils and to a more complete interpretation of the geology of Saskatchewan from a study of the soils of the Province. The great difficulty that is encountered in mapping the structure of the prairie regions of the west must be evident to all who have made the attempt. The rarity of good exposures, due to the extensive coverings of glacial drift, is the greatest obstacle, making it difficult to determine the exact stratigraphical position of such exposures as may be found. In many cases palæontological evidence is lacking, or, if available, our present knowledge of the stratigraphy is insufficient to justify division of the formations into horizons; and until many of these formations have been subjected to petrographic investigation, little can be done in using lithological differences as an aid to the correlation of the usually sparse outcrops met with in the Province. Topography may be of the utmost value as an indication of geological structure when considered in conjunction with other evidence. It does not necessarily follow that, because an area in Saskatchewan has resemblances in surface configuration to an area of oil-producing land in Texas, there is sufficient justification for sinking money in wells without further investigation. Such - investigation should include the study of available soil maps.

Jan 1, 1929

By P. A. Riveros, J. Binvignat, V. M. McNamara, D. Koren

The recovery of cyanide from a gold mill solution containing high levels of copper (400 mg/L to 900 mg/L) using the AVR process was evaluated. It was determined that acidification to pH 2 to 3 provides a suitable balance between HCN generation, copper precipitation and acid consumption. A short pilot plant campaign showed that ~75% of the feed WAD cyanide was recovered while the remainder precipitated along with copper upon acidification. The acid consumption averaged 3.5 g H2SO4 per litre of solution. The copper precipitate, consisting mostly of CuCN and CuSCN, was readily separated from the solution by gravity. The volatilization of HCN in countercurrent packed columns averaged 98.7% efficiency. Reabsorption of HCN was practically 100% in NaOH solutions and slightly lower in a lime slurry. Basic volatilizer design parameters applicable to a large-scale operation were determined, including the Henry’s Law constant and the mass transfer coefficient of HCN gas.

Jan 1, 1998

By W. L. Ott, J. E. Hawley, C. L. Lewis

"IntroductionTHE APPLICATION of spectrochemical analysis to metals of the platinum group was advocated by Harvey (3) as follows: ""The spectra of the platinum group metals have been studied less than many of the more common metals. The rarity of occurrence of these elements makes the analysis relatively unusual. Potentially, the analysis of this group is an excellent application of spectrographic methods, particularly in contrast to the tedious chemical procedure"".Wichers (8) divides platinum-metal analysis into three broad divisions as follows :( 1) The detection and estimation of these metals in other materials, e.g., ores, where the amounts present are very small.(2) The detection and estimation of impurities in the refined metals themselves ....(3) The analysis of alloys of the platinum metals .....The present paper deals with the second division: analysis of refined rhodium.Research on spectrochemical techniques for determination of trace contaminants in refined platinum metals was begun at Queen's University in 1949, under the supervision of Professor J. E. Hawley. Since 1953, the work has been continued in the Metallurgical Laboratories of Falconbridge Nickel Mines, Limited. Techniques for spectrochemical analysis of refined platinum and palladium have been published ( 4, 5). A technique for analysis of refined iridium has been developed but not yet published."

Jan 1, 1955

By S. Steinlechner

"Today the common recycling technologies of automotive catalysts are either energy intensive pyrometallurgical processes generating huge amounts of residues or hydrometallurgical ones which have to cope with effluent problems. Next to that, other valuable metals beside PGMs such as rare earths from the wash coat are not recovered.Therefore, the present paper introduces a hydrometallurgical concept developed in cooperation with the company Railly & Hill for the recovery of the PGMs as well as cerium from the wash coat of the catalysts in a closed loop. Next to the process concept, the required parameters for the different steps are discussed, including the chemical reactions, leaching efficiencies and mass flows, which form the basis for an economic estimation of the concept.Contrary to the pyrometallurgical recycling where the monolith is completely melted down to slag which is typically dumped, in this process the remaining monolith forms an utilizable product for the ceramics/refractory industry. As a result of the closed loop of the leaching media an environmentally friendly process was developed from which nearly no new residues or effluents are generated, with a sustainable usage of chemicals."

Jan 1, 2014

By Guy Chevalier

The QCM Mount-Wright mine and concentrator complex produces about 14 M tonnes of iron concentrate annually. Approximately 9.5 M tonnes of this concentrate are used to produce iron ore pellets at four different silica grades: Three for blast furnace operations and one for direct reduction furnaces. The paper presents the scientific approach that led to the realization of two projects where the acquisition of new process equipment led to an improved pellet plant iron recovery, a better flexibility and to lower operating costs as well as to the production of fine iron ore concentrate from the Port-Cartier tailings pond. Typical 4.8 % SiO2 concentrate is processed to achieve required pellet silica content. This is obtained with the aid of hindered settlers or hydraulic classifiers, screens, whims and, lately, spirals. The increasing demand for low silica iron ore products resulted in a greater need for upgrading. The Pellet Plant upgrading capacity being limited, more and more iron units were lost. Base on test works results and economic evaluations, QCM engineers figured out a way to increase efficiently their upgrading plant capacity and go back in the pond gather what has been lost in recent years of operation.

May 1, 2007

By F. Chiesa

Forty aluminium A356 castings were poured on a Low Pressure Permanent Mould industrial machine, 500x700mm in platen size. The 152mm wide casting comprised three steps, 25mm, 13mm, 6mm in thickness and a 2.5mm overflow which allowed to assess the thin wall capability of the process. The casting campaign, which produced 40 parts, allowed to test the influence of various production parameters including the time of application of the pressure in the crucible, artificial cooling of the mould and casting rate. The thermal history in the mould was recorded over the 40 cycles, which allowed to construct a reliable thermal model of the mould/casting assembly. The metallurgical quality of castings representative of the various conditions was assessed in the 25mm, 13mm and 6mm plates. This included measuring the level of microporosity, the dendrite fineness (DAS), along with the tensile properties in the T6 condition. The radiographic quality per ASTM E155 was also determined. Modelling filling and solidification allowed to verify the validity of the predictions based on available relationships relating microporosity, secondary dendrite arm spacing (DAS) and local tensile properties (Quality Index, Q) to the local thermal solidification parameters.

Jan 1, 2007

By D. E. G. Maschmeyer

The operation of the pilot plant for the S-C Copper Process during 1976 has provided the basic data for the design of a commercial-scale plant. This paper introduces the commercial aspects of the S-C Copper Process through the presentation of a process flow diagram, a schematic flow diagram and basic design parameters for 75,000 tonnes per year (tpy) copper rod production from chalcopyrite concentrate. Basic operating requirements are outlined and a preliminary estimate of operating and capital costs for a Western Canadian location are summarized. The results have been compared with a modern smelter/electrorefinery to highlight the advantages and disadvantages of these two alternatives and to show why the new S-C Copper Process technology should be of interest to the copper industry.

Jan 1, 1978

By I. Vazaios, M. S. Diederichs, N. Vlachopoulos

"As rock engineering moves from continuum to more discontinuum approaches for modeling, the engineer must make decisions regarding the degree of complexity to simulate for a given application, balancing the level of structural detail within the rockmass model with computational cost and result accuracy. It is important to consider that model does not need to include all the existent fractures and that representative geometrical properties for a given rock mass volume can be defined including only major structural entities.Within this paper, the scale-dependency associated with the geometrical properties of fractured rock is investigated utilizing a Synthetic Rockmass (SRM) approach with a view to characterize such ground to aid in the design of geotechnical works. In terms of process, the concept of the Representative Elementary Volume (REV) is used to determine the equivalent structural properties of the rockmass in order to justify the applicability of far-field behaviour of such ground. A large size Discrete Fracture Network (DFN) measuring 60m x 60m x 60m has been generated using the structural data obtained from LiDAR scanning of the Brockville Tunnel, Ontario, Canada. A number of DFN samples of varying sizes are extracted from the master network, generated using MoFrac, in order to be used as a the basis of the structural analysis of the rockmass. Volumetric measurements for the density and the intensity of jointing are employed in order to approximate the geometrical REV for the networks.In this paper a complete methodology of how to generate a DFN from LiDAR data and its analysis in order to determine the size of a geometrical REV is demonstrated. For the specific rockmass found in the area of the Brockville Tunnel, a geometrical REV measuring 3.5m x 3.5m x 7m is established. The results are generally in good agreement with the in-situ observations."

Jan 1, 2015

By C. Acuña

The case is presented that the key role of frother is control of bubble size in the pulp zone. Compared to water alone, the addition of frother produces a narrower distribution and finer bubble size. An empirical model is presented for bubble size as a function of frother type using a normalized concentration. The model provides a benchmark for assessing operations. There is no agreed upon mechanism of how frothers act to reduce bubble size. Prevention of coalescence is a common explanation and this action is illustrated. The case against the 'coalescence' model alone is presented and a breakup mechanism is introduced based on pilot cell and single bubble studies. Phenomena associated with bubble shape, velocity and surface flows are used to illustrate the force associated with surface tension gradients. Breakup mechanisms resulting from this force are proposed. The concept can be extended to high salt concentrations which also promote small bubbles.

Jan 1, 2007

By K. Dinh

The Ground Penetrating Radar (GPR) has been studied for a long time as a non-destructive evaluation (NDE) technology for inspection of concrete structures. Currently, the most widely used technique for interpreting GPR data of concrete bridge decks is the one that based on the amplitudes measured at various interfaces such as asphalt-concrete, top rebar, or slab bottom. The assumption behind this technique is that a sound concrete deck should have the same reflection amplitude at these interfaces while any low number would indicate some sign of deterioration. Unfortunately, this assumption is not completely valid in most cases. As a consequence, the reported test results usually do not reflect real condition of concrete bridge decks in question. The main goal of this paper is therefore twofold: (1) to discuss the limitations of the amplitude analysis method, and (2) to propose a new model that interprets GPR data of concrete bridge decks. The model methodology is based on the comparison of GPR A-scans between two inspections, using the so-called correlation analysis. The results, indicated by the correlation coefficients, are then employed to develop a contour map that estimates different levels of deterioration. The model is then implemented to a case study in order to illustrate its methodology.

Aug 1, 2013

"Liberation is a key requirement for efficient separation in mineral processing. As a consequence of this an understanding of the inherent textural features of an ore is no longer possible since during the process of liberation, texture is destroyed. Knowledge of key textural features, such as mineral grain size and distribution, prior to breakage processes provides the opportunity to understand the textural drivers for ore hardness. Modern characterisation methods, including automated SEM-based techniques, provide the possibility of measuring mineral characteristics at a range of scales. This paper discusses how textural features of two different ore types in a porphyry copper deposit can be measured and interpreted at a number of scales. Standard breakage tests conducted on the ores indicate that one of the ores can be characterised as hard and the other as soft. The impact of mineral grain size and the presence and scale of vein type structures in the two ores have been used to determine the extent to which these features influence ore hardness.INTRODUCTIONIn order to effectively convert ore into metal, knowledge of both the processing stages and the characteristics of the ore are essential. Prior to the advent of technologies that enabled the fundamental understanding of the sub-process at each stage of processing and the measurement of appropriate ore properties the most effective way to understand how an ore would respond to a process was to put it through that process, for example the way to determine how an ore would break was to first break it. Existing comminution models seek to predict the size distribution of rock fragments as the result of applied energy based on knowledge of the rock strength. It is common for these models to consider the rock as homogeneous and despite providing important data for the design and optimisation of industrial comminution circuits these models are only applicable within a narrow range of operation. In order for reliable predictive models to be developed that account for the inherent ore characteristics, a step change is required in the type of measurements that are carried out to characterise an ore and the type of data that is extracted and used as model inputs."

Jan 1, 2016

By Roorda H. J, R. R. Saddington, Curlook W

THE copper-nickel sulfide ore deposits of the International Nickel Company of Canada, Limited contain the minerals pyrrhotite, pentlandite, and chalcopyrite. In the extraction of the nickel, copper, and iron, much of the processing involves oxidation of the metals as well as sulfur. Roasting plays a predominant role at several stages in the operations which prepare the constituent metals for refining. Copper, nickel and iron concentrates of various grades, ranging from low-grade nickeliferous pyrrhotite to high-grade nickel sulfide, must be partially or completely oxidized. Figure 1 shows the main points at which roasting is conducted at INCO. Roasting experience at INCO dates back to the time when lump ore was partially roasted in heaps. It has progressed through single hearth roasters, sinter machines, multiple-hearth roasters, flash roasters, and more recently has centered on the development and utilization of fluid bed roasters. The primitive, slow, and inefficient method of heap

Jan 1, 1961

By G M. Thorpe

This paper discusses mine research at Inco, giving specific examples of research projects which illustrate the approach to mining problems. The first example covers the development of a new mining method, "undercut and fill," which was originated for mining badly broken-up pillars, but which is now rapidly replacing the square set method of pillar recovery. In the new method, ore is extracted in a series of successive horizontal cuts, progressing downward, a cut being completely mined and filled before the cut below is started. In the second example, improvements to the "cut and fill" method of mining are discussed. These improvements are the result of improved techniques and improved equipment, etc., with, in many cases, the former being made possible by the latter. The advances made have permitted the use of the "cut and fill" method at much greater depths than before. The third example is presented to illustrate research undertaken to obtain the earliest maximum advantage of the introduction of a new piece of equipment or material. For this purpose, the development of the "Under-ground use of AN /FO Blasting Agent " has been selected. Work on this project started in May, 1960, at a time when there was very little in-formation regarding the potentialities of AN /FO for underground blasting, either primary or secondary. By the end of 1961, AN /FO made up 64 per cent of the explosives used under-ground at Inco mines.

Jan 1, 1963

By X. Cao, A. Birur, R. R. Chromik, J. Cuddy, P. Wanjara, J. Gholipour Baradari, T. Shariff

In this study, 3.1 mm thick Ti-5553 (Ti-5Al-5V-5Mo-3Cr) butt joints were autogenously welded using a 4 kW continuous wave Nd:YAG laser. The effect of welding speed and defocusing distance on the weld quality was investigated in terms of the surface morphology, welding defects, microstructure and hardness. Welds with full penetration were achieved at a defocusing distance ranging from -1 mm to 0 mm and welding speeds from 2.25 to 6.0 m/min. Underfill and porosity were the two main defects most frequently observed but within the optimum process window these defects could be maintained to meet aerospace specification tolerances. The fusion zone (FZ) consisted entirely of retained beta with a refined dendritic morphology. Compared to the bimodal alpha (a) + beta (ß) microstructure of the base metal (BM), the dissolution of the a phase was observed in the heat affected zone (HAZ), which led to an 11 % decrease in hardness from the BM to the FZ. To determine the tensile properties of the welded samples, an automated 3D deformation measurement system was used to measure the local strain in the weld region. The yield strength (YS) and ultimate tensile strength (UTS) increased with increasing welding speed with a highest joint efficiency of 75 % being achieved, albeit with a concomitant reduction in the ductility.

Jan 1, 2010

By Curtin University Western Australian School Mines

"Curtin University’s Gold Technology Group has developed an online CIP/CIL simulation model called SIMCIL which has been used since 1999 to model and simulate industrial leach-adsorption circuits. Recently the model has been upgraded to include an integrated liberation-leach modelling (ILLM) approach which can be used to evaluate the impact of various process parameters (such as grind size, bleed to gravity etc.) and circuit configurations on leach-adsorption circuit behaviour and overall plant gold recovery. A new time-efficient ore characterisation methodology has been researched and developed to provide the required liberation-leach data used in the ILLM approach, which is implemented online for the modelling of gold operations. The model structure, modelling approach, and some scenarios are discussed.INTRODUCTIONCurtin University’s Gold Technology Group has developed an online CIP/CIL simulation model called SIMCIL which has been used since 1999 to model and simulate industrial leach-adsorption circuits. The model has recently been upgraded to include an integrated liberation-leach modelling (ILLM) approach. The ILLM approach provides the means to evaluate the impact of the gravity recoverable gold (GRG) characteristics of the ore (GRG content and liberation behaviour), various process parameters (such as grind size, bleed to gravity, etc.) and circuit configurations on the gravity gold recovery, leachadsorption circuit behaviour and overall plant gold recovery.A new time-efficient ore characterisation methodology has been researched and developed to provide the required liberation-leach data used in the ILLM approach. The data required for the ILLM calibration can be obtained directly from the 3 stage GRG test, leach tests and size-by-assay analysis of the 3 stage GRG test products, and leach test products.This paper describes the ore characterisation methodology, model structure, modelling approach, and the application of the ILLM."

Jan 1, 2016

By J. G. Phillips

Introduction Throughout the Great Plains region (the provinces of Manitoba, Saskatchewan, and Alberta), numerous clay deposits of widely varying composition and character are to be found. These may be classified into two general types: (1) surface clays, and (2) shales. The surface clays consist of a heterogeneous mantle of silts and clays interspersed with grave! and sand deposits, and may belong to any of the following groups: (1) lake clays: (2) river-terrace or flood-plain deposits; (3) delta deposits . In most cases, the water from which these deposits were ' laid down was derived from the melting ice of the continental glaciers. These surface clays, in general, possess certain characteristics in common, being all more or less calcareous, often silty, and showing a tendency to 'check' in air-drying. The shales found in this region are of Cretaceous and Tertiary age. These deposits have a wide extent, but there is frequently such a heavy covering of drift material that the clays are accessible chiefly along the walls of stream valleys, or along the escarpments of uplands.

Jan 1, 1929

By K. H. Concannon, K. I. Hindle

"The use of simulation modeling in the primary metals industry (including mining, smelting, and metals processing) is expanding as significant cost-benefits can be realized by companies employing capital intensive processes. The economic scale and complexity of operations found in this industry is well-suited to applications using this ""what-if' computer modeling technique, ranging from proof-of-concept projects to testing facility design or configuration, and determining resource requirements. More recently this technique is being used to support on-going planning and scheduling for operations using the simulation as the engine to derive the best schedule. With increased computer processing capability, deterministic models are now being developed to capture the workings of a production system or conversion process, allowing real-time monitoring and scheduling of these operations. This paper presents a sample of some recent discrete-event simulation modeling applications that demonstrate the capability and benefits of this technique in the primary metals industry. These include the use of simulation to support the long-range planning of underground mining operations; the modeling of a metals supply chain network that employs a multi-modal distribution system; the scheduling of a metals coil finishing process using a deterministic simulation model; and a more detailed description of the use of simulation to model furnace and converter aisle activities within a smelter operation in Northern Canada."

Jan 1, 2007