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By Ronald S. Conti

This U.S. Bureau of Mines report discusses the results of research conducted in the Bureau's experimental mine at Lake Lynn Laboratory on the response of fire sensors to simulated mine fires, which included (1) a slowly developing coal-conveyor belt fire, (2) a rapidly burning liquid fuel-belt fire, and (3) a liquid fuel-belt fire in the presence of diesel exhaust. During these tests, several mine fire sensors were evaluated with respect to sensor placement, spacing, and type. The data indicate that smoke sensors alarm several minutes before CO sensors do; and that, in the presence of diesel exhaust, a prototype diesel-discriminating smoke sensor can successfully function without being sensitive to the diesel contaminants. The vertical placement of sensors in the entry near the fire was also shown to be critical in terms of alarm times. Additional data showed that variations exist in response time and level of response for two brands of electrochemical CO sensor. Results also indicate that early detection of fires will improve the probability of miners' escape, because of reduced smoke concentrations during the incipient stages of the fire.

Jan 1, 2010

By P. T. Brooks

This Bureau of Mines study describes a process for recovering nickel, cobalt, molybdenum, and chromium contained in complex waste superalloy grindings that, for lack of an economical domestic recovery process, are being largely marketed abroad. The process, devised by laboratory scale operations, includes scrap preparation, dissolution of metallics in hot chlorinated acidic liquor, carbon adsorption, three successive solvent extraction separations, and selective chemical precipitations. Nearly 90 percent of the nickel, cobalt, molybdenum, and chromium were separated and recovered as oxides, carbonates, and basic sulfate products.

Jan 1, 1969

By G. E. Walden

The Bureau of Mines is currently engaged in a continuing investigation of the thermodynamic properties of certain inorganic compounds. As a part of this investigation, the heat contents of bismuth and cerous chlorides were measured throughout the temperature ranges of 370° to 630° K. and 370° to 1,200° K., respectively. Equations representing heat contents as a function of temperature were derived from the data by the method of least squares. These equations were used to calculate heat contents at selected temperature intervals ranging from the ice point to 650° K. for bismuth chloride and to 1,200° K. for cerous chloride; also, the heats of fusion of both compounds were calculated at their respective melting points. EXPERIMENTAL Materials The cerous chloride used in this investigation was supplied by the National Carbon Company of Cleveland, Ohio. A chemical analysis indicated Ce 56.57 percent and Cl 43.39 percent. No attempt was made to purify the compound or identify impurities since the analysis showed only about 0.04 percent total impurities. Reagent grade bismuth chloride was used without additional purification.

Jan 1, 1961

By J. M. Stuve

Low-temperature adiabatic heat-capacity determinations were made by the Bureau of Mines in the temperature range from 5 to 300 K for the two crystalline modifications of zinc sulfide, sphalerite (ß) and wurtzite (a). The entropy at 298.15 K of sphalerite was evaluated as l4.02±0.04 cal/deg mole and wurtzite, l4.06±0.04 cal/deg mole.

Jan 1, 1974

By Richard J. Bielicki

The possibility of replacing the brattice cloth closest to the coal mine working face with an air curtain mounted on top of a continuous-mining machine or with a diffuser fan was explored by the Bureau of Mines. Preliminary tests conducted at a full-scale model working face with the brattice end set at 18 feet showed that the air curtain improved face ventilation only slightly and was not nearly as effective as placing the brattice at 10 feet. A 2,000-ft3/min diffuser was more effective than the air curtain. It is concluded that the air curtain probably could not function as a line brattice extension, although the diffuser fan may have some potential.

Jan 1, 1975

By W. T. Benson

Peacetime production of mercury in the United States is controlled by world mercury prices, with significant lags to be expected between price increases or decreases and resultant increased or decreased production. Twenty-four mercury-bearing mines and prospects in widely separated districts in western and central Nevada and one property on the Nevada-Oregon border were examined and sampled. The purpose of the project was to determine if some of the properties warranted more extensive exploration work to obtain information on possible reserves of commercial-and sub-commercial-grade ores. The investigation of mercury deposits in Nevada was sufficiently widespread and indicated several areas of interest in the State that merit further exploration work.

Jan 1, 1956

By Laxman S. Sundae

In the vast majority of American coal mines, roof bolt holes are drilled dry, mainly because of mine operator concern with the spent water creating adverse working conditions. Wet drilling, however, can increase drilling rates and the effective lifetime of the drill bits used. This study, carried out as part of an ongoing cooperative research program between the U.S. Bureau of Mines and the University of Missouri-Rolla, shows that the large volumes of water conventionally used in wet drilling are not necessary, and the performance benefits from wet drilling can be achieved with total volume flows on the order of 0.4 L per hole. This conclusion is validated based on the measured respirable dust generated in drilling Berea sandstone. The results are confirmed using a variety of bit shapes, which are also shown to have a significant effect on penetration rate.

Jan 1, 2010

Reduce worker exposure to respirable dust without interfering with bag-filling operations. Approach A dust control hood was developed which contains and captures dust close to its source and prevents it from entering the bag-filling operator's work place. How It Works A sheet metal hood is placed around the nozzle of the bag filling machine. The hood is connected through ducts to the plant exhaust ventilation system. Air pulled into the front of the hood and around the sides of the bag picks up dust generated inside the hood, and carries it to the dust collector. The size of the hood can be adapted to fit most fluidized valve-type bag-filling machines. The height of the hood depends on the bulk density of the product and weight of the bags being filled. The 14-inch-width of the hood allows it to be used on multi-nozzle baging machines spaced 16 inches on center. Only 2/3 of the bag is actually within the hood, and this allows easy operator access for placing the bags on the nozzle.

Jan 1, 1978

Develop a method for recovering phosphate from a wide variety of complex western phosphate materials, including low-grade ores, tailings, and unused fines. Approach A flotation technique is used for this broad type of extraction. The method includes depression of phosphate minerals and anionic flotation of carbonate minerals, followed by cationic flotation of silicate minerals. How It Works A slurry is prepared for flotation by sizing to remove a low-grade, high-impurity slime fraction. Depending on the material, further sizing and/or grinding steps may be used to produce a size concentrate or to remove gangue. The flotation feed is conditioned with H2SiF6 and a fatty acid emulsion. The H2SiF6 is absorbed chemically to the phosphate mineral surface, making it strongly attracted to water and preventing adsorption of the fatty acid. Under these conditions, the fatty acid is a selective collector for carbonate minerals, which are removed as a froth product. Next, the silicates are floated with an amine reagent added directly to the slurry without additional pulp preparation.

Jan 1, 1982

By Sidney Katell

Tonnage oxygen plants are or can be made available in sizes ranging from 150 to 1,000 tons per day. Capital requirements are estimated from $5,400 to $14,700 per daily ton, depending upon size of plant, cycle employed, and purity and discharge pressure of the product. Similarly, operating costs before return on investment will range from $4.80 to $10 per ton. INTRODUCTION Several processes4 5/ that can be used to convert coal to synthetic liquid fuels, synthetic pipeline gas, or hydrogen require high-purity oxygen as one of the basic raw materials. Depending on the and product and its specific use, the oxygen required will be of 95 or 99.5 percent purity. The quantity required, in turn, depends on the process for which the oxygen will be used and the size of the processing plant and will range from 150 to 4,000 tons per day.

Jan 1, 1960

By Robert D. Schmidt

This Bureau of Mines report describes the development and application of a computer model for simulating the hydrological activity associated with in situ leaching. The model is intended to provide uranium resource developers with a description of the flow behavior of leachants and ground water during the development, production, and restoration phases of a leaching operation involving an arbitrary pattern of injection and recovery wells. Different aquifer environments are modeled, using a closed-form solution to the partial differential equation that describes three-dimensional changes in piezometric head as a result of pumping from leachant injection and recovery wells. The computer program can model a maximum of, 50 arbitarily located wells. Numerical techniques involving difference quotients and Taylor expansions about time points are used to derive time, velocity, areal sweep, and fluid volume parameters associated with leaching hydraulics. These parameters are output by the program in graphic and tabular formats. Other numeric methods insure that the program running time is minimized without significantly affect-ing the accuracy of results.

Jan 1, 1980

By David H. Yee

Because of environmental concerns, the Bureau of Mines investigated an anhydrous chlorination process for the recovery of copper from chalcopyrite, Pelletized concentrate was reacted continuously with chlorine in a vertical shaft reactor at 550° to 750° C to extract copper-iron chlorides and elemental sulfur. The resulting molten metal chlorides drained from the reactor and collected in a receiver while sulfur distilled from the top and condensed in a separate unit. The tests were conducted in a 10-cm-diam reactor constructed of glass and in l5-cm-diam reactors constructed from various refractory materials. A high-alumina ramming mix exhibited the best resistance to molten metal chlorides and elemental sulfur in chlorine atmospheres. A reactor made with this high-alumina refractory was operated for 55 hr under actual chlorinating conditions without suffering any deterioration. Tests results show that more than 96 pct of the chalcopyrite was converted to copper-iron chlorides and elemental sulfur. Good separation of the metal chloride and sulfur products was achieved. After filtration, elemental sulfur of greater than 99 pct purity was obtained.

Jan 1, 1977

By A. R. Rule

Laboratory tests were conducted to study removal of magnesium impurities from western phosphate rock concentrates by selective leaching. The systems evaluated included leaching with dilute sulfuric acid, with ammonium sulfate, and in an aqueous medium with sulfur dioxide gas. Set standards for the magnesium impurity level of phosphate rock concentrates are not available, but industrial practice has indicated that magnesium in excess of 0.3 percent MgO causes problems in phosphoric acid manufacture. Removal of magnesium was accomplished with all three systems. With dilute H2S04 the magnesium level was reduced to less than 0.1 percent MgO with an accompanying P205 loss of 6 percent. Magnesium oxide levels from 0.3 to 0.2 percent were obtainable with ammonium sulfate. However, the system requires concentrate roasting at temperatures of 900° C or higher, heated pulps (100° C), and large quantities of ammonium sulfate. Selective leaching was obtained using S02 gas in an aqueous concentrate slurry. Magnesium oxide content was reduced to less than 0.1 percent without loss of phosphate.

Jan 1, 1970

By Roy L. Soderberg

Ground support for metal, nonmetal, and coal mines was examined through fill placement with a pneumatic stower to increase extraction, reduce ground pressures, and improve general mine safety. Several pneumatically stowed stope-fill products were tested to determine the effects of specific gravity, gradation, moisture, and impact velocity on the in-place density of the stowed fill. Hydraulic sand filling has now served the mining industry for several decades but because of the low density does not always provide ample support to the hanging wall; therefore, the sill and crown pillars sometimes build up excessive stresses that are detrimental to mining. Cementation of a dense fill adjacent to a pillar to allow 100-pct extraction of the pillar, or a fill that can be placed without the use of water and where water is a detriment to rubber-tired mining equipment, was found to be a possible use of pneumatic fill. Placing of coal mine washery products into abandoned underground workings is another possibility in order to completely eliminate surface impoundments.

Jan 1, 1976

By M. J. Brevoort

Research work in the Bureau of Mines cryogenic laboratory requires the use of high-sensitivity galvanometers of the d'Arsonval type in a building that is subject to unusually severe vibrations. A modified form of the galvanometer suspension described by Julius3 has damped the vibrations so successfully that a short note concerning it is thought to be desirable, The laboratory is on the site of the Amarillo helium plant near a building that houses gas engines of from 180 to 250 hp., driving compressors and electric generators. The distances from the galvanometers to the individual engines range from about 80 to 180 feet. The subsoil, consisting of black clay loam, transmits the impulses without much damping. The usual methods of protecting galvanometers from vibration were tried and proved fruitless. A Julius suspension purchased on the market was carefully installed in the hope that it would overcome the difficulty, but the conditions were too severe even for this elaborate arrangement. Several mudifications of the original Julius suspension, which were then introduced, resulted in almost complete elimination of all vibrational effects.

Jan 1, 1931

By J. A. Kost

Contract H0242013 was originally to evaluate through underground tests, water spray systems for controlling respirable dust at the face of a longwall plow. A number of difficulties were encountered which made such an evaluation impractical. The contract was modified to evaluate, in the BCR dust tunnel facility, the live factors believed to affect respirable dust levels. A 60-foot long; plow face mock-up was constructed in the dust tunnel, a facility with controlled airflow and dust concentration. Six types of nozzles were tested with the following parameters: two nozzle orientations, two levels of water pressure, two levels of airflow, and with and without simulated airflow through the gob. Of these factors, the most significant in reducing respirable dust levels was nozzle orientation, where the nozzle directed 45 degrees downstream resulted in 27 percent lower dust levels than those directed 45 degrees upstream (against the airflow). Following in order of effectiveness were the higher water pressure and the lower airflow. All nozzles tested resulted in similar dust reduction, i.e., the type of nozzle was the least significant factor.

Jan 1, 1979

By Levent Ozdemir

The results of a laboratory research program aimed at the development of a water jet assisted drag bit cutting system for coal mine applications are presented. Two types of drag bits, a conical and a plow bit, were tested in a hard sandstone rock with jet pressures of up to 20,000 psi. Jet locations investigated were in-front and behind the bit. For each jet mounting location, three jet impingement distances with respect to bit tip were tested. The closest jet impingement location to bit tip was found most effective, providing the greatest force reductions on the bit. Overall, significant bit force reductions up to 50 percent were obtained with jet assist. Also observed was a drastic reduction in airborne dust when jets were employed.

Jan 1, 1986

By P. A. Lawless

The objective of the research performed A for the Bureau of Mines on this contract was to develop a portable instrument for the detection of carbon monoxide (CO) in a mine environment. The desired characteristics were sensitivity and specificity for CO with a stable calibration. The sensor of the instrument was to be of metal oxide composition, requiring low power for compatibility with the types of batteries presently used in personal equipment in mines. The solid state design was also desired for ruggedness and small size. A key design feature of the instrument was to be provided by adherence to the intrinsic safety design requirements for electrical equipments operated in potentially exposive mine atmosphere. The Research Triangle Institute has prior experience in developing a solid state oxygen sensor using a thin film of zinc-oxide (Ref. 1) and experience in fabricating thin film devices. Solid state sensors utilized by other workers (Refs. 2, 3, 4, 5, 6) have included metal and semiconductor films and crystals of materials like carbon and aluminum oxide for the measurement of water vapor in the air and have relied upon measuring resistance and capacitance changes in the sensor in response to adsorbed vapors or gases. Since the effect of carbon monoxide in changing the resistance of various materials such as molybdenum, platinum, and zinc oxide had been reported (Refs. 7, 8, 9, 10), the requirements appeared to be realisable, although it was recognized even at the inception of the work that specificity to carbon monoxide might require the incorporation of more than one sensor.

Jan 1, 1976

By D. Dolinar, T. P. Mucho

Horizontal stresses are caused by global plate-tectonic forces. During 1995 alone they were largely responsible for the closing of two longwall mines in the United States. This paper presents six case histories from Pennsylvania, West Virginia, Kentucky and Alabama. In each case, a mine encountered roof falls or difficult ground conditions at the headgate caused by horizontal-stress concentrations. The problems are detailed, and the control measures adopted are described. In most cases, nearby longwall panels without stress concentrations were trouble free. The paper also discusses detailed measurements that were made at two adjacent Pennsylvania longwalls. One headgate was oriented to avoid a horizontal-stress concentration, and the other was not. Eliminating the stress concentration dramatically reduced roof support loads and roof deformation. The paper concludes that proper panel orientation and sequence is the key to maintaining headgate ground control. The optimum orientation is not parallel to the maximum horizontal stress, as previously thought, but rather it is 20° in the stress shadow of the gob. Other stress-control techniques, including artificial support, are briefly discussed.

By Harry E. Tufft

Data were obtained by the writer from a number of the large coul-mine operators in Illinois, on the consumption and cost of timber used in their mines and the quality of the timber now being used as compared with former years. This information supplemented by comparative date for previous years published in bulletins of the filinois Coal Mining Investigation series, and other sources, is presented below. This survey is part of a cooperative study with the . S. Forest Service, of the mine timber situation, with particular regard to the economies to be derived by better selection, preparation, and storage of timber, and especially treatment with preservatives to prolong the life. Geo. S. Rice, chief mining engineer of the J. S. Bureau of Mines, under whose general direction the work was done, gave valuable advice and criticism. R. B. Miller, State Forester, contributed helpful data which he had recent- ly obtained in an independent study of the mine-timber situation in Illinois.

Apr 1, 1923