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By W. A. Calhoun

This investigation of low-grade bauxites as potential sources of aluminum by caustic desilication and alumina extraction was undertaken by the Bureau of Mines to develop extractive methods for winning alumina from domestic deposits of low-grade bauxites. This report is the second of a series covering the work by the Bureau of Mines' Rolla, Mo., and Bauxite, Ark., laboratories. The first report published in the Journal of Metals, December 1951,3/ and dealt with kaolin and halloysite. The present investigation is concerned with low-grade bauxites only. The purpose of these investigations is to increase the domestic supply of aluminum ores. With eventual depletion of high-grade deposits, aluminous materials, such as low-grade bauxite, clays, shales, and high-iron laterites, will become our principal domestic sources of aluminum. The development of extractive processes for winning alumina from these low-grade materials is one of the many national security measures undertaken by the Bureau of Mines. A method has-been developed in the laboratory for successfully treating high-silica bauxites from domestic deposits. In this process the bauxite was calcined at 980° C. to form amorphous silica and alumina. The calcine was then leached by percolation with 15-percent sodium hydroxide solution at 940 to 96° C., removing 67 to 77 percent of the silica with a loss of 4.1 to 5.0 percent of the alumina. The sodium hydroxide in the spent liquor used in desilication was 95 percent recoverable, and comparable desilication results were obtained with 100-percent reclaimed liquor, The indicated cost of reagents, for sodium hydroxide and lime used in the desilication and regenera¬tion of spent liquor, was about $4.00 per ton of calcine treated.

Jan 1, 1954

By Willard J. Tesch

The borehole surveying system described is used to measure ground movement over and near operating mines. The magnitude of any movement is con-trolled by the ground conditions, the mining method, and the mine progress. By correlating these factors with the measured movement, equations can be determined for predicting the effect of mine progress on the surrounding ground. These equations can also be used to predict the effect of mining a similar deposit with similar ground conditions. The borehole surveying system is used in cased boreholes to measure the inclination of the hole in two perpendicular planes. Grooved casing with an inside diameter of 3 inches is grouted in the hole. Two probes are used to obtain the data necessary to calculate the hole position versus depth. One of the probes contains a gyroscope, and the other contains a biaxial force-balance [s]ervoaccelerometer. Readings from the transducers in the probe are punched on paper tape by an automatic data acquisition system as the probe is pulled up the hole at 30 feet per minute by an electric winch. Readings from the inclinometer probe containing the accelerometer are used as input data to an on-line programmable calculator as they are punched on tape. The calculator computes preliminary results of the survey being made. The paper tapes obtained during the survey runs are later used as input to a computer that computes the offsets of the drill hole versus depth in true north-south and east-west planes. These offsets are printed for each foot of depth. Changes in these offsets between the first survey and subsequent surveys are a measure of the horizontal ground movement between the surveys.

Jan 1, 1976

By J. W. Miller

An investigation was begun by the Bureau of Mines in 1948 to determine the preparation characteristics of American coals. Results of the investigation were planned to be reported on a county basis and from the data developed, to determine: (a) Which coals either as mined or after beneficiation by conventional preparation are suitable chemically under present standards for producing metallurgical coke. (b) Which coals require special and more intensive treatment in preparation than is now practiced. (c) Which coals cannot be considered potential sources of metallurgical coke regardless of preparation. This report is one in a county series that describes the preparation characteristics of the coals of Mingo County, W. Va.

Jan 1, 1956

By W. M. Dressel

The Federal Bureau of Mines has obtained data by differential thermal analysis of the various minerals that represent the nation's resources in manganese. These data are supported by X-ray diffraction analysis, chemical analysis, mineralography, and optical mineralogy, and provide fundamental information on the response of each mineral to thermal treatment in oxidizing, reducing, and neutral atmospheres. The information can be applied advantage¬ously in the identification of manganese minerals. Its greatest potential value, however, lies in the application of the quantitative data on the reaction temperatures, rates, and products to the more efficient extraction of manganese from U.S. ores. Thermal analysis curves are presented for certain manganese minerals, namely hausmannite, bixbyite, braunite, pyrolusite, lithiophorite, cryptomelane, hollandite, manganite, rhodochrosite, and rhodonite. The original minerals and the products of their thermal decomposition were identified by X-ray diffraction analysis, supplemented by chemical analysis and mineralogical identification.

Jan 1, 1961

By Raymond O. Dannenberg

The gas-combustion retort developed by the Federal Bureau of Mines at the Rifle Oil Shale Project near Rifle, Colo., is a continuous, gravity-feed retort. The heat required to convert the kerogen in the oil shale to liquid oil is generated by the combustion of product gas and carbonaceous residue remaining on the retorted shale after the kerogen has been converted to oil, gas, and residue. A study of the effects of the process variables on retort operation, product yields, and product properties is important to the successful solution of the problems encountered in the development of a satisfactory process. Statistical methods were used to design the experiments and analyze the effects of the rate of shale throughput, the composition of dilution gas, the height of the shale bed above the air entry, air-gas distributor design, shale size range, and the ratios of the flow rates of the various gas streams entering the retort to the rate of shale throughput.

Jan 1, 1960

By H. M. Thorne

Oil shale, a potential source of products presently obtained from petroleum, is found in many countries. The most extensive known deposits from the standpoint of potential shale oil in place are those in Brazil and the United States of America. Mining methods used for oil shale range from open-pit operations for shallow deposits to room-and-pillar and longwall techniques for deposits with thick overburdens. Oil shales from different sources vary greatly in the amounts and types of organic and inorganic constituents. By retorting, the organic material is converted to oil, gas, and coke. The largest percentages of oil are obtained from materials having the highest hydrogen content. Over 2,000 retorting systems have been patented, but only a few have been used industrially, and no single process seems best for all types of shales or economic conditions. Shale oils have different characteristics, depending on the source rock and method of retorting. They contain large quantities of olefinic hydrocarbons and more oxygen, nitrogen, and sulfur derivatives of hydrocarbons than most petroleums. Consequently, petroleum refining methods usually must be modified for shale oil. This is particularly true in catalytic processing. Hydrogenation, even under mild conditions, improves shale-oil refinability. Several byproducts may be obtained from both the retorting and refining steps,

Jan 1, 1964

By W. L. Dare

This information circular is one of a series published by the Federal Bureau of Mines in which the methods and costs of producing uranium ore on the Colorado Plateau are discussed. This report describes the three largest company-operated uranium mines of Climax Uranium Co. - the G-1, the Mineral Joe, and the Frank No. 1. Climax Uranium Co., a subsidiary of American Metal Climax, Inc., was [corporated] May 11, 1950, just 2 years after establishment of the domestic uranium program by the Atomic Energy Commission. Twenty-five years earlier Arthur H. Bunker, now chairman of the board, American Metal Climax, Inc., organized and operated the U. S. Vanadium Co. at Rifle, Colo.3/ Soon after Climax Uranium Co. was organized, it entered into a contract with the Federal Government to build a uranium-vanadium processing mill in Grand Junction, Colo. Under the contract Climax leased from the Federal Government certain uranium-bearing lands that had been withdrawn from public entry in 1948. From Minerals, Engineering Co. on June 12, 1950, Climax acquired other uranium-vanadium properties on Calamity, Outlaw, and Monogram Mesas in Colorado and on Polar Mesa and in the Yellow Cat area of Utah. To house the milling equipment, Climax leased the old Grand Junction sugarmill building of the Holly Sugar Co. Milling facilities, based on a then new process developed for treating both uranium and vanadium, were completed, and the plant went into production in 1951.

Jan 1, 1959

By J. R. Thoenen

During 1928 questionnaires covering the calendar year 1927 were sent to over 1700 quarries: producing stone for purposes other thaw cutting to dimension. These inclined producers of stone for limn burning; cement manufacture, rip rag, and crushed stone. The various rinds of stone represented were limestone, trap rock, sandstone, granite, and marble. Replies received from limestone producers prior to November, 1928, were compiled into tables and published in February, 1925, as a preliminary report (Bureau of Mines Report of Investigation 2911).

Jan 1, 1930

By Herbert H. Einstein

The innate variability of natural materials and processes causes uncertainty in the models representing the natural phenomena and uncertainty in estimating the parameters that are used in these models. Reliability analyses, in contrast to the traditional factor of safety approach, are well suited to a rational incorporation of uncertainty in design and exploration decisions. Probabilistic kinetic and kinematic analyses were developed and combined to form reliability analysis methods. With one method the reliability, i.e.) the probability of failure, of an individual 2-plane wedge in a slope can be determined. The other method is aimed at slopes with a single slope parallel set of joints. In each case two approaches were developed, an encompassing one relying on computer codes and a simplified or summary approach relying on charts or pocket calculator computation. A major contribution of these approaches is the treatment of joint persistance. Instead of having to assume a certain persistence, it is now possible to use exploration data on joint geometry and to include the persistence effect rigorously.

Jan 1, 1979

By Kim B. Shedd

The Bureau of Mines measured fiber dimensions on crocidolites (riebeckite-asbestos and magnesioriebeckite-asbestos) from the world's four crocidolite mining regions. The objective of the study was to determine whether there are measurable morphological differences between crocidolite fibers that correlate with the high reported incidence of mesothelioma in miners and mill employees in the Cape Province of South Africa and Western Australia, as compared with little or no reported incidence of this cancer in the Transvaal Province of South Africa or Bolivia. Fiber dimensions measured with the scanning transmission elec-tron microscope showed that crocidolites from Western Australia and the Cape Province have more thin fibers than crocidolites from Bolivia and the Transvaal Province.

Jan 1, 1985

By Pedro Lilienfeld

This Final Report describes a program whose objective was to design, develop, fabricate, and test an airborne mass monitor for unattended and recording measurements of the concentration of dust in mining environments. Sensing collection are performed by beta-radiation attenuation and inertial implementation respectively. The instrument is portable, battery or line operated provides a digital printout of the mass concentration during each selection sampling period, as well as the accumulated mass of dust, and the elapsed sampling time.

Jan 1, 1974

By Joseph Blake Smith

Coal resource data from published sources and company files were used by the Bureau of Mines to determine the location and extent of strippable coal reserves in Wyoming. Total strippable reserves of 23 billion tons were estimated in seven major coal areas. Seven large strip mining operations were active in 1969, and their production totaled 45 million tons of coal. Cutoffs used to define strippable reserves were (1) minimum coalbed thicknesses of 5 feet; (2) overburden-to-coal ratios of less than 10 cubic yards of over- burden per ton of coal; and (3) total overburden thicknesses of less than 120 feet, except where reserves occur in multiple beds or a single thick bed. Tertiary rocks along margins of the Powder River basin contain most of the strippable coal reserves in Wyoming. The Wyodak beds, ranging in combined thickness from 30 to 1.30 feet, crop out on the east flank of the basin and contain an estimated 19 billion tons of strippable subbituminous C-rank coals under less than 200 feet of overburden. Partings between these beds total less than 60 feet. The 100- to 200-foot-thick. Healy bed on the western flank of the basin and the 35-foot-thick School and 20-foot-thick Badger beds on the south also contain large strippable reserves. Elsewhere in Wyoming, strippable reserves. Elsewhere in Wyoming, strippable deposits are subbituminous coal of Late Cretaceous and Tertiary ages, mostly in the Hanna and Great Divide basins in the south-central portion of the State and in the Kemmerer-Hamms Fork region in the southwestern corner.

Jan 1, 1972

By J. B. Cunningham

Lithium in the form of metal, salts, and alloys is particularly important because of increasing industrial uses resulting partly from wartime developments. Lithium carbonate and lithium strontium nitrate, which impart a brilliant red color to a flame, are used in pyrotechnics. Lithium chloride and fluoride are used in fluxes for welding aluminum to dissolve the oxide coating on the aluminum and prevent oxidation of the molten metal. Lithium carbonate is used in ceramics in raw alkaline glazes because of its unusual fluxing properties. The use of 9 to 12 percent lithium carbonate permits a marked increase in the amounts of alumina, calcium, and silica that may be Used and results in a more stable glaze with sufficient alkalinity to produce vivid copper blues and other typically alkaline colors. Lithium stearate is used as a grease in airplane engines because of its ability to withstand wide changes in temperature. In view of its great affinity for nitrogen, hydrogen, oxygen, sulfur, phosphorus, carbon, and silicon, lithium has an excellent scavenging action on molten metals. It forms stable nonmetallic compounds of low specific gravity or gases that are eliminated at pouring temperatures. Lithium is generally added to the melt in the form of a lithium-calcium alloy consisting of 50 percent of each ingredient or as an alloy of 98 percent copper and 2 percent lithium. The lithium-calcium alloy added to cast iron before pouring, acts as a scavenger and increases the fluidity of the melt. This alloy also is said to increase the corrosion-resistant properties of stainless steel alloys and to improve their polishing qualities.

Jan 1, 1948

By W. T. Wertman

A research program to aid development of better petroleum-recovery technology is in progress at the Appalachian Experiment Station, Bureau of Mines, Morgantown, W. Va. The work is part of the overall effort of the Federal Bureau of Mines to effect true conservation of the Nation's natural resources. Knowledge of the magnitude of the interstitial water content of oil-bearing formations is important to petroleum-reservoir engineers because of the influence of water on fluid flow during oil production and because of the significance of water volume in oil-reserve evaluation. Such information on Appalachian oil-bearing formations is needed to aid in planning secondary oil-recovery projects. Generally, the interstitial water content of oil sands can be estimated by one or more of the following methods: Analysis of cores obtained with oil-base drilling fluid, electric logging, restored-state or capillary-pressure tests, centrifuge tests, evaporation tests, or mercury-injection tests.

Jan 1, 1959

By W. W. Adams

"The main purpose in the compilation of accident statistics is to reveal conditions that may result in injury to persons or property so that remedial measures may be applied. For practical reasons it is usually found necessary to restrict inquiry to conditions which actually have caused personal injury, and to omit those which nay, but have not yet, resulted in damage, Fortunately or unfortunately, there is a sufficient number of the former to indicate the existence of hazards so numerous as to require all of the attention which the industry can devote to the subject.Two years ago, the Bureau of 'mines, in cooperation with the National Safety Council, undertook an intensive campaign to obtain more complete and satisfactory information regarding mine accidents than had theretofore been available. Since 1911 the bureau had been receiving annual summaries from all companies operating metal mines, showing, in a general way, the number and causes of accidents that occurred during the preceding year and the number of men employed at the mines. Monthly summaries of fatal accidents at coal mines were received from the state inspectors, showing the number of deaths attributed to each of 22 main causes of accidents, Information for individual coal mines was not furnished.While this information, nation-wide in scope, is indispensable because it epitomizes the progress or retrogression in the industry as a whole, and serves as a background of specialized studies, yet certain classes of acci¬dents, for example, those that are more or less peculiar to specific districts or mines, require an analysis in greater detail than is possible on the sole basis afforded by the annual summaries.The need for more specific information was realized some years ago in the State of Pennsylvania in connection with the administration of the workmen's compensation law, The mining industry is well acquainted with the val¬uable studies of accidents, particularly nonfatal accidents, in the mines of that State being conducted by Mr. Rush N. Hosier."

Sep 1, 1924

By Murray Jacobson

The respirable dust standard in the Federal Coal Mine Health and Safety Act of 1969 is designed to prevent disability and death from coal workers' pneumoconiosis. Beginning June 30, 1970, the operators of coal mines were required to maintain the average concentration of respirable dust in the active workings at or below 3.0 milligrams of dust per cubic meter of air. The standard is reduced to 2.0 milligrams per cubic meter after Dec. 30, 1972. This paper presents the equipment and procedures used by the coal mine operators in implementing the respirable dust sampling program established by the Secretary of the Interior and the Secretary of Health, Education, and Welfare and shows the effect of the law, during the first year, on the reduction of dust levels in selected mines. The system employed by the Bureau of Mines for analyzing and processing the dust samples is also presented.

Jan 1, 1971

By L. Garner McDonald

The U.S. Bureau of Mines tangentially impacted potential coal-cutter bit shank materials against sandstone to investigate the potential of the materials to ignite natural gas by a friction-generated hot streak. The shank material samples were mounted in a 24-in, 550-lb flywheel, which was rotated at surface speeds of 400 to 900 sfpm. The sandstone was advanced toward the rotating flywheel at feed rates of 1 mil per impact. The atmosphere mixture was 7 vol pct natural gas in air. Three grades of polycarbonate resin, an ultra-high-molecular weight polyethylene, and a zinc alloy (ZA27) were among the potential materials. None of these materials caused ignition of the methane at any of the three test speeds (400, 600, and 900 sfpm), but the above materials do not have sufficient strength to hold a carbide tip during coal cutting. Of the materials having sufficient strength to hold a carbide tip, three nickel-based alloys proved less likely to cause a natural gas ignition than did iron-based alloys such as 4340 (a commonly used shank material for coal cutters).

Jan 1, 2010

By Robert C. Gabler

Evaluation of incinerated sewage sludge as a secondary resource for aluminum, phosphorus, and minor constituents such as copper and zinc was initiated as part of the Bureau of Mines secondary resource program. The elemental composition of sludge ash for 14 plants in 11 U.S. cities was determined. Comparing industrialized cities with cities where most of the sewage is domestic, significant differences in heavy metal content were noted. Various parameters were investigated affecting the extraction of metals and phosphorus from a typical industrial city sludge ash and from a Palo Alto, Calif., sludge ash with a high precious metal content. Three extraction-recovery procedures for metals and phosphorus using sulfuric acid leaching, ion exchange, and various precipitation techniques were investigated. The last procedure developed was a combination approach using a three-stage countercurrent sulfuric acid leach that recovered most of the economic values from the sludge ash and also removed the leachable fraction of elements of environmental concern.

Jan 1, 1979

By C. R. Carpenter

A dynamic gas-mixing system assembled by the Bureau of Mines for the generation of precise gas mixtures from sources of concentrated or pure gases and diluent gases is described. A set of electronic mass flow controllers with maximum flows ranging from 10 to 5,000 ml/min, a so-called Pure Air Generator, and gases in cylinders are used to generate differing gas concentrations. The repeatability of the delivery rate of a flow controller, measured on different days, has a precision of 0.3 pct of the setting. This dynamic gas-mixing system reduces the cylinder inventory and the demurrage charges for special gas mixtures. Gas mixtures that cannot be shipped commercially, such as flammable mixtures of methane in air, can be conveniently prepared by this system. The maximum dilution ratio is 2.5 x 104. Thus, gas mixtures can be made over a wide range of concentrations, from the percent region (by dilution of a pure single-component gas) to fractional parts per million (by dilution of a premixed standard, e.g., a 1,000-ppm mixture). This system is especially useful in determining the response of gas detection devices over the entire range of their measurement. Because the controllers are voltage controlled they lend themselves easily to automated control using computer-based systems.

Jan 1, 1983

By Michael J. Beus

This Bureau of Mines report describes field investigations conducted in the Coeur d'Alene mining district of Idaho to obtain data on rock stress and physical properties. The resulting information has been utilized as input to detailed finite-element analyses to establish structural design criteria for deep-vein mine shafts. Measurement techniques include the Council for Scientific and Industrial Research biaxial and triaxial strain cells, the U.S. Geological Survey solid-inclusion probe, and the Colorado School of Mines dilatometer. Physical property testing was conducted in the laboratory on core obtained from each test site. Limited in situ physical property tests were also conducted. Reason-able success was obtained with the CSIR equipment, which was considered the most suitable for stress measurement in the study area. Test sites ranged in depth from 1,200 to 7,700 feet and are described in detail. The stress data were reduced by least-squares linear regression techniques to enable prediction of vertical and horizontal stresses to 7,500 feet. Ratios between the horizontal stresses as utilized for shaft design varied considerably, and a hydrostatic condition is the exception, based on Bureau measurements. Physical properties also varied widely, due to the complex geologic structure. Analyses of the data in terms of the tectonic history of the area show reasonable correlation. Data from previous rock mechanics investigations from the Coeur d'Alene district were also compiled and presented as part of this report to justify any generalizations regarding stress conditions and physical properties of the district as a whole.

Jan 1, 1980