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By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

The world’s first copper electrorefinery started production in 1869 at Burry Port in South Wales. Built within the Pembrey Copper Works which had commenced smelting operations in 1849, the new refinery was based on principles described in the British patents issued to J.B. Elkington in 1865 and 1869. Refining principles and practices pioneered there were key to the foundation of modern electro-refining practice in what is now a dominant international industry producing over 16 Mt of electrical grade copper annually. This paper explores the background to this pioneering application of the new, early 19th century, science of “electro-metallurgy” and examines its links to the contemporary decorative electro-plating industry and to the shortcomings of 19th century fire refining. The beginnings and early years of the Pembrey electrorefinery are briefly discussed in relation to the quality, applications and pyrometallurgy of copper at the time. More than a decade would elapse before the birth of the electrical age: the Pembrey refinery may be seen as one of its vital precursors. Note: This paper was originally published as part of the Copper 2013 proceedings (A.E. Wraith, P.J. Mackey and J. (formerly R.) Protheroe Jones, “Origins of Electrorefining: Birth of the Technology and the World’s First Commercial Electro-Refinery”, paper in Electrorefining, Vol. V, Book 2, (Eds. R. Abel and C. Delgado), Cu 2013 International Conference, pp. 19-33, IIMCh, Santiago, Chile, 2013). It is reproduced here together with a new Appendix and supporting references that lists the year of commencement of the first electrolytic copper refinery by country, 1869 to 1956. It all, the year of the first electrolytic copper refinery established for 15 countries is included. These 15 countries now produce more that 70% of world refined copper (for 2018). INTRODUCTION In the 1840s, the new science of ‘electro-metallurgy’, a term coined by Smee in 1841 (Smee, 1841), was being adapted to the decorative electro-deposition of silver in a thin, bright adherent coating that was evidently equal in appearance to traditional silverware (Williams, 1976). Chief among innovative manufacturers of decorative objects who took up the new art of silver electro-plating was the acclaimed firm of G.R. Elkington and Co. of Birmingham, England. The company, which vigorously developed all aspects of electro-metallurgy for the decorative trade, entered the field of ‘electrotyping’, a technique in which the surface features of a mould are copied on an electro-deposited copper layer which, when stripped off, can be used to reproduce an imprint of the mould. In essence, it is a form of casting by electrodeposition, invented in 1837 independently by Jacobi in Russia (Pavlova, 1968) and Spencer in England (Wyatt, 1851).

Jan 1, 2019

By Eleonardo Lucas, Christ Barriga

The use of saline water, a product of the sea water osmosis process, for the processing of the mineral from the Bayovar Mine in Peru, is part of the process of final disposal of the studied tailings. In this sense, this paper presents an experimental program implemented for the correct evaluation of this fine low-density phosphate tailings, the behavior of six solids contents prepared in the laboratory with limits between the range 8.5% to 21% were analyzed. The results achieved, from settling and consolidation tests by hydraulic consolidation test, attested to the effectiveness, in addition to being representative, based on the analyzes and comparisons instituted and the definition of the compressibility and consolidation characteristics of the phosphate tailings of the evaluation.

Sep 30, 2022

By Charles D. Walcott

Jan 1, 1901

By B M. Washington, R R. Lovel, G J. Sparrow, M J. Fisher-White

"Work in CSIRO with several Australian ores has shown that?by heating a high-phosphorus goethitic iron ore and then leaching with caustic or acid, the phosphorus levels in the ore can be lowered to a commercially acceptable value of around 0.08 weight per cent phosphorus (P). With increasing heating temperatures up to 1300¦C, the extent of phosphorus removal increased. This is considered to be associated with mineralogical changes in the iron oxide phases in the ore during the heating.Little phosphorus was removed from four high-phosphorus goethitic iron ores containing 0.12 - 0.16 weight per cent P in leaches with boiling water. However, leaches with sulfuric acid removed ten to 20 weight per cent of the phosphorus and leaching with sodium hydroxide removed even more phosphorus to produce leach products containing between 0.08 and 0.12 weight per cent P from three of the ores.After heating at 300¦C, leaches at a low pulp density of 0.5 weight per cent solids with 1 - 5 M NaOH and 0.1 - 1 M H2SO4 gave leach products with 0.06 - 0.09 weight per cent P. The lixiviant concentration required and extent of phosphorus removal depended on the ore. At a higher pulp density of 25 weight per cent solids, leach residues with between 0.07 - 0.14 weight per cent P were obtained.More phosphorus was removed from ores heated at 900¦C. Leaches at both the low and high pulp densities, with 1 - 5 M NaOH and 0.1 - 1 M H2SO4, gave leach products with 0.05 - 0.09 weight per cent P. However, the lowest phosphorus levels were obtained after heating the ores at 1200 or 1300¦C and leaching with 1 M NaOH or 0.1 M H2SO4. Leach residues with 0.02 - 0.06 weight per cent P were obtained, even from leaches at the higher pulp density of 25 weight per cent solids. Leaching tests on heated samples under heap leaching conditions at ambient temperatures have shown that phosphorus levels can be reduced to similar levels to that achieved in an agitation leach within ten days.CITATION:Fisher-White, M J, Lovel, R R, Sparrow, G J and Washington, B M, 2013. Effect of temperature on removal of phosphorus from Australian Goethitic iron ores, in Proceedings Iron Ore 2013, pp 373-380 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 12, 2013

By Sávio José de Oliveira

Neste trabalho foram caracterizados dois tipos de rejeitos arenosos, provenientes do processo de flotação do minério de ferro, com o intuito de aplicá-los na fundição de peças de alumínio. A caracterização foi conduzida de duas formas. Primeiro foram realizados os ensaios de caracterização científica, adotados pela indústria de fundição, de modo a avaliar as propriedades dos rejeitos. E, finalmente, os rejeitos foram misturados com aglomerantes para a fabricação de moldes de fundição por dois diferentes processos de moldagem: processo de moldagem de cura a frio e processo de moldagem em silicato de sódio/CO2. Os dois tipos de rejeito, que diferem na granulometria, se mostraram adequados para uso na indústria de fundição de alumínio, apresentaram propriedades adequadas e foi possível produzir peças sem defeitos.

Oct 30, 2017

By JESSICA W. A. AZURE, Samuel Frimpong, AZUPURI G. A. KABA, FORSYTH A. KADINGDI, PROSPER E. A. AYAWAH

The efficient and effective utilization of hydraulic excavators relies on, among other factors, a better understanding of the formation resistance during the excavation process. Studies on hydraulic shovel excavators have focused on optimizing the digging process by considering the reaction of the boom, stick and bucket, and analyzing the resulting moments at the shovel’s front-end joints. These studies failed to understand resistive forces from a statistical viewpoint. The purpose of this paper is to develop machine-learning models capable of predicting the formation of resistive forces during shovel excavation. The shovel’s excavation was simulated in the PFC 5.0 environment using a typical field-size hydraulic shovel bucket to generate the shovel contact forces required to overcome formation resistance

By D Connelly

Quartz deposits are common in nature but the presence of quartz suitable for yielding high purity quartz is exceedingly rare. This paper describes a test work study on producing high purity quartz (HPQ) product to meet the tight product specifications of greater than 99.97per cent, including four and even five nines, for uses including, lighting and fibre optics and modern-day high efficiency solar panels. Due to demand in renewable energy applications the market for high purity silica solar panels known for their increasing efficiency and durability is rapidly growing. Demand continues to rise for the use of high purity quartz in semiconductors, electronics, imaging and sensor markets. Microelectronic components are created by chemically fabricating wafers of semiconductors such as silicon to obtain the desired transport of electrical charge and control of the current. The production of silicon metal from high purity quartz has been designated a Strategic Mineral by the European Commission and by the US Department of Justice due to the growing significance of this metal in various industries. The subsequent processing of quartz is the key step to adding value and aiding technological advances. Overall, the high purity quartz market is a highly secretive, specialised market with increasing opportunities for stakeholders. The attempt to produce HPQ in this work was carried out using an Australian quartz ore following a typical HPQ process flow sheet. The unit processes included primary crushing, scrubbing, magnetic separation, flotation, acid leaching followed by hot chlorination. The results indicate that grinding of quartz requires specialist equipment due to the hardness and extreme abrasiveness of the ore leading to additional iron contamination in the ground ore. The critical impurities were aluminium, iron, sodium, potassium, lithium, titanium, zircon, calcium and magnesium. The chemical refining was found effective. The hot chlorination process needed to be done at 1200°C in a chlorine – hydrogen chloride gas atmosphere. The risk of any gas being released during this stage is very serious and only specialist companies should and can carry out this step. More recent studies reported many new options that appear to facilitate the production of HPQ with the requisite purities more easily, but costly equipment along with highly trained operators are required and hence unlikely to become available in standard metallurgical laboratories any time soon.

Sep 1, 2024

By L. Rodd, C. Walker, T. Koehler

"The energy content of slag represents approximately 80% of the total energy inputs to a laterite nickel electric smelting furnace. Conventional slag handling methods produce only low grade heat and the entire thermal content of the slag is wasted. A heat recovery system proven on BOF slag in the mid 1980's can be adapted to a laterite nickel rotary kiln electric furnace (RKEF) plant. Slag is granulated using a high velocity air jet inside a waste heat boiler to produce slag granules. Granules are cooled during flight via radiation to water-cooled boiler walls and by convection to the granulation air. This system has the potential to recover 80% of the total slag energy in the form of hot air and steam.Integration of the recovered slag energy into the RKEF smelter can be achieved by a number of methods, including the use of preheated air at the ore dryers, kiln or existing power plant. Energy from the slag boiler may be used to reheat boiler feed water from the power plant or to produce superheated steam and generate electricity. The heat recovery system can provide up to 25 - 30% of the total electrical requirement of each RKEF line and a reduction in CO2 emissions of 234,000 tonnes per year.The total cost of slag heat recovery, including CAPEX and OPEX, is $2.5/GJ, which is competitive with using coal when CO2 credits are $18 per tonne. With Clean Development Mechanism (CDM) carbon credits currently selling at €13 ($20 USD) per tonne CO2, there is considerable opportunity for slag producers in regions including South America, Korea, Indonesia and Africa. Increasing fuel costs and more wide-spread legislation for GHG emissions will likely create conditions in which slag heat recovery could generate a favourable return on investment."

Jan 1, 2010

By Maurício Covcevich Bagatini, Maycon Athayde

Water consumption reduction in pellet feed operation is of paramount importance. Compared with traditional ball mills, high-pressure grinding rolls (HPGR) play an important role in Blaine surface area (BSA) generation to improve agglomeration properties, although stability is still a challenge. Grindability improvement of existing operation has a direct impact on the performance of the filtering and pelletizing operation. The results of this study, as a pregrinding operation, can be applied not only in new operations but also in existing ones, helping the operator control process variation in a more effective way while ore hardness increases. 

By Angel Rafael Arce Chilque

Um estudo visando à caracterização metalográfica e metalúrgica foi realizado em um aço ARBL (alta resistência e baixa liga) tipo X80, soldado com o processo arame tubular (FCAW) robotizado, com três diferentes níveis de energia de soldagem. Para tal foram utilizadas técnicas de metalografia óptica e microdureza Vickers (Hv). Foram depositados cordões de solda em forma de camadas sobre chapas do aço X80, variando a energia de soldagem e sem pré-aquecimento, no estado como soldado. Os resultados mostram que a técnica de sobreposição utilizada, com baixa e média energia de soldagem, não foi suficientemente adequada para melhorar as propriedades metalúrgicas dos cordões depositados anteriormente, inclusive da ZTA do metal de base.Os cordões depositados com alta energia de soldagem promoveram crescimento do tamanho de grão da GGZTA do aço X80 com a consequente diminuição da resistência ao impacto.Este trabalho da subsídios para uma melhor compreensão das soldas multipasses.

Aug 16, 2017

By Egbert Burchardt

En las operaciones greenfield de roca dura, la tecnología de los rodillos de molienda de presión es la tecnología más empleada en la etapa de chancado terciario para preparar la alimentación del molino de bola. Sin embargo, los HPGR puede emplearse para actualizar y optimizar instalaciones de roca dura ya existentes. En ese sentido, el presente texto señala la implementación de HPGR en las plantas de molienda SAG (Cadia Hill, Australia), así como en las de molienda convencional de tres etapas (Freeport Grasberg, Indonesia) para aumentar la capacidad, recuperación, y reducir el costo de operaciones.

Oct 1, 2014

By Antti Porvali, Vivek Agarwal, Mari Lundström

Hydrometallurgical recovery of rare earth elements (REE) from NiMH battery waste can be performed using sulfuric acid leaching followed by selective precipitation as double salt (REENa(SO4)2·H2O) by adding Na2SO4 as a precipitating agent. The formed double salts can then be further converted with NaOH solution to form REE hydroxides. However, present literature has paid little attention to how to minimize the consumption of reagents in this recovery process. In the current study, a process model was built using HSC Sim software, and metamodeling of the simulated flowsheet was conducted with the design of experiments (DOE), after which the basic functionality of the flowsheet was verified by experimental work, starting from sulfuric acid leaching of spent batteries. As the process is based on chemical circulation internally in the process, the objective was to investigate the accumulation of the elements in solution, specifically Na+ , K+ , SO4 2− ions and impurities liberated in the NaOH conversion step. It was found out that metamodeling could be utilized in obtaining first estimate of the process behavior, prior to any experiments. Flowsheet functionality with circulated solution was confirmed, obtaining at best 96.9% La recovery.

By K. Morin

"Silver and gold leaching by cyanidation is a well-known process used around the world. This reaction is often accompanied by the leaching of other species throughtout the cyanidation circuit that causes the diversion of cyanide towards non valuable by-products (SCN-, Cu(CN)x, Fe(CN)x, etc.). One of the detrimental impacts of the formation of these by-products is the precipitation of silver-cyanide complexes that occurs when cyanide concentration is too low. Without any extra-addition of free cyanide, the precipitated silver is lost and cannot be recovered causing an important economic loss. To overcome silver precipitation, cyanidation circuits are often operated at higher cyanide concentrations. Recently, COREM’s research team has been working on a technology to measure and control silver precipitation during the cyanidation process. Moreover, a methodology has been elaborated in order to evaluate threshold cyanide level which corresponds to the cyanide concentration at which silver starts to precipitate. This technology has been tested on site on a real cyanidation circuit at Agnico Eagle’s LaRonde mine."

Jan 1, 2014

By W. R. Reed, Y. Zheng

A recent study conducted by the National Institute for Occupational Safety and Health (NIOSH) evaluated the roof bolter canopy air curtain (CAC) systemin a blowing face ventilation system, demonstrating its effectiveness and illustrating the CAC protection zones. This study evaluates the roof bolter machine CAC while operating in an exhausting face ventilation system. This study considers two similar locations to allow comparison with the previous blowing face ventilation (Zheng et al., Min Metal Explor 36(6):1115–1126, (2019)) study: (1) a roof bolter machine bolting the roof at 20 ft (6.1 m) from the face and (2) a roof bolting machine bolting at 4 ft (1.2 m) from the face. The environment introduces 6.0 mg/m3 of respirable dust to represent the roof boltingmachine operating downstreamof the continuous miner. However, the exhausting face ventilation uses an exhaust curtain with 9000 cfm (4.25 m3/s) of air. Two roof bolter machine working positions are simulated with the use of dual drill heads in the inward position for two inside bolts and in the outward position for two outside bolts. The influence of the CAC on airflows and dust dispersion is evaluated with the CAC operating at 250 cfm (0.12 m3/s) with dust reductions ranging from 39.5 to 82.8%. When the roof bolter machine operated close to the face, increasing CAC airflow was required for adequate protection since the dust reductions can be as low as 39.5%. Additional CAC airflows of 350 cfm(0.17 m3/s) and 450 cfm(0.21 m3/s) were evaluated and demonstrated that dust reductions increased to 59.7% (350 cfm) and 72.0% (450 cfm) for the worst location where the roof bolter operators located.

Aug 26, 2020

By Dwayne D. Tannant

The Adra tunnel near Naramata BC experienced a fire in 2010 that burned timber sets within the tunnel and caused severe spalling of rock from the roof and tunnel walls. The nature of the damage is documented and efforts completed to rehabilitate and open a portion of this tunnel to the public are described. The use of shortcrete and rock bolts is a technically and economically superior support system to timber sets as well as being far more fire resistant.

Jun 1, 2012

By Zay Jeffries

AN acute current shortage of copper, with the prospect that conditions may become worse, indicated by Office of Production Management information. Present estimates of copper requirement for defense indicate that nearly all the available metal will be required in the future for this purpose. Severe dislocations are, expected, but the objective is to distribute the copper available for civilian use in such a manner as to minimize these dislocations. The advisory committee on metals and minerals has been asked for a suggestions which may be helpful in meeting this situation.\

Jan 1, 1941

By David C. Kraft

Helical piles and ground anchors were used to meet critical design and constructability requirements for an urban forest Canopy Walk at the Atlanta Botanical Garden, Atlanta, GA. The 12-foot wide pedestrian walkway path was to be nestled among the treetops of a forest, extending to 600 ft. in length, and soaring 40 ft. high above the forest floor. Of particular concern during construction was that the foundation system for the temporary steel shoring system had to be non-invasive to the subsoil, could not damage the forest floor, trees, root systems, or foliage, and upon completion of the concrete walkway pour, could be removed, again without disturbing the subsoil. Accubrace, Inc. designed and installed all the helical foundation types, as well as provided steel braces, typically used in Tilt-Up building construction, for the walkway project. The braces, some extending to 43 ft. in length, were used to provide lateral support against wind loads for the walkway form. In addition, the braces acted as secondary support for lateral loads during the placement of wet concrete along the 600 ft. length of the walkway. Helical foundation products installed included vertical compression piles, ground anchors for tension rods, and ground anchors for the braces. The installation of the piles and anchors was particularly challenging since the forest floor elevation varied as much as 50 ft. due to the presence of a ravine. Information is provided on the subsoil conditions, required loads, design, installation, and acceptance criteria for each helical product type installed for the project. The results of vertical and lateral load tests on the helical piles in the pre-construction phase, conducted in conformance to project specifications are presented. Photographs to illustrate the nature and complexity of the project are included. The concrete pour for the walkway was successfully completed on December 12, 2009, and the walkway was opened for visitors in May, 2010.

Jan 1, 2011

By William H. Lesser

A recent survey of pumping plants in the anthracite region of Pennsyl¬vania showed that more than 90 percent of the pumps in use are the horizontal centrifugal types (1).2/ This report on the design and operation of centrifugal pumps should be helpful to engineers of the region who must select pumps that are best suited to particular pumping conditions in anthracite mines. Before a centrifugal mine pumping plant is designed, the special features of the pumps that may be used should be considered, especially when low repair costs and continuous operation during flood periods are prerequisites, and when acid mine water is to be pumped. Two important advantages of a centrifugal pump are that the flow is continuous and that it can be throttled without developing excessive pressure or overloading its driving unit.

Jan 1, 1950

By Colin Rawlings, Simon Pepper, Maria Karakitsiou, John Mathews, Peter Townsend, Russell Bowler, David Keeble, Christopher Darton, Scott Sadler

National Grid needs to maintain a connection between two existing electricity sub-stations (Beddington & Rowdown) in the Croydon (south London) area, and allow the replacement of two 275 kV cable circuits that are buried under roads. This is to be achieved using a single 400 kV cable circuit within a 10 km (6.25 mile) long, 3 m (9.8 ft) diameter high voltage cable tunnel which is being driven through water bearing Chalk, at depths ranging from 5 m (15 ft) to 80 m (262 ft), with four access shafts(12.5 m (41 ft) in diameter) ranging in depth from 10 m (31 ft) to 40 m (131 ft). The Chalk in this area acts as a source of public drinking water supply (PWS) and is protected by areas designated Groundwater Source Protection Zones. To minimise the groundwater risk the design and construction of the cable tunnel and shafts has paid particular attention to the construction materials used, including testing of these construction materials prior to use, developing construction methods (including the design of the Earth Pressure Balance TBM) and maintaining a groundwater monitoring & testing programme prior to and during construction to ensure the integrity of the Chalk aquifer is maintained as a drinking water source. This paper describes the tunnel &shaft design and construction in relation to these particular groundwater environmental issues which set new precedents for tunnel assessment, design and construction requirements in the United Kingdom.

Jan 1, 2007

By M Reid, H Arbon

Hillgrove Resources (HGO) commenced open pit mining in 2011 and from 2011 to 2016 the geology team experienced a consistent negative reconciliation between grade control estimated copper (Cu) grade and the mill received grade. For the first four years, despite trialling various grade control strategies, the monthly variance between geology and mill copper grades fluctuated between -5 per cent to -17 per cent Cu metal depending on the style of mineralisation.In 2015, HGO embarked on various measures which resulted in changes to grade control practices under the advice of consultants. These changes to grade control sampling, estimation and block out practices resulted in six to seven months of consistently poor Mine to Mill reconciliations from -25 per cent to -28 per cent Cu.In an effort to mitigate these poor reconciliations the geology team reintroduced the preconsultant block out and geology driven grade control methods. Blockout reconciliations from this point emulated those seen originally from -8 per cent to -12 per cent (Cu per cent). Early in 2016 the geology team introduced conditional simulation for grade control as opposed to ordinary kriging to better characterise the grade distribution, introduced separate estimation parameters appropriate for every zone of mineralisation, implemented a maximum profit function to optimise the selection of ore and waste, and retained the geology driven block out processes. Since March 2016 the mine has experienced consecutive months of positive Mine to Mill reconciliations, the first seen in six years. Year to date the expected copper metal is within 1 per cent of mill reconciled copper metal.This paper will compare the various sampling methods, estimation algorithms and block out procedures from the past six years to arrive at a robust open pit operating procedure applicable for mineralisation with high short scale variability.CITATION:Reid, M and Arbon, H, 2017. Setting new standards at Kanmantoo – effective grade control procedures, in Proceedings Tenth International Mining Geology Conference 2017, pp 401–408 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017