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By Baafi EY

Deposits of gold, silver and other precious metals often display a high variability of grade values, usually a very low average metal content and are frequently not easy to sample reliably. The characteristics, together with the volatility of precious metal prices, make evaluations of precious metal deposits extremely difficult to make. Geostatistical estimation techniques can be used to make grade estimates of precious metals and to assess the reliability of these estimates. Two case studies are presented.

Jan 1, 1987

By M Hino, D R. Swinbourne

The thermodynamic properties of arsenic in metal, speiss, matte, slag and gas phases are first summarised in this paper. Arsenic associates with sulphide minerals and generally has compounds of high volatility, but it has a weak affinity for sulphur and a strong affinity for metals, especially copper and iron. In the initial stage of the oxidation of sulphide concentrates arsenic is volatilised easily prior to the oxidation of FeS, although it tends to be fixed in the condensed phase as FeAsO4 if the concentrate is over-oxidised. Thermodynamic simulation of oxidative copper smelting reveals the distribution of arsenic between matte, slag and gas, and the possibility of condensation of arsenic from the resulting waste gas is discussed. In reductive smelting more arsenic remains in the metal or matte, and is sometimes concentrated as a separate speiss phase. The phase relations and thermodynamic properties of speiss are also summarised briefly. Arsenic refining from smelted copper metal is shown, from an examination of the basic principles of arsenic removal into slags, to be difficult. Owing to its weak affinity for lead however, arsenic refining from lead bullion is seen to be much easier.

Jan 1, 2000

By Muir D

A review of the various methods of degrad- ing cyanide either from gold processing liquors or electroplating baths is presented with some discussion on their relative merits or problems. Whilst alkaline chlorination is common practice in many U.S. and Canadian plants it poses particular problems for certain plants. Alter- native methods include electrolysis, hydrolysis and air oxidation with activated carbon as catalyst which are also integral steps in the carbon-in-pulp process. A basic study of the degradation of cyanide ion has been carried out therefore to determine the effect of temperature, oxygen and carbon. It is shown that carbon is an excellent catalyst for degradation by air and likely to lead to higher losses of cyanide in a C.I.L. circuit. Degradation by hydrolysis is important at high temperatures and high pH such as employed in the Pressure Zadra or Anglo elution processes. Carbon catalysed degradation of cyanide by oxygen in effluent streams may be an environmentally acceptable alternative to conventional chlorine degradation.

Jan 1, 1987

By D Jordan, R Wilmoth, J LeFever

Exposed, open pit mine highwalls contribute significantly to the production of acid mine drainage (AMD) thus causing environmental concerns upon closure of an operating mine. Four innovative technologies were evaluated under the US Environmental Protection AgencyÆs, Mine Waste Technology (MWTP), Prevention of AMD Generation from Open Pit Highwalls Demonstration Project. This project is funded by the US Environmental Protection Agency (EPA) and jointly administered by the EPA and the US Department of Energy (DOE) through an Interagency Agreement. The objective of the field demonstration was to evaluate the technologies ability to decrease or eliminate acid generation from treated areas of the highwall in comparison an untreated highwall area. The field demonstration was performed at the Golden Sunlight Mine (GSM) a subsidiary of Placer Dome US, located near Whitehall, Montana. GSM is an operating gold mine. The highwall at GSM was divided into five plots measuring 15.24 by 15.24 m and each technology was assigned a plot with the fifth plot being used for comparison as a background control plot. The four technologies were spray-applied. The applied in situ treatment technologies included: a modified, furfuryl alcohol resin sealant, utilising wood and agricultural by-products to coat the rock surface; EcobondTM ARD, a phosphate based process that forms a stable, insoluble compound, coating the rock surface; and two AMD passivation technologies, magnesium oxide and the Dupont technology developed to create an inert layer/coating on the pyrite, preventing oxidation. The technologies were evaluated using the following methods: ASTM D 5744-96, accelerated weathering of solid materials using a modified humidity cells; mine wall residual wall rinse sampling; microscopy; and core drilling followed by water injection testing. The following paper describes the technologies used for passivation of acid generation from the highwall, the field demonstration, and the testing results from the background and each technology plot.

Jan 1, 2003

In October 1993 it was decided to undertake the fourth phase of mining at Big Bell. This decision followed the exhaustion of open pit reserves in January 1993. Two stages of mining were proposed for the new underground mine. The initial stage would mine the remnant ore, consisting of the rib and crown pillars and lower grade ore on the hangingwall and footwall side of the old open stopes, which were mined from the 1930s to 1950s. Most of the old open stopes were backfilled with either deslimed mill tailings or development mullock, both of which were economic to recover. However, the mineable ore from this resource was difficult to evaluate. The second stage focused on mining ore outside the remnant areas and was initially proposed as a Core and Shell method under a caving hangingwall. This method has since been superseded with sublevel caving, in part due to the very high and deviatoric stress conditions encountered at Big Bell and the relatively long mining cycle required for open stoping. The problems and challenges discussed in this paper will cover the identification of remnant ore reserves, dewatering the old workings, and remnant mining.

Jan 1, 1998

XstrataÆs Mount Isa Copper Operations (MICO) is a world-class mining operation producing in excess of six million tonnes of copper ore per annum from its underground mining operations. The Mount Isa Copper Mines have been producing from the underground operations since 1952. Current copper reserves are 87 million tonnes at 2.8 per cent Cu, extending the mineÆs life beyond 2018. The underground orebodies in the copper mines are divided into nine distinct areas and are mined by sublevel open stoping techniques. One of the nine areas is the hanging wall lens, which consists of two sections; a northern lens (NHWL) and a southern lens (SHWL). The SHWL has a proven reserve of 2.2 million tonnes with an average grade of 2.9 per cent copper. Stopes in the SHWL have an average size of approximately 245 000 tonnes and will be extracted in a primary-secondary mining sequence, producing ore until 2009. This paper discusses various aspects of stope design applied in the southern hanging wall lens, including sequencing options and the rationale for the selected sequence. Design features are also discussed and how they have evolved as more is learnt about the SHWL orebody. These include mass firing techniques, focusing on minimising ground vibrations, using seed wave form analysis and prediction. Rock mechanics issues will also be discussed, in particular the reinforcement of stope hanging walls and the use of instrumentation to monitor behaviour within the hanging wall.

Jan 1, 2006

By D J. Fray

In this work, a fused salt electrochemical process was investigated experimentally for production of metals and alloys directly from respective solid oxides by electro-deoxidation. Direct electrochemical reduction of the oxides was carried out in molten CaCl2-based chlorides in an electrolytic cell, incorporating an oxygen-evolving inert anode, over the temperature range of 850 - 950¦C. The technical viability of the process was demonstrated by the electro-deoxidation of pure oxides and oxide mixtures including NiO, Nb2O5, Nb2O5/TiO2 and Nb2O5/SnO2 to produce nickel metal, niobium metal, NbTi alloys and the intermetallic compound, Nb3Sn. Compared to the conventional metallurgical processes for producing these metals and alloys, this new electrochemical process appears to be much less energy intensive, with lower costs and no direct greenhouse gas emissions from the electrolytic reduction process. The present electrolytic reduction process has the potential to be scaled up for the green extraction of a number of non-ferrous base metals and processing of many advanced alloys.

Jan 1, 2006

By Curless JM, Power SG

Polymetallic hydrothermal veins of the Western Cascades are hosted in propylitically altered Tertiary volcanics of calc-alkaline affinity and (or) in nearby, altered, and compositionally similar plutons. Ores from shallow and now abandoned mines produced mostly gold and were considered to be of epithermal origin. However, recent discovery of breccia and porphyry types of Cu-Mo mineralisation and other data suggest that the deposits of this terrane vary systematically both regionally, south to north, and locally, high to low altitudes. The evidence includes changes in (1) size, composition, and complexity of plutons, (2) types of mineral deposits; (3) assemblages of alteration and ore minerals; (4) trace metal geochemistry of host rocks; and (5) fluid inclusion and sulphur isotope data. They collectively imply a consanguineous origin of vein, breccia, and disseminated-veinlet types of mineralisation by magmatic hydrothermal processes.

Jan 1, 1987

By D von Horn

Mineral sand orebodies are typically mined for their TiO2 content. Increasingly over the past 30 years, the major mineral focus has shifted from natural rutile to ilmenite and an acceptance that the latter generally needs some form of upgrading for economic conversion into TiO2 pigment. This upgrading obviously has a cost, and in conjunction with diminishing mineable feed grades, results in higher cost TiO2 units for chloride route Pigment Plant feedstocks. The net cost of feedstock can be significantly influenced by the recovery and sale of accessory minerals and by-products from the processing chain to the extent that some producers have the potential to achieve a zero net cost. Whilst slagging plants typically reduce net cost from rutile, zircon and pig iron revenues, operations supporting Becher type synthetic rutile operations have been limited to revenues from rutile and zircon only. A range of alumino silicate minerals show industrial potential, as does activated carbon, iron oxide and gypsum, by-products of the synthetic rutile process. Tiwest is a good example of a company maximising revenue from the accessory minerals as well as from by-products of the synthetic rutile process.

Jan 1, 2001

An international raw material partnership, a $164 million 900,000 long ton per year aluxAna plant; an ideal location at Gladstone, Queensland, Australia - this is Queensland Alumina Limited, on stream in 1967 expanded 50 per cent by the end of 1968. Queensland Alumina Limited is the world¦s most modern alumina refining operation which is owned by an international consortium of four companies; Kaiser Aluminum & Chemical Corporation of the United States with 52 per cent; Alcan Aluminium of Canada with 20 per cent; Pechiney of France with 20 per cent; Conzinc Rio Tinto of Australia, 8 per cent. Q.A.L. operates as a co-operative -- the partners do not draw profits from the venture. Instead, each member of the consortium draws alumina in proportion to his share of the ownership. The method of disposal of this alumina is for the partner to decide.

Jan 1, 1969

Copper was first produced in Australia in 1844, at the Kapunda Mine in South Australia, and, by 18i>0, production exceeded 2,000 tons of copper a year. Output increased ,steadily, reaching a peak of 14,00Qo tons a year in 1867 and 1868, when the Burra Burra and Kapunda Mines in South Australia and the Peak Downs Moine at Clermont, Queensland, were at the height of their production. At this period, Australian copper formed a considerable percentage of the world's supply, its output equalling, for a short time, that of the United States. Production declined to between 3,000 and 4,000 tons a year after the closing of' these three mines between 18717 and 1879, and, at this stage, the Australian output came chiefly from the Wallatoo and Moonta mines in South Australia. About 19000, it began to rise again, with the extension of the railway to the copper fields of Chillagoe and Cloncurry, and, between 1905 and 1912, was at its greatest, with a maximum of 47,774 tons of copper in 1912. During this period, Australia contributed 4,7 per cent. of the world's annual production, and ranked among the six major copper-producing countries of the world (Table 1).

Jan 1, 1943

By Boyes B. A, Haydon D. J

The Paddington project is a gold mining and processing operation located 35 km north of Kalgoorlie in the Eastern Goldfields region of Western Australia (Figure 1). The project, which is operated by Pancontinental Goldmining Areas Pty Ltd, treats 1.25 Mtpa of oxidised gold ore, derived mainly from open cuts adjacent to the plant, with minor tonnages from other pits in the region treated on a custom-milling basis. Gold is recovered using a conventional CIL process. The process raw water supply of 3 500 kUd is derived from the local groundwater system. Average salinity of the raw water is around 90 000 - 100 000 mg/L total dissolved solids. A small portion of the raw water is passed through a vacuum distillation desalination plant to produce the project's 200 kUd requirement for high quality water for potable use and gold recovery.

Jan 1, 1988

The curbing of expansion in tertiary level education in Australia and the question- ing of its objectives which are now occurring are likely to have important effects on mining and metallurgical education. Student enrol- ments are low but the serious shortage of specialised minerals industry graduates pre- dicted during the boom of the late 60's has not eventuated. Other manning problems of a less quantitative but possibly equally import- ant kind have been identified. They point to a need for a full and deep review of the education and training programmes available to Australian graduates planning to enter product- ion areas of the minerals industry. An alter- native educational structure providing greater flexibility is suggested.

Jan 1, 1977

By Denholm WT

The main objective of the experimental study was to investigate the dissolution kinetics of various forms of carbon under iron bath converting or smelting-reduction conditions, i.e., particulate, free moving carbon in contact with a turbulent iron melt. Iron/carbon melts were contained in cast magnesia-lined silicon carbide crucibles heated by a medium frequency induction furnace. The melts were stirred by injecting nitrogen through 2 mm I.D. alumina lances submerged to a depth of 50 mm in the 100 mm deep baths. Particulate carbon in the form of graphite, brown coal char and petroleum coke, were dropped directly onto the turbulent bath. The dissolution rates of the various carbon types were monitored by taking periodic bath samples for subsequent carbon analyses. The effect of carbon particle size (1-6.25 mm), the degree of bath turbulence (nitrogen stirring rates of 0-20 litres/min), and bath temperature (1300-1500¦C) were assessed. The analysis of the results was complicated by particle buoyancy effects, but it was established that the dissolution rates of the three carbon types investigated were similar, and increased linearly with increases in the gas stirring power inputs. Particle size had relatively little effect on the dissolution rates.

Jan 1, 1984

By Dixon D. R, Sparrow G. J

Pressure leach liquors from the pressure oxidation of a bulk flotation concentrate prepared from a complex Cu-Pb-Zn sulphide ore were treated to remove iron, either by pressure oxidation (the Hematite process) or with particles of magnetite (the Magnetite process), followed by cementation of various metals with zinc dust to obtain a purified solution from which zinc was electrowon. Satisfactory iron removal was achieved by both processes after neutralisation to pH 4.5 or 5.5. Pressure oxidation of the liquor at 200¦C and 690 kPa oxygen overpressure, conditions similar to those of the Hematite process used in the zinc industry, resulted in the precipitation of the iron as hematite. With the Magnetite process, an iron hydroxide was precipitated onto magnetite at atmospheric pressure and ambient temperature and removed by a magnetic separation step. The performances of both these processes for the removal of iron are compared. It is concluded that the Magnetite process offers considerable cost savings. Other impurities, in particular arsenic, were also removed with the iron in both processes. Cementation at pH 5.2 and 85-90 ¦C with 3.5 g/L zinc dust reduced the levels of copper, cadmium, and nickel to a satisfactory level and subsequent electrolysis in a laboratory cell gave an acceptable deposit of zinc.

Jan 1, 1989

By Tapponnier P

In North Vietnam, large ductile shear zones are observed along the Red river fault and the Dienbien fault. Left-lateral sense of the Red river shear zone is related to the direction of shortening E-W. NE dipping foliation planes is subvertical. Stretching lineation is subhorizontal ( 25¦). Left-lateral slip observed in the Oligocene Yansun granites demonstrates the major tectonic phase in Neogene, The stress field established from microfaults observed in triassic limestones, Oligocene granites and Neogene Conglomerates. Measurements of striations on fault mirors are used for calculating the stress tensor and for separating tectonic phases. Two tectonic phases in tertiary are separated : first tectonic phase related to the compressive direction E-W corresponds to the major tectonic phase represented by NW left-lateral shear zone. Second phase having the compressive direction N-S associated with the right-lateral movement of the Red-river fault zone opening of the Eastern sea and the Red-river and the Red-river delta is associated with the left-lateral movement along the Red-river.

Jan 1, 1990

The Olympic Dam deposit is located some 600 km north of Adelaide in South Australia. It was discovered in 1975 by Western Mining Corporation and in 1979 a joint venture was formed with British Petroleum for the evaluation and development of the project. Studies were completed and construction started in 1986 with the plant being commissioned progressively between April and August of 1988. In 1993 Western Mining acquired BP's interest and are now owners of the whole deposit. The scale of the initial development was 1.5 Mtpa of ore for the production of 45 000 tpa of copper cathode, 900 tpa of uranium oxide and some gold and silver. Two expansion programs have occurred in 1992 and 1995 and current performance is at the rate of 3 Mtpa of ore for the production of 84 000 tpa of copper cathode, 1500 tpa of uranium oxide, 24 000 oz per year of confined gold and 380 000 oz per year of confined silver (Table 1). An aerial view of the plant is shown in Figure 1. The benefit of diversifying into the production of more than one product is undoubted and the flexibility of being able to produce variable quantities of copper and uranium also allows advantage to be taken of a change in market conditions.

Jan 1, 1996

By R C. Schodde

The future of any mining company depends on maintaining and growing its access to high-quality mineral resources. Often the true size of a given resource is not fully recognised until after mining has commenced. Also, the strong desire to increase production puts pressure to expand the resource base of the mine to get maximum value out of the capital employed. This, plus diminishing M&A opportunities and declining world-class greenfield discovery rates, makes brownfields exploration a high priority activity in any operating company. For the success and long-term survival of the company it is critical that this is done well. The primary aim of brownfields exploration is to find or acquire new deposits within economic transport distance of an existing mine that will add materially to shareholder value through: mine or capacity expansion, displacement of lower-margin ore from the mine plan, preserving and extending the mine life, and ensuring potential value is understood in order to maximise potential future mine development or exit. A number of strategic principles are important in any program designed to achieve these aims: understanding the life of mine (LOM) production profile and the related key drivers for exploration, understanding the dynamic nature of the brownfields search space, understanding and measuring depletion of the brownfields search space, understanding the potential of the near-mine region, investing in exploration technology to expand the search space, and investing in a basic geological understanding of the ore-environment. Examination of the LOM profile will highlight critical issues facing development plans for the mine including future grade and throughput issues, key technology requirements or innovations and scenarios for increased production. Exploration targets in the brownfields program should address these key issues. Often it is as æsimpleÆ as keeping mine development sufficiently far ahead of extraction to allow time for the various phases of exploration and resource assessment drilling. Because of the low additional capital costs required, expansion of the brownfields search space is strongly leveraged to: metal prices, development of new markets, incremental operating cost reductions, strategic changes in downstream requirements in integrated businesses, depletion of higher unit-value ores, and new technologies (both extraction and exploration). Therefore the brownfields search space is likely to incrementally expand through time and must be regularly reviewed. This is also important as any given search space will be progressively exhausted, resulting in smaller and higher cost discoveries. It is therefore important to monitor and critically review sustained trends of increasing brownfields discovery cost. The first wave of discoveries in any camp are usually empirically driven and do not need a strong geological understanding. However, an improved geological understanding is critical to making the next generation of hidden discoveries. To illustrate these points, a case study was carried out on the exploration and development history of the Kambalda nickel camp. Over a period of 40 years, more than 40 deposits were found containing over 1.7 million tonnes of nickel metal. Efficient mines need to maintain reserves for operating flexibility. Consequently, the company needs to clearly understand the global resource in order to maximise its full potential. In addition, understanding the full brownfields potential earlier in the development of a deposit rather than later, creates optionality through the flexibility that this understanding brings to future development choices. To ensure best practice in attaining this aim, the roles and responsibilities of the exploration team and the mine operation should be clearly understood. It is important for the explorers and the operators to have shared views about what needs to be done. Typically, mine operators would be accountable for identifying future resource requirements to support the life-of-mine production schedule whilst explorers would be accountable to ensure best-practice assessment of brownfields exploration opportunities. This would include an assessment of the global undiscovered endowment in the regional near-mine area. The balance between brownfield exploration drilling and resources to reserve conversion will need to be decided to ensure efficient operations are maintained. Both need to agree the optimum level of brownfields funding taking into account: urgency to replace or grow reserves, and quality of opportunities (relative to those elsewhere). The ultimate cost of ignoring the full brownfields potential of an operating asset can be significant, ranging from inefficient and poorly planned operations, lost opportunity cost and resultant value through under-utilised resources and, in the worst case, early exit from the asset at the bottom of the commodity cycle û leaving behind huge amounts of shareholder value.

Jan 1, 2006

By H Ramandi, H Masoumi, I Canbulat, B Hebblewhite, J Oh, S Saydam, W Timms, S Mo

This paper reviews the floor heave mechanisms in underground coal mine roadways. Previous studies have reported three main failure mechanisms: bearing capacity failure, buckling and swelling. The buckling failure has been observed where immediate floor strata are relatively strong and thinly bedded. On the contrary, the weak floor strata have been associated with both the bearing capacity failure and swelling mechanisms. The bearing capacity floor failures are likely to induce other types of instability such as pillar punching, tensile failure of pillar, roof fall and subsidence as well as floor heave. Despite a considerable amount of research, predicting the magnitude, location and timing of floor deformation is challenging with current state of knowledge. CITATION:Mo, S, Ramandi, H, Oh, J, Masoumi, H, Timms, W, Canbulat, I, Hebblewhite, B and Saydam, S, 2018. A review of floor heave mechanisms in underground coal mine roadways, in Proceedings The Fourth Australasian Ground Control in Mining Conference (AusRock), pp 196–206 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 30, 2018

By Smart RST C, Johnson NW, Ralston J, Griffin LF

At the Copper Concentrator of Mount Isa Mines, the largest diluent of the copper concentrate is liberated fine pyrite. Laboratory flotation tests carried out as a function of grind and flotation Eh in combination with surface analysis by X-ray photoelectron spectroscopy (XPS) have identified the major mechanisms of iron sulphide flotation. It was found that a significant proportion of the iron sulphide minerals had surface coverages of graphitic carbon, sufficient to impart moderate hydrophobicity in the absence of collector. A smaller, but economically significant proportion of chalcopyrite was also affected by the graphitic carbon coating. Two methods were tested to reduce the impact of the natural floatability of the iron sulphides on concentrate grades. 1. Depression through the use of organic depressants. 2. Preflotation to remove the "naturally hydrophobic" iron sulphides (flotation independant of Eh ) prior to chalcopyrite flotation. Preflotation was tested at the pilot plant scale. It was found that the amount of chalcopyrite reporting to the preflotation rougher concentrate could be minimised through flotation at a mildly reducing Eh by the use of nitrogen as the flotation gas to maintain the low Eh conditions resulting from grinding. The preflotation rougher concentrate was upgraded to an iron sulphide concentrate or a low grade copper concentrate.

Jan 1, 1991