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By Éric Létoumeau, Julie Fournier, Sylvain Caron, Yves Breau, Martin Plante, Dominique Girard, Luc Tardif, François Robichaud

"Since 1999, COREM (formerly the Centre de Recherche Minérale) has conducted and coordinated research and development activities for a consortium of mining companies that uses the benefits and advantages of collaborative pre-competitive research. In particular, COREM’s “In Situ Optimization Group” is involved in the development and implementation of modem information technologies related to process optimization and control.The POP Project was launched in order to increase and consolidate the use of such technologies applied to mineralurgical and metallurgical processes. To ensure a successful transfer to the industry, there are a number of essential activities that have to be undertaken. These activities have been identified by COREM’s members and are grouped into three main modules:- R&D Module: research and development in universities and research centres;-Technology Transfer Module: integration of new tools into the POP Software, industrial applications and technical support;- Training Module: education of new engineers in universities and continuing education of plant personnel through on-site workshops.This paper outlines the opportunities that led to the definition of the POP Project, presents its main objectives and describes its main modules. The main features of the POP Software are outlined, the first applications at COREM’s member plants are presented and, finally, future developments are discussed."

Jan 1, 2002

By C. L. Reichardt

"Pressure exerted on gold producers by regulators, project financiers, and civil society in the wake of the Baia Mare tailings spill in Romania during 2000 prompted most responsible gold companies to sign up to the International Cyanide Management Code for the Manufacture, Transport, and Use of Cyanide in the Production of Gold (the Code). The Code stipulates a ‘cradle to grave’ approach more comprehensive than that applied to any other mining reagent and poses particular challenges for operators who use cyanide-bearing tailings for backfill. This paper examine some of the challenges for Code compliance facing deep underground gold mines that employ backfill technology, most particularly the requirement to demonstrate that the potential migration of cyanide (and its degradation products) from emplaced backfill will not have an unacceptable impact on worker health and safety or on the receiving environment, either during mine life or after closure.Although the Code only contains a single reference to backfill, more careful consideration confirms that most sections of the Code that deal with tailings management are potentially applicable to mines where tailings material is used for backfill. Certain principles of the Code also pertain to aspects of operations, worker safety, emergency response, training, and dialogue with stakeholders relating to backfilling practice.For gold mines of the Far West Rand, the most significant cyanide-related risks associated with backfill operations relate to worker exposure to cyanide-bearing seepage and HCN gas. There is potential for seepage of cyanide-bearing water from backfill to compromise the beneficial use of surface and groundwater, and thus impact on downstream users and ecosystems. However, the extreme depth of mining and the specific geological and hydrological controls on the Far West Rand suggest that the potential environmental risks associated with backfill are likely to be considerably less significant than the cyanide-related risks to the workforce."

Jan 1, 2007

The Silvermines area of north County Tipperary in Ireland has experienced mining activity for over a thousand years, with lead, zinc, copper, barite and sulphur being extracted from a series of Carboniferous limestones. The last mine to operate in the area was closed in 1993. A legacy of contamination and derelict surface structures remain. Following the death of cattle in the vicinity in 1999, a governmental Inter-Agency Group was established to conduct an investigation. The ?Silvermines Rehabilitation Project? resulted, and included a proposal for the development of a Mine Waste Management Facility (MWMF) to act as a repository for waste materials from problematic sites across the area. The nature of the setting supported an effective solution from both a cost and performance perspective; and with limited maintenance requirements. Locating the MWMF where most wastes were identified would help minimise handling and relocation of materials. This position coincided with an area of artesian groundwater pressures. The resulting MWMF design consisted of a perimeter engineered embankment with the crest elevation designed to just exceed the groundwater piezometric surface. The base would remain unlined and groundwater permitted to rise up into and saturate the contained in-situ tailings deposits and imported mine wastes. The proposed system thus benefited from the ?wet cover? approach to minimising further oxidation of wastes and metal leaching, but without the usual accompanying outward hydraulic gradient and leachate management issues. A sub cap drainage layer with downstream outlet was incorporated to prevent any possibility of hydraulic rupture following an unexpected rise in groundwater heads. Leakage rates from the MWMF were deemed to essentially be driven by surface infiltration rates alone (characteristic of a ?dry cover? approach), with the proposed composite capping system simulated to perform at an infiltration rate of less than 1 mm per year. A toe drain was incorporated with the perimeter containment system, and this collection together with diverted neighbouring drainage was directed under gravity to a dedicated Passive Treatment System (PTS). Overall, effluent water quality from the PTS has been predicted to reflect an annual mass metals removal in the order of 95% below baseline.

Aug 1, 2013

By Andre Vien, D. H. Hendriks, D. Willet, B. C. Flintoff

"For many years the training of mill operators was an informal process which involved senior operators training junior operators on an as-needed basis. Recognizing the needs and benefits of better training some companies, and even some provinces through legislation, have moved to ensure that a formalized training program exists in the plants. These programs tend to focus on basic safety and operations. Much remains to be done. With the more rapid incorporation of new processing and information technologies, and the goal to keep labour costs to a minimum by doing more with less, operator training has become a critical issue. This paper briefly examines the evolution of training programs, provides some measure of their effectiveness, and explores some recent developments which could have a very significant impact on the industry.PreambleOne can draw an analogy between operator training and the mechanical support of production equipment. When we buy a piece of process equipment it is critical that the mechanical installation be done properly to ensure that the device will operate at peak performance on start-up. Once the equipment is running, some form of preventive maintenance is required to ensure continued efficient operation. The operators and the equipment are both elements of the processing system, yet the former do not seem to get the same ""start-up"" or ""operating"" support. Are they not seen as critical to efficient operation? Why is this so? What impact does it have? How can we improve?These are all very logical and important questions, although the answers are not nearly so obvious. In the mineral processing industry, progress in operator training over the past thirty years has been limited and quite variable. To address the perceived need for a more coherent and consistent approach, some provinces have moved to incorporate basic training requirements in their legislation. Some plants have gone a few steps further by building integrated training programs into their operating culture. One conclusion which can be easily reached is that there are no standards, and that the range of training activity is great. In other words, a flotation operator is not a flotation operator is not a flotation operator. Their knowledge and skills are very much a function of training and experience, which are clearly corporate and site specific."

Jan 1, 1994

By Max W. Ball

YOU have been kind enough to ask me to speak to you on "The War and Anglo-American Relations." A speaker always takes the liberty of putting his own interpretation on the scope of his subject. I am going to exercise that privilege, and try to look back over a generation of Anglo-American relationships and forward beyond the present war. I should like particularly to consider responsibilities as well as relationships. A more accurate caption for what I am going to say would be "Anglo-American Responsibilities.?? THE WAR WILL BE WON I am assuming that sooner or later we shall win this war. History and economics point to the same conclusion, that Germany has attempted the impossible and that the seeds of defeat are already sown. As to one ecof1:omic factor, I am already on public record as believing that Germany's oil supply is inadequate for the war she has launched. That opinion is unchanged. Aside from such tangible factors, moreover, I am convinced that the spirit of freedom is unquenchable, and that no combination of powers will be able to rout it from the British Commonwealth of Nations and the United States. Stronger even than this conviction is my faith in a God who will not suffer the defeat of man's aspiration to be master of his own soul. I am sure that all of you share that faith, and that we need not argue it. We can start with the assumption that the war will end in victory. The subject we are to consider, then, is the relationship of the English-thinking peoples during the conflict, and their joint responsibilities in the difficult days that will follow it. A CANADIAN-AMERICAN No talk on such a subject is worth listening to unless the audience knows the background and fundamental beliefs of the speaker. No human statement stands alone; behind and beside and within it are the ideals and the bias of the man who makes it. Because I am a stranger to most of you, I am constrained to talk about myself before I talk about more important matters. The review may be profitable, not because of the subject, but because it may illustrate the evolution of an attitude toward England.

Jan 1, 1941

By Bruce A. McFarlane

"I WOULD LIKE TO SAY how honoured I am that I have been invited to participate in this panel discussion. I have taken the liberty of narrowing my topic somewhat so that instead of speaking on the Sociology of Professions as a whole I will speak on one aspect of it, that is, on Manpower Problems in the Minerals industry of Canada, with some reference to a new social role for the professionals engaged in this industry. This probably means that I will be encroaching on areas covered or to be covered by other speakers, but I hope that when I do so I will do so from a slightly different vantage point. That is, from a sociological perspective rather than from a historical, industrial, business or professional perspective. I plan to divide my discussion into three areas, namely: (i) problems of ownership and control; (ii) environmental problems; and (iii) manpower and recruitment problems. I do not plan nor am I able to provide clear-cut solutions to the various problems I raise under these three headings. Rather, I hope that my discussion of the problems may form the basis for an extended discussion here and elsewhere. Because of the limitations of time, I will only briefly discuss the first two problem areas noted above – (i) ownership and control and (ii) environmental problems - and I plan to concentrate on the manpower issue."

Jan 1, 1972

By A. Ignatow

"A review is made of some of the principal factors and conditions that are, and will be, important to the over-all market climate for asbestos fibre and for the future of Canada's asbestos industry: - health hazard associated with asbestos exposure;- uncertain international regulatory environment for continued asbestos use;- adverse public reaction to asbestos;- product liability/litigation costs (U.S.A. primarily);- promotion of substitution by governments and asbestos user industries; and- minimal product and market development efforts by asbestos producing and consuming industries.In addition, Canadian producers, who export some 95 per cent of their production, face additional constraints:- dramatically reduced integration with asbestos-consuming industries;- 60 per cent of exports to most rapidly declining markets (U.S.A., Europe);- increased competition from offshore producers favourably located to growth markets in developing countries;- increasing production costs;- a strong dollar;- disadvantageous freight rates; and- loss of price leadership and price erosion.Future market trends, as well as prospects for Canada's asbestos industry, will be projected in this paper.Economic FactorsTable 1 presents asbestos fibre production in all countries for the period 1980-82. In certain instances, e.g. U.S.S.R. and China, these are capacity estimates as production statistics are not officially published. The U.S.S.R, by far, is the world's largest producer accounting for some 50 per cent of world production, though most production is consumed internally or by COMECON countries. It is estimated that some 700 plants produce asbestos-containing products within the U.S.S.R.Canada accounts for some 25 per cent of world production though it ranks first in world trade. Other important producers are South Africa Zimbabwe, Brazil and Italy. Since 1979, Canada's asbestos mining industry has experienced a dramatic drop in production and exports of asbestos fibre, as demonstrated in Table 2."

Jan 1, 1985

By D. C. Rance

"The Quintette Coal Limited property is located in the north east coal area of British Columbia. A basic agreement with the Japanese steel industry was ex ecuted on January 27, 1981 for the sale of 69.5 million tonnes of Quintette metallurgical coal over a 14.5-year period. This contract period can be extended by Jive years by mutual agree ment. Sale agreements have also been signed for the sale of 19.4 million tonnes of oxidized coal over a 15-year period. Work started on site development in the late summer of 1981, and at present, two of the four eventual pits-the McConkey and Frame-are under development. The pits are currently in a pres/ripping phase. These pits are notable for the stripping volumes that have to be removed from relatively small pit areas. in order to provide for the required detailed rapid short-range planning of these pits, engineering will be computerized, as will the truck dispatch system. The mining area lies 21.1 km from the plant site by road and the transport of raw coal LO the plant is by means of a highspeed conveyor system which has a total length of 13.4 km with a vertical drop of 740 m. The surface plant facility was designed on a modularized basis to facilitate maintenance, and is designed to enable the use ofgravity flow ofraw coal and heavy media in the plant to minimize the use of pumps. The construction of the plant and mine site facilities is on-going, and the first coal production is scheduled for early December 1983. Introduction Quintette Coal Limited is a Canadian company incorporated in the province of British Columbia in 1971. Denison Mines Limited is the manager of Quintette's activities. Equity in Quintette Coal Limited is held by several shareholders, with interests as follows: Denison Mines 'Limited, 500Jo; Charbonnages de France International S.A., 120Jo; and Japanese interest, 38%. The project will develop almost 120 million tonnes of coal for marketing during its first 20 years of production. All of the planned production tonnage has been committed to Japanese markets. Most of the coal will be metallurgical grade, and the remainder will be a high-quality thermal coal. The Mcconkey and Frame pits, which will initially provide the mine's production, will commence production in early December 1983 and will, in 1985, reach the full annual production of 5 million tonnes clean metallurgical coal and 1,380,000 tonnes of clean thermal coal."

Jan 1, 1985

By O. C. Rojas, J. Sanhueza, J. C. Vargas

Empresa Nacional de Minería (ENAMI) is dedicated to the promotion of small and mid scale Chilean mining industry. Paipote, ENAMI Copper Smelter, processes a variety of mineral products as the result of this promotion. The mineral products characterize a wide variation of copper, iron, sulfur and precious metals content as well as the significant dispersion in the content of impurities, such as arsenic, antimony and bismuth. The Smelter Modernization Program, initiated in1997, introduced a series of technological and operational changes. The development of operational planning and control strategies was necessary to optimize the blending of a wide variety of concentrates and the control of metallurgical processes in order to ensure the stable operation, fulfillment of environmental regulations and the quality of produced copper anodes. A permanent optimization process carried out in the last decade led to the permanent increase of the smelting capacity and the production of anodes and sulfuric acid. Additionally, introduced improvements affected the smelter efficiency and metallurgical recovery, demonstrating the possibilities of the optimization of a small smelting facility reflected in good metallurgical and economic results. This paper presents the smelter evolution, introduced technological and process control changes as well as incorporated new reactors and equipment as a continuous process of optimization.

Jan 1, 2007

By L. Van Wyk, J. Fernandez, J. Suarez, L. J. Diaz, A. Uria, D. Breeuwer

"Ventilation is an essential component of any underground mine, playing a vital role in ensuring the health and safety of workers, and a mine’s continuous operation. At a time when mining companies are increasingly having to move to deeper underground operations in pursuit of high-grade ore-bodies, the search is on for more efficient ventilation systems that will allow mining to be carried out at even deeper levels whilst ensuring the protection of workers and the maximisation of productivity through temperature management and the lowering of energy costs. Mining companies today are looking for innovative ways to deliver new technologies and procedures to enhance their mine’s profitability. Energy consumption by mine ventilation systems is higher than ever due to stringent specifications of underground equipment (primarily combustion engine emissions), air quality standards and mining at deeper levels which all require more powerful ventilation systems. With energy costs associated with operating ventilation systems being a mine’s second-highest cost of production after labour, finding the optimal ventilation solution is critical to a mine’s performance. Proper fan design remains a major factor in reducing capital expenditures (CAPEX) and operational expenditures (OPEX), which means that there are compelling reasons for making use of comprehensive factory testing at full power before fans are dispatched to site to simulate the mine’s current and future design requirements, and thus verify the fan’s effectiveness in ‘real’ conditions.INTRODUCTION A primary mine fan is considered the heartbeat of the entire mine ventilation system, drawing fresh air from the surface and providing a safe environment for miners. A ventilation system’s lack of performance often leads to a reduction in acceptable air quality levels for underground working operations and can potentially have an adverse impact on production rates."

Jan 1, 2019

By G. A. Brown

"Mining executives are becoming increasingly involved with decisions of the ""What would happen if ... "" variety. Potential changes in government policy, such as tax incentives, E.G.M.A. allowances, etc. affect the economic future of present and proposed mining ventures.This paper will discuss various measures of effectiveness normally used in assessing this future, such as discounted cash flow, etc., and will describe means of introducing uncertainty into the computations. As the recognition of risk and attitudes toward accepting it are very important in the life of a mine executive, there will be a brief discussion of utility theory and its application to risk analysis.Risk models are usually of a size to warrant the use of an electronic computer. Therefore, to demonstrate the simple interaction necessary between a financial analyst and such a model, data will be read into a remote computer from a time-sharing terminal in the meeting room. It will be shown that changes may be rapidly made and alternative policies investigated ""on line"" to a computer."

Jan 1, 1970

By G. J. Heferen, A. Pranowo, N. J. Aslin, P. O. Eriksson

Glencore Technology (GT) has over four decades experience supplying stainless steel cathode plates (“cathode plates”) to the electro-refining and electro-winning industry. Cathode plates are typically the single biggest capital investment in a refinery. Refineries may view cathode plates as fixed asset or consumables depending on their operational characteristics. This paper examines the issue of cathode plate life and the strategies and philosophies used by different plants in the management of their cathode plate asset. Some plants operate with their original plates after more than 20 years. Others accept high turnover and regular maintenance as normal operating practice. Reference data are provided on plate life for various operating plants including benchmark plants achieving best-practice plate life and operating cost. The role of the electrode handling equipment on cathode plate longevity is also examined, including latest developments in Cathode Stripping Machine, robotic copper stripping, and full-automation production cranes. The ability to identify and manage the population of plates in service is also critical for maximising plate life and minimising its overall operating cost. This paper discusses a novel and unique RFID system for tracking and managing cathode plate inventory. INTRODUCTION Permanent cathode plates The adoption of permanent stainless steel cathode electrodes in the electro-refining of copper was the most significant process development since the first commercial electro-refineries were built in the late 19th century. It provided significant improvement over the labour intensive and complicated starter sheet system. Copper grows over the permanent cathode blade for a number of days before being stripped, and the permanent cathode can be returned straight back to cells for the next cathode cycle. Glencore Technology (formerly Mount Isa Mines (MIM), then Xstrata Technology) has been manufacturing permanent stainless steel cathode plates from the late 1970s with the birth of ISA PROCESS™, and the Kidd process that came one decade later. Invented and commercialised by Mount Isa Mines, the ISA PROCESS™ was first implemented into Copper Refineries Limited (CRL), Townsville, in 1978. The KIDD PROCESS by Falconbridge evolved in the 1980s and was first implemented into the Kidd Creek Tankhouse, both operations converting from traditional copper starter sheets.

Jan 1, 2019

By D J. Murray

This paper outlines the principles of friction hoisting and the components involved, and gives a description of a specific mine hoist. Friction hoisting is compared with conventional drum hoisting, and the depth of shaft at which friction hoists become more economical than drum hoists, with respect to power consumption, is determined. Introduction T HE purpose of this paper is to outline the principles of friction hoisting, to describe the components and to show the advantages of multi-rope friction hoisting. Some calculations are made to show that the power requirements and the initial costs of friction hoists are less than those of conventional drum hoists, once a certain depth of shaft has been reached. The use of multi-rope friction hoists is gradually superseding the employment of the conventional drum hoist in many parts of the world. It results in heavier payloads from deeper levels, an increase in shaft safe-ty and a more compact installation for protection against adverse weather conditions. It was observed that where drums and friction sheaves exceeded 30 feet in diameter, a number of mechanical disadvantages were being experienced;

Jan 1, 1965

By Charles Graham

It is the general belief that the coal deposits on Vancouver Island are extremely large, and easily available. Indeed, they are frequently described by prominent public men and by writers in the press as "illimitable" and "inexhaustible." It is well that the facts that have been established as a result of seventy years of surface prospecting, underground operations and extensive diamond-drilling in this coalfield should be disclosed. HISTORY The presence of coal on the coast of British Columbia was first made known by Dr. W. F. Tolmie in 183 5. This coal was brought to him by Indians from the north-east coast of Vancouver Island, probably from Suquash. In 1850 the existence of coal at Nanaimo was announced by Mr. ]. W. MacKay. Development was started in 1852, and coal was shipped before the close of 185 3. The first operations were carried on by the Hudson's Bay Company, who operated the mines until 1861, when they sold them to the Vancouver Coal Mining and Land Company. Practically all of the operations in the immediate vicinity of Nanaimo have been carried on by this Company and its successors. In 1869, Mr. Robert Dunsmuir discovered coal about five miles north-west of Nanaimo, at Wellington. The Welling-ton Colliery Company was organized, and began to produce coal from the Wellington mines in 1871, the coal being shipped from Departure bay. This colliery was a large producer for several years, but was finally closed in 1900.

Jan 1, 1924

By A. R. Chambers

Malagash received its name from the Indians many years ago on acco.unt of its turbid (milky) waters, although,' the red men did not appreciate the significance of this turbidity, and were, of course, entirely ignorant of the crystal beds of pure salt that lay beneath their feet. The salt lake of the Mississippian, or Lower Carboniferous period, in which these beds occur, was apparently a large one, for there is evidence of its existence at intervals all the way from Sydney, Cape Breton, to St. John, New Brunswick, 300 miles as the crow flies, and there is no knowing what its other dimensions may have been, as much of this horizon is now buried on the one side beneath the waters of the Gulf of St. Lawrence, and on the other underneath the Atlantic ocean. About midway of the area and underlying the counties of Colchester and Cumberland, there occurs a synclinal basin of which the Malagash salt outcrop forms only a small portion of its northern limit. This basin has been described very fully by A. C. Hayes. (1) The operations carried on at Malagash since Hayes wrote his report have brought to light very little in the way of new geological data, except to confirm his pre-dictions as to the probable faulting of the salt strata, and the effect which these faults would have on mining operations.

Jan 1, 1924

By P. K. Kaiser, C. D. Martin, F. Amann

"This article focuses on the uniaxial compressive strength (UCS) of homogeneous and heterogeneous rocks. Critical factors impacting the UCS of rocks are reviewed and then separate assessments of UCS data from homogeneous and heterogeneous rocks are presented. The variability (coefficient of variation) of UCS test results for homogeneous rocks is found to be generally <25% while for heterogeneous rocks the variability is >35%. Failure mode variation is found to be the cause of the variability of UCS test results in heterogeneous rocks. Empirical engineering design methods that use UCS as an input parameter are discussed and suggestions are provided for selecting appropriate UCS values.INTRODUCTIONThe UCS is one of the most commonly used rock engineering parameters whether for rock mass classification or for strength determination. The mean UCS and its variability are often assumed to represent a reliable rock material property. For the reasons discussed in this article, UCS is rarely representative of the intact rock UCS. The UCS test simply records the collapse load during uniaxial loading of a cylindrical specimen. As suggested by many, the UCS is an index rather than a unique engineering parameter. The UCS is thus a proxy for rock strength which depends on the loading rate (e.g., Bieniawski 1967), specimen geometry (e.g., Hudson et al., 1971), specimen size (e.g., Bieniawski 1968), and many other factors. Furthermore, the UCS is not the same as the Hoek-Brown strength criterion parameter sci.There are differences in opinion on what is commonly considered to be ‘intact rock’. When sampling ‘intact’ pieces of core from drillholes crossing blocks of rock bound by block forming discontinuities, samples will be ‘intact’ but some samples will be veined, others will be damaged, and others will be neither. According to Hoek (1983), intact rock pieces are “the unfractured blocks occurring between structural discontinuities in a typical rock mass” and the sci parameter for intact rock is determined using the fitting procedure proposed by Hoek and Brown (1997) based on the data requirements outlined by Hoek (1983). Studies (e.g., Bewick and Kaiser 2014; Kaiser and Kim 2014) have shown that independently determined UCS and sci values for the same rock type are not equivalent. Thus, UCS data cannot be used as a replacement for sci."

Jan 1, 2015

By A. J. Oliver, C. E. O’Neil, I. J. Itzkovitch, V. A. Ettel

A new solvent extraction process for the separation of cobalt, copper and zinc from nickel sulphate process streams has been developed. It involves selective extraction of these elements with a quaternary ammonium thiocyanate dissolved in an aromatic diluent. The chemical principles of this process have been investigated and are described, together with background physico-chemical data relating to the use of this solvent. Long-term testing in a continuous "mini-plant" circuit gave high-purity nickel and cobalt products (Ni/Co —200011 and Co/Ni ~1000/1 respectively).

Jan 1, 1976

By H. W. Kasaini, E. Bourricaudy, T. Larochelle

Rare Element Resources Inc., a U.S. based company, has developed a three-stage process for producing a +98% mixed REO powder from hard rock feedstock (-48 mesh, 2.9-4.8% REO) consisting of bastnaesite and ancylite minerals. Firstly, the whole ore is digested in chloride media at low temperature in counter-current flow mode. Secondly, the rare earths (REEs) are selectively precipitated as oxalates directly from an impure pregnant leach solution (PLS). Finally, significant amounts of free acid and water are recovered from the REE-depleted filtrate and subsequently recycled within the process. Excess heat from the oxalate calcination process is captured and reused in the plant. Due to the low leach temperature (45 ºC) and moderate acid dosage (240-297 kg/t, HCl), rare earth oxides (REOs) are preferentially leached out of fine solids leaving most of the base metals (Ba, Fe, and Al ) in the residue. Selective recovery of REEs from the PLS is achieved by mixing dilute oxalic acid (33% H2C2O4) and PLS at elevated temperature (85-95 ºC). The REEs plus thorium are precipitated as oxalates (REE2 (C2O4).xH2O) while the base metals are left behind in the barren filtrate. Multiple batch and pilot test results have confirmed that 50-80% of the oxalic acid can be recovered from the REE-depleted PLS through low-temperature crystallization (10-15 ºC). Typical leach efficiencies of critical rare earths at 45 ºC range from 85-99% (average 93%) while oxalate precipitation at high temperature increases the crystal size of RE oxalates (>450 microns, d80) thereby improving filtration. The economic benefits of this process include elimination of flotation and magnetic separation Capex and driving hydrometallurgical Opex down to $6- 7/kg, REO produced. As part of a comprehensive risk mitigation strategy, Rare Element Resources Inc has operated multiple pilot plants at SGS in Lakefield, Ontario, Canada to optimize counter-current leaching (CCL), REE oxalate precipitation (OXP), and thorium removal circuits. This paper presents pilot testing data from CCL and REE OXP circuits.

Jan 1, 2016

By K. S. Raja, F. Battick, B. Pesic

"CeO2 doped with lower valence cations, such as Y3+, Sm3+, Gd3+ etc. is considered as electrolyte material for low temperature SOFC. Doping introduces additional oxygen vacancies and improves ionic conductivity. This work describes the preparation of yttria-calcia doped-ceria precursor material, its sintering in DC and AC field methods, and characterization of sintered electrolytes with respect to the ionic conductivity. Doped precursor materials were prepared by a controlled co-precipitation process. Sintering of prepared, pelletized particulates was carried out using three different methods such as: 1) conventional; 2) spark plasma sintering; and 3) an alternating current field at 1125°C (AC assisted sintering). The mechanism involved in the conductivity improvement as a function of defect density, grain boundary area and phase stability will be discussed. INTRODUCTIONThe performance of SOFCs depends highly on the properties of materials. Subtle variations in the composition, microstructure, or density of SOFC components can considerably alter the power output capabilities of fuel cells. Early SOFCs utilized zirconia based electrolytes but efforts in lowering the operating temperatures of SOFCs have prompted investigations into several other oxygen ion conductors – often modified with dopants to either promote the formation of oxygen vacancies or to stabilize a vacancy rich high temperature phase – such as bismuth oxide, lanthanum gallate, and ceria.The transport of oxygen ions through the electrolyte first begins with diffusion into the material. While this is generally a surface kinetics phenomenon, it is safe to say that it is highly dependent on oxygen pressure and vacancy gradients. The role of the cathode in SOFCs is to reduce oxygen at the electrolyte surface creating an O2– ion gradient which induces permeation into the material. Once inside and under the influence of a potential field, O2– ions migrate by a vacancy hopping mechanism, Catlow, C.R.A. (1990), effectively exchanging positions throughout the matrix until they reach the anode and react, thus leaving the matrix."

Jan 1, 2012

By P. Trudel, M. A. . Cloutier

This lithogeochemical study demonstrates that the Gilman and Blondeau Formations in the Chibougamau area belong to a subalkaline suite of tholeiitic affinity poor in potassium. The Gilman Formation is composed mostly of basalts, with subordinate andesites and rare dacites, while the Blondeau Formation comprises all lithologies of the basalt-andesite-dacite-rhyodacite-rhyolite ensemble. Both AFM and Harker variation diagrams show that all these rocks originated by differentiation from the same magma reservoir, and are related to one volcanic episode, This study did not, however, identify hydrothermal alteration zones useful for regional geochemical prospect ion.

Jan 1, 1984